藏南喜马拉雅造山带造山型马扎拉Au-Sb矿床和沙拉岗Sb矿床流体包裹体He-Ar同位素组成:对成矿流体来源的制约

马扎拉Au-Sb矿床和沙拉岗Sb矿床是藏南金锑成矿带中典型的造山型矿床。马扎拉Au-Sb矿床中矿体以含金辉锑矿石英脉的形式产于下中侏罗统陆热组地层中,主要组成矿物有自然金、辉锑矿、石英和碳酸盐矿物;沙拉岗Sb矿床中矿体主要以辉锑矿石英脉的形式产于下白垩统多久组地层和辉长岩体中,主要组成矿物为辉锑矿、辰砂、锑华、石英和少量碳酸盐矿物。在两个矿床的矿脉石英和辉锑矿中均发现有三类原生和假次生包裹体:水溶液包裹体、CO2-水溶液包裹体和有机包裹体。流体包裹体显微测温结果显示:马扎拉Au-Sb矿床的成矿温度为160～280℃,沙拉岗Sb矿床的成矿温度为140～240℃。He-Ar同位素分析显示马扎拉Au-Sb矿辉锑矿石英脉矿石中辉锑矿和石英以及赋矿地层中沉积层状硫化物中黄铁矿的流体包裹体均具有低的3He/4He比值,分别为0. 01382～0. 05642Ra和0. 03353～0. 08744Ra,40Ar/36Ar比值具有比较大的变化范围,分别为346. 8～4770. 1和349. 4～2689. 1;沙拉岗Sb矿床中辉锑矿样品的3He/4He比值为0. 02385～0. 11488Ra,40Ar/36Ar比值变化小,为300. 6～537. 5。与藏南Au-Sb成矿带中造山型Au矿床成矿流体中含一定量的幔源挥发份相对比,马扎拉AuSb矿床和沙拉岗Sb矿床成矿流体中均无幔源流体的参与,马扎拉Au-Sb矿床成矿流体为壳源变质流体与改造型饱和大气水形成的混合流体;沙拉岗Sb矿床成矿流体以改造型饱和大气水为主,并有壳源变质流体的加入。     

Study of late-Mesozoic magmatic rocks and their related copper-gold-polymetallic deposits in the Guichi ore-cluster district,Lower Yangtze River Metallogenic Belt,East China

ABSTRACT

The Guichi ore-cluster district in the Lower Yangtze River Metallogenic Belt hosts extensive Cu–Au–Mo polymetallic deposits including the Tongshan Cu–Mo, Paodaoling Au, Matou Cu–Mo, Anzishan Cu–Mo, Guilinzheng Mo and Zhaceqiao Au deposits, mostly associated with the late Mesozoic magmatic rocks, which has been drawn to attention of study and exploration. However, the metallogenic relationship between magmatic rocks and the Cu–Au-polymetallic deposits is not well constrained. In this study, we report new zircon U–Pb ages, Hf isotopic, and geochemical data for the ore-bearing intrusions of Guichi region. LA-ICP-MS U–Pb ages for the Anzishan quartz diorite porphyrite is 143.9 ± 1.0 Ma. Integrated with previous geochronological data, these late Mesozoic magmatic rocks can be subdivided into two stages of magmatic activities. The first stage (150–132 Ma) is characterized by high-K calc-alkaline intrusions closely associated with Cu–Au polymetallic ore deposits. Whereas, the second stage (130–125 Ma) produced granites and syenites and is mainly characterized by shoshonite series that are related to Mo–Cu mineralization. The first stage of magmatic rocks is considered to be formed by partial melting of subducted Palaeo-Pacific Plate, assimilated with Yangtze lower crust and remelting Meso-Neoproterozoic crust/sediments. The second stage of magmatism is originated from partial melting of Mesoproterozoic-Neoproterozoic crust, mixed with juvenile crustal materials. The depression cross to the uplift zone of the Jiangnan Ancient Continent forms a gradual transition relation, and the hydrothermal mineralization composite with two stages have certain characteristics along the regional fault (Gaotan Fault). Guichi region results from two episodes of magmatism probably related to tectonic transition from subduction of Palaeo-Pacific Plate to back-arc extensional setting between 150 and 125 Ma, which lead to the Mesozoic large-scale polymetallic mineralization events in southeast China.     

额尔齐斯碰撞带东段结构与形成时代

阿尔泰地体与萨吾尔岛弧之间的额尔齐斯碰撞带其结构与形成时代是中亚造山带构造演化研究的热点问题之一。本文报道了额尔齐斯碰撞带东段结构与形成时代的研究结果。新的结果显示:额尔齐斯碰撞带东段由4个走向NWNNW陡立的韧性变形带组成,剖面上呈扇状挤压变形的结构;这4个韧性变形带的应变类型为收缩应变与平面应变;片理带的变形从宏观到微观都表现出对称的结构,不同变形带不同地段可具变化的流动方向而表现出"奶油饼结构",其可能整体形成于共轴挤压机制;玉勒肯与老山口韧性变形带花岗闪长质糜棱岩、花岗闪长质超糜棱岩中变质重结晶锆石U-Pb定年结果显示韧性变形时间约为360Ma。这可能意味着早石炭世时卡拉先格尔地区已进入碰撞阶段,即萨吾尔岛弧与阿尔泰地体间在360Ma时已发生碰撞。     

潞安矿区煤储层裂隙及其与人工裂缝的关系

为了研究潞安矿区煤储层压裂人工裂缝与天然裂隙的关系,井下实测了矿区煤储层宏观裂隙,扫描电镜观测了煤储层显微裂隙;探讨了矿区含裂缝非均质煤岩破裂规律。对原位煤储层条件下人工裂缝沿天然裂隙扩展的最大水平主应力方向与天然裂隙走向夹角的临界值进行了计算。结果表明:矿区的漳村、司马、屯留、常村和五阳5个区块临界值分别为12.00°、9.22°、9.16°、8.56°和7.42°,当最大水平主应力方向与天然裂隙走向的夹角小于此临界角时,人工裂缝沿天然裂隙扩展,反之沿最大水平主应力方向扩展。据此,探讨了潞安矿区原位煤储层压裂裂缝沿天然裂隙扩展的3种模式。     

钦-杭结合带硅质岩的分布特征及其地质意义

钦州—杭州(钦-杭)结合带位于中国东南部地区,跨越浙江、江西、湖南、广东和广西5省(区)。大致以南岭为界,该带可划分为北、中、南三段。中段与南岭带重合,大致分布在北纬24°~27°范围,以北为北段,包括江西、浙江及安徽南部,以南为南段,包括粤西桂东南地区。钦-杭结合带跨带内沉积硅质岩广泛发育,地质和地球化学证据展示它们主要为热水成因。硅质岩相关的热水活动分布偏向于靠近结合带的两侧。钦-杭结合带"北、中、南"三段的硅质岩时空分布存在明显差异:南段及两侧邻区大规模热水活动集中于晚古生代,中段及两侧邻区的集中于早古生代,北段及邻区的热水活动集中于元古宙。这种大规模热水活动自北向南逐渐变新的特点与钦-杭结合带分段演化具有较好的对应关系。作为热水活动地质遗迹的硅质岩,其形成与大地构造与地球动力学背景的演化有密切的关系,特别是与钦-杭结合带的几个拉张阶段存在较好的对应关系。富含硅质的热水活动伴随了丰富的成矿作用,热水喷流沉积型块状硫化物矿床和热水沉积型金矿在该构造带内均较为典型。     

Metallogenic Mechanism and Tectonic Setting of Tungsten Mineralization in the Yangbishan Deposit in Northeastern China

The Yangbishan iron–tungsten deposit in the Shuangyashan area of Heilongjiang Province is located in the center of the Jiamusi Massif in northeastern China. The rare earth element and trace element compositions of the scheelite show that it formed in a reducing environment and inherited the rare earth element features of the ore-forming fluid. The geochemical characteristics of the gneissic granite associated with the tungsten mineralization show that the magma formed in this reducing environment and originated from the partial melting of metamorphosed shale that contained organic carbon and was enriched with tungsten. In addition, in situ Hf isotopic analysis of zircons from the gneissic granite indicates that they probably originated from the partial melting of a predominantly Paleo–Mesoproterozoic crustal source. According to LA-ICP-MS zircon dating, the Yangbishan orerelated gneissic granite has an Early Paleozoic crystallization age of 520.6 ± 2.8 Ma. This study, together with previous data, indicates that the massifs of northeastern China, including Erguna, Xing'an, Songliao, Jiamusi, and Khanka massifs, belonged to an orogenic belt that existed along the southern margin of the Siberian Craton during the late Pan-African period. The significant continental movements of this orogeny resulted in widespread magmatic activity in northeastern China from 530 Ma to 470 Ma under a tectonic setting that transitioned from compressional syn-collision to extensional postcollision.     

Atypical stratiform sulfide-poor platinum-group element mineralisation in the Agnew – Wiluna Belt komatiites,Wiluna, Western Australia

A new style of komatiite-associated sulfide-poor platinum-group element (PGE: Os, Ir, Ru, Rh, Pt, Pd) mineralisation has been identified at Wiluna in the strongly nickel sulfide (NiS) mineralised Agnew – Wiluna Greenstone Belt, Western Australia. The komatiite sequence at Wiluna is ～200 m thick and comprises a basal pyroxenite layer, a thick ortho-to-mesocumulate-textured peridotite core, which is overlain by rhythmically layered wehrlite, oikocrystic pyroxenite and thick upper gabbroic margins. Pegmatoid and dendritic (harrisitic) domains are common features, whereas spinifex-textured horizons and flow-top breccias are absent. The presence of anomalous PGE-enriched horizons (ΣPt – Pd = 200 – 500 ppb) in the oikocrystic pyroxenite and in the layered melagabbro and gabbronorite horizons directly overlying the wehrlite unit is due to the presence of fine-grained (1 – 10 μm) platinum-group minerals (PGMs). More than 70 PGM grains were identified, and a considerable mineralogical variability was constrained. However, only Pd – Pt-bearing phases were identified, whereas no Ir – Ru-bearing PGMs were found in any of the sections examined. Interestingly, all PGMs are not in paragenetic association with sulfides, and only sulfide-poor/free intervals contain significant PGM concentrations. The whole-rock PGE sequence largely reflects the PGM distribution. It is hypothesised that the Pd – Pt enrichment in the oikocrystic pyroxenite and melagabbros and the overall Ir – Ru depletion in the upper mafic section of the sequence are the result of extensive olivine and chromite crystallisation in the basal ultramafic section. PGE saturation was driven by extensive crystallisation of silicate and oxide phases in a sulfide-undersaturated environment. The crystallisation of clinopyroxene in the oikocrystic pyroxenite horizon may have triggered the formation of Pt – Pd-bearing alloys and arsenides, which were the first PGMs to form. Stratiform sulfide-poor PGE mineralisation at Wiluna is more similar in stratigraphic setting, style and composition to PGE-rich sulfide-poor mineralisation zones in thick differentiated intrusions, rather than to other PGE-enriched zones in komatiite-hosted systems, where PGE enrichment is directly associated with accumulations of magmatic sulfides.     

Plate-driven extension and convergence along the East Gondwana active margin: Late Silurian–Middle Devonian tectonics of the Lachlan Fold Belt,southeastern Australia

The Lachlan Fold Belt of southeastern Australia developed along the Panthalassan margin of East Gondwana. Major silicic igneous activity and active tectonics with extensional, strike-slip and contractional deformation have been related to a continental backarc setting with a convergent margin to the east. In the Early Silurian (Benambran Orogeny), tectonic development was controlled by one or more subduction zones involved in collision and accretion of the Ordovician Macquarie Arc. Thermal instability in the Late Silurian to Middle Devonian interval was promoted by the presence of one or more shallow subducted slabs in the upper mantle and resulted in widespread silicic igneous activity. Extension dominated the Late Silurian in New South Wales and parts of eastern Victoria and led to formation of several sedimentary basins. Alternating episodes of contraction and extension, along with dispersed strike-slip faulting particularly in eastern Victoria, occurred in the Early Devonian culminating in the Middle Devonian contractional Tabberabberan Orogeny. Contractional deformation in modern systems, such as the central Andes, is driven by advance of the overriding plate, with highest strain developed at locations distant from plate edges. In the Ordovician to Early Devonian, it is inferred that East Gondwana was advancing towards Panthalassa. Extensional activity in the Lachlan backarc, although minor in comparison with backarc basins in the western Pacific Ocean, was driven by limited but continuous rollback of the subduction hinge. Alternation of contraction and extension reflects the delicate balance between plate motions with rollback being overtaken by advance of the upper plate intermittently in the Early to Middle Devonian resulting in contractional deformation in an otherwise dominantly extensional regime. A modern system that shows comparable behaviour is East Asia where rollback is considered responsible for widespread sedimentary basin development and basin inversion reflects advance of blocks driven by compression related to the Indian collision.     

内蒙古四子王旗黑脑包岩体年代学与地球化学特征及其构造演化

内蒙古四子王旗黑脑包岩体位于华北板块北缘早古生代增生造山带,主要由花岗闪长岩和花岗斑岩组成。对花岗闪长岩进行La-ICP-MS锆石U-Pb定年,获得四子王旗黑脑包侵入岩体的2个侵位年龄为407.4±4.7 Ma和268.0±2.7 Ma,分别代表洋陆俯冲事件以及陆陆碰撞事件年龄。岩石地球化学数据显示,四子王旗黑脑包岩体属钙碱性系列,逐步向低钾拉斑系列靠近,并且亏损高场强元素。同位素地质年龄及地球化学数据表明,样品具有同碰撞花岗岩特征。结合区域大地构造背景认为,四子王旗黑脑包地区主要构造背景为西伯利亚板块与华北板块之间俯冲、碰撞和对接过程,属古亚洲洋构造域,而后期的构造演化还有待进一步研究。     

秦岭-大别-苏鲁印支造山带连接枢纽的形成时代——来自宁陕断裂带同构造花岗岩锆石U-Pb年代学的限定

最新的研究表明,南秦岭勉略缝合带可以经宁陕左行走滑断裂带与大别苏鲁的高压/超高压变质带相连。对于这个模型,两带间的"连接枢纽"—宁陕走滑断层的活动时间是关键问题之一。研究显示宁陕断裂带是南秦岭中的一条走向近E-W的走滑剪切带,早期为左行韧性剪切变形,晚期叠加了左行脆性剪切变形。对带内千糜岩化石英片岩中的两期同构造花岗岩脉的构造地质学、岩石学和锆石U-Pb和Lu-Hf同位素研究,获得早期面理化细粒花岗岩的年龄为214.4±1.1Ma(MSWD=1.3),εHf(t)主要集中在-8.58~-0.29之间,tDM2=2.45~1.62Ga;晚期钾长花岗岩脉的年龄212.8±1.6Ma(MSWD=2.1),εHf(t)=-5.79~2.07,tDM2=2.53~1.49Ga。同位素数据表明两期花岗岩脉具有相同的岩浆源区,是古老地壳物质的再循环;晚期钾长花岗岩脉是早期花岗岩演化的产物。两期同构造花岗岩脉年龄的确定,表明宁陕左行走滑断层至少从晚三叠世中期之前就已经开始活动,而不是前人认为的早-中侏罗世或晚三叠末。尤其是宁陕左行走滑断裂带与勉略缝合带具有相同的左行韧性走滑叠加晚期脆性走滑的构造样式和活动时间,表明二者的形成可能都与古特提斯洋的斜向俯冲或者扬子板块的顺时针旋转有关。本研究成果为南秦岭的"古特提斯洋缝合带"——勉略缝合带向东经宁陕断裂带与大陆俯冲和深俯冲形成的耀岭河-桐柏-大别-苏鲁高压/超高压变质带相接提供了关键的年代学证据。