Evaluation of the potential risks of heavy metal contamination in rice paddy soils around an abandoned Hg mine area in Southwest China

To assess the potential ecological and health risks of trace elements(Hg,Cd,As,Mn,Sb,Pb,Cu,Ni,Cr,and Zn),a total of 138 soil samples from rice paddies were collected during the rice harvest season in the Wanshan mining area,Guizhou Province,Southwest China.Factors of the pollution load index(PLI),geo-accumulation index(I-Geo),enrichment factor(EF),and risk index(RI)were determined.High concentrations of Hg,Sb,As,Zn,Cd,Cu,and Mn were observed in the soils.The PLI,I-Geo,and EF results all showed high levels of contamination by Hg and Sb and moderate levels of contamination by As,Pb,Zn,Cu,Cd,and Mn.There was no significant contamination from Ni and Cr.The RI was very high,with Hg as the dominant pollutant,as expected,indicating that the historical large-scale Hg mining,as well as artisanal mining,has had a significant impact on the Wanshan area.Moreover,coal combustion,manganese factories,and the use of agrochemicals by the local population could also have an impact on the soil through the introduction of heavy metal loads.To address the current state of contamination,pollutant remediation and the regulation control of the anthropogenic activities in Wanshan are urgently needed.     

Organohalogen contaminants and total mercury in forage fish preyed upon by thick-billed murres in northern Hudson Bay

Twelve marine fish species collected from a thick-billed murre (Uria lomvia) breeding colony in northern Hudson Bay in the Canadian Arctic during 2007–2009 were analyzed for legacy organochlorines (e.g. PCBs, DDT), polybrominated diphenyl ethers (PBDEs), perfluorinated carboxylates (PFCAs) and sulfonates (PFSAs), and total mercury (Hg). No one species of prey fish had the highest levels across all contaminant groups analyzed. For the two pelagic fish species sampled, concentrations of the major organochlorine groups (e.g. Σ₂₁PCB, ΣDDT, ΣCHL, ΣCBz), ΣPBDE, ΣPFCA and Hg were consistently higher in Arctic cod (Boreogadus saida) than in capelin (Mallotus villosus). Biomagnification factors from whole fish to thick-billed murre liver across all species were generally higher for Σ₂₁PCB and ΣDDT. ΣPBDE did not biomagnify.     

Mercury enrichments in core sediments in Hugli–Matla–Bidyadhari estuarine complex,north-eastern part of the Bay of Bengal and their ecotoxicological significance

Mercury concentrations (Hg_T) in fine-grained fraction (<63 μm) of core sediments of the Hugli–Matla–Bidyadhari estuarine complex, India were analyzed. Results revealed a wide range of spatial variations (<4–93 ng g⁻¹ dry weight) with a definite enhancement level at the lower stretch of the estuarine complex infested with mangrove plants, which might act as a sink to Hg_T. An elevated concentration of Hg was encountered in surface/subsurface layer of the core in majority of the cases resulting from physical, biogenic and postdepositional diagenetic processes that remobilized and resuspended the metal from deeper sediments. A strong positive correlation was observed between the Hg and clay fraction content of the sediments, while the correlations of Hg with Al, Fe and Mn were poor. Based on the index of geoaccumulation (I _geo) and effects range-low (ER-L) value, it is considered that the sediments are less polluted and thus there is less chance of ecotoxicological risk to organisms living in sediments.     

Could giant impacts cripple core dynamos of small terrestrial planets?

Large impacts not only create giant basins on terrestrial planets but also heat their interior by shock waves. We investigate the impacts that have created the largest basins existing on the planets: Utopia on Mars, Caloris on Mercury, Aitken on Moon, all formed at ∼4 Ga. We determine the impact-induced temperature increases in the interior of a planet using the “foundering” shock heating model of Watters et al. (Watters, W.A., Zuber, M.T., Hager, B.H. [2009]. J. Geophys. Res. 114, E02001. doi:10.1029/2007JE002964). The post-impact thermal evolution of the planet is investigated using 2D axi-symmetric convection in a spherical shell of temperature-dependent viscosity and thermal conductivity, and pressure-dependent thermal expansion. The impact heating creates a superheated giant plume in the upper mantle which ascends rapidly and develops a strong convection in the mantle of the sub-impact hemisphere. The upwelling of the plume rapidly sweeps up the impact-heated base of the mantle away from the core-mantle boundary and replaces it with the colder surrounding material, thus reducing the effects of the impact-heated base of the mantle on the heat flux out of core. However, direct shock heating of the core stratifies the core, suppresses the pre-existing thermal convection, and cripples a pre-existing thermally-driven core dynamo. It takes about 17, 4, and 5 Myr for the stratified cores of Mars, Mercury, and Moon to exhaust impact heat and resume global convection, possibly regenerating core dynamos.     

Constraints on Mercury’s Na exosphere: Combined MESSENGER and ground-based data

We have used observations of sodium emission obtained with the McMath-Pierce solar telescope and MESSENGER’s Mercury Atmospheric and Surface Composition Spectrometer (MASCS) to constrain models of Mercury’s sodium exosphere. The distribution of sodium in Mercury’s exosphere during the period January 12-15, 2008, was mapped using the McMath-Pierce solar telescope with the 5″ × 5″ image slicer to observe the D-line emission. On January 14, 2008, the Ultraviolet and Visible Spectrometer (UVVS) channel on MASCS sampled the sodium in Mercury’s anti-sunward tail region. We find that the bound exosphere has an equivalent temperature of 900-1200 K, and that this temperature can be achieved if the sodium is ejected either by photon-stimulated desorption (PSD) with a 1200 K Maxwellian velocity distribution, or by thermal accommodation of a hotter source. We were not able to discriminate between the two assumed velocity distributions of the ejected particles for the PSD, but the velocity distributions require different values of the thermal accommodation coefficient and result in different upper limits on impact vaporization. We were able to place a strong constraint on the impact vaporization rate that results in the release of neutral Na atoms with an upper limit of 2.1 × 10⁶ cm⁻² s⁻¹. The variability of the week-long ground-based observations can be explained by variations in the sources, including both PSD and ion-enhanced PSD, as well as possible temporal enhancements in meteoroid vaporization. Knowledge of both dayside and anti-sunward tail morphologies and radiances are necessary to correctly deduce the exospheric source rates, processes, velocity distribution, and surface interaction.     

The dayside magnetospheric boundary layer at Mercury

Magnetic field and plasma data from the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft on the outbound portions of the first (M1) and second (M2) flybys of Mercury reveal a region of depressed magnetic field magnitude and enhanced proton fluxes adjacent to but within the magnetopause, which we denote as a dayside boundary layer. The layer was present during both encounters despite the contrasting dayside magnetic reconnection, which was minimal during M1 and strong during M2. The overall width of the layer is estimated to be between 1000 and 1400 km, spanning most of the distance from the dayside planetary surface to the magnetopause in the mid-morning. During both flybys the magnetic pressure decrease was ∼1.6 nPa, and the width of the inner edge was comparable to proton gyro-kinetic scales. The maximum variance in the magnetic field across the inner edge was aligned with the magnetic field vector, and the magnetic field direction did not change markedly, indicating that the change in field intensity was consistent with an outward plasma-pressure gradient perpendicular to the magnetic field. Proton pressures in the layer inferred from reduced distribution observations were 0.4 nPa during M1 and 1.0 nPa during M2, indicating either that the proton pressure estimates are low or that heavy ions contribute substantially to the boundary-layer plasma pressure. If the layer is formed by protons drifting westward from the cusp, there should be a strong morning–afternoon asymmetry that is independent of the interplanetary magnetic field (IMF) direction. Conversely, if heavy ions play a major role, the layer should be strong in the morning (afternoon) for northward (southward) IMF. Future MESSENGER observations from orbit about Mercury should distinguish between these two possibilities.     

Measurement of the radius of Mercury by radio occultation during the MESSENGER flybys

The MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft completed three flybys of Mercury in 2008–2009. During the first and third of those flybys, MESSENGER passed behind the planet from the perspective of Earth, occulting the radio-frequency (RF) transmissions. The occultation start and end times, recovered with 0.1 s accuracy or better by fitting edge-diffraction patterns to the RF power history, are used to estimate Mercury's radius at the tangent point of the RF path. To relate the measured radius to the planet shape, we evaluate local topography using images to identify the high-elevation feature that defines the RF path or using altimeter data to quantify surface roughness. Radius measurements are accurate to 150 m, and uncertainty in the average radius of the surrounding terrain, after adjustments are made from the local high at the tangent point of the RF path, is 350 m. The results are consistent with Mercury's equatorial shape as inferred from observations by the Mercury Laser Altimeter and ground-based radar. The three independent estimates of radius from occultation events collectively yield a mean radius for Mercury of 2439.2±0.5 km.     

The transition from complex crater to peak-ring basin on the Moon: New observations from the Lunar Orbiter Laser Altimeter (LOLA) instrument

Impact craters on planetary bodies transition with increasing size from simple, to complex, to peak-ring basins and finally to multi-ring basins. Important to understanding the relationship between complex craters with central peaks and multi-ring basins is the analysis of protobasins (exhibiting a rim crest and interior ring plus a central peak) and peak-ring basins (exhibiting a rim crest and an interior ring). New data have permitted improved portrayal and classification of these transitional features on the Moon. We used new 128 pixel/degree gridded topographic data from the Lunar Orbiter Laser Altimeter (LOLA) instrument onboard the Lunar Reconnaissance Orbiter, combined with image mosaics, to conduct a survey of craters >50 km in diameter on the Moon and to update the existing catalogs of lunar peak-ring basins and protobasins. Our updated catalog includes 17 peak-ring basins (rim-crest diameters range from 207 km to 582 km, geometric mean = 343 km) and 3 protobasins (137-170 km, geometric mean = 157 km). Several basins inferred to be multi-ring basins in prior studies (Apollo, Moscoviense, Grimaldi, Freundlich-Sharonov, Coulomb-Sarton, and Korolev) are now classified as peak-ring basins due to their similarities with lunar peak-ring basin morphologies and absence of definitive topographic ring structures greater than two in number. We also include in our catalog 23 craters exhibiting small ring-like clusters of peaks (50-205 km, geometric mean = 81 km); one (Humboldt) exhibits a rim-crest diameter and an interior morphology that may be uniquely transitional to the process of forming peak rings. A power-law fit to ring diameters (D_ring) and rim-crest diameters (D_r) of peak-ring basins on the Moon [D_ring = 0.14 ± 0.10(D_r)^1.21±0.13] reveals a trend that is very similar to a power-law fit to peak-ring basin diameters on Mercury [D_ring = 0.25 ± 0.14(D_rim)^1.13±0.10] [Baker, D.M.H. et al. [2011]. Planet. Space Sci., in press]. Plots of ring/rim-crest ratios versus rim-crest diameters for peak-ring basins and protobasins on the Moon also reveal a continuous, nonlinear trend that is similar to trends observed for Mercury and Venus and suggest that protobasins and peak-ring basins are parts of a continuum of basin morphologies. The surface density of peak-ring basins on the Moon (4.5 × 10⁻⁷ per km²) is a factor of two less than Mercury (9.9 × 10⁻⁷ per km²), which may be a function of their widely different mean impact velocities (19.4 km/s and 42.5 km/s, respectively) and differences in peak-ring basin onset diameters. New calculations of the onset diameter for peak-ring basins on the Moon and the terrestrial planets re-affirm previous analyses that the Moon has the largest onset diameter for peak-ring basins in the inner Solar System. Comparisons of the predictions of models for the formation of peak-ring basins with the characteristics of the new basin catalog for the Moon suggest that formation and modification of an interior melt cavity and nonlinear scaling of impact melt volume with crater diameter provide important controls on the development of peak rings. In particular, a power-law model of growth of an interior melt cavity with increasing crater diameter is consistent with power-law fits to the peak-ring basin data for the Moon and Mercury. We suggest that the relationship between the depth of melting and depth of the transient cavity offers a plausible control on the onset diameter and subsequent development of peak-ring basins and also multi-ring basins, which is consistent with both planetary gravitational acceleration and mean impact velocity being important in determining the onset of basin morphological forms on the terrestrial planets.     

The effects of the target material properties and layering on the crater chronology: The case of Raditladi and Rachmaninoff basins on Mercury

In this paper we present a crater age determination of several terrains associated with the Raditladi and Rachmaninoff basins. These basins were discovered during the first and third MESSENGER flybys of Mercury, respectively. One of the most interesting features of both basins is their relatively fresh appearance. The young age of both basins is confirmed by our analysis on the basis of age determination via crater chronology. The derived Rachmaninoff and Raditladi basin model ages are about 3.6 Ga and 1.1 Ga, respectively. Moreover, we also constrain the age of the smooth plains within the basins' floors. This analysis shows that Mercury had volcanic activity until recent time, possibly to about 1 Ga or less. We find that some of the crater size-frequency distributions investigated suggest the presence of a layered target. Therefore, within this work we address the importance of considering terrain parameters, as geo-mechanical properties and layering, into the process of age determination. We also comment on the likelihood of the availability of impactors able to form basins with the sizes of Rachmaninoff and Raditladi in relatively recent times.     

Mercury resolved spectroscopy from NTT

Mercury has been observed in June 2006 with the SofI instrument at NTT. Resolved spectroscopy was performed in the range. The observations were acquired close to a favorable quadrature with maximum elongation, and span mostly the southern hemisphere in the 235–315°E longitude area.In contrast to recent observations from IRTF, the present study does not indicate any pyroxene absorption in the near-infrared range, neither in the region nor at . Detailed spectral analysis allows to derive an upper limit of 1.5% type-A pyroxene (hedenbergite) or 1.1% enstatite (assuming minimum lunar iron content) in the regions observed, at the 700 km scale. Assuming lunar-like maturity effects on band depth, this corresponds to an upper limit of 0.15 and 0.6 wt.% FeO content in silicates, an order of magnitude less than previous estimates.