藏南侏罗纪残留洋弧的地球化学特征及其大地构造意义

沿雅鲁藏布江缝合带残留一系列中生代洋弧,厘定这些洋弧的形成时代和地球化学性质对于理解新特提斯洋的消减过程、确定南拉萨地体的组成和限定印度-欧亚板块的碰撞时限等都具有重要的意义。泽当微地体位于雅鲁藏布江缝合带东段,主要由英云闪长岩、花岗闪长岩和角闪岩组成。SHRIMP锆石U-Pb定年结果表明,位于泽当西部的花岗闪长岩(简称泽当花岗闪长岩)形成于157.5±1.4Ma,与东部的英云闪长岩形成时代相近。全岩元素和同位素(Sr和Nd)地球化学分析结果表明泽当花岗闪长岩具有以下地球化学特征:(1)较高的SiO2(64.4%～68.4%)和Al2O3(16.9%～18.4%);(2)较高的Na2O/K2O比值(>2.1),显示富钠的特征;(3)富集LREE,亏损HREE,从Ho到Lu稀土分布样式上翘((Ho/Yb)N=0.69～0.90)和明显的Eu负异常;(4)较低的Y(<7.19×10-6)和Yb(<0.88×10-6),较高的Sr/Y>119.7和La/Yb>22.4,在Sr/Y-Y和La/Yb-Yb图解中,泽当花岗闪长岩都落入埃达克岩区域内;(5)87Sr/86Sr(t)(0.704065～0.704439)值较低,εNd(t)(+5.1～+6.1)值较高,显示其来自亏损地幔的特征;(6)亏损Zr、Hf、Ti和Y等高场强元素,富集大离子亲石元素,显示了岛弧岩浆岩的典型特征。上述数据表明,泽当花岗闪长岩不仅具有明显的岛弧岩浆岩的特征,而且具有显著的埃达克质特征,可能是在来自地幔楔部分熔融体的板底垫托作用下,新生基性下地壳重熔的产物。泽当微地体是一个残留的晚侏罗纪洋弧系统,是中生代新特提斯洋洋内俯冲系统的残留。     

Experiments on the Element Distribution between the Granodiorite JG-1a and 2M NaCl Hydrothermal Solution at Temperatures of 300 to 800°C and a Pressure of 1 kb

Abstract. The distribution of Na, K, Ca, Mg, Mn and Fe between the granodiorite JG-la, one of the geochemical standard rocks, and 2M NaCl aqueous solution was experimentally determined at temperatures of 300 to 800C and a pressure of 1 kb using standard cold seal-type pressure vessels. The solid run products melted partially at 800C. Only K shows a significantly different behavior from the experiments using the basalt JB-la (Uchida and Tsutsui, 2000) due to the presence of ortho-clase in the JG-la. The transition elements tend to be preferably partitioned into the aqueous chloride solutions with increasing temperature. At 800C and 1 kb, the Fe concentration of the aqueous chloride solutions reached up to 5,000 ppm, and the Mn concentration up to 350 ppm. The distribution coefficient, K_{D, i} = C_{i, sol}/C_i, rock, is in the order of Na>K>Mn>Ca> Fe>Mg at 300C, but changed in the order of Mn>N>K>Fe>Ca>Mg at 800C. The distribution coefficients of the divalent cations for the JG-la are higher than those for the JB-1a. The distribution coefficient of the transition elements, Fe and Mn, increases significantly with increasing temperature. The thermodynamic analysis for aqueous speciation revealed that this is attributable to the formation of the tri-chloro complexes of the transition elements at higher temperatures.     

广西苍梧宝山铜多金属矿床花岗岩锆石U-Pb年龄及其地质意义

广西苍梧县宝山矿床位于大瑶山隆起区的东南部,是一个与石英斑岩有关的铜多金属矿床。本文对该矿区内花岗闪长岩、细粒花岗岩和石英斑岩进行了单颗粒锆石LA-ICP-MS U-Pb测年,获得了3件花岗闪长岩的~(206)Pb/~(238)U加权平均年龄分别为433.7±1.2 Ma、435.0±1.2 Ma和449.7±2.3 Ma;1件细粒花岗岩的~(206)Pb/~(238)U加权平均年龄为100.4±0.5 Ma,2件石英斑岩样品的~(206)Pb/~(238)U加权平均年龄分别为95.4±0.7 Ma和92.5±0.5 Ma。本文认为,宝山矿区存在晚奥陶世、早志留世、早白垩世晚期和晚白垩世早期等多期岩浆活动,与成矿有关的石英斑岩锆石U-Pb年龄揭示宝山铜铅锌多金属矿床形成于晚白垩世早期。这些高精度花岗岩锆石U-Pb测年数据为进一步深入研究大瑶山地区的岩浆活动及其成矿作用提供了重要的年代学依据。     

K-Ar法同位素地质年龄测定标准样——ZBH-黑云母的矿物特征

作为中国K-Ar法同位素地质年龄测定标准样的ZBH-黑云母取自北京房山花岗闪长岩体。该黑云母在结晶以后,放射成因~(40)Ar在矿物晶格中保存良好,没有遭受热力扰动,它完全适合用作K-Ar法同位素地质年龄测定的标准样。     

Chemical and physical weathering in a hot‐arid,tectonically active alluvial system of Anza Borrego Desert,California

Investigation of chemical and physical weathering of bedrock and alluvial sediment in the Anza Borrego Desert, California, sheds light on weathering processes in hot‐arid systems and clarifies interpretations of climate from alluvial sediment. All of the alluvial sediment in the study area emanates from Cretaceous tonalite of the Peninsular Range, enabling exploration of the effects of external variables – climate, transport distance and tectonics – on the physical and chemical properties of the sediment. Chemical weathering in this area is dominated by plagioclase alteration observed in both bedrock outcrops and sediment, evinced most clearly by changes in the Eu anomaly. Biotite chemical weathering, manifested by interlayer K⁺ loss, is not evident in bedrock, but clearly observed in the sediment. Despite the weak intensity of chemical weathering (Chemical Index of Alteration = 56 to 62), fine‐grained (<63 μm) sediment displays a clear weathering trend in A–CN–K space and contains up to 25% clay minerals. Physical abrasion and grain‐size reduction in biotite during transport predominates in the sediment, whereas physical (insolation) weathering affecting bedrock is inferred from estimates of differential thermal expansion of mineral phases in response to extreme temperature changes in the study area. Chemical alteration and Brunauer–Emmett–Teller surface area both increase within the active Elsinore fault zone at the distal end of the depositional transect, reflecting tectonic‐induced fracturing and associated accelerated weathering. Extensive fracturing, together with a more humid Pleistocene climate, probably facilitated in situ bedrock weathering, preceding arid alluvial deposition in the Holocene. This study demonstrates that both climate and tectonic processes can affect chemical and physical weathering, resulting in alteration of plagioclase, leaching of K⁺ from biotite in the sediment and formation of clay minerals, even in hot, arid systems.     

Genesis of Mafic Microgranular Enclaves in the Shaocunwu Granodiorite,Southern China,and their Implications: Evidence from Zircon and Whole-rock Geochemistry

Magmatic microgranular enclaves (MMEs) are widely developed in the Shaocunwu granodiorite at the northeast margin of the eastern Jiangnan orogenic belt.Field geology showed that the MMEs occur as irregular ellipsoids near the edge of the intrusion,and consist of diorite,dominantly composed of amphibole,biotite,and plagioclase grains,with minor acicular apatite.Zircon U-Pb dating showed the ages of the host granodiorites and MMEs are 145.9±1.1 Ma and 145.6±2.5 Ma,respectively,indicating both originated during coeval late Jurassic magmatism.Whole-rock geochemical results show that the host granodiorite and MMEs have similar rare earth and trace element partition curves in spider grams,and similar ~(87)Sr/~(86)Sr,and ~(147)Nd/~(144)Nd isotope ratios,and their zircon ~(177)Hf/~(176)Hf isotopic ratios are similar.Geochemical studies indicate that both the host granodiorite and MMEs formed by mixing of coeval magma.Zircon Ti thermometers and oxygen fugacity of the host granodiorite and the MMEs show high oxygen fugacity,similar to that of W-Cu (Mo) mineralized granitoids in the eastern Jiangnan orogenic belt.A similar magma mixing process was probably one of the mechanisms that generated the W-Cu (Mo) fertile melts.     

广东新丰新坪花岗闪长岩(104 Ma)地球化学、锆石U-Pb年龄和Hf同位素研究

新坪铜钼矿化花岗闪长岩体位于佛冈复式岩体中北部,LA-ICP-MS锆石U-Pb年龄为（104.6±1.8）Ma（MSWD=1.2）,侵位时间为早白垩世晚期。岩石呈中酸性（SiO₂=63.43%~65.27%）、准铝质（ACNK=0.76~0.92）、中等碱含量（ALK=6.09%~7.63%）和富钾钙碱性特征,富集轻稀土,LREE/HREE=8.26~13.20,（La/Yb）_N=8.17~16.64,轻微的铕亏损（δEu=0.73~0.87）,富集Rb、U、Th和La,亏损Nb、Ta、Ti和P、Ba、Sr。锆石ε_Hf（t）值为-3.0~0.2,Hf二阶段模式年龄t_DM2=1.16~1.36Ga,镁指数（Mg^#）=42.64~46.95,表明源岩主要为中元古代地壳物质,并有亏损地幔组分的参与。Nb/U和Nb/La比值分别为0.20~0.38和1.7~2.2,显示源区受古太平洋板块俯冲流体交代作用的影响。研究表明,新坪岩体成岩过程主要受部分熔融作用控制,形成于燕山晚期古太平洋板片俯冲消减作用下的伸展拉张环境,与玄武质岩浆底垫诱发中元古代结晶基底的部分熔融有关。早白垩世晚期为中国东南部晚中生代重要的Cu-Au-Mo成矿期,位于南岭中东段的新坪花岗闪长岩体与邻区闽西南紫金山铜多金属岩（矿）体形成时代一致、岩石地球化学特征较为相似,且野外能观察到明显的铜钼矿化,因此具有较好的铜钼找矿前景。     

Paleo-Tethyan Oceanic Crust Subduction in the Eastern Section of the East Kunlun Orogenic Belt: Geochronology and Petrogenesis of the Qushi'ang Granodiorite

The Qushi'ang granodiorite(QSG) is located at the central east of the ophiolitic melange belt in the East Kunlun Orogenic Belt(EKOB) in the northern margin of the Qinghai-Tibetan Plateau. LA-MC-ICP-MS zircon U–Pb dating suggests that the granodiorite and mafic microgranular enclaves(MMEs) crystallized 246.61±0.62 and 245.45±0.9 Ma ago, respectively. Granodiorite, porphyritic diorite, and MMEs are metaluminous and medium-K calk-alkaline series, with island-arc magma features, such as LILE enrichment and HFSE depletion. The porphyritic diorite has high Cr(13.50 ppm to 59.01 ppm), Ni(228.53 ppm to 261.29 ppm), and Mg~#(46–54). Granodiorite and porphyritic diorite have similar mineral compositions and evolved major and trace elements contents, particularly Cr and Ni, both of which are significantly higher than that in granites of the same period. The crystallization age of MMEs is close to that of granodiorite, and their major and trace elements contents are in-between porphyritic diorite and granodiorite. The results suggest that the original mafic magma, which was the product of mantle melting by subduction process, intruded into the lower crust(Kuhai Rock Group), resulting in the formation of granodiorite. Countinous intrusion of mafic magma into the unconsolidated granodiorite formed MMEs and porphyritic diorite. The granodiorite reformed by late-stage strike-slip faulting tectonic event indicates that the strike-slip fault of Middle Kunlun and the collision of the Bayanhar block with East Kunlun were later than 246 Ma. Therefore, the formation of the QSG not only indicates the critical period of evolution of East Kunlun but also represents the tectonic transition from oceanic crust subduction to slab breaking.     

Petrogenesis and W-Mo fertility indicators of the Gaojiabang “satellite” granodiorite porphyry in southern Anhui Province,South China

The Gaojiabang W-Mo mineralized granodiorite porphyry occurs as a “satellite” intrusion on the northern margin of the Qingyang-Jiuhua pluton in southern Anhui Province, South China. The geology, mineral and whole-rock geochemistry of the granodiorite porphyry is I-type and formed from a reduced melt. The Gaojiabang mineralized granodiorite porphyry was derived from the transition zone between the lower crust and upper mantle, and underwent high-degree fractional crystallization during emplacement. There is no obvious genetic relationship between the granodiorite porphyry and the granodiorite pluton of the Qingyang-Jiuhua plutonic complex. The key characteristics of the W-Mo mineralized Gaojiabang granodiorite porphyry include: 1) small volume (<0.5 km³), 2) an abundance of hornblende (>5 vol%), 3) low ∑REE concentrations (145.50–159.46 ppm) accompanying weak negative Eu anomalies (0.85–0.94), 4) high differentiation-indices degree and water contents, and 5) low oxygen fugacity. These criteria can be used to identify potential W-Mo mineralized intrusions in southern Anhui Province, South China.     

柴北缘牛鼻子梁地区花岗闪长岩锆石U-Pb年代学及地球化学研究

柴北缘牛鼻子梁地区的花岗闪长岩锆石U-Pb年代学及岩石地球化学研究结果表明,该花岗闪长岩的锆石LA-ICP-MS U-Pb谐和年龄为393.2~395.6Ma,对应的加权平均年龄为(394.4±2.4)Ma,表明该岩石形成于中泥盆世。岩石主量元素具有较高的SiO_2(65.70%~69.22%)和Al_2O_3(14.96%~16.03%)、较低的MgO(1.37%~1.89%)含量,A/CNK值为0.95~0.98,属于钙碱性、准铝质系列,具有I型花岗岩的特征,表明其岩浆起源于下地壳部分熔融。岩石稀土总量较高,无明显的Eu异常(δEu=0.95~1.30),富集轻稀土元素和K、Rb、Ba、U等大离子亲石元素,相对亏损重稀土元素和Nb、Ta、Ti、Th、Zr等高场强元素。综上可知,岩石具有碰撞后花岗岩的地球化学特征属性,结合区内晚泥盆世牦牛山组陆相火山岩和区域构造演化特征,认为牛鼻子梁地区的花岗闪长岩形成于柴达木地块与南祁连地块碰撞后的伸展环境。