The free precession and libration of Mercury

An analysis based on the direct torque equations including tidal dissipation and a viscous core-mantle coupling is used to determine the damping time scales of O(¹⁰⁵) years for free precession of the spin about the Cassini state and free libration in longitude for Mercury. The core-mantle coupling dominates the damping over the tides by one to two orders of magnitude for the plausible parameters chosen. The short damping times compared with the age of the Solar System means we must find recent or on-going excitation mechanisms if such free motions are found by the current radar experiments or the future measurement by the MESSENGER and BepiColombo spacecraft that will orbit Mercury. We also show that the average precession rate is increased by about 30% over that obtained from the traditional precession constant because of a spin-orbit resonance induced contribution by the C₂₂ term in the expansion of the gravitational field. The C₂₂ contribution also causes the path of the spin during the precession to be slightly elliptical with a variation in the precession rate that is a maximum when the obliquity is a minimum. An observable free precession will compromise the determination of obliquity of the Cassini state and hence of C/MMR² for Mercury, but a detected free libration will not compromise the determination of the forced libration amplitude and thus the verification of a liquid core.     

Determination of the properties of Mercury's magnetic field by the MESSENGER mission

The MESSENGER mission to Mercury, to be launched in 2004, will provide an opportunity to characterize Mercury's internal magnetic field during an orbital phase lasting one Earth year. To test the ability to determine the planetary dipole and higher-order moments from measurements by the spacecraft's fluxgate magnetometer, we simulate the observations along the spacecraft trajectory and recover the internal field characteristics from the simulated observations. The magnetic field inside Mercury's magnetosphere is assumed to consist of an intrinsic multipole component and an external contribution due to magnetospheric current systems described by a modified Tsyganenko 96 model. Under the axis-centered-dipole approximation without correction for the external field the moment strength is overestimated by ∼4% for a simulated dipole moment of , and the error depends strongly on the magnitude of the simulated moment, rising as the moment decreases. Correcting for the external field contributions can reduce the error in the dipole term to a lower limit of ∼1-2% without a solar wind monitor. Dipole and quadrupole terms, although highly correlated, are then distinguishable at the level equivalent to an error in the position of an offset dipole of a few tens of kilometers. Knowledge of the external magnetic field is therefore the primary limiting factor in extracting reliable knowledge of the structure of Mercury's magnetic field from the MESSENGER observations.     

Mercury mobility in mine waste from Hg-mining areas in Almería,Andalusia (Se Spain)

Mining wastes and calcines from two abandoned mining areas (Valle del Azogue and Bayarque in Almería) have been characterized. In the mining wastes, the dominant mercury phases are cinnabar and elemental mercury in the matrix. In the calcines, however, the dominant mercury phase is elemental mercury bounded to the matrix. Water-leaching experiments were conducted on low-grade stockpiles and calcines in order to simulate the mobilization of mercury by runoff under environmental conditions. The laboratory column-leaching experiments show a possible mobilization of mercury from Hg⁰ dissolution, colloid transport and a possible dissolution of calomel and other soluble phases in the mine wastes from the Valle del Azogue and Bayarque mines. Equilibrium speciation modeling of Hg, conducted using the numerical code MINTEQ, showed that the theoretical dominant mercury species in the calcine and mining wastes samples are Hg(OH)₂, HgCl₂, HgClOH and Hg⁰. In some leachates obtained from the Valle del Azogue mining wastes (sample A06), the high Hg concentrations may indicate the possible dissolution of mineral phases such as calomel and other soluble phases, which are subsaturated. The environmental results indicate a great environmental mobility of mercury, especially during wet episodes associated with intense precipitation events, when there are significative amounts of secondary soluble minerals.     

Investigation on piezoelectric lead zirconate titanate detector bombarded obliquely with hypervelocity iron particles

A cosmic dust detector for use onboard a satellite is currently being constructed from piezoelectric lead zirconate titanate (PZT). The characteristics of the PZT detector were studied by bombarding it with hypervelocity iron particles, which were supplied by a Van de Graaff accelerator. There was a linear relationship between the rise time of the signal observed from the detector and the particle's velocity, which was above 10 km/s on impact. It was also found that the rise time was almost independent of the collisional angle between the particles and the PZT surface within the limits of the particle's parameters used in this experiment.     

Mercury's integral phase curve: Phase reddening and wavelength dependence of photometric quantities

We present results of a five-filter photometric study of Mercury's integral phase curve in the Johnson-Cousins UBVRI system, performed with the 0.90-m Westerlund Telescope in Uppsala, Sweden. CCD observations were made of the integrated disk for the phase angle range 22-152°, and the study is the first to cover the extended visible spectrum of Mercury. The observations are analyzed with Hapke's semi-empirical radiative transfer-based light-scattering model and photometric quantities are derived. A statistically significant phase reddening effect of is determined for Mercury based on color index observations, which is similar to that of the Moon. Phase coefficients fit to integral absolute magnitude data and Hapke models in combination with color index data provide a phase reddening effect of which does however not provide statistically significant evidence for its presence. Phase coefficients indicate that phase reddening may be decreasing in magnitude with wavelength. As for the case with the Moon, the value of the phase integral increases with wavelength, but at an eight times higher rate. This value is consistent with the difference in the rate of change in the spectral slope-emission angle relation for the two bodies. We attribute these differences with Mercury's redder spectral slope and an increase with wavelength of the backscattering lobe amplitude in the double Henyey-Greenstein particle phase function formulation. The normal albedo of integral Mercury at 1064 nm, pertinent to the return pulse energy of the BepiColombo laser altimeter (BELA), is estimated to 0.23±0.06 with a range of 0.13-0.33 for 99% of the surface.     

Experimental test of a radiative transfer model of the optical effects of space weathering

We compare laboratory measurements of the optical effects of nanophase iron on near-IR reflectance spectra of transparent silica gel infused with small iron particles [Noble, S.K., Pieters, C.M., Keller, L.P., 2007. Icarus 192, 629-642] with a radiative transfer model of the process [Hapke, B., 2001. J. Geophys. Res. 106 (E5), 10039-10074]. We find that the measurements exhibit reddening and darkening effects of nanophase (<50 nm) iron particles, a darkening effect of somewhat larger particles (>50 nm) and mixing effects of silica gel particles of varying total iron abundance. The radiative transfer model reproduces the effects of nanophase iron within the experimental uncertainties.     

气汞的第一个同震效应记录

利用杭州超距科技有限公司最近研发的ATG-6138型测汞仪在云南省弥勒井气汞（Hg）观测中记录到尼泊尔8.1级地震的同震效应。这是我国气汞观测的第一个同震效应的纪录。这一事实表明了进一步提升地震地下流体化学量观测仪器的观测精度与采样率,有可能记录到固体潮与同震效应等更多的地壳动力作用信息,从而进一步提升其地震前兆监测能力。     

The Plat Sjambok Anorthosite and its tonalitic country rocks: Mesoproterozoic pre-tectonic intrusions in the Kaaien Terrane,Namaqua–Natal Province,southern Africa

The Plat Sjambok Anorthosite crops out near Prieska Copper Mines in the Namaqua–Natal Province of southern Africa. It is a massif-type anorthosite, previously regarded as a late-tectonic intrusion and part of the ca. 1100 Ma bimodal Keimoes Suite. Our new ion probe U–Pb zircon data show that the Plat Sjambok massif intruded at 1259 ± 5 Ma, before the 1220 Ma Namaqua collision events and is thus approximately 150 million years older than the Keimoes Suite. Despite the proximity to Prieska Mines, the anorthosite is located in the Kaaien Terrane close to the Brakbos Fault, which is the boundary with the Areachap Terrane in which Prieska Mines is situated. We dated the Nelspoortjie Tonalite, the main country rock of the Plat Sjambok Anorthosite, by laser ablation ICPMS at 1273 ± 13 Ma. Both intrusions thus originated concurrently with the 1286–1241 Ma volcanic rocks of the Areachap Group, which developed in a subduction-related arc setting, prior to its collision with the Kaaien Terrane and Kaapvaal Craton. Metamorphic zircon rims in the Plat Sjambok Anorthosite give an age of 1122 ± 7 Ma, a time that corresponds to a quiet period in the Areachap Terrane. We propose a tectonic model in which formation of the Nelspoortjie Tonalite and Plat Sjambok Anorthosite was driven by intrusions from the mantle into a back-arc related tensional environment within the Kaaien Terrane, possibly situated above an Archaean crustal tongue. This led to heating in a thickened crustal setting in which the tonalite originated as a partial melt of amphibolite. The anorthosite then formed as a mixture of mantle-derived gabbro and Archaean crustal rocks, which explains the 2100–2600 Ma zircon–Hf crustal residence ages and the Sm–Nd trend towards an old crustal source. The anorthosite and its country rocks were only juxtaposed with the Prieska Copper Mining District by late-tectonic uplift and transpressional movements on the Brakbos Fault towards the end of the Namaqua tectogenesis.     

野外电位溶出法测铜新探索

溶液中加入氧化剂（高锰酸钾）,氧化电极表面的金属铜形成铜离子进入溶液中,金属氧化溶出时间与溶液中的金属离子的浓度成正比,峰值与溶出时间成正比,因此峰高与溶液中金属离子浓度成正比,以此测定溶液中铜离子的浓度。     

Impact of mining activities on soils and sediments at the historical mining area in Podljubelj,NW Slovenia

The abandoned Hg mine in Podljubelj was in operation with interceptions from 1557 to 1902. The entire operating period yielded about 110 000 tons of ore, from which 360 tons of Hg was produced. The objective of the research project was to establish the contents and spatial distribution of Hg in soils and stream sediments in the vicinity of the mine. On an area of 88 ha the soil was sampled in a 100 × 100 m grid. Two soil horizons (0–5 cm and 20–30 cm) were sampled in order to distinguish between geogenic and anthropogenic Hg sources. It was established that on an area of about 9 ha Hg content in soil exceeds The New Dutchlist action value for Hg (10 mg/kg). Total Hg concentrations in soil samples vary between 0.17 and 719 mg/kg, with a mean of 3.0 mg/kg. Mercury contents in stream sediments range from 0.065 to 1.4 mg/kg, with a mean of 0.64 mg/kg. The highest determined value in soils was found in the area around the former roasting furnace, where the ore was processed. Increased Hg concentrations were also found on the mine waste dump (108 mg/kg). Mercury contents in soils generally decrease with soil profile depth and with the distance from the mine and from the roasting furnace location. Mercury also appears in higher concentrations along the road that runs through the valley, which results from the use of Hg-bearing ore residues in road construction. The average enrichment factor (EF) of Hg in topsoil with respect to subsoil is 3.3. Calculated enrichment factors show higher values also for Cd (3.2), Pb (2.7), Ca (2.4) and P (1.9). The average enrichment factor of Hg in topsoil with regard to the established Slovenian soil averages (EF_slo) is 19. EF_slo of other determined chemical elements do not exceed 3.0.