Transport and dispersion of particulate Hg associated with a river plume in coastal Northern Adriatic environments

The role of suspended particulate matter (SPM) as an important carrier of mercury (Hg) dispersed into the Gulf of Trieste and in the adjacent Grado lagoon (Northern Adriatic Sea) was studied during a high Isonzo River inflow and the resulting river plume formation. Despite the fact that extreme flood events are rare during the year, they account for most of the PHg influx (37-112 ngL(-1)) into the Gulf of Trieste. When the river plume is diverted to the SW under the influence of an E-NE wind, the tidal flux acts as a "transport belt" carrying the PHg, mostly inorganic, into the Grado lagoon. A preliminary estimation indicates that the amount of PHg entrapped in the lagoon basin following a tidal semi-cycle accounts for 1.4 kg/12h, which corresponds to about 49% of the total Hg carried by the tidal flow. These findings should be considered in future remediation strategies in the lagoon environment.     

Mercury's capture into the 3/2 spin-orbit resonance including the effect of core-mantle friction

The rotation of Mercury is presently captured in a 3/2 spin-orbit resonance with the orbital mean motion. The capture mechanism is well understood as the result of tidal interactions with the Sun combined with planetary perturbations [Goldreich, P., Peale, S., 1966. Astron. J. 71, 425-438; Correia, A.C.M., Laskar, J., 2004. Nature 429, 848-850]. However, it is now almost certain that Mercury has a liquid core [Margot, J.L., Peale, S.J., Jurgens, R.F., Slade, M.A., Holin, I.V., 2007. Science 316, 710-714] which should induce a contribution of viscous friction at the core-mantle boundary to the spin evolution. According to Peale and Boss [Peale, S.J., Boss, A.P., 1977. J. Geophys. Res. 82, 743-749] this last effect greatly increases the chances of capture in all spin-orbit resonances, being 100% for the 2/1 resonance, and thus preventing the planet from evolving to the presently observed configuration. Here we show that for a given resonance, as the chaotic evolution of Mercury's orbit can drive its eccentricity to very low values during the planet's history, any previous capture can be destabilized whenever the eccentricity becomes lower than a critical value. In our numerical integrations of 1000 orbits of Mercury over 4 Gyr, the spin ends 99.8% of the time captured in a spin-orbit resonance, in particular in one of the following three configurations: 5/2 (22%), 2/1 (32%) and 3/2 (26%). Although the present 3/2 spin-orbit resonance is not the most probable outcome, we also show that the capture probability in this resonance can be increased up to 55% or 73%, if the eccentricity of Mercury in the past has descended below the critical values 0.025 or 0.005, respectively.     

Latitudinal librations of Mercury with a fluid core

In the framework of the space missions to Mercury, an accurate model of rotation is needed. Librations around the 3:2 spin-orbit resonance as well as latitudinal librations have to be predicted with the best possible accuracy. In this paper, we use a Hamiltonian analysis and numerical integrations to study the librations of Mercury, both in longitude and latitude. Due to the proximity of the period of the free libration in longitude to the orbital period of Jupiter, the 88-day and 11.86-year contributions dominate Mercury’s libration in longitude (with the Hermean parameters chosen). The amplitude of the libration in latitude is much smaller (under 1 arcsec) and should not be detected by the space missions. Nevertheless, we point out that this amplitude could be much larger (up to several tens of arcsec) if the free period related to the libration in latitude approaches the period of the Jupiter-Saturn Great Inequality (883 years). Given the large uncertainties on the planetary parameters, this new resonant forcing on Mercury’s libration in latitude should be borne in mind.     

Spectral emissivity measurements of Mercury's surface indicate Mg- and Ca-rich mineralogy, K-spar, Na-rich plagioclase, rutile, with possible perovskite, and garnet

Mid-infrared 2-D spectroscopic measurements from 8.0 to 12.7 μm of Mercury were taken using Boston University's Mid-Infrared Spectrometer and Imager (MIRSI) mounted on the NASA Infrared Telescope Facility (IRTF) on Mauna Kea, Hawaii, 7-11 April 2006. Measurements reported here cover radar bright region C, a dark plains region west of Caloris Basin, and the interior of Caloris Basin. By use of spectral deconvolution with a large spectral library composed of many mineral compositions and grain size separates, we fitted, or “unmixed”, the Mercury spectra. We find mineral suites composed of magnesium-rich orthopyroxene and olivine, Ca-, Mg-, Na-rich clinopyroxene, potassium feldspar, and Na-bearing plagioclase feldspar. Both Ca- and Mg-rich garnet (pyrope and grossular, respectively) are apparently present in small amounts. Opaque minerals are required for spectral matching, with rutile (TiO₂) repeatedly providing the “best fit”. However, in the case of the radar bright region C, perovskite also contributed to a very good fit. Caloris Basin infill is rich in both potassium feldspar and Na-rich plagioclase. There is little or no olivine in the Caloris interior smooth plains. Together with the high alkali content, this indicates that resurfacing magmas were low to intermediate in SiO₂. Data suggest the dark plains exterior to Caloris are highly differentiated low-iron basaltic magmas resulting in material that might be classified as oligoclase basalts.     

Mercury’s magnetosphere-solar wind interaction for northward and southward interplanetary magnetic field: Hybrid simulation results

Analysis of global hybrid simulations of Mercury’s magnetosphere-solar wind interaction is presented for northward and southward interplanetary magnetic field (IMF) orientations in the context of MESSENGER’s first two encounters with Mercury. The global kinetic simulations reveal the basic structure of this interaction, including a bow shock, ion foreshock, magnetosheath, cusp regions, magnetopause, and a closed ion ring belt formed around the planet within the magnetosphere. The two different IMF orientations induce different locations of ion foreshock and different magnetospheric properties: the dayside magnetosphere is smaller and cusps are at lower latitudes for southward IMF compared to northward IMF whereas for southward IMF the nightside magnetosphere is larger and exhibits a thin current sheet with signatures of magnetic reconnection and plasmoid formation. For the two IMF orientations the ion foreshock and quasi-parallel magnetosheath manifest ion-beam-driven large-amplitude oscillations, whereas the quasi-perpendicular magnetosheath shows ion-temperature-anisotropy-driven wave activity. The ions in Mercury’s belt remain quasi-trapped for a limited time before they are either absorbed by Mercury’s surface or escape from the magnetosphere. The simulation results are compared with MESSENGER’s observations.     

Spatial variations of the sodium/potassium ratio in Mercury’s exosphere uncovered by high-resolution spectroscopy

High-resolution spectroscopy of Mercury has been obtained with two different instruments in 2006: the EMMI instrument at the 3.6-m NTT telescope of ESO La Silla Chile and the ESPADON spectrograph at the 3.6-m CFHT telescope on top of Mauna Kea (Hawaii). The disk of the planet has been scanned for spatial variation of the exospheric species. The large spectral range and high resolution allow simultaneous measurements of the integrated column density of Na and K.We measure Na/K ratio between 80 and 400 with values between 60 and 90 when the telescope was pointed towards the subsolar region of Mercury’s disk and much larger value when we looked to other part of the exosphere. Moreover, we observed that the Na and K exospheres display very different spatial distributions. Even if these two species are probably ejected with very similar mechanisms from the surface, their differences in mass and sensitivity to solar pressure acceleration imply very different behavior in Mercury’s exosphere.     

Observations of metallic species in Mercury’s exosphere

From observations of the metallic species sodium (Na), potassium (K), and magnesium (Mg) in Mercury’s exosphere, we derive implications for source and loss processes. All metallic species observed exhibit a distribution and/or line width characteristic of high to extreme temperature - tens of thousands of degrees K. The temperatures of refractory species, including magnesium and calcium, indicate that the source process for the atoms observed in the tail and near-planet exosphere are consistent with ion sputtering and/or impact vaporization of a molecule with subsequent dissociation into the atomic form. The extended Mg tail is consistent with a surface abundance of 5-8% Mg by number, if 30% of impact-vaporized Mg remains as MgO and half of the impact vapor condenses. Globally, ion sputtering is not a major source of Mg, but locally the sputtered source can be larger than the impact vapor source. We conclude that the Na and K in Mercury’s exosphere can be derived from a regolith composition similar to that of Luna 16 soil (or Apollo 17 orange glass), in which the abundance by number is 0.0027 (0.0028) for Na and 0.0006 (0.0045) for K.     

Behavior of planetary dynamos under the influence of external magnetic fields: Application to Mercury and Ganymede

For planets with strong intrinsic magnetic fields such as Earth and Jupiter, an external magnetic field is unlikely to affect the internal dynamo, but for bodies with weak intrinsic fields in appropriate environments, such as Mercury and Ganymede, the interaction with nearby field sources may determine the internal dynamics and overall behavior of their liquid iron cores. On the basis of simulations of such interactions using numerical models for fluid flow and dynamo generation, the parameter regimes for stable dipolar and multipolar reversing dynamo magnetic fields established for isolated systems can be substantially changed by the action of external sources. Relatively weak external background fields (as low as 2% of the averaged undisturbed field at the core-mantle boundary) may change the energy balance and alter the regime over which natural isolated dynamos operate.     

Constraints on Mercury’s surface composition from MESSENGER and ground-based spectroscopy

The composition and chemistry of Mercury’s regolith has been calculated from MESSENGER MASCS 0.3-1.3 μm spectra from the first flyby, using an implementation of Hapke’s radiative transfer-based photometric model for light scattering in semi-transparent porous media, and a linear spectral mixing algorithm. We combine this investigation with linear spectral fitting results from mid-infrared spectra and compare derived oxide abundances with mercurian formation models and lunar samples. Hapke modeling results indicate a regolith that is optically dominated by finely comminuted particles with average area weighted grain size near 20 μm. Mercury shows lunar-style space weathering, with maturation-produced microphase iron present at ∼0.065 wt.% abundance, with only small variations between mature and immature sites, the amount of which is unable to explain Mercury’s low brightness relative to the Moon. The average modal mineralogies for the flyby 1 spectra derived from Hapke modeling are 35-70% Na-rich plagioclase or orthoclase, up to 30% Mg-rich clinopyroxene, <5% Mg-rich orthopyroxene, minute olivine, ∼20-45% low-Fe, low-Ti agglutinitic glass, and <10% of one or more lunar-like opaque minerals. Mercurian average oxide abundances derived from Hapke models and mid-infrared linear fitting include 40-50 wt.% SiO₂, 10-35 wt.% Al₂O₃, 1-8 wt.% FeO, and <25 wt.% TiO₂; the inferred rock type is basalt. Lunar-like opaques or glasses with high Fe and/or Ti abundances cannot on their own, or in combination, explain Mercury’s low brightness. The linear mixing results indicate the presence of clinopyroxenes that contain up to 21 wt.% MnO and the presence of a Mn-rich hedenbergite. Mn in M1 crystalline lattice sites of hedenbergite suppresses the strong 1 and 2 μm crystal field absorption bands and may thus act as a strong darkening agent on Mercury. Also, one or more of thermally darkened silicates, Fe-poor opaques and matured glasses, or Mercury-unique Ostwald-ripened microphase iron nickel may lower the albedo. A major part of the total microphase iron present in Mercury’s regolith is likely derived from FeO that is not intrinsic to the crust but has been subsequently delivered by exogenic sources.     

Monte Carlo modeling of sodium in Mercury’s exosphere during the first two MESSENGER flybys

We present a Monte Carlo model of the distribution of neutral sodium in Mercury’s exosphere and tail using data from the Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft during the first two flybys of the planet in January and September 2008. We show that the dominant source mechanism for ejecting sodium from the surface is photon-stimulated desorption (PSD) and that the desorption rate is limited by the diffusion rate of sodium from the interior of grains in the regolith to the topmost few monolayers where PSD is effective. In the absence of ion precipitation, we find that the sodium source rate is limited to ∼10⁶-10⁷ cm⁻² s⁻¹, depending on the sticking efficiency of exospheric sodium that returns to the surface. The diffusion rate must be at least a factor of 5 higher in regions of ion precipitation to explain the MASCS observations during the second MESSENGER flyby. We estimate that impact vaporization of micrometeoroids may provide up to 15% of the total sodium source rate in the regions observed. Although sputtering by precipitating ions was found not to be a significant source of sodium during the MESSENGER flybys, ion precipitation is responsible for increasing the source rate at high latitudes through ion-enhanced diffusion.