太原市大气扩散数值模拟

本文采用数值方法求解平流扩散方程，对太原市的一次示踪物实验进行了大气扩散的数值模拟。模拟结果表明：采用数值方法准确地反映出了由于风的切变而导致的污染物烟羽的转向，能较好地模拟复杂地形下太原市污染物的输送扩散过程。     

Chemical aspects of iron oxide coagulation in water: Laboratory studies and implications for natural systems

Initial coagulation rates of colloidal hematite (-Fe₂O₃) particles (diameter less than 0.1 µm) were measured experimentally in well-defined laboratory systems at constant temperature. The relative stability ratio,W, was obtained at various ionic strengths in NaCl medium and at pH values in the range from 3 to 12. ExperimentalW values ranged from 1 to 10⁴ in various systems. The results delineate the roles ofspecific andgeneralized coagulation mechanisms for iron oxides. Among the specifically-interacting species (G _ads ⁰ >G _coul ⁰ ) studied were phosphate, monomeric organic acids of various structures, and polymeric organic acids. The critical coagulation-restabilization concentrations of specifically-interacting anions (from 10^–7 to 10^–4 molar) can be compared with the general effects of non-specific electrolyte coagulants (10^–3 to 10^–1 molar). The laboratory results are interpreted with the help of a Surface Complex Formation/Diffuse Layer Model (SCF/DLM) which describes variations of interfacial charge and potential resulting from variations of coagulating species in solution. Comparison of these laboratory experiments with observations on iron behavior in estuarine and lake waters aids in understanding iron removal mechanisms and coagulation time scales in natural systems.     

Triassic warm subduction in northeast Turkey: Evidence from the Ağvanis metamorphic rocks

Within the Tethyan realm, data for the subduction history of the Permo–Triassic Tethys in the form of accretionary complexes are scarce, coming mainly from northwest Turkey and Tibet. Herein we present field geological, petrological and geochronological data on a Triassic accretionary complex, the A?vanis metamorphic rocks, from northeast Turkey. The A?vanis metamorphic rocks form a SSE–NNW trending lozenge‐shaped horst, ～20 km long and ～6 km across, bounded by the strands of the active North Anatolian Fault close to the collision zone between the Eastern Pontides and the Menderes–Taurus Block. The rocks consist mainly of greenschist‐ to epidote‐amphibolite‐facies metabasite, phyllite, marble and minor metachert and serpentinite, interpreted as a metamorphic accretionary complex based on the oceanic rock types and ocean island basaltic, mid‐ocean ridge basaltic and island‐arc tholeiitic affinities of the metabasites. This rock assemblage was intruded by stocks and dikes of Early Eocene quartz diorite, leucogranodiorite and dacite porphyry. Metamorphic conditions are estimated to be 470–540°C and ～0.60–0.90 GPa. Stepwise ⁴⁰Ar/³⁹Ar dating of phengite–muscovite separates sampled outside the contact metamorphic aureoles yielded steadily increasing age spectra with the highest incremental stage corresponding to age values ranging from ～180 to 209 Ma, suggesting that the metamorphism occurred at ≥ 209 Ma. Thus, the A?vanis metamorphic rocks represent the vestiges of the Late Triassic or slightly older subduction in northeast Turkey. Estimated P–T conditions indicate higher temperatures than those predicted by steady state thermal models for average subduction zones, and can best be accounted for by a hot subduction zone, similar to the present‐day Cascadia. Contact metamorphic mineral assemblages around an Early Eocene quartz diorite stock, on the other hand, suggest that the present‐day erosion level was at depths of ～14 km during the Early Eocene, indicative of reburial of the metamorphic rocks. Partial disturbance of white‐mica Ar–Ar age spectra was probably caused by the reburial coupled with heat input by igneous activity, which is probably related to thrusting due to the continental collision between Eastern Pontides and the Menderes–Taurus Block.     

三峡库区奉节县宝塔坪小区大型复杂滑坡特征及成因机制

奉节县新城宝塔坪小区的地质灾害问题是当前学术界关注的焦点,也是库区具有普遍性问题。本文首次提出,在小区发育有５个复杂结构的滑坡。滑坡具３种成因：（１）碎裂－溶蚀－杏黄色泥质条带发育－滑坡;（２）碎裂－溶蚀－Ｔ２ｂ＾２粉砂质泥岩顶层泥化－滑坡;（３）Ｔ２ｂ＾４泥岩溶蚀－滑坡。岩溶蚀作用为主导作用。断裂的发育为溶蚀作用提供了通道。     

浙东晚白垩世小雄破火山中火山-侵入杂岩的岩石成因

破火山内出露的火山岩与浅成侵入岩为硅质岩浆演化研究提供了 一个重要窗口,从而备受关注.小雄破火山内的火山-侵入杂岩是中国东南沿海晚白垩世岩浆活动的典型代表,包括小雄组火山岩(K2*)与两类侵入岩(花岗斑岩、正长斑岩).本文以小雄火山-侵入杂岩为研究对象,开展了系统的锆石U-Pb年代学、岩石学和地球化学研究,旨在深入探讨...     

直线立体匹配中遮挡问题的解

遮挡会引起不同视角图像中特征间"一配多"和"多配多"的复杂对应关系,是特征立体匹配面临的主要难题之一。本文提出一个遮挡存在条件下直线特征间对应关系的求解模型,在此基础上实现了一种能够完整建立各种对应关系的直线立体匹配算法。     

赣东北前寒武纪港边杂岩体的岩浆混合（和）作用及其地质意义

赣东北地区沿江绍断裂北缘和江南造山带南侧有大量的前寒武纪火山侵入杂岩呈带状分布,主要由大面积的陆相火山岩和若干长英质镁铁质火成杂岩体组成,后者中出露面积最大的港边杂岩体在填图尺度上可划分为长英质岩、镁铁质岩和过渡性岩3大组成部分,长英质岩颗粒锆石U_Pb谐和不一致曲线上交点年龄为822±4Ma,代表杂岩体中岩浆混合作用发生的时间。港边岩体中长英质岩石的Nd模式年龄为1·49~1·68Ga,镁铁质岩中玄武质岩石为1·51~2·21Ga,辉长岩的Nd模式年龄与玄武质岩石基本相同,为1·54~2·13Ga,经计算的过渡性岩石的Nd模式年龄为1·58~1·90Ga,因此认为镁铁质岩石从源区分离的时间要远早于长英质岩石,而过渡性岩石含有前两个端员岩浆相互混合(和)的信息。长英质岩石的εNd(t=822Ma)值为-0·8~-4·4,87Sr/86Sr(822)比值为0·70368~0·70549;玄武质岩石的εNd(822)值为-2·6~+2·3,87Sr/86Sr(822)比值为0·70387~0·70527,这反映了镁铁质岩浆的源区接近总地球,长英质岩浆则来自具壳幔混合性质的EMⅠ型地幔的源区。可以推测,赣东北前寒武纪也曾发生过岩浆底侵作用。底侵作用对港边火成杂岩体岩浆的形成起着重要的作用。底侵于壳幔边界的玄武质岩浆使地壳熔融形成长英质岩浆并聚集于浅部岩浆房。随着长英质岩浆房降温,长英质岩浆的结晶度和粘度增加,其物理状态发生液态→(固+液)混合态→固态的变化;当玄武质岩浆穿透下地壳并不断进入物理状态变化的长英质岩浆房时,持续地发生两种岩浆的化学混合作用或两岩浆的机械混合作用或玄武质岩浆的侵入,其混合作用的时间以长英质岩锆石的U_Pb谐和不一致曲线上交点年龄822±4Ma界定。根据Nd模式年龄(tDM)和Nd富集系数(fSm/Nd)分布特征,可以确定中元古代江南造山带为太古宙扬子古陆核的横向增生体,而新元古代陆相火山侵入杂岩带则横向增生于江南造山带南缘。至此,扬子古陆横向增生作用结束,开始与华夏古陆拼贴,包括港边火成杂岩体在内的新元古代火山侵入杂岩带则成为两古陆连结的纽带。     

大别杂岩中混合岩的矿物空间分布研究

介绍了矿物空间分布研究的基本原理及两种统计方法(接触频数法和线切法)。作者对混合岩矿物空间分布的研究表明:(1)前人提出的统计方法存在方法上的缺陷和应用上的局限性,作者推导出矿物接触类型的概率公式;(2)部分浅色体中矿物显示聚集分布的特征,而绝大部分的浅色体中矿物具有分散分布的特点。结合质量平衡和地球化学研究认为:大别杂岩中主体混合岩成因机制是重熔和交代作用。     

海水中磷酸盐在固体粒子上阴离子交换作用 海水中磷酸盐-固体粒子相互作用的台阶型等温线

通过研究氯化钠溶液中磷酸盐在4种固体粒子（针铁矿、δ－氧化锰、伊利石和高岭石）上的交换等温线及钙对上述交换等温线的影响，发现磷酸盐液－固界面作用的台阶型等温线（2个台阶），可用分级离子／配位子交换等温式定量描述。钙能够促进磷酸盐在针铁矿和δ－氧化锰上的交换作用，其机理是交换在固体粒子上的钙再结合溶液中的磷酸盐，形成表面无机三元络合物。     

岩石复电阻率Dias模型及其参数求取方法

Dias模型是众多描述岩石复电阻率的频散特性模型中的一种,它不但参数少,且可由这些参数导出具有特定物理意义的参数。针对Dias模型参数的求取及反演解的不确定性评价,这里提出了一种模拟退火阻尼最小二乘联合反演方法。该方法首先将参数求解空间离散化,利用模拟退火找到全局最优解区间,然后利用阻尼最小二乘法在解空间进行求解。该方法有效地克服了原来两种方法的反演速度慢、反演结果依赖于初值的缺点,并实现了对反演结果多解性的评价。研究结果表明,对于岩石复电阻率数据的处理解释,Dias模型的使用比传统的Cole模型及其变形更具有潜在的优势。