广西平桂地区观赏石简介

广西平桂地区观赏石资源丰富。本文简介该区观赏石的常见品种及其特点、成因类型、分布规律、质量评价及开发前景。     

海沟金矿区脉岩特征及其与金矿成矿关系

海沟金矿区脉岩发育,主要类型有闪长玢岩、次安山岩、徨绿岩、正长闪长玢岩,按其与矿脉穿切关系划分为矿脉就位前脉岩、就位后脉岩,它们的地球化学特征表明这些脉岩具有良好的同源演化关系,它们不仅与成矿具有密切的时空关系,而且为金矿成矿带来成矿流体和部分成矿物质.     

皖西贵池、宿松地区中下三叠统沉积环境及层序分析

摘要：皖西中、下三叠统为一套碳酸盐岩沉积。从下往上,其沉积环境经历了从盆地－开阔陆棚－开阔台地－局限台地－潮上蒸发台地这样一个海水逐渐变浅、盐度不断增高的环境演化序列．据露头剖面分析,这套碳酸盐岩地层可分成３个层序。层序均由低水位、海进和高水位体系域组成,特征明显。据其岩性特征及准层序的叠置方式,识别出了追赶碳酸盐体系（ｃａｔｃｈｕｐｃａｒｂｏｎａｔｅｓｙｓｔｅｍ）和并进碳酸盐体系（ｋｅｅｐｕｐｃａｒｂｏｎａｔｅｓｙｓｔｅｍ）。     

利用铝饱和指数评价中酸性岩浆岩的含矿性——以山西省210个中酸性岩体为例

利用常量元素地球化学特征参与评价岩体的含矿性具有重要意义.通过计算山西境内210个中酸性岩体的铝饱和指数,发现含矿岩体与非矿岩体的铝饱和指数存在一个明显的分界值,即铝饱和指数大于1.7的岩体基本与矿有关,小于此值的岩体绝大多数尚未发现与矿有关.铝饱和指数可能是反映岩体中矿元素活化释放程度或能力的一项重要指标,是本次探讨的重点,对评价其他区域中酸性岩的含矿性有重要参考意义.     

结晶岩的膨胀性能研究

采集了来自德国大陆深钻（ＫＴＢ）中的一组结晶岩,在实验室用位移记录仪或应变片接通电桥测量了岩石浸入不同流体中应变随时间的变化．结果表明：１．不同的岩石浸入水中,其膨胀速率和膨胀量是不同的,这与岩石的孔隙结构有关．２．同一岩样浸入极性和非极性的流体中,其膨胀性能是不同的,这与水分子的极化特性及其表面张力有关．３．很多情况下,膨胀是各向异性的,尤其是片麻岩．因此体积的增长可根据在３个互相垂直方向上的相对长度变化的总值来计算．可以认为,膨胀的主要因素是极性流体与岩石颗粒作用的结果,膨胀性能是由于颗粒表面的双扩散层造成的．实验证实了地壳岩石变形的机制强烈地受到流体的存在与否以及不同类型流体的影响．流体与岩石间相互作用的研究将对深入探讨地壳内流体的热过程、力学过程、油气运移以及岩石物理性质有重要意义．     

东营凹陷古近系升藿烷生物标志物参数分布及演变规律

为研究实际地质体或地质剖面中的C31到C3517α(H), 21β(H)升藿烷生物标志物构型转化参数22S/(22S+22R)及升藿烷指数C35/∑（C31—C35)等的分布、演化特征,对东营凹陷主要烃源岩层系古近系沙河街组三段（淡水—微咸水层系）和沙河街组四段（咸水层系）的系列样品进行了研究,分析样品来源于1 300~4 000的暗色泥岩,其中2 800~4 000 m的样品对应于东营凹陷古近系烃源岩的生油初期到生油晚期。研究结果表明,C31、C32、C33、C34、C35升藿烷（17α(H), 21β(H)）构型转化参数的分布除与异构体之间的手性碳立体构型转化作用有关外,不同异构体之间降解或裂解速率和新生成速率的差异也是其主要控制因素,沉积环境（如高盐环境）也在一定程度上影响了其分布;从未熟—低熟状态到成熟状态,相关升藿烷构型转化参数22S/(22S+22R)总体均表现出随埋藏深度增大而加大的特点,并从离散状态聚集到热演化的平衡状态附近;在到达成熟状态后,相关升藿烷的构型转化参数22S/(22S+22R)从缓慢增大过渡到一个持续的热演化平衡状态,并且该构型转化参数的热演化平衡状态对应于生油门限附近;在高盐环境中除C33升藿烷保持不变的热演化平衡状态外,其它升藿烷均呈现不同幅度的逆转特征,表明高含量的盐类矿物对升藿烷成熟度参数亦具有抑制作用或迟缓效应;C31、C32、C33、C34、C3517α升藿烷之间的22S/(22S+22R)分布型式复杂多变,其中对于成熟源岩样品,C35升藿烷22S/(22S+22R)值变化强烈,表现出“翘尾”状的上升型特征和“坠尾”状的下降型特征,而对于低熟—未熟样品, C32升藿烷的22S/(22S+22R)显示相对高值,并且多数样品显示为C31C33C35的偶数碳优势的特征;研究显示C31到C33升藿烷的构型转化参数S/(S+R)热演化平衡值均为0.6,而C34 S/(S+R)及C35S/(S+R)热演化平衡值相对较高,沙三段、沙四段的C34 S/(S+R)及沙四段的C35S/(S+R)分别达到0.63、0.62、0.65;升藿烷指数C35/∑（C31—C35)受热演化影响也比较明显,在生油期间随着埋藏深度增加而减小,在高盐环境中表现出相对高值,研究表明该指数的变化与其22R异构体演化有关,并且参数C31/∑（C31—C35）、C32/∑（C31—C35）、C33/∑（C31—C35）、C34/∑（C31—C35）、C35/∑（C31—C35)演化特征截然不同。     

勉略构造带新元古代洋盆俯冲作用：来自略阳地区纸房沟岩片火山岩锆石U- Pb年龄和Lu- Hf同位素的证据

纸房沟岩片位于勉略构造带略阳地区。通过细致的岩石学和地球化学研究,将纸房沟岩片内的火山岩分为拉斑玄武岩系列（Ⅰ类）和钙碱性火山岩系列（Ⅱ类）。Ⅰ类火山岩稀土配分曲线左倾,富Na贫P,整体具有N- MORB特点,形成于洋脊构造环境。相比Ⅰ类火山岩,Ⅱ类火山岩具有更高的SiO2(49.02％~61.86％)和K2O(0.32％~1.55％)含量,相对亏损Nb、Ta、P和Ti,形成于陆缘弧构造环境。Ⅱ类火山岩锆石Lu- Hf同位素测试结果显示,εHf(t)值主体为负值,介于-8.01~+0.77,表明其主要为古老地壳物质熔融成因。Ⅱ类火山岩LA- ICP- MS锆石U- Pb测年结果为854±3Ma(MSWD=0.12, n=30)、844±4Ma (MSWD=0.03, n=15),表明纸房沟岩片火山岩结晶时代为新元古代早中期。综合前人成果认为,纸房沟岩片火山岩为新元古代勉略洋盆俯冲的产物,俯冲作用一直持续到800Ma左右,该俯冲过程很可能是对全球性Rodinia超大陆聚合事件的响应。     

Distribution Characteristics of Effective Source Rocks and Their Control on Hydrocarbon Accumulation: A Case Study from the Dongying Sag, Eastern China

The exploration conducted in the Bohai Bay basin, eastern China has demonstrated that the abundant petroleum resources have close affinities to the hydrocarbon kitchen with rich organic matter. A number of oil-generating associations with various characteristics of organic geochemistry and assemblages of multiple reservoir facies are developed due to the multi-center sedimentation, multi-source supply and multi-cycle evolution of filling, which have resulted in the formation of multiple oil and gas accumulation zones of various layers and trap styles. Among them the Paleogene Shahejie Formation is the most important hydrocarbon accumulation combination in the Dongying sag. Heretofore, its proved reserve has reached nearly 1.8×109t, which accounts for more than 90% of the total proved reserves of the Dongying sag. Based on previous studies, more than 600 source rock samples and 186 crude oil samples of the Shahejie Formation, collected from 30 oilfields, have been treated with organic geochemical testing     

Marine hydrocarbon source rocks of the Upper Permian Longtan Formation and their contribution to gas accumulation in the northeastern Sichuan Basin,southwest China

Identification of the main hydrocarbon source rocks of the large Puguang gas field (northeastern Sichuan Basin, southwest China) has been the subject of much discussion in recent years. A key aspect has been the lack of a comprehensive understanding of the development of hydrocarbon source rocks of the Upper Permian Longtan Formation, which had been thought to contain mainly coal seams and thick carbonate layers. In this paper, based on geological data from more than ten wells and outcrops and their related mineralogy and geochemistry, we investigated the depositional environment and main factors controlling organic matter enrichment in the Longtan Formation. We propose a model which combines information on the geological environment and biological changes over time. In the model, organic matter from prolific phytoplankton blooms was deposited in quiescent platform interior sags with rising sea-levels. During the Longtan period, the area from Bazhong to Dazhou was a platform interior sag with relatively deep water and a closed environment, which was controlled by multiple factors including syngenetic fault settling, isolation of submarine uplifts and rising sea-levels leading to water column stratification. Although the bottom water was anoxic, the phytoplankton were able to bloom in the well-lit upper euphotic zone thus giving rise to a set of sapropelic black shales and marlstones containing mostly algal organic matter with minor terrestrial contributions. As a consequence, these rocks have a high hydrocarbon generation potentials and can be classified as high-quality source rocks. The area from Bazhong to Dazhou is a center of hydrocarbon generation, being the main source of reservoired paleo-oils and presently discovered as pyrobitumen in the Puguang gas field. The identification of these source rocks is very important to guide future petroleum exploration in the northeastern Sichuan Basin.     

Petroleum composition in the Cuu Long Basin (Mekong Basin) offshore southern Vietnam

The Cuu Long Basin (Mekong Basin) is a rift basin off southern Vietnam, and the most important petroleum producing basin in the country. However, information on petroleum type and characteristics has hitherto been largely unavailable to the public. This paper presents petroleum geochemical data on nine oil samples from four different producing fields in the Cuu Long Basin: the Dragon (Rong), Black Lion (Sutu-Den), Sunrise (Rang ?ong) and White Tiger (Bach Ho) Fields. The oils are highly paraffinic with bimodal normal alkane distributions and show moderate pristane to phytane ratios and a conspicuous hyperbolic decrease in abundance with increasing carbon number of hopane homologues from C₃₀ to C₃₅. The TPP-index of Holba et al. (Holba, A.G., Dzou, L.I., Wood, G.D., Ellis, L., Adam, P., Schaeffer, P., Albrecht, P., Greene, T., Hughes, W.B., 2003. Application of tetracyclic polyprenoids as indicators of input from fresh–brackish water environments. Organic Geochemistry 34, 441–469) is equal to 1 in all samples which in combination with tricyclic triperpane T26/T25 ratios >1 and the n-alkane and hopane distributions mentioned above provide a strong indication of an origin from lacustrine source rocks. This is supported by the absence of marine C₃₀ desmethyl steranes (i.e. 24-n-propylcholestanes) and marine diatom-derived norcholestanes. Based on the overall biological marker distributions, the lakes probably belonged to the overfilled or balanced-fill types defined by Bohacs et al. (Bohacs, K.M., Carroll, A.R., Neal, J.E., Mankiewicz, P.J., 2000. Lake-basin type, source potential, and hydrocarbon character. An integrated sequence-stratigraphic–geochemical framework. AAPG Studies in Geology 46, 3–34). The oils were generated from source rocks at early- to mid-oil-window maturity, presumably Oligocene lacustrine shales that are present in the syn-rift succession. Oils from individual fields may, however, be distinguished by a combination of biological marker parameters, such as the oleanane index, the gammacerane index, the relative abundance of tricyclic terpanes, the proportions of diasteranes and 28-norspergulane, complemented by other parameters. The oils of the Cuu Long Basin show an overall similarity to the B-10 oil from the Song Hong Basin off northern Vietnam, but are markedly different from the seepage oils known from Dam Thi Nai on the coast of central Vietnam.