An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry

Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO₃ results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF₃ precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH₄HF₂ open vessel digestion and (c) NH₄F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF₃ and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH₄HF₂ or NH₄F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO₃, the white precipitates and the semi‐transparent gels present in the NH₄HF₂ and NH₄F digestion methods could be efficiently dissolved by evaporation with HClO₄. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time.     

Egg production of Calanus finmarchicus—A basin-scale study

Egg production of Calanus finmarchicus was studied during joint basin-scale surveys in April–June 2003 in the Norwegian Sea. Surveys covered the whole Norwegian Sea and were conducted from Norwegian, Icelandic and Faroese research vessels. Stations were classified as being in pre-bloom, bloom or post-bloom phase according to levels of chlorophyll a and nitrate. Individual egg production rates and population egg production rates were calculated and compared between areas. Both individual egg production rates (eggs female⁻¹ day⁻¹) and population egg production rates (eggs m⁻² day⁻¹) were significantly higher in bloom areas compared with pre-bloom and post-bloom areas. However, when integrated over an estimated duration of the three phases, the time-integrated egg production (eggs m⁻²) in most years was highest in the pre-bloom phase, and this was explained by the longer duration of this phase compared with the two other phases.     

基于Chandra的活动星系核观测

活动星系核（AGN）是宇宙中最奇特的天体之一。它是真正意义上的全波天体，其中X射线波段的发射功率占到全波段功率的50％左右。AGN的X射线辐射研究涉及天体物理中的最基本问题，例如能量产生、辐射机制和宇宙论等，而Chandra X射线卫星的高分辨率图像和光谱对这一研究有着重要作用。以Chandra卫星的部分观测结果为例，简要介绍了几类不同类型AGN的X射线辐射研究进展：（1）宽吸收线类星体APM08279＋5255（z=3．91）的X射线谱分析，以及高红移类星体的观测概况；（2）Seyfert星系NGC 4151延展X射线发射问题的解决，及NGC 1068X射线辐射与光学波段的高激发态发射线（[OⅢ]λ5007）有很强相关性的发现；（3）6个BLLac天体样本的X射线环境分析；（4）射电星系X射线喷流的观测等。     

A Study on the Long-term Spectral Variability of the Black-hole Candidate X-ray Binary Cyg X-1

Using the All-Sky Monitor (ASM, 1.5–12–kev) data of Rossi X-ray Timing Explorer (RXTE) from January 1996 to May 2005, we have made a detailed analysis of the correlation between photon-count rate and spectral hardness ratio HR2 (5–12 keV/3–5 keV) of the black-hole candidate X-ray binary Cyg X-1 in 3 energy bands, namely the A-band (1.5–3 keV), B-band (3–5 keV) and Cband (5–12 keV). By the study on the ASM data of 1-day time scale, we find: (1) When Cyg X-1 is in the soft state, the A-band photon-count rate and hardness ratio HR2 exhibit an anticorrelation, but in B-band and C-band there appears the positive correlation. When Cyg X-1 is in hard state, the photon-count rates in the A,B,C bands are all inversely correlated with the hardness ratio HR2; (2) No matter whether Cyg X-1 is in the soft state or the hard state, the hardness ratios HR2 and HR1 are always positively correlated. In addition, we have analyzed the “dwell by dwell” data of the ASM, and obtained the following interesting results: (1) In the period of MJD = 52600–52760 (while Cyg X-1 is in the hard state), the photon-count rates in the A-band and B-band are inversely correlated with HR2, but in the C-band there appears a relatively strong positive correlation; (2) During the hard state, a clear anticorrelation exists between the hardness ratios HR2 and HR1.     

Evolution of the photospheric magnetic field and coronal null points before solar flares

Based on a topological model for the magnetic field of a solar active region (AR), we suggest a criterion for the existence of magnetic null points on the separators in the corona. With the problem of predicting solar flares in mind, we have revealed a model parameter whose decrease means that the AR evolves toward a major eruptive flare. We analyze the magnetic field evolution for AR 9077 within two days before the Bastille Day flare on July 14, 2000. The coronal conditions are shown to have become more favorable for magnetic reconnection, which led to a 3B/X5.7 eruptive flare.     

水下荧光光谱探测装置控制系统的设计与实现

海水中有色可溶性有机物(CDOM,Chromophoric Dissolved Organic Matter,常称之为黄色物质)是影响海洋水色的三大成分之一,海水中CDOM的研究具有重要的意义。本文针对CDOM水下原位探测激光诱导荧光光谱探测装置开发了一套控制系统,该控制系统分为水上甲板控制和水下数据采集两部分,水上甲板控制部分通过8芯电缆与水下数据采集部分实现供电及通信,水下数据采集部分以PC104嵌入式工控机为核心,控制整体采集部分的工作,甲板控制部分通过远程控制软件来操控PC104以实现水下数据的采集和存储。实验室环境测试及近海现场实验表明,该系统能够可靠完成水下荧光光谱装置的控制和数据的采集及通信需求,实现海水中有色可溶性有机物的水下原位探测。     

海洋浮游植物三维荧光光谱的逐层分类方法研究

提出活体海洋浮游植物三维荧光光谱逐层分类法,将浮游植物区分为不同的"光谱类别"。选取中国近海常见的26种分属于甲藻、硅藻、黄藻、金藻、隐藻、绿藻、蓝藻的浮游植物,在室温20℃和3个光照条件下培养,在第3,6,9,12,15天测其三维荧光光谱。采用主成份分析结合非负最小二乘回归法(NNLSR),以浮游植物叶绿素a的发射峰680nm所对应的激发光谱作为第一特征谱以区分门类,以EX730谱作为硅藻的逐层分类的第二特征谱,SY350谱作为甲藻的第二特征谱,将实验所用9种硅藻和8种甲藻各划分为3个光谱类别;分析405个浮游植物混合物,门类识别正确率大于94%,光谱类别的识别正确率为75%,该方法可用于海洋浮游植物种群结构变化的快速宏观监测。     

Authigenic carbonates from the eastern Black Sea as an archive for shallow gas hydrate dynamics – Results from the combination of CT imaging with mineralogical and stable isotope analyses

Authigenic carbonates associated with cold seeps provide valuable archives of changes in the long-term seepage activity. To investigate the role of shallow-buried hydrates on the seepage strength and fluid composition we analysed methane-derived carbonate precipitates from a high-flux hydrocarbon seepage area (“Batumi seep area”) located on the south-eastern Black Sea slope in ca. 850 m. In a novel approach, we combined computerized X-ray tomography (CT) with mineralogical and isotope geochemical methods to get additional insights into the three-dimensional internal structure of the carbonate build-ups.     

台湾浅滩西部水域海洋动物的石油烃含量和荧光光谱特征

本文报道了台湾浅滩西部水域鱼类、虾类和软体头足类动物的总石油烃含量,分析了主3类动物样品的荧光光谱特征,并将本文数据与南海其他水域海洋动物的石油烃含量作了比较。     

Microphytobenthos vertical migratory photoresponse as characterised by light-response curves of surface biomass

The migratory response of intertidal microphytobenthos to changes in irradiance was studied on undisturbed estuarine sediments. Two non-destructive optical techniques were used to trace variations in vivo of surface biomass: PAM fluorometry, for measuring the minimum fluorescence level (F_o); and spectral reflectance analysis, for quantifying the normalized difference vegetation index (NDVI). Following the formation of a dense biofilm at the surface, replicated sediment samples were simultaneously exposed to six different irradiance levels, ranging from 50 to 1500 μmol m⁻² s⁻¹, during a period of 120 min. The migratory photoresponse of the biofilms was characterised by constructing biomass vs. light curves (BLC), relating the accumulation of microalgal biomass after that period (estimated by F_o or NDVI) to the irradiance level incident on the surface. BLCs allow characterising the main features of the migratory photoresponse of intact biofilms. Typical BLC showed a clear biphasic pattern, with an increase in microalgal accumulation under irradiances below 100 μmol m⁻² s⁻¹, maximum values under 100–250 μmol m⁻² s⁻¹, and a gradual decrease of surface biomass under higher irradiances, indicating a strong photophobic downward migratory response. Similar BLC patterns were obtained when measuring F_o or NDVI. The construction of BLCs for biofilms from intertidal sites with distinctive sediment characteristics and diatom taxonomic composition allowed to detected significant differences in the migratory photoresponse. Biofilms from a muddy sediment exhibited considerably larger amplitude in the migratory photoresponse than the biofilms from a sandy mud site, especially under high irradiances. The photophobic migratory response to high light was found to vary among diatom species, particularly in the case of the biofilms from the muddy sediments.