内蒙古乌拉山大桦背岩体成因:地球化学、锆石U-Pb年代学及Sr-Nd-Hf同位素制约

大桦背岩体由钾长花岗岩和似斑状黑云母二长花岗岩组成。锆石LA-MC-ICP-MS U-Pb定年获得其侵位年龄为328.3±1.5Ma,表明该岩体属早石炭世岩浆活动产物。大桦背岩体总体上富硅(Si O2=70.59%~76.04%)、富碱(Na2O+K2O=8.41%~8.99%)、准铝质-弱过铝质(A/CNK=0.98~1.11),形成温度较低(620~810℃),属于高分异高钾钙碱性I型花岗岩。岩石富集大离子亲石元素K、Rb、Th、U和LREE,亏损高场强元素Nb、Ta、Ti、P和HREE,具有较高的Th/Ta比值(10.30~21.60)及较低的Ce/Pb比值(0.90~3.13),显示大陆弧岩浆岩地球化学特征。除暗色微粒包体广泛发育外,岩体具有均一Sr-Nd同位素组成((87Sr/86Sr)i=0.704799~0.706272,εNd(t)=-8.8~-8.2)和较大变化范围的锆石Hf同位素(εHf(t)=-8.3~-2.6),暗示岩体为岩浆混合成因。结合区域地质背景,认为大桦背岩体的形成与古亚洲洋向华北克拉通之下的俯冲密切相关,是俯冲板片流体交代诱发熔融的岩石圈地幔岩浆与下地壳岩浆相混合的产物。混合岩浆在上升侵位过程中又发生了显著的分离结晶作用和较弱的地壳物质的同化混染。     

Improved Inter‐calibration of Faraday Cup and Ion Counting for In Situ Pb Isotope Measurements Using LA‐MC‐ICP‐MS: Application to the Study of the Origin of the Fangshan Pluton,North China

A laser ablation multi‐collector inductively coupled plasma‐mass spectrometry (LA‐MC‐ICP‐MS) method was developed to obtain precise and accurate Pb isotopic ratio measurements in low‐Pb materials (< 10 μg g^?1) using a combination of Faraday cups and ion counters (FC–IC). The low abundance ²⁰⁴Pb (~ 1.4%) was collected using an IC. A NBS 981 standard solution was used to cross‐calculate the FC–IC gain and to investigate the signal response characteristics of the IC. A significant, continuous and linear decrease in the FC–IC gain was observed within 1 hr, but this drift could be corrected using the calibrator‐sample‐calibrator bracketing method. In addition, a non‐linear response of the IC used in this study was observed and corrected by a non‐linear correction algorithm, which was established by measuring a series of gravimetrically prepared NBS 981 standard solutions (NIST SRM 981). Compared with the conventional arrangement, the use of the newly designed X skimmer cone and Jet sample cone improved the signal intensities from Pb isotopes by a factor of 1.9. Compared with only Faraday cups, using a combination FC–IC array was found to enhance the measurement repeatability (RSD) of ^20xPb/²⁰⁴Pb by approximately one order of magnitude when the ²⁰⁴Pb intensity was < 8 mV. Eight natural glasses and the NIST SRM 612 reference material glass (as a calibration material) were measured to evaluate the new protocol for Pb isotope determination. The analytical results were in agreement with the reference values within 2s measurement uncertainties. For MPI‐DING ATHO‐G (5.67 μg g^?1 total Pb), KL2‐G (2.07 μg g^?1 total Pb) and ML3B‐G (1.38 μg g^?1 total Pb), the typical accuracies of ^20xPb/²⁰⁴Pb were 0.09% of preferred values with precisions of < 0.33% (2RSD). The Pb isotope ratios in feldspars from granodiorite and within mafic microgranular enclaves (MMEs) from the Fangshan pluton, North China, were measured using the present method. The Pb isotopic compositions of feldspars from the whole host granodiorite show that that are radiogenic in the margin zone and gradually become less radiogenic. For the MMEs, the Pb isotopic compositions of feldspars are highly variable and overlap with those of the whole host granodiorite. For single‐grain feldspar, the strong rim‐core‐rim variations of the Pb isotopic compositions and trace elements are interpreted to have been generated via magma mixing. These results suggest that the Fangshan pluton underwent magma mixing of mantle‐derived mafic magmas with felsic magmas, and the proportion of the mafic magma influx decreased over time.     

湖南大义山、塔山岩体锆石U-Pb年龄及其构造意义

华南中部地区大义山、塔山等早中生代花岗岩的展布和侵入特征与这一时期褶皱构造之间存在着非常密切的关系,对这些岩体进行精确年代学研究,可以为构造变形时代提供年代学约束。大义山岩体南部地区锆石U-Pb LA-ICP-MS年龄为东缘(171.8±1.9)Ma、西缘(169.9±1.8)Ma、中部(164.2±2.6)Ma,塔山岩体东段为(247±5.9)Ma。大义山岩体在164.2—171.8 Ma之间经历两个期次的侵入,形成了一个复式岩体,岩体形成后至125 Ma经历了快速隆升,之后以接近1°C/Ma的冷却速率抬升到地表。大义山和塔山岩体记录了华南早中生代印支和燕山两期重要的岩浆活动。阳明山、塔山岩体等E—W向展布岩体受印支期构造带控制;大义山、骑田岭等岩体年龄限定了燕山期构造地层的变形下限时代,华南地区NNE向褶皱构造形成时代应早于(171.8±1.9)Ma。     

花岗岩铀地球化学特征新认识——以赣南富城产铀花岗岩体为例

对富城花岗岩U、Th含量分析结果进行的频数统计分析表明富城花岗岩U的均值为8．92×10＾－6、众数为8．0×10＾－6、中位数为7．03×10＾－6,其概率密度曲线偏向高端呈右偏非对称分布（偏度系数CSK＝1．10）。Th的均值、众数和中位数三者一致,分别为25．7×10＾－6,25．75×10＾－6,25．8×10＾－6,其概率密度曲线呈对称正态分布（偏度系数CsK＝0．11）。核诱发裂变径迹研究查明富城花岗岩中铀有4种存在形式：（1）显微粒状铀矿物（晶质铀矿）;（2）以类质同像形式存在于锆石、磷灰石等副矿物之中;（3）均匀分散赋存在造岩矿物晶格之中的结构铀;（4）沿造岩矿物（长石、石英）微裂隙及粒间分布的非结构铀。对富城花岗岩铀配分研究发现,赋存在造岩矿物中均匀分散状的结构铀含量与全岩铀不呈消长关系,而是存在一定的极限值：长石、石英〈3X10＾－6,白云母〈5×10＾－6,黑云母〈9×10＾－6。溶浸实验结果表明,富城花岗岩活动性铀浸出率很高（平均值52％）,为富城花岗岩具有较大铀成矿潜力提供了佐证。     

南秦岭新院岩体及其包体的锆石SHRIMPU-Pb定年和意义

南秦岭新院岩体位于略阳县城以北约35 km处,呈椭圆形,出露面积约200 km2,主要岩性为花岗闪长岩,岩体中含有大量的铁镁质微粒包体和细晶岩脉.锆石SHRIMP U-Pb定年结果表明,花岗闪长岩的结晶年龄为219.6±4.6 Ma,其中的铁镁质微粒包体的结晶年龄为2 21.5±4.2 Ma,晚于勉县—略阳洋盆闭合时期...     

南秦岭西坝花岗质岩体矿物学特征及成岩意义

西坝花岗质岩体位于南秦岭构造-岩浆带中部,为南秦岭印支期花岗岩带五龙岩体群的重要组成部分,与双王金矿有密切的空间关系。该岩体主要由石英二长闪长岩和花岗闪长岩组成,岩体中发育较多的镁铁质包体。通过对岩体及镁铁质包体的系统的矿物学特征研究发现,本区花岗质岩体属于I型花岗岩类,成岩物质主要来源于地壳,并且有地幔物质的加入。岩体及镁铁质包体显示有多种壳-幔岩浆混合的岩相学证据:如包体的冷凝边、斜长石环带成分显示核部和边缘偏基性,而幔部偏酸性,包体中见大量的长针状磷灰石及角闪石,包体中有两种产状的角闪石等。根据矿物温度压力计计算,西坝岩体的结晶温度为646.72~703.84℃,压力为1.67×108~3.66×108Pa,平均为3.12×108Pa。岩体形成于相对高氧逸度(lgfO2为-16.16×105~-17.06×105Pa)、中等水逸度(fH2O为46.82×105~136.85×105Pa)和氢逸度(fH2为0.32×105~0.91×105Pa)环境。岩体的这种高氧逸度条件有利于金进入熔体相或流体相,是金矿形成的有利条件。     

Metasomatic Stages and Scapolitization Effects on Chemical Composition of Pasveh Pluton,NW Iran

Pasveh gabbros are mafic component of a plutonic complex in the northwest Sanandaj-Sirjan Zone.These cumulative rocks are composed of plagioclase and calcic clinopyroxene(Cpx) ,which yield unusually high CaO(>19 wt.%) in whole-rock chemistry.Petrographical and geochemical data suggest that Pasveh gabbros can be divided into two groups:free scapolite and scapolite-bearing gabbros.The second group has higher Na2O,K2O,and P2O5 relative to free scapolite ones and is enriched in LIL(large ion lithophile) and HFS...     

东昆仑造山带白日其利辉长岩体LA-ICP-MS锆石U-Pb年龄及地质意义

东昆仑中段的白日其利基性岩体由橄榄辉长岩、斜长岩和角闪辉长岩组成.主体岩相角闪辉长岩的锆石LA-ICP-MSU-Pb年龄表明,其侵位于248.9Ma+4.2Ma,为早三叠世阿尼玛卿古特提斯洋关闭过程中的岩浆活动.结合前人的研究,认为东昆仑造山带中生代岩浆混合作用至少始于早三叠世,白日其利岩体为研究俯冲阶段岩浆混合作用提...     

浙江绍兴地区广山-栅溪岩体LA-ICP-MS锆石 U-Pb定年:对漓渚铁矿成矿时代的限定

选取与漓渚铁矿成矿关系密切的栅溪和广山岩体为研究对象,采用高精度的LA-ICP-MS锆石U-Pb定年方法对栅溪岩体黑云母花岗岩和广山岩体花岗斑岩代表性样品进行了详细的测年工作,在此结果的基础上,结合区域上矿床成矿的时代,讨论了漓渚铁矿的成矿时代。定年结果显示,栅溪岩体的成岩时代为150.1Ma±2.6Ma,而广山岩体经历了多期的岩浆事件,主体成岩时代为147.2Ma±1.7Ma,2个岩体均属于燕山早期岩浆活动的产物。矿区地质特征显示,漓渚铁矿的形成与广山、栅溪岩体成岩期岩浆热液作用关系密切,广山-栅溪岩体的成岩时代即代表了漓渚铁矿矿化的时代,漓渚铁矿矿体主要形成于中侏罗世(约150Ma)。漓渚铁矿成矿时代的精确厘定为邻区寻找同类型矿床指明了方向。     

The zoned Bruinbun granitoid pluton and its aureole

The Bruinbun pluton is a small, massive, I‐type granitoid intruded into the meta‐sedimentary Hill End Trough, in eastern N.S.W. It is a multiple pluton representing two discrete magma pulses, the granodiorite core intruding the adamellite margin. A weak alignment of orthoclase megacrysts in the granitoids is best developed adjacent to both the internal and external intrusive contacts, and is considered by the writer to be a product of magmatic flow. Part of the northern contact and the southern and western contacts dip inward at moderate angles, whereas the eastern contact is vertical to outward‐dipping. The pluton is inferred to be mushroom‐shaped, and slightly tilted.

The intensity of aureole deformation is low. The aureole has been flexed into concordancy with the pluton roof, and a rudimentary rim fold‐zone is present around lower levels of the pluton. Intrusion of the granitoid is inferred to be primarily by uplift of its roof and depression of its floor.

The highest‐grade contact metamorphic parageneses developed are: cordierite‐K feldspar‐biotite‐quartzite ± andesine ± epidote in metapelites, and ferrohornblende‐biotite‐muscovite‐andesine‐epidote‐quartz in metavolcarenites. No intrusion‐related foliation or lineation was formed.