Geochemical Stream Sediment Survey in the Wadi Umm Rilan Area, South Eastern Desert, Egypt: A New Occurrence for Gold Mineralization

The present paper investigates the stream sediment geochemistry, behavior of gold and associated elements, delineates Au-anomalous sites and defines related sources in the Wadi Umm Rilan area. Fifty three major and trace elements were analyzed using ICP-MS and treated applying various statistical and mapping techniques. The results showed a significant difference of mean and median Au and most chemical elements in the three portions of the area, and higher values were recorded in the western portion. Furthermore, Au-anomalous sites appeared in upper and lower parts of the Wadi Umm Rilan, along the tributaries of metavolcanic unit and near granitoid contacts. This indicates the main source of Au mineralization is related to emplacement of granitoid plutons and accompanying hydrothermal solutions. There are significant indications for the presence of more than one mineralization event forming a probable single major episode of mineralization in the area, involving Au, Pb and U mineralizations. Geology, geomorphologic aspects and weathering processes could control stream sediment geochemistry, anomalies of Au and associated elements, elemental association and their dispersion patterns. Therefore, the area is fruitful and regarded as a promising target for Au exploration, using Ag, As, Sb, Cd, Cs, and Tl as pathfinder elements.     

Low-temperature alteration of uranium–thorium bearing minerals and its significance in neoformation of radioactive minerals in stream sediments of Wadi El-Reddah,North Eastern Desert,Egypt

The stream sediments of Wadi El Reddah(North Eastern Desert,Egypt)are geochemically and mineralogically investigated.Their content of radioactive and other heavy minerals is mainly represented by thorite,uranothorite,zircon,monazite,xenotime,columbite,fergusonite,and unknown rare earth elements(REEs)bearing minerals as well as cassiterite.Special emphasis on REE content of thorite,uranothorite,zircon and xenotime has been done to correlate them with the increase of uranium contents in these sediments.The key evidence for the presence lowtemperature alteration processes includes the presence of some zircon crystals as remnants after complete dissolution of the overgrowth zircon in severe acidic environment,the sulphur content,biogenic minerals,occurrence of unusual minerals as cassiterite pore filling in zircon,variation in the REEs content from the surrounding granites to the stream sediments and the abundance of monazite in the surrounding granites.Most minerals are partially and/or completely altered,which indicated by the pseudomorphism of zircon by xenotime,thorite,and uranothorite.     

Luminescence dating of ephemeral stream deposits around the Palaeolithic site of Ifri n'Ammar (Morocco)

The prehistoric site of Ifri n'Ammar is situated in northeastern Morocco, in the northern prolongation of the Middle Atlas Mountains. It is a key location in unravelling the history of anatomically modern humans (AMH) in northern Africa as it reveals Middle and Late Palaeolithic occupation phases since ∼170 ka. Whilst the archaeological sequence within the rock shelter has been well studied, the timing of landscape dynamics around Ifri n'Ammar is still poorly understood. This study therefore aims to establish a detailed chronology of the Wadi Selloum profile at the apron of the shelter, based on optically stimulated luminescence (OSL) dating of ephemeral stream deposits. Coarse-grain quartz was used for single-grain and multiple-grain dating procedures to investigate the luminescence properties of these deposits and to get more accurate age information concerning the phases of human occupation. Continuous wave OSL (CW-OSL) revealed a dominant fast component for all quartz samples. The dose distribution of the uppermost samples showed overdispersion values >25% and significant positive skewness. We identified partial bleaching as the main source of scatter in the equivalent dose (D_e) distribution. The lowermost sample appeared to be close to signal saturation. The shapes of the dose response curve varied widely between aliquots and coarse quartz grains exhibited therefore very different dose saturation behaviours among aliquots. With fully saturated dose response curves (DRCs), meaningful D₀ values were assumed for D_e estimation.The eight OSL samples yielded stratigraphically consistent ages ranging from 1.3 ± 0.2 ka to 76 ± 5 ka, thus reaching the Middle Palaeolithic period. Moreover, a pottery shard dated to 7.4 ± 0.6 ka (Early Neolithic period) by thermoluminescence (TL), perfectly matched the Holocene OSL samples extracted at the same depth of the profile. In summary, our results point to fluvial aggradation during OIS 5.1, the late glacial period, and the Holocene.     

Alteration Mechanisms of Chromian-Spinel during Serpentinization at Wadi Sifein Area, Eastern Desert, Egypt

Wadi Sifein podiform chromite deposits, Central Eastern Desert of Egypt, are hosted by fully serpentinized peridotite that is a part of the dismembered Pan‐African ophiolite complexes. Relics of primary minerals and the chemical characters indicate that the ophiolitic rocks were derived from depleted mantle peridotite of harzburgite and subordinate dunite compositions. The mantle rocks were initially formed at a mid‐oceanic ridge and subsequently thrust at a supra‐subduction zone. The chromite mineralization at Wadi Sifein area displays either pod‐shaped bodies with massive and lumpy chromitite appearance or dissemination of chromian‐spinel in serpentinite matrix. The podiform chromitite exhibits a very limited compositional range in terms of Cr# [Cr/(Cr + Al) atomic ratio] and Mg# [Mg/(Mg + Fe) atomic ratio]. The chromian‐spinel, however, frequently displays optical and geochemical zoning. Four zones can be identified from core to edge: inner core representing the original composition of the chromian‐spinel; narrow Cr‐rich ferritchromit zone; wide ferritchromit zone; and outer Cr‐magnetite/magnetite zone. The zonation of chromian‐spinel is interpreted to be a result of serpentinization rather than magmatic or metamorphic processes. The geochemical data obtained from the chromitite and chromian‐spinel was statistically processed using discriminant and R‐mode factor analyses. Two trends, minor and major, were achieved considering the formation of ferritchromit. The minor trend is controlled by the redistribution of trivalent cations, where Cr₂O₃ increased on the expense mainly of Al₂O₃ and to less extent Fe₂O₃ to form zone II during the peak of serpentinization. The major trend of alteration, however, is explained by the exchange between Mg‐Fe²⁺ rather than Cr, Al, and Fe³⁺ to form zone III. Kammererite formation was accompanied the formation of zones III and IV at a 314°C temperature of formation.     

Geology and fluid inclusion of Wadi Sharis Neoproterozoic orogenic gold deposits in northwestern Yemen

The Wadi Sharis orogenic gold deposit in northwestern Yemen is related to the fault and shear zones vein at medium depth in the crust in the Neoproterozoic meta-sedimentary and meta-volcanosedimentary succession of greenschist to amphibolite facies metamorphism.Three distinct fluid inclusion types have been identified in the gold-bearing quartz sulphide veins of the deposit:(1) type I:vapour-liquid two-phase(VH2O-LH2O),(2) type II:three-phase CO2(VCO2-LH2O-LCO2) and(3) type III:vapour-rich(LCO2-VCO2) inclusions.Six analysis of individual fluid inclusion indicate the fluid inclusions comprise mainly of H2O and CO2.Formation P-T conditions recorded by fluid inclusions in quartz crystals correspond to 180℃-380℃ and up to 130 MPa,as indicated by high-density CO2 bubbles(up to 0.98 g/cm3) observed in some inclusions.The estimated crystallization pressures correspond to approximately 4-10 km of overburden,assuming a lithostatic load.The salinity ranges from 0 to 22 wt%.The deposit holds at 0.2-5 g/t Au and contains low-moderate salinity.     

Geochemistry and genesis of magmatic PGE-bearing Cu-Ni sulphide deposit in Wadi Bayhan，southeastern Yemen

The Wadi Bayhan mafic-ultramafic intrusions associated with magmatic PGE-bearing Cu-Ni sulphide deposit are located in the south margin of the Arabian-Nubian Shield,SW Yemen.The intrusions consist of dunite,olivine-pyroxenite,lherzolite,hornblendite,gabbro and gabbronorite.The dunite and lherzolite are the main host rock for the Cu-Ni ores.The new data of the chemical compositions of the rocks have SiO2(50%-53.6%),Al2O3(0-32%) and MgO(4%-28%),and relatively low TiO2(0-3.2%) and K2O+Na2O(0.04%-5.2%).The geochemical characteristics indicate that the parental magma is high-magnesium tholeiitic.Sulfur had reached saturation and immiscible sulfides droplets segregated from silicate magmas before their emplacement.     

Groundwater recharge and salinization in the arid coastal plain aquifer of the Wadi Watir delta,Sinai, Egypt

The Quaternary coastal plain aquifer down gradient of the Wadi Watir catchment is the main source of potable groundwater in the arid region of south Sinai, Egypt. The scarcity of rainfall over the last decade, combined with high groundwater pumping rates, have resulted in water-quality degradation in the main well field and in wells along the coast. Understanding the sources of groundwater salinization and amount of average annual recharge is critical for developing sustainable groundwater management strategies for the long-term prevention of groundwater quality deterioration. A combination of geochemistry, conservative ions (Cl and Br), and isotopic tracers (^87/86Sr, δ⁸¹Br, δ³⁷Cl), in conjunction with groundwater modeling, is an effective method to assess and manage groundwater resources in the Wadi Watir delta aquifers. High groundwater salinity, including high Cl and Br concentrations, is recorded inland in the deep drilled wells located in the main well field and in wells along the coast. The range of Cl/Br ratios for shallow and deep groundwaters in the delta (∼50–97) fall between the end member values of the recharge water that comes from the up gradient watershed, and evaporated seawater of marine origin, which is significantly different than the ratio in modern seawater (228). The ^87/86Sr and δ⁸¹Br isotopic values were higher in the recharge water (0.70,723 < ^87/86Sr < 0.70,894, +0.94 < δ⁸¹Br < +1.28‰), and lower in the deep groundwater (0.70,698 < ^87/86Sr < 0.70,705, +0.22‰ < δ⁸¹Br < +0.41‰). The δ³⁷Cl isotopic values were lower in the recharge water (−0.48 < δ³⁷Cl < −0.06‰) and higher in the deep groundwater (−0.01 < δ³⁷Cl < +0.22‰). The isotopic values of strontium, chloride, and bromide in groundwater from the Wadi Watir delta aquifers indicate that the main groundwater recharge source comes from the up gradient catchment along the main stream channel entering the delta. The solute-weighted mass balance mixing models show that groundwater in the main well field contains 4–10% deep saline groundwater, and groundwater in some wells along the coast contain 2–6% seawater and 18–29% deep saline groundwater.A three-dimensional, variable-density, flow-and-transport SEAWAT model was developed using groundwater isotopes (⁸⁷Sr/⁸⁶Sr, δ³⁷Cl and δ⁸¹Br) and calibrated using historical records of groundwater level and salinity. δ¹⁸O was used to normalize the evaporative effect on shallow groundwater salinity for model calibration. The model shows how groundwater salinity and hydrologic data can be used in SEAWAT to understand recharge mechanisms, estimate groundwater recharge rates, and simulate the upwelling of deep saline groundwater and seawater intrusion. The model indicates that most of the groundwater recharge occurs near the outlet of the main channel. Average annual recharge to delta alluvial aquifers for 1982 to 2009 is estimated to be 2.16 × 10⁶ m³/yr. The main factors that control groundwater salinity are overpumping and recharge availability.     

Sedimentary environments and depositional characteristics of the Middle to Upper Eocene whale‐bearing succession in the Fayum Depression,Egypt

The discovery of whale fossils from Eocene strata in the Fayum Depression has provoked interest in the life and lifestyle of early whales. Excellent outcrop exposure also affords the dataset to develop sedimentological and stratigraphic models within the Eocene strata. Previous work generally asserts that the thick, sand‐rich deposits of the Fayum Depression represent shoreface and barrier island successions with fine‐grained lagoonal and fluvial associations capping progradational successions. However, a complete absence of wave‐generated sedimentary structures, a preponderance of thoroughly bioturbated strata and increasingly proximal sedimentary successions upwards are contrary to accepted models of the local sedimentological and stratigraphic development. This study considers data collected from two Middle to Upper Eocene successions exposed in outcrop in the Wadi El‐Hitan and Qasr El‐Sagha areas of the Fayum Depression to determine the depositional affinities of Fayum strata. Based on sedimentological and ichnological data, five facies associations (Facies Association 1 to Facies Association 5) are identified. The biological and sedimentological characteristics of the reported facies associations indicate that the whale‐bearing sandstones (Facies Association 1) record distal positions in a large, open, quiescent marine bay that is abruptly succeeded by a bay‐margin environment (Facies Association 2). Upwards, marginal‐marine lagoonal and shallow‐bay parasequences (Facies Association 3) are overlain by thick deltaic distributary channel deposits (Facies Association 4). The capping unit (Facies Association 5) represents a transgressive estuarine depositional environment. The general stratigraphic evolution resulted from a regional, tectonically controlled second‐order cycle, associated with northward regression of the Tethys. Subordinate cycles (i.e. third‐order and fourth‐order cycles) are evidenced by several Glossifungites‐ichnofacies demarcated discontinuities, which were emplaced at the base of flooding surfaces. The proposed depositional models recognize the importance of identifying and linking ichnological data with physical–sedimentological observations. As such – with the exception of wave‐generated ravinement surfaces – earlier assertions of wave‐dominated sedimentation can be discarded. Moreover, this study provides important data for the recognition of (rarely reported) completely bioturbated sand‐dominated offshore to nearshore sediments (Facies Association 1) and affords excellent characterization of bioturbated inclined heterolithic stratification of deltaic deposits. Another outcome of the study is the recognition that the whales of the Fayum Depression are restricted to the highstand systems tracts, and lived under conditions of low depositional energy, low to moderate sedimentation rates, and (not surprisingly) in fully marine waters characterized by a high biomass.