黑硼锡镁矿孪晶的电子衍射分析

黑硼锡镁矿是1985年在我国发现的一种新矿物,微孪晶特别发育,其电子衍射斑点往往具规律的分裂现像。用选区电子衍射获得[010]、[141]和[121]定向带轴电子衍射斑点分裂图,经矩阵分析,确定两套斑点分裂是由其呈挛晶结构关系所致,孪晶面为(101),属于面律孪晶,这种孪晶的微形貌由明场像(BF)得到证实。根据不同取向的电子衍射图,确定该矿物属单斜晶系,a_0=10.7,b_0=3.01,c_0=5.39,β=94.5°。上述挛晶结构特征及其晶体学数据与X射线单晶研究结果有很好的可比性。     

X射线荧光光谱仪的性能检验

本文介绍了理学3080E型X射线荧光光谱仪性能检验的主要项目,说明了测量方法和技术指标。     

衍射指标h和k的互换问题

通过衍射线指标和面网指标的联系讨论了晶体的对称性对衍射指标h和k互换的影响。在下列情况下衍射指标h和k是不能互换的:在低级晶族;在四方晶系C_(4h)—4/m劳厄点群,六方品系C_(6h)—6/m劳厄点群和立方晶系T_h—m3劳厄点群对于hko和kkl型衍射;在三方晶系选取六方晶胞的情况下,在C_(3i)—3劳厄点群对于hol,okl,hko和hkl型衍射,在D_(3d)—3m劳厄点群对于holokl和hkl型衍射,以及在菱面体点阵除非h和k都是三的倍数。     

沉积岩中蒙脱石-伊利石混层矿物的SEM/EDAX分析

本文利用扫描电子显微镜与X射线能量色散分析联合法,对沉积岩中蒙脱石-伊利石混层矿物进行系统微区成分分析,求出混合层中伊利石的百分含量。     

合成斜方辉石系列的红外光谱研究

在30kbar和900℃条件下,用等化学计量氧化物混合物合成了11个斜方辉石系列的样品,并对合成的样品进行了X射线粉晶分析和红外光谱分析。分析结果表明,晶胞参数和红外光谱随化学成分的改变而产生复杂的变化。不仅晶胞参数b和M而且频率ν_(670cm)-1和M之间存在很好的线性相关关系,通过用最小二乘法所拟合的相关方程可容易地测定斜方辉石的成分,但是α和c与M之间只有较差的线性关系,而ν_(450cm)-1和M以及ν_(380cm)-1和M之间并无简单的线性相关关系,这可归因于Fe~(2+)在M_1和M_2位置的有序分布。     

攀西地区长石的X射线研究

本文对四川攀枝花—西昌（即攀西裂谷）地区各个不同时期、不同产状、不同岩类中的斜长石、碱性长石进行了X射线研究,配合单矿物化学分析、电子探针成分分析,结合红外光谱、光学测定,精确地计算了42个斜长石,60个碱性长石的晶胞参数,求出其四个四面体的Al含量,确定长石的成分和结构态。为探索攀西地区岩浆活动演化规律,研究攀西裂谷形成、发展及其消亡历史提供了客观依据。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Uniform half-plane elastodynamic problems by an approximate boundary element method

In this paper the applicability of an approximate Boundary Element Method to uniform half-plane elastodynamic problems is investigated. This method employs the concept of images to construct approximate fundamental solutions for the half-plane and does not require any half-plane surface discretization. The method is formulated in the frequency domain for the case of harmonic disturbances or the Laplace transform domain for the case of transient disturbances. In the latter case a numerical inversion of the transformed solution is necessary to obtain the time domain response. The proposed method can be used as an alternative to boundary element methods that either utilize the infinite plane fundamental solution and thus require a half-plane surface discretization, or employ the exact half-plane fundamental solution, which even though leads to no surface discretization, is of a very lengthy and complicated form. Two characteristics numerical examples are used to illustrate the proposed method and study its advantages and disadvantages.     

罕见的蓝色饵-纳透闪石研究

尽管角闪石在地壳中大量存在 ,但是蓝色钾 钠透闪石却是角闪石中的稀有品种。本文采用X射粉晶线衍射和晶胞参数计算 ,确定该矿物为蓝色的钾 钠透闪石 ,用电子探针 (EMPA)精确分析了它的化学成分 ,确定为钾 钠透闪石 ,而不是蓝色软玉 (即不是透闪石或阳起石 )。     

A method to estimate hydraulic conductivity from bulk geochemical compositions

A new method has been developed to estimate the hydraulic conductivity in unconsolidated aquifers. The method uses bulk geochemical compositions correlated with hydraulic conductivities measured by pumping tests. The concept is based on a general rule that hydraulic conductivity is principally controlled by grain-size distribution and particle shape,both of which relate to mineralogical composition. Using a MINLITH algorithm, normative mineralogical compositions can be derived from bulk geochemical compositions economically and expediently, and then correlated to the hydraulic conductivity determined by pumping tests in the field. In this study, 202 sediment samples from nine unconsolidated aquifers were analyzed by X-ray fluorescence. Although hydraulic conductivity does not show a definite relationship with geochemical compositions, it does demonstrate a linear logarithmic equation to the content of normative earthy minerals. However, linear regressed equations should not be applied to aquifers composed of medium to coarse sand and gravel sizes due to interference from lithic fragments. In addition, this equation tends to overestimate hydraulic conductivity possibly because the effect of compaction is ignored in this study.