湘南中山地区中棚岩体地球化学特征与铀成矿

通过对中棚岩体地球化学特征的研究,探讨其与铀矿化的关系。中棚岩体属于过铝质花岗岩,高钾钙碱性岩石系列。分析认为,岩体具有S型花岗岩特征,为陆壳物质部分熔融的产物,原岩可能为寒武系浅变质砂岩。构造环境判别认为,岩体属于后碰撞花岗岩范畴,在岩石圈伸展作用构造环境下由寒武系部分熔融所形成。岩体的原岩铀含量较高,为富铀的中棚岩体形成奠定了基础,也为后期成矿提供了充足的铀源。     

Geochemistry of S-type granitic rocks from the reversely zoned Castelo Branco pluton (central Portugal)

The zoned pluton from Castelo Branco consists of Variscan peraluminous S-type granitic rocks. A muscovite>biotite granite in the pluton's core is surrounded successively by biotite>muscovite granodiorite, porphyritic biotite>muscovite granodiorite grading to biotite=muscovite granite, and finally by muscovite>biotite granite. ID-TIMS U–Pb ages for zircon and monazite indicate that all phases of the pluton formed at 310 ± 1 Ma. Whole-rock analyses show slight variation in ⁸⁷Sr/⁸⁶Sr_310 Ma between 0.708 and 0.712, Nd_310 Ma values between − 1 and − 4 and δ¹⁸O values between 12.2 and 13.6. These geological, mineralogical, geochemical and isotopic data indicate a crustal origin of the suite, probably from partial melting of heterogeneous Early Paleozoic pelitic country rock. In detail there is evidence for derivation from different sources, but also fractional crystallization linking some of internal plutonic phases. Least-squares analysis of major elements and modelling of trace elements indicate that the porphyritic granodiorite and biotite=muscovite granite were derived from the granodiorite magma by fractional crystallization of plagioclase, quartz, biotite and ilmenite. By contrast variation diagrams of major and trace elements in biotite and muscovite, the behaviours of Ba in microcline and whole-rock δ¹⁸O, the REE patterns of rocks and isotopic data indicate that both muscovite-dominant granites were probably originated by two distinct pulses of granite magma.     

诸广山南部白云岩体岩石地球化学特征及成因

白云岩体位于诸广山南部岩体中东部,是一个重要的产铀岩体,其岩性为粗粒斑状黑云母花岗岩。在主量元素方面,该岩体的岩石富硅（SiO2平均为73.47%）、富铝（A/CNK值平均为1.09）和高的K2O/Na2O值（平均为1.99）;在微量元素方面,富集大离子元素Rb、Th,而Ba、Sr、Ti、Nb、Ta、P亏损明显,具有高的Rb/Sr（平均为6.22）和Rb/Nb值（平均为29.07）,富含铀（平均为9.04×10-6）,可为岩体内铀矿床的形成提供铀源;轻稀土元素富集和轻、重稀土元素分馏相对明显,稀土元素配分曲线呈右倾型,Eu亏损明显;在同位素方面,εNd（t）值低（平均为-10.6）,（87Sr/86Sr）i值高（平均为0.71688）,Nd模式年龄古老（1865～1874 Ma）。这些特征表明,白云岩体属于典型的壳源型花岗岩,是在华南地块和印支地块碰撞结束后不久形成的伸展构造环境中,位于地壳中-下部的古-中元古代地壳组分在伸展、减薄作用产生的减压、导水和地幔上涌等因素的综合影响下,由泥质岩源区发生部分熔融而形成。     

西藏冈底斯中段桑桑花岗质岩体锆石U-Pb年龄与Hf同位素组成及其对岩石成因和构造演化的制约

以西藏冈底斯中段西侧桑桑花岗质岩体为对象,进行了系统的年代学、元素地球化学和锆石Hf同位素组成研究,据此阐明了岩体成因,并探讨了其构造意义。锆石LA-ICP-MS U-Pb定年表明,桑桑花岗质岩体的成岩年龄为49~54 Ma。化学组成上,岩体具有亚碱、准铝、贫磷的特征(A/NKC1.10,P_2O_50.20%),属钙碱性I型花岗岩类。岩体富Cs、Rb、Ba、Th、U、K、Pb和轻稀土,贫Nb、Ta、P与Ti,表现出弧岩浆岩的地球化学特征。岩体的锆石εHf(t)值变化较大,散布于正值与负值之间(=-4.24~+5.49),指示其形成存在不同来源物质的贡献。综合分析表明,桑桑花岗质岩体起源于初生地壳的部分熔融,但在成岩过程中有古老地壳组分的参与。结合区域地质背景,笔者认为这一古老地壳组分最可能来自印亚碰撞过程中俯冲下插的印度地壳,由此说明印度-欧亚大陆碰撞的起始时间应早于54 Ma。     

华北板块南缘伏牛山花岗岩锆石LA-MC-ICP-MS U-Pb定年、Lu-Hf同位素特征及岩石成因

伏牛山花岗岩体出露于华北板块南缘,南召县城以北,面积超过4200km~2。岩体的岩石组合为花岗岩+花岗闪长岩+石英闪长岩,具有I型花岗岩的特征。花岗岩锆石的LA-MC-ICP-MS U-Pb定年得到145.4±1.0Ma和118.5±0.6Ma,说明岩体形成于燕山期,并经历了至少两期岩浆活动。锆石Hf同位素分析表明,第一期花岗岩的ε_(Hf)(t)平均值为-16.53,二阶段模式年龄(t_(DM2))平均为2216Ma,表明其源岩以壳源物质为主;第二期花岗岩的源岩分为两个部分,一部分花岗岩的ε_(Hf)(t)平均值为-13.67,二阶段模式年龄(t_(DM2))平均为2044Ma,表明其源岩以壳源物质为主,另一部分花岗岩的ε_(Hf)(t)平均值为1.61,二阶段模式年龄(t_(DM2))平均为1073Ma,表明其源岩以新生地壳为主。根据研究结果及区域地质构造分析,认为第一期岩浆作用是由于太平洋板块俯冲导致秦岭造山带断裂构造再活动,发生部分熔融形成小规模的岩浆作用;而第二期岩浆作用是由于太平洋板块俯冲导致岩石圈拆沉,使地幔软流圈的物质上升,形成巨大的热场,引起大陆地壳大规模的部分熔融形成花岗岩浆。最终形成的花岗岩浆沿着华北板块与扬子板块之间的断裂上侵至地壳浅处,形成了伏牛山复式岩体。     

张广才岭燕山早期白石山岩体成因与壳幔相互作用

出露于东北地区张广才岭的白石山岩体,其全岩-矿物Rb-Sr等时线年龄为196士4 Ma,表明形成于中生代的燕山早期,而非传统认识上的印支期.岩体主岩和闪长质包体均具有低ISr(≈0.705)和正εNd(t)(+1.7～+2.2)值的特点,反映岩体成因与地幔具有密切的联系.地质学、岩石学和地球化学的详细研究表明该岩体具有壳幔混合成因,闪长质包体是较基性的地幔岩浆进入主岩浆中淬火结晶而成,花岗质岩浆的源区主要为新生的地壳物质.动力学分析表明,本区在华北板块和西伯利亚板块碰撞拼合后,由于东侧大洋板块的俯冲及后续的岩石圈拆沉效应,导致软流圈地幔上隆及幔源岩浆的板底垫托,并进而造成先存和新生地壳的部分熔融和不同源区岩浆的混合作用.底垫的新生地壳是兴蒙造山带造山后晚期形成的.因此,古生代-中生代是本区地壳生长的重要时期,且这种地壳生长是在垂向构造机制下进行的.     

湖南川口岩体型钨矿赋矿花岗岩地球化学特征及LA-ICP-MS锆石U-Pb定年

川口矿田钨矿床产于湖南衡阳川口岩体的外接触带及岩体内部,矿床类型主要有岩浆热液石英细脉带型和石英大脉型。近年川口矿田取得了重大找矿突破,并发现了新类型的岩体型钨矿。本文对川口岩体型钨矿床的黑云母二长花岗岩及赋矿的白云母二长花岗岩分别进行了 LA-ICP-MS锆石U-Pb定年和岩石地球化学特征研究,获得川口岩体的成岩年龄为(223.1 ± 0.78)Ma,MSWD=0.98,n=24,岩体型钨矿成矿年龄为(224.6±1.31)Ma,MSWD=0.33,n=9,为印支期成岩成矿。川口花岗岩具有高SiO_2,富K_2O+Na_2O,低CaO、MgO的特点,属于过铝质高钾钙碱性系列S型花岗岩,形成于碰撞环境下弱挤压构造体制。川口岩体稀土总量(∑REE)整体较低,轻稀土相对较富集,具有强烈的负Eu异常,富集大离子亲石元素Ba、K和高场强元素Ta,而亏损大离子亲石元素Sr和相容元素P、Ti等,表明该岩体各阶段花岗岩来自同一岩浆源,且经历了高度演化。赋矿花岗岩更低的δEu值及(La/Yb)_N值,表明其结晶分异程度更高。     

内蒙古苏尼特左旗地区阿木乌岩体LA-ICP-MS锆石U-Pb年龄及其地球化学特征

对苏尼特左旗地区阿木乌岩体进行LA-ICP-MS锆石U-Pb测年、主量元素、稀土元素和微量元素测试分析。结果表明,岩体成岩年龄为235.1±3.2 Ma,属中三叠世。岩体具有高SiO2、富K2O、低CaO、低TiO2的特征。强烈亏损Sr、Ba、Ti、P等元素,富集K、Rb、Th等亲石元素,具有右倾"海鸥型"球粒陨石标准化稀土配分型式及强烈的负铕异常等特点。A/CNK=0.77～1.19,A/NK=1.26～1.64,表明阿木乌岩体具有偏铝质A型花岗岩的特征。具有较高的Y/Nb值(2.31～3.001.2),显示出A2型花岗岩的特征,说明岩体形成于造山后的伸展环境。     

Zircon U-Pb ages and Hf isotopic characteristics of the Dehe biotite monzonitic gneiss pluton in the North Qinling orogen and their geological significance

The Dehe granitic pluton intruded the Xiahe Group which is in the core complex of the North Qinling Orogenic Belt(NQOB).It shows gneissic bedding and possesses typical S-type granite minerals such as muscovite and garnet.LA-ICP-MS U-Pb isotopic dating of the Dehe granite yielded a weighted average age of 925±23 Ma which represents the emplacement age of the pluton.Most of the εHf(t) values are negative,and the two-stage model ages are consistent with the age of the Qinling Group.The isotope data show that the Dehe granite was formed in the following geological setting:in the syn-collision setting of the NQOB in the Neoproterozoic,crustal thickening induced partial melting of materials derived from the Qinling complex,and then the maga upwelled and intruded into the Xiahe Group.The formation of the Dehe S-type granite implied the occurrence of a convergent event in the QOB during the Neoproterozoic.     

Timing of Magma Mixing in the Gangdisě Magmatic Belt during the India-Asia Collision： Zircon SHRIMP U-Pb Dating

Abstract  Abundant mafic microgranular enclaves (MMEs) extensively distribute in granitoids in the Gangdisê giant magmatic belt, within which the Qüxü batholith is the most typical MME‐bearing pluton. Systematic sampling for granodioritic host rock, mafic microgranular enclaves and gabbro nearby at two locations in the Qüxü batholith, and subsequent zircon SHRIMP II U‐Pb dating have been conducted. Two sets of isotopic ages for granodioritic host rock, mafic microgranular enclaves and gabbro are 50.4±1.3 Ma, 51.2±1.1 Ma, 47.0±1 Ma and 49.3±1.7 Ma, 48.9±1.1 Ma, 49.9±1.7 Ma, respectively. It thus rules out the possibilities of mafic microgranular enclaves being refractory residues after partial melting of magma source region, or being xenoliths of country rocks or later intrusions. Therefore, it is believed that the three types of rocks mentioned above likely formed in the same magmatic event, i.e., they formed by magma mixing in the Eocene (c. 50 Ma). Compositionally, granitoid host rocks incline towards acidic end member involved in magma mixing, gabbros are akin to basic end member and mafic microgranular enclaves are the incompletely mixed basic magma clots trapped in acidic magma. The isotopic dating also suggested that huge‐scale magma mixing in the Gangdisê belt took place 15–20 million years after the initiation of the India‐Asia continental collision, genetically related to the underplating of subduction‐collision‐induced basic magma at the base of the continental crust. Underplating and magma mixing were likely the main process of mass‐energy exchange between the mantle and the crust during the continental collision, and greatly contributed to the accretion of the continental crust, the evolution of the lithosphere and related mineralization beneath the portion of the Tibetan Plateau to the north of the collision zone.