Simultaneous Determination of Fluorine,Chlorine, Bromine and Iodine in Six Geochemical Reference Materials Using Pyrohydrolysis,Ion Chromatography and Inductively Coupled Plasma‐Mass Spectrometry

Concentrations of halogens (fluorine, chlorine, bromine and iodine) were determined in six geochemical reference materials (BHVO‐2, GS‐N, JG‐1, JR‐1, JB‐1b, JB‐2). Halogens were first extracted from powdered samples using a pyrohydrolysis technique, then hydrolysis solutions were analysed by ion chromatography for F and Cl and inductively coupled plasma‐mass spectrometry for Br and I. The detection limits in solutions were 100 μg l^?1 for both F and Cl and 10 ng l^?1 for Br and I. Considering the extraction procedure, performed on a maximum of 500 mg of sample and producing 100 ml of pyrohydrolysis solution, detection limits in rock samples were 20 mg kg^?1 for F and Cl and 2 μg kg^?1 for Br and I. The mean analytical errors on the studied composition ranges were estimated at 10 mg kg^?1 for F and Cl, 100 μg kg^?1 for Br and 25 μg kg^?1 for I. The concentration values, based on repeated (generally > 10) sample analysis, were in good agreement generally with published values and narrowed the mean dispersion around mean values. Large dispersions are discussed in terms of samples heterogeneity and contaminations during sample preparation. Basaltic RMs were found to be more suitable for studies of halogen compositions than differentiated rock material, especially granites – the powders of which were heterogeneous in halogens at the 500 mg level.     

X荧光与幅频激电法综合勘查川西北某铜矿

为了查清川西某铜矿勘查区内的铜矿资源量,给区内进一步勘查提供线索,同时为山地工程布设提供依据,在矿区开展了X荧光与幅频激电法测量,控制了矿区内矿体的延伸方向、位置与长度。工作结果表明,X荧光与幅频激电法联袂勘查铜矿（化）体具有探测能力强、效率高、易于施工的优点,可以推广到其他铜矿床的定位预测研究中。     

High-Pressure Behavior of Copper Carbonate: Data from Malachite

Abstract: In-situ high-pressure energy dispersive X-ray diffraction experiments of malachite have been performed using diamond anvil cell and synchrotron radiation. The highest recorded pressure is up to 17.4 GPa. The experimental results reveal that malachite experienced two phase transitions at 0.7 and 7.8 GPa, and the last one is reversible.     

静电场轨道阱质谱在水中溶解性有机质表征中的应用进展

溶解性有机质(Dissolved Organic Matter,DOM)在水生生态环境中广泛存在,影响着水环境中多种物质的生物地球化学性质.分析其组成与含量具有重要的生态环境意义,是生态环境科学领域研究的热点.溶解性有机质组成非常复杂,其分子组成的解析一直是难题.近年来,具有高分辨率、高灵敏度、高通量、高扫描速率等特性...     

不典型卵巢畸胎瘤的CT表现与病理对照分析

目的：探讨不典型卵巢畸胎瘤的CT表现。方法：分析经手术病理证实的CT检查呈不典型表现的卵巢畸胎瘤50例,并与病理结果对照。结果：50例中,均发生于单侧卵巢,右侧27例、左侧23例。大小范围为1．1～12．8am。形状呈类圆形43例、分叶状5例、不规则形2例。囊性或以囊性为主45例、实性5例。根据肿瘤CT表现与病理特征分：囊肿型38例（偏低密度囊肿型12例,高密度囊肿型9例,厚壁囊肿型9例,薄壁囊肿型8例）、无壁全脂肪型3例、实性型5例和混合肿瘤型4例。结论：有些不典型畸胎瘤也具有一定的CT特点,熟悉其CT征象及病理基础有利于提高诊断和鉴别诊断水平。     

眼眶内血管外皮细胞瘤影像诊断及鉴别诊断

目的：探讨眼眶内血管外皮细胞瘤影像学表现,提高对本病影像学特征的认识。方法：报道1例经手术、病理证实的右侧眼眶内血管外皮细胞瘤,对其CT平扫、MRI平扫及强化表现进行分析。结果：肿瘤CT表现为右侧眶内上方球后团块状软组织密度影。MRI表现为右侧眼眶内上方球后团块状T1WI等及稍低信号,T2WI稍高信号影,动态增强扫描,动脉期及实质期有明显强化。结论：运用多种影像学检查方法,可提高对眼眶内血管外皮细胞瘤的认识,做出准确的诊断。     

纳米TiO2分离富集ICP-MS法测定河口环境样品中重金属研究

建立了以纳米二氧化钛（TiO2）作为吸附剂填充微柱,电感耦合等离子体质谱（ICP-MS）法测试Cu^2＋,Cd^2＋,Pb^2＋和Ni^2＋离子的分析方法．考察了不同pH值、洗脱液浓度、样品流速、体积和外源干扰离子的影响,实验结果表明在pH值8～10范围内待测离子可被TiO2定量吸附,2．0molL^-1HNO3可将吸附在微柱上的待测物完全洗脱,优化条件下本方法对溶液中Cu^2＋,Cd^2＋,Ph^2＋和M^2＋离子检出限分别为：0．02,0．01,0．01,0．02μgL～,相对标准偏差小于2％（n=7）,富集系数50倍．对水系沉积物标准物质（GBW07310）的测定值与标准值相一致,方法具有简便、快速,灵敏度高,重现性好的优点,可满足河口水体与沉积物样品中痕量金属元素定量分析的要求．     

The potential of historic rock avalanches and man-made structures as chlorine-36 production rate calibration sites

Samples from three medieval rock avalanches from the French (Le Claps, Mont Granier) and Austrian Alps (Dobratsch) and a man-made structure, i.e. the Stephansdom in Vienna, have been analysed for in-situ produced ³⁶Cl by accelerator mass spectrometry (AMS). All four sampling sites of independently known exposure duration turned out to be not appropriate as calibration sites for the determination of the ³⁶Cl-production rate from Ca. Indeed, the determination of short exposure ages for dating rock avalanches and man-made structures by ³⁶Cl is hindered dramatically by inheritance, especially for samples characterized by high ^natCl-concentrations. Generally, there are hints that the theoretical calculation of ³⁶Cl-production from epithermal and thermal neutron-capture on ³⁵Cl is highly underestimated in all existing models, thus, asking for particular precaution if working on high-Cl samples for any project. Hence, this work evidences that potential high inheritance, even for samples reasonably shielded before exhumation, has to be considered especially when dealing with recently exposed surfaces such as glacially polished rocks, alluvial terraces, fault scarps etc.     

叶绿素荧光遥感在陆地生态系统碳循环和陆气相互作用中的应用研究进展

陆地生态系统通过植被光合作用可以吸收约30％的人为碳排放,在全球碳循环、减缓大气二氧化碳浓度上升等方面具有重要作用。最近10年发展起来的日光诱导叶绿素荧光遥感技术,可以监测植被实际光合作用,为全球陆地生态系统碳循环的研究提供了新的思路和方法。本文回顾了叶绿素荧光遥感产品发展及其在陆地生态系统碳循环和陆气相互作用中的应用研究进展,特别是在全球植被总初级生产力估算和陆地生态系统碳循环模型发展方面的进展,并进一步讨论了该领域研究面临的挑战和未来的发展方向。     

原子荧光光度法测定植物样品中的铋

植物样品经硝酸-高氯酸1次湿法消解后,用氢化物发生-原子荧光光谱法测定铋。测定时加入消泡剂磷酸三丁酯,可有效消除泡沫,降低记忆效应,提高精密度。方法精密度(RSD=12)铋1.50%。经加标回收试验和国家一级标准物质验证,测定结果与标准值吻合。