Cu–Fe Bearing Zinc Sulfide from Laloki Stratabound Massive Sulfide Deposit, Papua New Guinea: Chemical Characterization

Abstract: A strange, unidentified, Cu-Fe bearing zinc sulfide occurs in the Laloki massive sulfide deposit, Papua New Guinea. The mineral is optically uniform in texture but is chemically variable and zoned even within a single grain. Copper contents vary from 0.1 up to 8.85 wt%. Iron reaches 18.31 wt% at maximum and decreases as Cu increases. It is remarkable, however, that the total Fe+Cu remains essentially unchanged between roughly 18 and 20 wt%. Zn and S are least variable, giving 45.85–47.84 wt% and 33.48–34.58 wt%, respectively. Other trace elements such as Cd and Mn are in general less than 0.2 wt%. It is strongly suggested that the mineral in question constitutes a unique Fe-Cu substitutional solid solution series belonging essentially to the Zn–Fe–Cu–S system.
The ideal chemical formula of the solid solution series can well be presented as Zn₁₀(Fe, Cu)₅S₁₅ or Zn₂(Fe, Cu)S₃, where Fe is always greater than Cu. It is intriguing that chalcopyrite blebs are recognizable restrictively only in nearby portions of the Cu-rich end member with the ideal composition close to Zn₁₀Fe₃Cu₂S_15. It has been confirmed by vacuum-sealed heating experiments that this mineral is decomposed to produce chalcopyrite and Fe-bearing normal sphalerite at temperatures below 200C. This would provide another evidence for the existence of such distinct phase as suggested here.     

Horizontal and vertical components of earthquake ground motions at liquefiable sites

Field observations on ground motions from recent earthquakes imply that current knowledge is limited with regard to relating vertical and horizontal motions at liquefiable sites. This paper describes a study with the purpose of clarifying this emerging issue to some extent. A series of numerical analyses is carried out on a liquefiable soil deposit with a verified, fully coupled, nonlinear procedure. It is shown that the transformation of vertical motions in the deposit differs considerably from the transformation of horizontal motions. Both the amplitude and frequency content of the horizontal motions are strongly dependent on the shaking level or the associated nonlinear soil behavior. The transfer function for vertical motions is however likely to be independent of the intensity of input motions; no reduction in the amplitude occurs even in the case of strong shaking. The results are shown to be in consistence with the laboratory observations on shaking table tests and recent field observations that less nonlinearity exists for vertical motions. It is also shown that the possibility exists for using information on spectral ratios between the horizontal and vertical surface motions to quickly identify in situ soil behavior and liquefaction that are not readily covered by conventional field or laboratory experimentation procedures.     

Computational modeling of cyclic mobility and post-liquefaction site response

Under seismic excitation, liquefied clean medium to dense cohesionless soils may regain a high level of shear resistance at large shear strain excursions. This pattern of response, known as a form of cyclic mobility, has been documented by a large body of laboratory sample tests and centrifuge experiments. A plasticity-based constitutive model is developed with emphasis on simulating the cyclic mobility response mechanism and associated pattern of shear strain accumulation. This constitutive model is incorporated into a two-phase (solid–fluid), fully coupled finite element code. Calibration of the constitutive model is described, based on a unique set of laboratory triaxial tests (monotonic and cyclic) and dynamic centrifuge experiments. In this experimental series, Nevada sand at a relative density of about 40% is employed. The calibration effort focused on reproducing the salient characteristics of dynamic site response as dictated by the cyclic mobility mechanism. Finally, using the calibrated model, a numerical simulation is conducted to highlight the effect of excitation frequency content on post-liquefaction ground deformations.     

Spatial variation of seismic motion induced by propagation of body waves

Spatial variation of earthquake ground motion is an important phenomenon that cannot be ignored in the design and safety of strategic structures. Several models have been developed to describe this variation using statistical, mathematical or physical approaches. The latter approach is not specific to an event. A recent contribution, which uses such an approach and called complete stochastic deamplification approach (CSDA), was developed [1]. The aim of this paper is to analyze the spatial variation of earthquake motion induced by the propagation of body waves using the CSDA. Coherency functions are evaluated for the cases of SH–SV–P waves propagating through stratified soil. Results obtained show that the variation of the coherency function is not the same for vertical and horizontal components and that the motion is more coherent at depth than at the free surface. In fact, we found that the rate of decrease with frequency and distance is not the same if P–SV waves propagate through stratified soil.     

关于水资源承载力理论与方法的研究

本文首先明确了水资源承载力的基本概念 ,指出可持续发展理论、水 -生态 -社会经济复合系统理论、二元模式下的水文循环机制和过程是水资源承载力研究的理论基础 ,对水资源承载力研究的基本内容、评价指标体系的建立和评价方法进行了较全面的概括和总结。     

旅游自组织系统:区域旅游规划的根本目标

随着旅游活动不断走向大众化，旅游现象各要素之间已形成相互联系，具有特定结构和功能的有机整体，即旅游系统，旅游规划的对象也由旅游业发展到旅游系统。文中认为旅游系统规划的最终目标就是促使旅游系统6向旅游自组织系统进化，为促进旅游自组织系统的形成，编制科学的规划方案是基础，加强规划的实施监控是关键，成立实施监管小组是制度保障。     

资源环境与社会经济协调发展探析

文章首先回顾了资源环境与社会经济发展的理论，提出资源环境与社会经济协调发展内涵：一方面，要在资源环境承载力范围内发展社会经济，追求社会经济发展的最大化，另一方面，环境承载力是动态的，要依靠社会经济发展不断提高，这两个方面是相互作用、相互制约的。在此基础上，详细论述了资源环境与社会经济协调发展的内容,并从社会经济发展、资源环境管理等角度探讨了资源环境与社会经济协调发展的政策调控，通过建立节约型国民经济体系、深化资源环境管理，实现区域一体化，以保证资源环境与社会经济协调发展的实现。     

Velocity profile of a sand cloud blowing over a gravel surface

Particle dynamic analyzer (PDA) measurement technology was used to study the turbulent characteristics and the variation with height of the mean horizontal (in the downwind direction) and vertical (in the upward direction) particle velocity of a sand cloud blowing over a gravel surface. The results show that the mean horizontal particle velocity of the cloud increases with height, while the mean vertical velocity decreases with height. The variation of the mean horizontal velocity with height is, to some extent, similar to the wind profile that increases logarithmically with height in the turbulent boundary layer. The variation of the mean vertical velocity with height is much more complex than that of the mean horizontal velocity. The increase of the resultant mean velocity with height can be expressed by a modified power function. Particle turbulence in the downwind direction decreases with height, while that in the vertical direction is complex. For fine sands (0.2–0.3 mm and 0.3–0.4 mm), there is a tendency for the particle turbulence to increase with height. In the very near-surface layer (<4 mm), the movement of blown sand particles is very complex due to the rebound of particles on the bed and the interparticle collisions in the air. Wind starts to accelerate particle movement about 4 mm from the surface. The initial rebound on the bed and the interparticle collisions in the air have a profound effect on particle movement below that height, where particle concentration is very high and wind velocity is very low.     

旅游心理容量的测定——以武陵源黄石寨景区为例

旅游容量是旅游规划和管理中的重要工具之一。该文引入边际满意度的概念,提出了旅游心理容量的满意度模型,并且以武陵源黄石寨景区为实证研究,进行了旅游心理容量的测定。     

旅游生态环境容量的经济学探讨

在总结旅游环境容量研究进展的基础上，提出了研究旅游环境容量意义及其概念体系，并就影响旅游环境容量的关键性因子－旅游生态环境容量进行了分析，运用经济学的理论和方法，提出了引起旅游生态环境容量的深层原因是外部不经济性，最后就为了实现资源环境的可持续发展，应该从法律、行政，经济、社会等角度对社会各利益加以协调，构建了有效的制度平台和相应的措施，使外部成本内部化，并提出了解决这些问题的具体对策和建议。