Neutron Activation Analysis,Atomic Absorption and X‐Ray Fluorescence Spectrometry Review for 2006–2007

These mature analytical techniques do not show any change in publication level from the previous two years and AAS remains dominant in terms of the number of publications. The last two years have seen fewer technical improvements than in the previous review period. Some interesting papers dealing with uncertainty and quality assurance in INAA were published during 2006–2007. It is suggested that photon activation should be reconsidered because the source of electron accelerators has recently improved. A technique to preconcentrate Se for INAA determination has also been proposed. In the case of AAS, papers on analyte preconcentration continue to be more abundant than those relating to instrumental modification. Sample preparation for AAS is also active and ultrasound‐assisted leaching shows some promising applications. There were an unusual number of reviews concerned with AAS and those important to geological samples are cited here. A technique to preconcentrate Cr in water is presented and a new device to determine As and Se is showing some potential uses. Confocal X‐ray mapping continues to show interesting developments. One group developed a technique to perform XRF inside an oyster and an interesting application of μ‐XRF mapping of sediments is presented. Determination of platinum‐group elements (at μg g¹ concentrations) can be carried out very quickly with an improved XRF technique.     

多种地图符号系统布尔代数结构的简要证明

布尔代数是计算机进行逻辑运算的基础,它为自动化制图提供了理论基础和数学工具。本文根据论域的幂集P(X)为布尔代数且其偏序关系为包含关系的数学原理,通过改变论域而分别对地图图像系统、地图符号系统和地图数据库系统等多种地图符号系统的布尔代数结构,分别作出了有别于应用布尔代数定义和定理的简要证明。文章给出了以点的特征变换构建地图符号、地图注记和实现面状域色彩变换的实例,阐释了地图图像系统中的布尔运算;还给出了通过基础图层上地图符号的增删,构建不同图层和不同图层叠合构建不同类型地图的实例,说明以点集形式为基本元素的地图符号系统和地图数据库系统也适于布尔运算。     

GGR Biennial Critical Review: Analytical Developments Since 2012

Advances in the chemical, crystallographic and isotopic characterisation of geological and environmental materials can often be ascribed to technological improvements in analytical hardware or to innovative approaches to data acquisition and/or its interpretation. This biennial review addresses key laboratory methods that form much of the foundation for analytical geochemistry; again, this contribution is presented as a compendium of laboratory techniques. We highlight advances that have appeared since January 2012 and that are of particular significance for the chemical and isotopic characterisation of geomaterials. Prominent scientists from the selected analytical fields present publications they judge to be particular noteworthy, providing background information about the method and assessing where further opportunities might be anticipated. In addition to the well‐established technologies such as thermal ionisation mass spectrometry and plasma emission spectroscopy, this publication also presents new or rapidly growing methods such as electron backscattered diffraction analysis and atom probe tomography – a very sensitive method providing atomic scale information.     

X‐ray tomography of tsunami deposits: Towards a new depositional model of tsunami deposits

X‐ray computed microtomography is used to obtain high resolution imagery of a historical tsunami deposit in Andalusia, Spain (1755 Lisbon tsunami). The technique allows characterization of grain‐size distribution, structures, component analysis and sedimentary fabric of fine‐grained unconsolidated tsunami deposits at resolutions down to particle scale. The results are validated by comparing to data obtained using other techniques such as laser diffraction, anisotropy of magnetic susceptibility and X‐ray microfluorescence on the same deposits. Specific technical details such as sampling, scanning and image processing methods, and further improvements are addressed. The use of X‐ray computed microtomography provides new insights into the stratigraphy of the deposits and gives access to significantly more detailed view of key sedimentary features such as mudlines, rip‐up clasts, crude laminations, convolutions, floating outsized clasts and contacts between successive units. This analysis of the 1755 tsunami deposits using X‐ray computed microtomography allows the proposal of new hypotheses for the sedimentary processes forming tsunami deposits. Deposition by settling is limited and the section analysed here is dominated by a high shear stress leading to the development of traction carpets, with laminated mudlines corresponding to the basal frictional region of these carpets. The onset of the tsunami backwash is marked by a micro‐vortex resembling Kelvin–Helmoltz instabilities.     

X波段天气雷达电磁辐射对环境影响的评估

为了定量分析X波段天气雷达电磁辐射对环境的影响,依据X波段天气雷达的主要性能参数,理论推导X波段天气雷达的电磁辐射特性,分析X波段雷达站点周边环境,对电磁辐射进行水平和垂直立体监测,理论计算和实际监测结果均表明X波段雷达电磁辐射大小满足《电磁环境控制限值》(GB8702—2014)和《辐射环境保护管理导则电磁辐射监测仪器和方法》(HJ/T10. 2—1996)的要求,电磁辐射水平低于公众曝露的控制限值。     

青海省哇洪山断裂带中段构造变形特征及X光岩组分析

通过对哇洪山断裂带中段构造变形宏观及微观特征的研究,认为该断裂带经历了两种不同层次、不同性质的构造变形,早期以韧性变形为主,形成了沿断裂带广泛分布的NW-NNW向糜棱岩带;晚期以脆性变形为主,形成了广泛分布断层破碎带,并将早期的糜棱岩带错断。X光岩组分析结果表明,糜棱岩带构造岩内矿物排列定向性明显,其中石英变形以底面滑移或近底面滑移为主,兼有柱面滑移,为中低温-中温变形环境所形成;另外动态重结晶对变形岩石中石英优选方位的形成也可能发挥了重要作用。华里西晚期花岗闪长岩、印支期钾长花岗岩、花岗岩、二长花岗岩均没有明显的优选方位,因此韧性变形发生在该类岩石侵位之前。构造变形分析及同位素测年结果证实韧性剪切带形成于晚志留世,即加里东晚期。     

一种绢云母样品的综合鉴定分析

运用X射线衍射、差热分析以及扫描电子显微镜等现代分析测试技术，对某地绢云母矿样品进行了综合分析，查明了该样品中矿物组成；证明样品中的粘土矿物成分是绢云母，而不是伊利石，为更好地对该绢云母资源进行开发利用提供了可靠的依据。     

地质样品痕量氯溴和硫的X射线荧光光谱法测定

报道了粉末压样－X射线荧光光谱法测定地质样品中痕量Cl、Br、S的分析方法。采用水系沉积物、岩石和土壤等国家一级标准物质进行校准。实验表明，对于不同岩性样品中Br的分析，特别是当Br的含量低于2μg/g时，采用谱峰强度（未扣除背景）与背景强度的比进行校准所得到的结果，明显优于铑靶线的Compton散射线内标法，分析精度（RSD,n=6)为2.4%-15.3%，大多数优于10％；平均值的相对误差低于24％。对于Cl的分析，只需对Ca的影响加以校正即可得到非常好的结果；不同样品中Cl的分析精度（RSD，n=6)为2.1%-13.6%，大多数优于5％；平均值的相对误差不大于25％，多数优于10％。S的校准曲线的离散性较大，矿物学效应是影响S分析准确度的主要因素，其分析精度（RSD,n=6)为0.87%-5.6%，除个别样品外，平均值的相对误差优于36％。Cl和S均存在分析结果随测量时间（次数）的增加而增高的现象，必须在制样后立即测量。方法的检出限（μg/g)Br、Cl、S分别为0．43、5．8和2．2。     

含Mg矿物和玻璃中Mg的局部结构研究

本文用同步辐射的MgK-边X射线近边结构谱(XANES)研究了9种含Mg矿物的MgK-边特征谱,其谱的能量位置随着配位数的增加而增大;建立了含Mg矿物中Mgk-边的能量与Mg-O键距的关系CaMgSi2O6(Di)-NaAlSi3O8(Ab)玻璃中MgK-边XANES的能量和Mg-O的键长的关系.在Di-Ab玻璃中的Mg-O键距是0.2±0.004nm.表明本方法可以作为研究含Mg矿物Mg的配位与局部结构新的结构探针.     

珊瑚的影像密度恢复南海海表温度

将南海西沙永兴岛 ( 1 6°50′N,1 1 2°2 0′E)西北的造礁珊瑚的岩芯 ,制成 X射线负片。用显微光密度计在 X射线负片上获得沿生长轴方向的影像密度值 ,时间序列为 1 937～ 1 993年。根据影像密度数据 ,计算出珊瑚的各年生长率和钙化率的代用指标。珊瑚生长率和钙化率的代用指标都与 SST呈显著正相关。根据 1 960～ 1 993年的资料统计 ,相关系数分别是 0 .91和 0 .85,从而建立了珊瑚生长率温度计和钙化率代用指标温度计。并用这两个温度计测算到 1 937年 ,揭示出南海的 SST变化既受到全球气候环境变化为主的影响 ,也受到半封闭海域格局的影响