The Roccamonfina volcano is characterised by two stages of volcanic activity that are separated by volcano-tectonic caldera
collapses. Ultrapotassic leucite-bearing rocks are confined to the pre-caldera stage and display geochemical characteristics
similar to those of other volcanoes in the Roman Province. After the major sector collapse of the volcano, occurred at ca.
400 ka, shoshonitic rocks erupted from cinder cones and domes both within the caldera and on the external flanks of the pre-caldera
Roccamonfina volcano. On the basis of new trace element and Sr–Nd–Pb isotope data, we show that the Roccamonfina shoshonitic
rocks are distinct from shoshonites of the Northern Roman Province, but are very similar to those of the Neapolitan volcanoes.
The last phases of volcanic activity erupted sub-alkaline magmas as enclaves in trachytic domes, and as lavas within the Monte
Santa Croce dome. Ultrapotassic rocks of the pre-caldera composite volcano are plagioclase-bearing leucitites characterised
by high levels of incompatible trace elements with an orogenic signature having troughs at Ba, Ta, Nb, and Ti, and peaks at
Cs, K, Th, U, and Pb. Initial values of 87Sr/86Sr range from 0.70926 to 0.70999, 143Nd/144Nd ranges from 0.51213 to 0.51217, while the lead isotope rations vary between 18.788–18.851 for 206Pb/204Pb, 15.685–15.701 for 207Pb/204Pb, and 39.048–39.076 for 208Pb/204Pb. Shoshonites show a similar pattern of trace element depletions and enrichments to the earlier ultrapotassic leucite-bearing
rocks but have a larger degree of differentiation and lower concentrations of incompatible trace elements. On the other hand,
shoshonitic rocks have Sr, Nd, and Pb isotopes consistently different than pre-caldera ultrapotassic leucite-bearing rocks.
87Sr/86Sr ranges from 0.70665 to 0.70745, 143Nd/144Nd ranges from 0.51234 to 0.51238, 206Pb/204Pb ranges from 18.924 to 19.153, 207Pb/204Pb ranges from 15.661 to 15.694, and 208Pb/204Pb ranges from 39.084 to 39.212. High-K calc-alkaline samples have intermediate isotopic values between ultrapotassic plagioclase
leucitites and shoshonites, but the lowest levels of incompatible trace element contents. It is argued that ultrapotassic
magmas were generated in a modified lithospheric mantle after crustal-derived metasomatism. Interaction between the metasomatic
agent and lithospheric upper mantle produced a low-melting point metasomatised veined network. The partial melting of the
veins alone produced pre-caldera leucite-bearing ultrapotassic magmas. It was possibly triggered by either post-collisional
isotherms relaxation or increasing T°C due increasing heat flow through slab tears. Shoshonitic magmas were generated by further melting, at higher temperature,
of the same metasomatic assemblage with addition 10–20% of OIB-like astenospheric mantle material. We suggest that addition
of astenospheric upper mantle material from foreland mantle, flowing through slab tearing after collision was achieved.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
The Jiutai area is tectonically situated at the eastern segment of the Central Asian Orogenic Belt(CAOB) and is close to the North China Craton(NCC) to the south, serving as an ideal place to investigations of the closure of the PaleoAsian Ocean(PAO). Sandstone samples collected from the Yangjiagou Formation and the Lujiatun Formation in this area have been studied in detail in terms of petrology, geochronology and geochemistry. The maximum depositional time of the Yangjiagou and Lujiatun formations has been constrained to early Middle Triassic(ca. 245 Ma) and middle Late Triassic(ca. 219 Ma), respectively. The Yangjiagou Formation, with a major provenance of dissected island arcs, is dominantly composed of Phanerozoic sediments from Northeastern China(NE China) massifs. The Lujiatun Formation, with major sediments from active continental margins, has a relatively larger proportion of Precambrian sediments, in which the ~1.85 Ga and ~2.5 Ga sediments are typical of the crystalline basements of the NCC and NE China massifs, which were uplifted and eroded during the closure of the PAO. Besides, both formations show the enrichment in LREEs and the depletion in HREEs, the common Eu negative anomalies, and trace element contents similar to that of the upper continental crust. Based on the provenance analysis of these two formations, the final closure time of the PAO in this area is constrained as from the early Middle Triassic(ca. 245 Ma) to the middle Late Triassic(ca. 219 Ma). 相似文献
The Moulin de Chéni orogenic gold deposit is the only granite-hosted deposit of the Saint-Yrieix district, French Massif Central. It occurs in 338±1.5 Ma-old peraluminous leucogranites and is characterized by intense microfracturing and bleaching of the granite in relation to pervasive sulfide crystallization. Formation of quartz veins and gold deposition occurred in two successive stages: an early mesozonal stage of quartz-sulfide (Fe-As-S) deposition, usually devoid of gold and a late epizonal stage of base metal and gold deposition. Both stages postdate peak metamorphism and granite intrusion. The genesis of the deposit is the result of four successive fluid events: (1) Percolation of aqueous-carbonic metamorphic fluids under an assumed lithostatic regime of 400–450 °C, at a maximum depth of 13 km; (2) Formation of the main quartz lodes with coeval K-alteration and introduction of As and S from aqueous-carbonic fluids percolating along regional faults. Arsenopyrite and pyrite deposition was linked to the alteration of Fe-silicates into K-feldspar and phengite at near-constant iron content in the bulk granite. Temperature was similar to that of the preceding stage, but pressure decreased to 100–50 MPa, suggesting rapid uplift of the basement up to 7.5 km depth; (3) The resulting extensional tectonic leads to the deposition of gold, boulangerite, galena and sphalerite in brecciated arsenopyrite and pyrite from aqueous fluids during a mixing process. Temperature and salinity decrease from 280 to 140 °C and 8.1 wt% eq. NaCl to 1.6 wt% eq. NaCl, respectively; (4) Sealing of the late fault system by barren comb quartz which precipitated from dilute meteoric aqueous fluids (1.6 wt% eq. NaCl to 0.9 wt% eq. NaCl) under hydrostatic conditions at 200–150 °C.Editorial handling: B. Lehmann 相似文献