Stability of fluorite and titanite in a calc-silicate rock from the Vizianagaram area, Eastern Ghats Belt, India

In the Vizianagaram area (E 83°29.442′; N 18°5.418′) of the Eastern Ghats Belt, India, a suite of graphite‐bearing calc‐silicate granulites, veined by syenitic rocks, developed wollastonite‐rich veins at 6–7 kbar and > 850 °C. During subsequent near‐isobaric cooling wollastonite was replaced by calcite + quartz and a graphic intergrowth of fluorite + quartz ± clinopyroxene. Titanite with variable Al and F contents is present throughout the rock. Combining the compositional variation of titanite and recent experimental data, it is demonstrated that the mineral assemblage, the composition of coexisting fluids and the mobility of Al exert a far greater control on the composition of titanite than pressure, temperature or the whole rock composition. Thermodynamically computed isothermal–isobaric logf_O2– logf_CO2 and logf_F2– logf_O2 grids in the systems Ca–Fe–Si–O–F (CISOF; calcite‐free) and Ca–Fe–Si–O–F–C–H (CISOFV; calcite‐present) demonstrate the influence of bulk rock and fluid compositions on the stability of the fluorite‐bearing assemblages in diverse geological environments and resolve the problem of the stability of titanite in fayalite + fluorite‐bearing rocks in the Adirondacks. The mineralogy of the studied rocks and the topological constraints tightly fix the logf_O2, logf_F2 and logf_CO2 at ?15.8, ?30.6 and 4.1, respectively, at 6.5 kbar and c. 730 °C. Because of the similarity in the P–T conditions, the compositions of pore fluids in the fluorite‐bearing assemblages of the Adirondacks and the Eastern Ghats Belt have been compared.     

Continental crustal growth and the supercontinental cycle: evidence from the Central Asian Orogenic Belt

Studies of supercontinental cycle are mainly concentrated on the assembly, breakup and dispersal of supercontinents, and studies of continental crustal growth largely on the growth and loss (recycling) of the crust. These two problems have long been studied separately from each other. The Paleozoic–Mesozoic granites in the Central Asian Orogenic Belt have commonly positive Nd values, implying large-scale continental crustal growth in the Phanerozoic. They coincided temporally and spatially with the Phanerozoic Pangea supercontinental cycle, and overlapped in space with the P-wave high-V anomalies and calculated positions of subducted slabs for the last 180 Ma, all this suggests that the Phanerozoic Laurasia supercontinental assembly was accompanied by large-scale continental crustal growth in central Asia. Based on these observations, this paper proposes that there may be close and original correlations between a supercontinental cycle, continental crustal growth and catastrophic slab avalanches in the mantle. In this model we suggest that rapid continental crustal growth occurred during supercontinent assembly, whereas during supercontinental breakup and dispersal new additions of the crust were balanced by losses, resulting in a steady state system. Supercontinental cycle and continental crustal growth are both governed by changing patterns of mantle convection.     

Fold-Thrust-Belt Structure of the Proterozoic Eastern Ghats Mobile Belt: A Proposed Correlation Between India and Antarctica in Gondwana

The Proterozoic Eastern Ghats Mobile Belt along the east coast of India shares a thrusted lower contact with the surrounding cratons. The thrust, known as the Terrane Boundary shear zone, is associated with two large lateral ramps resulting in a curved outline on the northwestern corner of the mobile belt. The Eastern Ghats Mobile Belt is divided into two lithotectonic units, the Lathore Group and the Turekela Group, based on their lithological assemblages and deformational history. On the basis of published data from a Deep Seismic Sounding (DSS) profile of the Eastern Ghats crust, the Terrane Boundary Shear Zone is considered to be listric in nature and acts as the sole thrust between craton and mobile belt. The Lathore and Turekela Groups are nappes. With this structural configuration the NW part is described as a fold thrust belt. However, the thrusting postdates folding and granulite metamorphism that occurred in the Eastern Ghats, as in the Caledonide type of fold thrust belt of NW Scotland. The Terrane Boundary Shear Zone is interpreted to be contiguous with the Rayner-Napier boundary of the Enderby Land in a Gondwana assembly.     

西秦岭铧厂沟金矿床流体包裹体特征研究及矿床成因

铧厂沟金矿位于西秦岭勉略缝合带南侧,其产出受韧脆性剪切带控制,赋矿围岩为泥盆系细碧岩、凝灰质绢云千枚岩和灰岩。根据脉体穿切关系和矿物交代关系,可以将铧厂沟金矿分为早、中、晚3个成矿阶段。在铧厂沟金矿的石英中发育了CO₂-H₂O型、纯CO₂型、H₂O溶液型和含子矿物型四种类型流体包裹体。早期石英中原生包裹体主要是CO₂-H₂O型和纯CO₂型,其成分为CO₂+H₂O±N₂±CH₄±H₂S,均一温度集中在320~360℃,盐度为0.43%~5.14% NaCleqv;中阶段为主成矿阶段,该阶段石英中包含了所有四种类型的包裹体,其中H₂O溶液型包裹体占了大多数,CO₂-H₂O和水溶液包裹体均一温度集中在240~320℃,盐度为0.43%~11.19% NaCleqv;晚阶段石英仅发育水溶液型包裹体,具有较低的均一温度(118~228℃)和盐度(0.18%~6.59% NaCleqv)。根据CO₂-H₂O型包裹体计算主成矿阶段压力为70~195MPa,成矿深度为5~7km。总体而言,铧厂沟金矿的初始流体具有中高温、富CO₂、低盐度的变质流体特征,晚成矿阶段流体演化为低温、低盐度水溶液流体,流体的不混溶导致了主成矿期的矿质的大量沉淀,铧厂金矿为中浅成的造山型矿床。     

Insights into the complexity of crustal differentiation: K2O‐poor leucosomes within metasedimentary migmatites from the Southern Marginal Zone of the Limpopo Belt,South Africa

Differentiation of the continental crust is the result of complex interactions between a large number of processes, which govern partial melting of the deep crust, magma formation and segregation, and magma ascent to significantly higher crustal levels. The anatectic metasedimentary rocks exposed in the Southern Marginal Zone of the Limpopo Belt represent an unusually well‐exposed natural laboratory where the portion of these processes that operate in the deep crust can be directly investigated in the field. The formation of these migmatites occurred via absent incongruent melting reactions involving biotite, which produced cm‐ to m‐scale, K₂O‐poor garnet‐bearing stromatic leucosomes, with high Ca/Na ratios relative to their source rocks. Field investigation combined with geochemical analyses, and phase equilibrium modelling designed to investigate some aspects of disequilibrium partial melting show that the outcrop features and compositions of the leucosomes suggest several steps in their evolution: (1) Melting of a portion of the source, with restricted plagioclase availability due to kinetic controls, to produce a magma (melt + entrained peritectic minerals in variable proportions relative to melt); (2) Segregation of the magma at near peak metamorphic conditions into melt accumulation sites (MAS), also known as future leucosome; (3a) Re‐equilibration of the magma with a portion of the bounding mafic residuum via chemical diffusion (H₂O, K₂O), which triggers the co‐precipitation of quartz and plagioclase in the MAS; (3b) Extraction of melt‐dominated magma to higher crustal levels, leaving peritectic minerals entrained from the site of the melting reaction, and the minerals precipitated in the MASs to form the leucosome in the source. The key mechanism controlling this behaviour is the kinetically induced restriction of the amount of plagioclase available to the melting reaction. This results in elevated melt H₂O and K₂O and chemical potential gradient for these components across the leucosome/mafic residuum contact. The combination of all of these processes accurately explains the composition of the K₂O‐poor leucosomes. These findings have important implications for our understanding of melt segregation in the lower crust and minimum melt residency time which, according to the chemical modelling, is <5 years. We demonstrate that in some migmatitic granulites, the leucosomes constitute a type of felsic refractory residuum, rather than evidence of failed magma extraction. This provides a new insight into the ways that source heterogeneity may control anatexis.     

Geochemistry of late Palaeozoic granitoids of the Balkhash metallogenic belt,Kazakhstan: implications for crustal growth and tectonic evolution of the Central Asian Orogenic Belt

ABSTRACT

The Balkhash metallogenic belt (BMB) in Kazakhstan is a famous porphyry Cu–Mo metallogenic belt in the Central Asian Orogenic Belt (CAOB). The late Palaeozoic granitoids in the BMB are mainly high-K calc-alkaline and I-type granites, with shoshonite that formed during a late stage. Geochemical analyses and tectonic discrimination reveal a change in the tectonic environment from syn-collision and volcanic arcs during the Carboniferous to post-collision during the Permian. The late Palaeozoic granitoids from the Borly porphyry Cu deposit formed in a classical island-arc environment, and those from the Kounrad and Aktogai porphyry Cu deposits and the Sayak skarn Cu deposit are adakitic. The ε_Nd(t) values for the late Palaeozoic granitoids are between ?5.87 and +5.94, and the ε_Sr(t) values range from ?17.16 to +51.10. The continental crustal growth histories are different on either side of the Central Balkhash fault. On the eastern side, the ε_Nd(t) values of the granitoids from the Aktogai and Sayak deposits are very high, which are characteristic of depleted mantle and suggest that crustal growth occurred during the late Palaeozoic. On the western side, the ε_Nd(t) values of the granitoids from the Borly and Kounrad deposits are slightly low, which suggests the presence of a Neoproterozoic basement and the mixing of crust and mantle during magmatism. The granitoids have initial ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb values of 18.335–20.993, 15.521–15.732, and 38.287–40.021, respectively, which demonstrate an affinity between the late Palaeozoic magmatism in the BMB and that in the Tianshan, Altai, and Junggar orogens.     

Reconstructing the Cryogenian–Ediacaran evolution of the Porongos fold and thrust belt,Southern Brasiliano Orogen,based on Zircon U–Pb–Hf–O isotopes

The Neoproterozoic geotectonic triad of the Brasiliano Orogen is reconstructed in southern Brazil from studies focused on the Porongos fold and thrust belt. We integrate field geology with isotopic studies of zircon U–Pb SHRIMP and Lu–Hf–O laser determinations in seven metasedimentary and three metavolcanic rock samples. The results indicate that the Porongos palaeo-basin was derived from mixed sources (3200–550 Ma), with major contributions from Rhyacian (2170 Ma) and Ediacaran (608 Ma) sources. Minor contributions from Archaean to Tonian sources are also registered. The maximum depositional age of the Porongos palaeo-basin is established by the age range of 650–550 Ma with T_DM model ages between 2.5 and 1.3 Ga. The reworked signature (ε_Hf values = ?34 to ?4) and the characteristic crustal magma reservoirs (δ¹⁸O ≥5.3 ‰) indicate that these sediments are equivalent to Neoproterozoic granites of the Dom Feliciano Belt. The episodic depositional history started in the Cryogenian (650 Ma) and lasted until the Ediacaran (most likely 570 Ma). A magmatic event of Tonian age is recorded in rhyodacite samples interleaved with the metasedimentary rocks and dated at 773, 801, and 809 Ma. The crustal evolution of the Sul-Riograndense Shield included mountain building, folding and thrusting and flexural subsidence in the foreland. An orogenic triad is revealed as the Pelotas Batholith, the Porongos fold and thrust belt and the Camaquã Basin, all part of the Dom Feliciano Belt.     

Chronological constraints on the tectonic evolution of the Chinese Tianshan Orogen through detrital zircons from modern and palaeo-river sands

The Chinese Tianshan Orogen marks prolonged and complicated interactions between the southwestern Palaeo-Asian Ocean and surrounding blocks. New and previously published detrital zircon chronological data from modern and palaeo-river sands were compiled to reveal its tectonic evolution. It is characterized by predominant Palaeozoic as well as minor Mesozoic and Precambrian detrital zircon ages with a multimodal characteristic. The oldest Phanerozoic zircon population (peaking at 475 Ma) is a result of subduction and closure of the early Palaeozoic Terskey Ocean. However, the absence of this peak in the Chinese North and southern South Tianshan suggests that subductions of the North and South Tianshan oceans may not have initiated until the Late Ordovician with subsequent 460–390 and 360–320 Ma arc magmatism. Similar to the magmatic suite in classic collisional orogens, the youngest massive 320–270 Ma magmatism is suggested to be post-collisional. The North and South Tianshan oceans therefore probably had their closure to form the Chinese Tianshan Orogen during the late Carboniferous. The weak Mesozoic intra-plate magmatism further rejects a late Permian–Triassic Tianshan Orogen due to a lack of extensive syn- and post-collisional magmatism. Moreover, diverse Precambrian detrital zircon age patterns indicate that the surrounding blocks have distinct evolutionary processes with short-term amalgamation during the Meso- to Neoproterozoic.     

东昆仑东段香加南山花岗岩基中加鲁河中基性岩体形成时代、成因及其地质意义

东昆仑东段香加南山花岗岩基中加鲁河中基性岩体主要岩石类型包括角闪辉长岩和石英闪长岩。LA-ICP-MS锆石U-Pb同位素定年结果显示加鲁河中基性岩体的结晶年龄为220 Ma。岩体SiO_2含量较低,为47.91%~58.92%,Al_2O_3含量为15.54%~18.35%,Na2O为1.70%~3.34%,K_2O为0.58%~1.92%,Na_2O/K_2O比值为1.34~2.93,平均1.92,MgO含量为3.69%~8.24%,Mg~#为46~61,铝饱和指数A/CNK介于0.70~0.90之间,主体属于准铝质中钾钙碱性系列。岩体富集轻稀土元素,亏损重稀土元素,具明显的Eu负异常(δEu=0.40~0.59);微量元素富集Rb、Th、Ba等大离子亲石元素(LILE),亏损Nb、Ta、Ti等高场强元素(HFSE)。岩石学和地球化学研究显示岩体在地壳深部和浅部经历了两次岩浆混合作用。在深部,幔源岩浆底侵作用使下地壳部分熔融形成长英质岩浆,两种岩浆不同比例混合,经过化学扩散均一化,从而具有相似的同位素特征和岩石地球化学特征。在地壳浅部,经深部混合的岩浆注入花岗质岩浆,岩浆边部同花岗岩完全混合形成加鲁河岩体中石英闪长岩,不完全混合则形成暗色微粒包体。对加鲁河中基性岩体研究表明,东昆仑东段在晚三叠世处于古特提斯演化的后碰撞阶段,在这一时期存在岩浆底侵事件。     

Discovery of Iapetognathus fauna from far western New South Wales: towards a more precisely defined Cambrian–Ordovician boundary in Australia

Conodont species Iapetognathus fluctivagus and Iapetonudus ibexensis are documented for the first time from Australia. The former is the primary marker internationally defining the base of the Ordovician, and the latter is also a distinctive species previously recorded only from the base of the Ordovician in North America. Both species were recovered from a single sample in the Kandie Tank Limestone of the Kayrunnera Group, located about 50 km west of White Cliffs in far western New South Wales. Other species recovered from this sample include Prooneotodus spp., Cordylodus lindstromi, Cordylodus proavus, Hirsutodontus simplex, Teridontus nakamurai and Variabiloconus sp. Recognition of the Iapetognathus fluctivagus Biozone in the Kandie Tank Limestone supports its correlation with the Green Point section (Global Stratigraphic Section and Point for the base of the Ordovician) in western Newfoundland and the Lawson Cove section of Utah (Auxiliary Stratigraphic Section and Point), as well as sections in Asia and South America. Review of other sections in Australia and elsewhere spanning the Cambrian–Ordovician boundary confirms that, in the absence of I. fluctivagus, the presence of C. lindstromi is a good proxy for this level.