西藏多龙矿集区花岗闪长斑岩地球化学特征及其意义

班公湖-怒江成矿带是近年来在西藏地区发现的继玉龙铜矿带和冈底斯铜矿带之后的又一成矿带,以多龙矿集区为典型代表,并具有巨大的找矿潜力。为了研究多龙矿集区内花岗闪长斑岩的地球化学特征、构造背景、物质来源等问题,对矿集区内北东向构造带上分布的拿顿、波龙、多不杂、拿若、铁格龙以及尕尔勤6个矿床的花岗闪长斑岩开展了系统的主微量元素以及Pb-Sr-Nd同位素研究。结果显示,花岗闪长斑岩K2O含量介于2.03%~6.07%之间,主要为高钾钙碱性和钾玄岩系列;富集大离子亲石元素(LILE:Rb、K等),而亏损高场强元素(HFSE:Nb、Ta、P、Ti);∑REE介于48.95×10-6~249.02×10-6之间,LREE/HREE为4.09~21.47,显示富集轻稀土元素,δEu为0.56~1.03,平均值为0.78;208Pb/204Pb在38.554~39.419之间,平均值为38.835,207Pb/204Pb在15.534~15.665之间,平均值为15.615,206Pb/204Pb在18.465~19.161之间,平均值为18.659,较为富集放射性成因铅,在铅同位素图解上位于造山铅演化线附近;(87Sr/86Sr)i在0.705 79~0.711 12之间,平均值为0.707 74;εNd(t)值介于-15.3~-1.7之间,平均值为-4.5。铅锶钕同位素显示壳幔混合特征。认为多龙矿集区形成于增生造山背景中,成矿背景为增生杂岩上发育的岛弧环境;含矿岩浆由俯冲板片释放的流体及熔体交代地幔并在上涌过程中得到地壳物质的加入而形成。多龙矿集区内矿床以及青草山和雄梅矿床等一系列成矿时代相近矿床的发现,表明在班公湖-怒江成矿带有望发现更多斑岩型铜矿床。     

黑龙江三矿沟铁铜矿床花岗闪长岩锆石U-Pb定年、岩石成因及构造意义

黑龙江三矿沟Fe-Cu矿床是中亚造山带东段大兴安岭北部裸河-多宝山-三矿沟NW向成矿带中矽卡岩型矿床的典型代表。LA-ICP-MS锆石U-Pb年代学表明,与成矿密切相关的黑云母花岗闪长岩的锆石谐和年龄和238U/206Pb加权平均年岭分别为175.9±1.6Ma和175.9±1.1Ma,二者在误差范围内具有良好的一致性,表明多宝山成矿区在早侏罗世晚期存在一期重要的岩浆-热液成矿事件。三矿沟花岗闪长岩的元素地球化学特征具有岛弧岩浆岩的地球化学亲缘性:岩石富钠(Na2O/K2O=1.39～1.59),准铝质(A/CNK=0.87～0.91),富集轻稀土元素(LREE),(La/Yb)N=8.02～10.45,Eu显示弱负异常(δEu=0.82～0.98),富集大离子亲石元素(LILE,如Rb、Ba、K)和元素地球化学性质活泼的不相容元素(U、Th、Pb),相对亏损高场强元素(HFSE,如Nb、Ta、Zr、Hf、Ti)。Sr-Nd-Pb同位素分析结果表明:三矿沟花岗闪长岩具有低的Sr同位素初始比值((87Sr/86Sr)i=0.7041～0.7045)、高的Nd同位素初始比值((143Nd/144Nd)i=0.512556～0.512576)、正的εNd(t)值(2.8～3.9)、年轻的二阶段亏损地幔模式年龄(tDM2=647～733Ma)和幔源铅同位素组成特征((206Pb/204Pb)t=18.121～18.418;(207Pb/204Pb)t=15.480～15.511;(208Pb/204Pb)t=37.628～37.713),上述同位素地球化学特征均显示花岗闪长质岩浆主要源于亏损地幔源区。结合东北地区区域构造演化和岩体微量元素及同位素组成特征反映该矿床形成于岛弧的构造背景,其形成可能与侏罗纪古太平洋板块的俯冲作用密切相关。     

皖南绩溪县靠背尖高Ba-Sr花岗闪长斑岩年代学及其成因

皖南绩溪县靠背尖花岗闪长斑岩侵位于新元古代南华系、震旦系和下古生界海相沉积盖层中,岩石学、地球化学研究表明其为高钾钙碱性系列准铝质Ⅰ型斑岩体,稀土、微量元素及Sm-Nd、Rd-Sr同位素数据指示其主要来自地壳重熔,并有幔源物质的加入.异常高的Ba-Sr含量源于对区域早期富Ba-Sr岩浆岩物质的继承,幔源物质的加入使岩浆由S型转为Ⅰ型.微量元素构造判别图指示其形成于岛孤环境.三件样品锆石SHRIMP U-Pb测年得出的年龄加权平均值分别为151.9±1.1Ma、147.7±1.3Ma和152.7±1.1Ma,表明岩体侵位于晚侏罗世.靠背尖岩体受后期热液影响广泛发育钾化、硅化等高温蚀变,并可能有高温条件的韧性变形,因此前人报道的黑云母40Ar/39 Ar年龄134.3±1.4Ma可能代表构造热事件的年龄.     

北大别山商城汤家坪富钼花岗斑岩体地球化学特征及构造环境

本文详细论述了汤家坪富钼花岗斑岩的地球化学特征,利用图解判别了其形成的构造环境,并初步探讨其成因机制。研究认为汤家坪花岗斑岩化学成分具超酸(SiO2 72.94%～77.9%)、富碱(K2O+Na2O为7.06%～9.66%),贫钠富钾(K2O/ Na2O为1.21～2.12)等特点,属超酸性铝不饱和高钾钙碱性系列岩浆岩,轻稀土明显富集,重稀土亏损,(La/Yb)N在18.12～23.52之间,具较平坦的HREE配分模式,铕异常系数（δEu）0.46～0.59,铕负异常中等。汤家坪花岗斑岩体形成于华北地块和扬子地块陆—陆主碰撞期后,区域伸展机制下的后碰撞构造环境。通过对岩体中角闪安山岩包体的研究表明,花岗斑岩的形成与加厚下地壳拆沉作用密切相关,拆沉作用引起下地壳不同深度位置的岩石同时发生部分熔融,后侵位的角闪安山岩浆与早期花岗岩浆在通道内发生混合作用。软流圈减压熔融流体系统提供了岩浆侵位动力和成矿物质来源。     

临汾断陷盆地孤峰山花岗闪长岩的地球化学和年代学及其地质意义

临汾断陷盆地孤峰山花岗闪长岩的SiO2含量为64.62%-65.57%,具有富碱(Na2O+kO=7.38%-7.71%)、富钠(Na2O/K2O=1.37-1.54)、准铝质(A/CNK=0.94-0.99)和较低镁指数(M9#=31.8-36.2)的特点,属于高钾钙碱性岩系.岩石明显富集轻稀土[(La/Yb)N=1...     

大兴安岭乌奴耳地区石炭纪花岗闪长岩锆石U-Pb年龄及形成地质背景

对乌奴耳地区花岗闪长岩进行的LA-ICP-MS锆石U-Pb测年和岩石地球化学测试结果表明:花岗闪长岩的锆石U-Pb加权平均年龄为332.6±6.9Ma(MSWD=3.1),时代为早石炭世. 岩石地球化学数据显示,花岗闪长岩属准铝质低钾(拉斑)系列.花岗闪长岩总体富集大离子亲石元素,亏损高场强元素. Th、U表现,为明显正异常,Nb、Ta、Zr、Ti表现明显负异常,La、Hf、Lu等富集,δEu值为0.61~0.69,具有负铕异常,与I型花岗岩相似,具有火山弧花岗岩的特征,表明该侵入岩的形成与俯冲作用有关. 综合区域地质特征及本研究认为,花岗闪长岩为早石炭世古亚洲洋俯冲时的产物,可为古亚洲洋及东北地块构造演化研究提供新的约束和佐证实例.     

Geochronology,geochemistry and Hf isotopic study of Early Carboniferous granodiorites in Taerqi region,central Daxing'anling and its tectonic implication

Zircon U-Pb age,whole rock geochemical and zircon Hf isotopic data are presented for Late Paleozoic granodiorites from the Taerqi region,central Daxing'anling to constrain its petrogenesis and tectonic implication.LA-ICP-MS zircon U-Pb age data indicates that the Late Paleozoic granodiorites were emplaced with age of333.4 ± 2.2 Ma(Early Carboniferous).Geochemically,the granodiorite samples have Si O2= 60.54%-71.40%,Na2 O = 4.04%--4.66%,K2 O = 1.65%--4.27% and Mg O = 0.96%--3.53%,belonging to medium-K to high-K calc-alkaline I-type granites.They are slightly enriched in large ion lithophile elements(e.g.Rb,Th,U and K) and light rare earth elements,and depleted in high field strength elements(e.g.Nb,Ta and Ti),with εHf(t) values of 8.0--11.8 and Hf two-stage model ages of 586-829 Ma.All these geochemical features suggest that the primary magma was derived from partial melting of Neoproterozoic to Phanerozoic newly accreted lower crust.According to the geochemical data and regional geological investigations,the Early Carboniferous granodiorites formed in an island arc setting linked to the subduction of the Paleo-Asian Oceanic Plate beneath the Xing'an Terrane.This also implies that the Xing'an and Songliao terranes have not amalgamated before the Early Carboniferous.     

湖南水口山花岗闪长岩的地球化学特征及成因

中生代花岗质岩石在华南分布广泛,且常与W-Sn、Pb-Zn等金属矿床具有紧密的时空联系,而湖南水口山花岗闪长岩是与Pb-Zn成矿作用有关的典型代表。与华南改造型花岗岩相比,水口山花岗闪长岩及其成矿作用的研究程度较低。本文系统研究了该花岗闪长岩的岩相学特征、主元素、微量元素和Sr-Nd同位素组成,重点讨论了其岩石成因类型、物质来源及形成的构造环境。研究结果表明,水口山花岗闪长岩为贫Si O2、富碱、富铁镁、准铝质-弱过铝质的高钾钙碱性岩;表现出轻稀土元素富集,轻重稀土分馏强烈,弱负Eu异常;不相容元素Ba、Ta、Nb、Sr、Ti亏损,而Rb、Th、U、K、LREE相对富集的特征。岩体的(87Sr/86Sr)i比值为0.707364~0.711380,εNd(t)值为–6.61~–2.40,具明显的亏损地幔和华南上地壳混合特征。水口山花岗闪长岩的矿物组成、元素地球化学和同位素地球化学特征均表明,该岩体为同熔型花岗岩。该岩体是在晚中生代由太平洋板块向欧亚大陆板块俯冲诱发的华南板块伸展-减薄构造环境下,玄武质岩浆上涌,底侵中下地壳,与中上地壳混合形成的燕山早期高钾钙碱性花岗岩。     

内蒙古扎兰屯地区新立屯岩体锆石U-Pb年龄及地球化学特征

对内蒙古扎兰屯地区新立屯岩体进行了系统的地球化学及锆石U-Pb同位素年代学研究,并对其岩浆源区和成因进行讨论.研究结果表明,扎兰屯地区花岗闪长岩中锆石具有典型的岩浆振荡生长环带和较高的Th/U比值(0.63¹.07),反映了岩浆成因特征.LA-ICP-MS锆石U-Pb定年结果为135.6±1.3 Ma.岩石SiO2含量63.49%1.07),反映了岩浆成因特征.LA-ICP-MS锆石U-Pb定年结果为135.6±1.3 Ma.岩石SiO2含量63.49%⁶6.68%,具有高钾钙碱性特征,呈准铝质特点.LREE/HREE比值和(La/Yb)N比值分别为10.0766.68%,具有高钾钙碱性特征,呈准铝质特点.LREE/HREE比值和(La/Yb)N比值分别为10.07¹3.42、15.813.42、15.8²3.3,为轻稀土富集、重稀土亏损型.δEu值0.6123.3,为轻稀土富集、重稀土亏损型.δEu值0.61⁰.80,为弱亏损.以上特征表明,扎兰屯地区新立屯岩体为准铝质I型花岗岩.新立屯岩体呈高Sr低Yb型,形成于较高压的下地壳.具有类似于活动大陆边缘花岗岩的岩石组合特征,暗示其可能形成于活动大陆边缘构造背景,即与古太平洋板块的俯冲有关.     

Zircon U–Pb ages,geochemistry, and Sr–Nd–Pb isotopic compositions of Middle Triassic granodiorites from the Kaimuqi area,East Kunlun,Northwest China: implications for slab breakoff

The Qimantage area of Northwest China lies in the western part of the East Kunlun Orogenic Belt, and is dominated by late Permian to Late Triassic granitoids. Among these, the Middle Triassic granitoids are mainly distributed south of the North Kunlun Fault, and consist of two main granitic assemblages: the Kaimuqi assemblage in the east and the Mositu assemblage in the west. To better constrain the Indosinian tectonic evolution of this area, we present data on the geochronology, geochemistry, and petrology of ore-bearing granodiorites from the Kaimuqi area in eastern Qimantage. The granodiorite samples have porphyritic or fine-grained textures. Laser ablation inductively coupled plasma mass spectrometry U–Pb zircon dating yields emplacement ages of 238–242 Ma, interpreted here as the result of the Middle Triassic magmatism. The granodiorites are mostly of the high-K calc-alkaline series, and are enriched in light rare earth elements, depleted in heavy rare earth elements such as Nb, Ta, P, and Ti, and have weak negative Eu (Eu/Eu*) anomalies. The Kaimuqi granodiorites have lower SiO₂ and Sr contents, and higher Na₂O/K₂O ratios than the Mositu granodiorites. They also show initial ⁸⁷Sr/⁸⁶Sr ratios of 0.712151–0.715436, εNd(t) values of ?7.4 to ?6.3, and two-stage Nd model ages of 1.53–1.61 Ga. Together with their radiogenic Pb isotopic ratios for ²⁰⁶Pb/²⁰⁴Pb_(t) (18.271–18.622), ²⁰⁷Pb/²⁰⁴Pb_(t) (15.637–15.651), and ²⁰⁸Pb/²⁰⁴Pb_(t) (38.452–37.870), these data indicate both mantle and crustal contributions to the source of the granodiorites. Field investigations show that Middle Triassic granitoids in both the Mositu and Kaimuqi assemblages contain large numbers of mafic microgranular enclaves, which supports an interpretation of mantle and crustal magmatic mixing. Based on a comparison of these results with data from coeval granites in the Mositu assemblage, we propose that the Middle Triassic granitoids in the Qimantage area were produced at ca. 240 Ma, as a result of the end of subduction and the initiation of collision during the Variscan–Indosinian orogeny. Magma mixing may be interpreted as the result of slab breakoff in a subduction zone environment, which led to fluid metasomatism and induced partial melting of an enriched lithospheric mantle, resulting in the formation of voluminous granitic magma.