Water-rock-tailings interactions and sources of sulfur and metals in the subtropical mining region of Taxco,Guerrero (southern Mexico): A multi-isotopic approach

Multi-isotope (H, O, S, Sr, Pb) systems coupled with conventional (major and trace element) hydrogeochemical analysis were applied to determine the origin of water, to model water-rock-tailings interactions and for source apportionment of sulfur and associated toxic metals in the mining region of Taxco, Guerrero in southern Mexico. Oxygen and H isotopes indicate that meteoric water in the zone is rainwater undergoing varying degrees of isotopic fractionation by atmospheric evaporation whereas Sr isotopes trace the interaction of pristine water from volcanics of the regional recharge zone and subsequently flowing through sandstone and shale to spring points. Leachates form from two distinctive sources (spring water and surface water) having differential interactions with bedrocks prior to entering the tailings. Compared to pristine water, leachates are enriched in sulfate, metals (e.g. Fe, Mn, Pb and Zn) and metalloids (e.g. As). The sulfur isotopic composition of ore-sulfides, leachates, secondary precipitates, regional surface water and hypogenic sulfates is described in terms of a two-component mixing model with shale of Mexcala and limestone of Morelos formations representing the light and heavy end-members, respectively, whereas Sr isotopic composition is bracketed combining three lithogenic (Mexcala/Morelos, Tilzapotla and Taxco Schist) sources. Finally, leachates have a mixture of lead from ore-sulfides and Taxco Schist Formation (Family I) or from ore-sulfides alone (Family II). The application of multiple environmental isotopic techniques is an outstanding tool for elucidating complex interactions of water with bedrocks and tailings and for determining the source of sulfur and toxic metal from mining and other metal polluted environments.     

Reactive transport impacts on recovered freshwater quality during multiple partially penetrating wells (MPPW-)ASR in a brackish heterogeneous aquifer

The use of multiple partially penetrating wells (MPPW) during aquifer storage and recovery (ASR) in brackish aquifers can significantly improve the recovery efficiency (RE) of unmixed injected water. The water quality changes by reactive transport processes in a field MPPW-ASR system and their impact on RE were analyzed. The oxic freshwater injected in the deepest of four wells was continuously enriched with sodium (Na⁺) and other dominant cations from the brackish groundwater due to cation exchange by repeating cycles of ‘freshening’. During recovery periods, the breakthrough of Na⁺ was retarded in the deeper and central parts of the aquifer by ‘salinization’. Cation exchange can therefore either increase or decrease the RE of MPPW-ASR compared to the RE based on conservative Cl⁻, depending on the maximum limits set for Na⁺, the aquifer’s cation exchange capacity, and the native groundwater and injected water composition. Dissolution of Fe and Mn-containing carbonates was stimulated by acidifying oxidation reactions, involving adsorbed Fe²⁺ and Mn²⁺ and pyrite in the pyrite-rich deeper aquifer sections. Fe²⁺ and Mn²⁺ remained mobile in anoxic water upon approaching the recovery proximal zone, where Fe²⁺ precipitated via MnO₂ reduction, resulting in a dominating Mn²⁺ contamination. Recovery of Mn²⁺ and Fe²⁺ was counteracted by frequent injections of oxygen-rich water via the recovering well to form Fe and Mn-precipitates and increase sorption. The MPPW-ASR strategy exposes a much larger part of the injected water to the deeper geochemical units first, which may therefore control the mobilization of undesired elements during MPPW-ASR, rather than the average geochemical composition of the target aquifer.     

南水北调中线突发水污染事件的快速预测

依据南水北调中线干渠资料,开展了正常输水情况下串联明渠内可溶污染物浓度分布规律数值模拟研究。采用数值模拟、数学归纳和统计分析方法,提出表征污染物输移扩散特征的峰值输移距离、污染带长度和峰值浓度的快速预测公式;通过示范工程验证了快速预测公式的可行性。结果表明:①串联明渠内,峰值输移距离随渠道流速减小而减小,并且污染带长度增加值随明渠内流速减小而减小,但是峰值浓度随明渠流速减小而增加;②快速预测公式计算结果与现场试验实测结果的误差均不到15%,证明了快速预测公式的合理性和可行性。这些研究结果为南水北调中线工程突发可溶性水污染事件应急预警方案的制定提供了科学依据。     

辽宁省地下水动态成因类型分析

根据辽宁省2006—2010年地下水水位实际监测数据,分析地下水水位动态变化规律、形成原因及发展趋势,再结合地下水动态变化的自然与人为影响控制因素,以及地下水的补给、径流、排泄条件等,将辽宁省地下水动态成因类型划分为:气候型、开采型、灌溉型、水文型和径流型,经过较为全面系统的统计分析计算,绘制出地下水动态变化历时曲线,对五种地下水动态成因类型分别予以较为详细的综合分析研究,总结出辽宁省地下水动态变化规律特征。     

Experimental and theoretical study of a cylindrical oscillating water column device with a quadratic power take-off model

The wave power extraction by a cylindrical oscillating water column (OWC) device with a quadratic power take-off (PTO) model was studied experimentally and theoretically. In the experiment, a scaled model OWC was tested in a wave flume, with an orifice being used to simulate a quadratic PTO mechanism. In the theoretical analysis, the quadratic PTO model was linearized based on Lorenz's principle of equivalent work, which allows us to perform a frequency domain analysis using an eigen-function matching method. The effects of higher harmonic components and the spatial non-uniformity of the surface velocity inside the chamber were discussed. A semi-analytical model was proposed to understand the viscous loss affecting the measured capture length. Our treatment of the quadratic PTO model was validated by comparing quasi-linear theoretical capture length and the laboratory measurement. Our results also showed that the effects of spatial non-uniformity and viscous loss could be noticeable for shorter waves.     

青岛冷水团的消亡机理研究

本文基于多年月平均水温资料,分析了青岛冷水团的长消过程,并利用气候态月平均大气数据和数值模拟结果,探讨了青岛冷水团的消亡机理。结果表明,青岛冷水团3月出现,4月成型,5月最盛,6月减弱,7月消失;南黄海6-7月间偏南风的增强和温跃层以下反气旋涡的减弱是青岛冷水团消亡的动力机制,而海面净热通量的下传和水平热量的输入则是青岛冷水团消亡的热力机制。     

Numerical Investigation of Submarine Hydrodynamics and Flow Field in Steady Turn

This paper presents numerical simulations of viscous flow past a submarine model in steady turn by solving the Reynolds-Averaged Navier?Stokes Equations (RANSE) for incompressible, steady flows. The rotating coordinate system was adopted to deal with the rotation problem. The Coriolis force and centrifugal force due to the computation in a body-fixed rotating frame of reference were treated explicitly and added to momentum equations as source terms. Furthermore, velocities of entrances were coded to give the correct magnitude and direction needed. Two turbulence closure models (TCMs), the RNG model with wall functions and curvature correction and the Shear Stress Transport (SST) model without the use of wall functions, but with curvature correction and low-Re correction were introduced, respectively. Take DARPA SUBOFF model as the test case, a series of drift angle varying between 0° and 16° at a Reynolds number of 6.53×106 undergoing rotating arm test simulations were conducted. The computed forces and moment as a function of drift angle during the steady turn are mostly in close agreement with available experimental data. Though the difference between the pressure coefficients around the hull form was observed, they always show the same trend. It was demonstrated that using sufficiently fine grids and advanced turbulence models will lead to accurate prediction of the flow field as well as the forces and moments on the hull.     

Driving forces and their interactions of built-up land expansion based on the geographical detector – a case study of Beijing,China

Scientific interpretation of the driving forces of built-up land expansion is essential to urban planning and policy-making. In general, built-up land expansion results from the interactions of different factors, and thus, understanding the combined impacts of built-up land expansion is beneficial. However, previous studies have primarily been concerned with the separate effect of each driver, rather than the interactions between the drivers. Using the built-up land expansion in Beijing from 2000 to 2010 as a study case, this research aims to fill this gap. A spatial statistical method, named the geographical detector, was used to investigate the effects of physical and socioeconomic factors. The effects of policy factors were also explored using physical and socioeconomic factors as proxies. The results showed that the modifiable areal unit problem existed in the geographical detector, and 4000 m might be the optimal scale for the classification performed in this study. At this scale, the interactions between most factors enhanced each other, which indicated that the interactions had greater effects on the built-up land expansion than any single factor. In addition, two pairs of nonlinear enhancement, the greatest enhancement type, were found between the distance to rivers and two socioeconomic factors: the total investment in fixed assets and GDP. Moreover, it was found that the urban plans, environmental protection policies and major events had a great impact on built-up land expansion. The findings of this study verify that the geographical detector is applicable in analysing the driving forces of built-up land expansion. This study also offers a new perspective in researching the interactions between different drivers.     

沂蒙缺水山区地下水赋存规律及找水定井范例

沂蒙山区是山东省重点贫困缺水地区,缺水区域分布较广,区内地质条件复杂,找水难度极大。通过综合分析区内气象水文、岩性特征、地质构造及地形地貌等地质因素,初步查明了不同地段含水层的结构和富水性;并结合水文地质调查、物探、钻探等综合勘探方法和手段,实施了探采结合孔8口,成功率100%,满足了区内约3万余人的饮用及300余亩土地灌溉用水需求,取得了良好的经济和社会效益。为我国北方严重缺水山区找寻地下水起到了宝贵的指导和示范作用。     

浮托安装进船过程中护舷碰撞力实测研究

浮托安装法广泛应用于大型组块海上安装。导管架平台上部组块浮托安装进船过程中,风、浪、流引起的浮托驳船横向运动造成浮托驳船与导管架桩腿的碰撞,碰撞力可能会对导管架结构造成损伤。陆丰7-2上部组块浮托安装中,为了监测碰撞力大小,设计了碰撞力海上监测系统。通过在导管架外侧四个桩腿上安装光纤光栅应变传感器对碰撞过程中导管架桩腿进行应力监测,进而计算碰撞力。对碰撞过程,载荷作用位置、方向进行简化,并对载荷大小及垂向作用位置对计算的影响进行了研究。结构分析模型简化后,测点von-Mises应力与碰撞力大小成正比,对导管架整体结构建模计算并取局部结构计算比例系数,结合应力实测数据计算出进船过程中驳船对导管架桩腿碰撞力。