A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).     

Diagenetic history and porosity evolution of Upper Carboniferous sandstones from the Spring Valley #1 well, Maritimes Basin, Canada–implications for reservoir development

Eighty-two core samples were collected from the Spring Valley #1 well which penetrates the Upper Carboniferous strata in the Late Devonian–Early Permian Maritimes Basin. The strata consist of alternating sandstones and mudstones deposited in a continental environment. The objective of this study is to characterize the relationship of sandstone porosity with depth, and to investigate the diagenetic processes related to the porosity evolution. Porosity values estimated from point counting range from 0% to 27.8%, but are mostly between 5% and 20%. Except samples that are significantly cemented by calcite, porosity values clearly decrease with depth. Two phases of calcite cement were distinguished based on Cathodoluminescence, with the early phase being largely dissolved and preserved as minor relicts in the later phase. Feldspar dissolution was extensive and contributed significantly to the development of secondary porosity. Quartz cementation was widespread and increased with depth. Fluid inclusions recorded in calcite and quartz cements indicate that interstitial fluids in the upper part of the stratigraphic column were dominated by waters with salinity lower than that of seawater, the middle part was first dominated by low-salinity waters, then invaded by brines, and the lower part was dominated by brines. Homogenization temperatures of fluid inclusions generally increase with depth and suggest a paleogeothermal gradient of 25 °C/km, which is broadly consistent with that indicated by vitrinite reflectance data. An erosion of 1.1–2.4 (mean 1.75) km of strata is inferred to have taken place above the stratigraphic column. δ¹⁸O values of calcite cements (mainly from the late phase) decrease with depth, implying increasing temperatures of formation, as also suggested by fluid-inclusion data. δ¹³C values of calcite cements range from −13.4‰ to −5.7‰, suggesting that organic matter was an important carbon source for calcite cements. A comparison of the porosity data with a theoretical compaction curve indicates that the upper and middle parts of the stratigraphic column show higher-than-normal porosity values, which are related to significant calcite and feldspar dissolution. Meteoric incursion and carboxylic acids generated from organic maturation were probably responsible for the abundant dissolution events.     

Early Cretaceous planktonic foraminifera from the Tethys: the large, many-chambered representatives of the genus Globigerinelloides

This paper deals with the taxonomic revision of the Early Cretaceous large, many-chambered planispiral planktonic foraminifera, historically assigned to the genus Globigerinelloides or alternatively assigned in the 1990s to the genera Globigerinelloides Cushman and ten Dam, Biglobigerinella Lalicker, Blowiella Krechmar and Gorbachik and Alanlordella BouDagher-Fadel. In a previous paper we demonstrated that the morphological and microstructural features used in the literature for distinguishing Blowiella from Globigerinelloides have value only at species level, and the former genus was thus invalidated (being the junior synonym). Moreover, the Late Aptian specimens assigned to Biglobigerinella by some authors, based on the presence of twin last chamber(s), are also included in Globigerinelloides because individuals sharing the same features (number of chambers, growth rate, size of umbilicus, and a finely perforate wall) may or may not possess twin last chamber(s). Meanwhile, Moullade et al. questioned the taxonomic value of Alanlordella, erected by BouDagher-Fadel to accommodate planispiral taxa possessing a macroperforate wall. All the species analysed here possess a finely perforate wall and consequently cannot be assigned to this taxon.The large species of Globigerinelloides retained here, with six or more chambers in the outer whorl, are G. algerianus Cushman and ten Dam, G. aptiensis Longoria, G. barri (Bolli, Loeblich and Tappan) and G. ferreolensis (Moullade).In the sections studied, Globigerinelloides aptiensis was first found close to the Barremian/Aptian boundary, even though this species was recorded in Spain (Rio Argos) in the mid Upper Barremian; very rare, small, seven-chambered individuals here assigned to Globigerinelloides ferreolensis are recorded in the Lower Aptian (just below and within the Selli Level, OAE1a), while a few specimens belonging to Globigerinelloides barri occur in the Globigerinelloides ferreolensis Zone (Upper Aptian). Globigerinelloides aptiensis and G. ferreolensis range up to the Ticinella bejaouaensis Zone while Globigerinelloides barri disappears at the top of the Globigerinelloides algerianus Zone; finally, Globigerinelloides algerianus obviously spans the eponymous total range zone.From an evolutionary point of view, two lineages within the many-chambered Globigerinelloides have been recognized. In the first, already known in the literature, Globigerinelloides aptiensis gave rise to G. ferreolensis, which evolved into G. algerianus; the latter in turn gave rise to Pseudoplanomalina cheniourensis as the final evolutionary member. In the second lineage Globigerinelloides barri originated from G. blowi.     

昆仑山口西8.1级地震前青藏块体边界断层异常活动

系统分析了青藏块体边界断层的形变资料，研究了断层活动的动态过程及空间分布。结果表明，昆仑山口西8．1级地震前孕震影响范围达到青藏块体的周边地区；发震断层所在的构造带震前断层活动最为剧烈；加强对构造块体断层整体活动的宏观动态比较和分析，有助于判定未来强震发生的危险地段；震后应力将转移并集中到西秦岭构造带及其邻近地区。     

2001年11月14日昆仑山口西8.1级地震前地震活动性异常及其思考s

2001年11月14日在昆仑山口西发生了8.1级地震，震中位置为90.9E、36.2N．分析表明，8.1级地震前一些主要地震活动性异常都出现了，例如空区、条带、增强、平静和震群等，且与7级大震比较，这些前兆图象的演变具有类似的过程，所不同的是8.1级地震的前兆地震活动图象涉及的区域范围更大、地震震级更高，这为特大地震的前兆识别和预报提供了依据．最后回顾了对这次大震的粗略预测，并讨论了有关大震预测的某些问题．      

禾青井动水位对断层蠕动与慢地震过程的响应初析

以湖南禾青井深井水位观测的异常图象为例进行定性分析，发现动水位观测有可能直接反映出断层的滑动或断层的慢地震过程，前者可能为地下水物理参量的观测与研究提供亲折思路，后者则可能对震源物理学的发展和地震预报水平的提高具有特殊的意义。     

井孔变径与井水位的固体潮效应

根据多孔介质渗流理论和弹性理论，在井孔变径条件下，得出水井含水层系统对潮汐信号响应的偏微分方程，认为井径变化相当于改变了井水柱的有效高度，从而影响了水井含水层系统的固有振动周期。分析了井孔变径对潮汐信号响应的周期特征，认为当含水层水体很大（含水层水平面积比井孔面积大得多），且含水层的渗透系数也很大的条件下，井径变化对井水位固体潮响应幅度影响很小     

Pb同位素三维空间拓扑投影与化探评价

通过对数据集合的拓扑学分析，获得了Pb同位素三维空间拓扑投影特征值V1和V2。运用特征值可以定量地预测隐伏铜金矿床的埋藏深度和隐伏矿量，是隐伏矿预测评价的新方法，开创了同位素化探的新领域。     

IAEA-S-1 参考物质及V-CDTS 同位素标准的32S/34S绝对比值

采用高纯S同位素物质和SF6的分析方法对IAEA-S-1参考物质及V-CDT S同位素标准的32S/34S绝对比值进行了实验标定，V-CDT的32S/34S比值为22.6496±0.060，IAEA-S-1的32S/34S比值为22.6564±0.0060.     

金属成矿学研究的若干进展

主要讨论近１０年来国内外在金属矿床地质研究中的若干进展，内容包括：成矿地质环境和深部背景；矿床、成矿带和全球的成矿作用演化；成矿系统和成矿动力学；地质流体与成矿作用以及超大型矿床的形成条件等。在这５个重点研究领域中，分别介绍了对它们的研究和已取得的一些进展，又展望了其在今后的研究前景。认为上述５个方面的系统深入研究，将构成２１世纪上半世纪新的成矿理论基础，并将对金属矿产勘查工作有重大影响。