Origin and mechanisms of K–Si-metasomatism of ca. 3.4–3.3 Ga volcaniclastic deposits and implications for Archean seawater evolution: Examples from cherts of Kittys Gap (Pilbara craton, Australia) and Msauli (Barberton Greenstone Belt, South Africa)

The effects of K–Si-metasomatism during the formation of Early Archean replacement cherts have been quantified in this study by the investigation of two well-known stratigraphic sections: the Msauli chert (MC, Barberton greenstone belt, South Africa) and the Kittys Gap chert (KGC, Pilbara craton, Western Australia). The KGCs have a dacitic precursor similar to Duffer Formation dacites (Pilbara craton), while the MCs are derived from Al-depleted komatiites similar to those from the Weltevreden Formation (Barberton greenstone belt). Mass balance calculations reveal that the volcaniclastic deposits had initial porosities of up to 85 vol.% for the KGC and of 65 vol.% for the MC. Secondary porosities (27 vol.%: MC, 8 vol.%: KGC) produced during K-metasomatism are proportional to the dissolution of Fe, Ca, Mg-rich glass and precursor minerals. Komatiites have a higher chemical exchange potential than dacites, each gram releasing 1.2 mmol Fe²⁺, 2.8 mmol Mg²⁺, 1.4 mmol Ca²⁺ and 1.1 mmol Na⁺ to seawater, together with 4.4 mmol O²⁻. K-metasomatism of 1 g of komatiite further implies an uptake of 0.67 mmol of K⁺ and 2.7 mmol of H⁺. The highest silica uptake is achieved for the KGC (82 mmol/g of precursor). This silica enrichment most likely operated in the water column and at the sediment–water interface by sorption mechanisms on the surface of detrital particles and particulate organic matter, as a result of seawater silica-saturation. Acidic conditions (pH 5.5–6.5) and hot temperatures (>70 °C) favored the formation of K-rich phyllosilicates by interaction with seawater during the early diagenetic alteration of the volcaniclastic particles. The widespread occurrence of K–Si-metasomatism in volcanic and sedimentary rocks can be regarded as a general alteration process of the Early Archean seafloor, with a major influence on seawater composition. The highly K-selective metasomatism confirms previous studies suggesting that the Archean ocean was acidic and probably in equilibrium with a CO₂-rich atmosphere.     

赣南淘锡坑钨多金属矿床花岗岩和云英岩岩石特征及云英岩中白云母40Ar/39Ar定年

赣南崇义县淘锡坑钨矿位于南岭东西向构造带东段,属于以黑钨矿石英脉型为主的钨多金属矿床。矿床形成与燕山期中酸性岩浆作用有密切关系,石英矿脉受一组北西向断裂控制,穿切新元古界。本文在淘锡坑钨矿区3个揭露到花岗岩体顶部的中段（206、106、56中段）采集到岩体顶部云英岩样品,利用40Ar/39Ar同位素定年测得云英岩中的白云母的坪年龄分别为152.7 ± 1.5 Ma（206中段）,153.4 ± 1.3 Ma（106中段）,155.0 ± 1.4 Ma（56中段）。与前人用其他方法测定的花岗岩成岩和成矿年龄几乎一致。花岗岩和云英岩全岩稀土元素均具有M型四分组效应和强烈的Eu亏损特征,反映出花岗质岩浆经历了高度分异演化及其岩体结晶晚期流体/熔体相互作用。综合前人在南岭地区同类矿床的研究资料,可知南岭地区160～150Ma成岩成矿作用主要分布于南岭中-东段,可能为大陆边缘弧后岩石圈伸展的构造动力学背景的产物。     

柴达木盆地北缘侏罗系不同沉积环境烃源岩生物标志物特征及其应用

柴达木盆地北缘地区侏罗系(中下侏罗统)的优质烃源岩主要发育于湖相与三角洲相环境。研究了不同时代、不同沉积环境中烃源岩的生物标志物组成特征,结果发现,有3类化合物的分布与组成差异显著,包括三环萜烷(C19、C20、C21)的分布型式、重排藿烷的丰度以及规则甾烷的相对组成。其中,不同时代的差异主要体现在规则甾烷组成上;而不同沉积环境的差异主要体现为三环萜烷(C19、C20、C21)的分布型式及重排藿烷的丰度。分析认为,这些差异与烃源岩的沉积环境及其生源组成有密切关系。据此,初步将这些参数应用于两方面研究,一是为划分地层沉积环境提供“生物标志物相标志”,二是研究油源对比,取得良好效果。因此,本文研究结果具有重要实用价值与参考意义。     

山东省济宁强磁异常区深部铁矿初步验证及其意义

山东省济宁磁异常是一个重、磁同源体,面积大于100 km2,磁异常峰值为3800nT。钻探验证在孔深1041.57～1796.54m位置发现铁矿体,矿体总厚度74.04～220m,磁性铁平均品位15.89～25.19%。矿石类型有条带状方解磁铁石英岩和条带状磁铁石英大理岩,矿石的主要组成矿物为石英、方解石、磁铁矿、磁赤铁矿、菱铁矿。矿体产于济宁岩群浅变质岩系中,矿床特征与条带状铁建造（BIF）铁矿或鞍山式铁矿有明显区别,铁矿成因类型属与千枚岩、变质中酸性火山岩、大理岩有关的沉积变质型铁矿床。该区铁矿资源潜力巨大。     

华北地台东部石炭系—二叠系优质煤储层形成分布控制因素

优质煤储层在此指厚度大、分布广、储集物性好的煤层。沉积相对优质煤储层的形成和分布有重要控制作用。通过浅海和泻湖淤积填平发育起来的潮坪环境和三角洲环境是最有利的优质煤储层形成环境,煤储层厚度大、分布广。沉积环境对煤储层中的灰分含量和镜质组含量有重要影响,而灰分含量和镜质组含量又直接影响煤储层的储集物性。灰分充填了煤储层中的孔隙,其含量越高,储集物性越差;镜质组有利于割理的形成,其含量越高,储集物性越好。由于在灰分含量、煤岩显微组分等方面的差异,潮坪环境沉积的煤储层的储集物性优于三角洲的煤储层,下三角洲平原沉积的煤储层优于上三角洲平原沉积的煤储层。海平面变化对优质煤储层的形成和分布也有重要控制作用。高位体系煤储层富集,单层厚度大,横向分布相当稳定,尤其是高位体系域晚期,是形成优质煤储层最有利的层位。而水进体系域煤储层稀少,单层厚度小,横向分布不稳定,不利于优质煤储层形成。     

江西浒坑钨矿含矿石英脉的地质特征及成矿构造演化

位于赣西武功山地区的江西浒坑钨矿是一个大型石英脉型钨矿床,与赣南典型的“五层楼”模式不同,矿脉主要集中在岩体内接触带。含矿石英脉除了普通的块状构造以外,还普遍存在条带状构造。详细的野外编录和镜下研究表明含矿块状石英脉在形成后遭受不同程度的韧性剪切,从而形成不同成分的分异条带。剪切带以出现新生的面理和线理（拉伸线理）为特征。岩石学研究表明条带状矿石属于糜棱岩,具有丰富的塑性变形显微构造特征。通过对含矿石英脉的构造解析,认为与岩浆岩有关的原生节理系统基本上是同时形成的,沿节理充填的石英脉经历了长期的、多期次的构造运动,从而形成了复杂的石英脉和矿石类型。建立了原生节理形成→石英充填→韧性剪切发生→二期石英充填→脆性碎裂的矿区构造演化序列。韧性剪切作用的动力学背景可能是受后期岩浆侵入的影响,最后的脆性破裂应与区域上存在南北向的压应力有关。     

江西省武功山地区浒坑钨矿床的Re-Os年龄及其地质意义

浒坑钨矿床是位于江西省中部武功山成矿带的大型石英脉型黑钨矿床。为了确定该矿床的成矿时代,笔者选取了浒坑含钨石英脉中与黑钨矿共生的辉钼矿进行了高精度Re-Os同位素定年,并获得5个辉钼矿样品的Re-Os等时线年龄和模式加权平均年龄分别为150.2±2.2Ma和149.82±0.92Ma。测年数据表明浒坑钨矿床的成矿时代为150Ma左右,是华南地区中生代大规模成岩成矿作用高峰期的产物。辉钼矿含铼较低,表明成矿物质可能来自壳源,与形成浒坑花岗岩体的燕山期重熔S型花岗岩岩浆活动有关。该矿床形成于燕山期岩石圈伸展减薄环境。     

Determination of historical emission of heavy metals into the atmosphere: Celje case study

The research shows that in the Celje area (Slovenia), the historical anthropogenical emissions are 1,712 tons of Zn and 9.1 tons of Cd. For Zn, this value represents approximately 0.3% of the total Zn production in that area. Close to the former zinc smelting plant, the “Zn precipitation” has been estimated to be up to 0.036 mm. The 100-year Zn production left behind a heavily contaminated area with maximum concentrations of Zn of up to 5.6% in attic dust and 0.85% in the soil, and 456 mg/kg of Cd in attic dust and 59.1 mg/kg in the soil. The calculation of historical emissions is based on the data of heavy metals concentration in the attic dust at 98 sampling points and on the data from 19 measurement sites of the weight of total monthly air deposit. The main idea behind determining past emissions is that when the weight of the deposited dust on a small area is multiplied by the concentration of the element in that area, the mass of the polluter which has been transported to the place of interest by air can be calculated. If we sum up all the weight over the whole geochemical anomaly, we get the quantity of historical emissions.     

金川镍铜矿床数学模型对深部矿化变化趋势的指示

按矿化特征将金川X矿区主矿体分为致密块状特富矿、海绵状富矿和浸染状贫矿.应用MicroMine软件对3类矿化体分别建立了数学模型,并应用距离平方反比法对模型单元块进行了镍、铜品位估值.通过分析和对比矿床数学模型900m至1300m不同水平剖面上的Ni、Cu品位及Ni/Cu比值的变化,得出在X矿区的中部西侧是一个Ni和Cu的矿化中心,并且向深部Cu的矿化强度高于Ni.     

冀北万全寺银金矿床地质地球化学特征

万全寺银金矿床位于张宣幔枝构造东侧的侏罗纪断陷盆地中,成矿时限晚于133.33Ma～101.82 Ma.通过硫、铅、氢、氧、碳及稀有气体同位素研究认为,成矿物质应源自地球深部,在中生代冀西北幔枝构造演化过程中集中成矿.成矿热液以岩浆水为主并加入了部分天水.