新疆西准噶尔庙尔沟岩体的地球化学及年代学研究

新疆西准噶尔庙尔沟岩体侵入于早中石炭世海相火山-沉积建造中,主体由碱长花岗岩组成,局部分布有紫苏花岗岩和碱长花岗岩脉。碱长花岗岩及岩脉高硅、富碱、贫钙,里特曼指数(δ)=2.17~2.98,A/CNK=0.96~1.03,A/NK=1.08~1.13,为准铝质-弱过铝质高钾钙碱性花岗岩,其富集LILEs(Rb、U、K、Th),相对亏损HFSEs(Nb、Ta、P、Ti)和Ba、Sr等,以及强烈Eu负异常,过渡族地幔相容元素Cr、Ni含量低,U、Th、Pb等地壳富集元素含量较高。Sr、Nd同位素组成:(87Sr/86Sr)i=0.70370~0.70541,εNd(t)=+4.10~+6.79,tDM=0.57~0.99Ga。锆石LA-ICP-MS U-Pb定年研究获得锆石U-Pb年龄为309±1.4Ma,表明岩体碱长花岗岩的形成时代为晚石炭世。紫苏花岗岩的SiO 2含量为60.88%~62.06%,Al2O3含量为15.50%~15.72%,里特曼指数(δ)=2.59~2.77,A/CNK=0.86~0.88,A/NK=1.50~1.53,为准铝质钙碱性-高钾钙碱性过渡的花岗岩,相对富集LREE(Rb、U、K、Th),而亏损HREE(Nb、Ta、P、Ti)和Sr,以及较显著的Eu负异常,过渡族地幔相容元素Cr、Ni含量低,U、Th、Pb等地壳富集元素含量较高。Sr、Nd同位素组成:(87Sr/86Sr)i=0.70382~0.70388,εNd(t)=+6.67~+6.98,tDM=0.59~0.62Ga。锆石LA-ICP-MS U-Pb定年研究获得锆石U-Pb年龄为302.1±2.1Ma,表明岩体紫苏花岗岩的形成时代为晚石炭世。综合庙尔沟岩体的地质特征、地球化学特征、年代学和区域地质背景,认为庙尔沟岩体碱长花岗岩及岩脉为A2型花岗岩,紫苏花岗岩具有A型花岗岩的地球化学性质,且它们是可能来自同一个岩浆源区,属于西准噶尔后碰撞阶段的岩浆活动产物。     

朝鲜半岛平南盆地中元古代岩浆事件

朝鲜平南盆地翁津地区发育中元古代黄海群和同时期(称之为瓮津期)花岗岩,花岗岩体侵入于黄海群。本文采用锆石原位微区U-Pb定年技术,对黄海群中的酸性火山岩及花岗岩进行了年龄测试。获得的数据表明,黄海群中下部层位及上部层位的酸性火山岩分别在1235±5Ma和1203±7Ma喷发,由此说明黄海群的沉积时代应为中元古代,而不是传统上认为的古元古代;两个翁津期花岗岩体(翁津和黄衣山岩体)的侵位年龄分别为1251±22Ma和1248±13Ma,为中元古代花岗质岩浆活动的产物。上述1251~1203Ma年龄的获得,表明朝鲜半岛发育中元古代岩浆作用,从而明确朝鲜黄海裂谷与华北东缘裂谷在时间上具有同期性,同时也表明中国华北与朝鲜在中元古代具有类似的发展历史。     

华南与花岗岩有关的一种新类型的锡成矿作用：矿物化学、元素和同位素地球化学证据

华南是我国最重要的锡成矿省,产有大量的与花岗岩有关的大型-超大型锡多金属矿床。近年来,在湘南新探明一个超大型锡矿床—芙蓉锡矿床,其中,最重要的锡矿化产在骑田岭花岗岩体西南部的破碎蚀变带内,与绿泥石化密切相关。骑田岭花岗岩富含角闪石,具有较高的氧逸度,显示出准铝的地球化学特征,在花岗岩形成过程中发生过壳-慢岩浆混合作用。这些特点都表明骑田岭花岗宕并不同于一般的 S 型含锡花岗岩,而显示出 A 型花岗岩的地球化学特征。同位素定年分析表明,芙蓉锡矿床主成矿阶段的形成时代要晚于骑田岭花岗岩侵位年龄近20Ma。氢、氧同位素分析表明,发生过水-岩反应的大气降水在成矿流体中占有很重要的地位。硫同位素分析表明花岗岩和地层都提供了成矿所需的硫。因此,用花岗岩浆结晶分异过程中分离出富锡的岩浆流体来形成锡矿的传统模式并不适合于解释芙蓉锡矿的形成。我们认为芙蓉锡矿的形成主要与骑田岭花岗岩的绿泥石化蚀变有关,循环的大气降水与花岗岩发生水-岩反应,富锡的铁镁矿物在蚀变成绿泥石的同时释放出 Sn 和 Ti 等金属到流体中,当物理化学条件改变时,沉淀形成锡矿体。这是一种比较独特的锡矿化模式,丰富了华南与花岗岩有关的锡矿化类型。     

内蒙古苏尼特左旗南两类花岗岩同位素年代学及其构造意义

内蒙古北部索伦缝合带（索伦-苏尼特左旗-锡林浩特）被多数中外学者认为是西伯利亚板块南缘和华北板块北缘的最终缝合带,本文选择该缝合带上苏尼特左旗南两类花岗岩-与俯冲有关和与碰撞有关的岩浆岩（分别叫弧岩浆岩和碰撞岗岩）进行同位素年代学研究,结果表明：（1）弧岩浆活动有两期,分别约为490Ma和310Ma(锆石U-Pb,SHRIMP);碰撞花岗岩的侵位年代在230-250Ma(Rb-Sr全岩和锆石U-Pb);（2）根据本文新的年代学数据,索伦缝合带的最终缝合时间可能是在230-310Ma,这显然不同于国内多数学者坚持的“晚泥盆世碰撞”模式;而Sengor等推测的“晚二又开展碰撞”模式与本文数据一致。     

华北地块西南缘古元古代花岗斑岩及其构造意义

在六盘山南段陇县固关镇东部出露多个原认为属于中-新生代的花岗斑岩岩体,其中的白家沟花岗斑岩显示古元古 代壳源岩浆活动的记录,属于钙碱性花岗岩系。该花岗斑岩高SiO2 （71.14%~73.33%）,高碱（Na2O+ K2O=7.61%~8.70%）, 富钾（K2O/Na2O=1.21~2.52,平均为2.03）,具有准铝-弱过铝质特点（铝饱和指数A/CNK=0.93~1.09,平均1.00）。稀土元 素配分曲线呈轻稀土强烈富集的典型“海鸥型”样式,具有明显的Eu负异常（δEu=0.44~0.47）。岩石富集大离子亲石元素 K,Rb,Ba,Th,亏损高场强元素Ti,Nb,Ta,具有壳源A型花岗岩的地球化学特征。对该花岗斑岩进行的锆石U-Pb LA-ICP-MS同位素年代测定获得了1 846±32 Ma的上交点年龄,说明花岗斑岩形成于古元古代而不是前人认为的中-新生 代,上奥陶统背锅山组砾屑灰岩实际上是沉积于古元古代花岗斑岩之上。结合区域地质资料研究结果表明华北地块西南缘 在古元古代时期处于强烈的伸展环境,这可能为古元古代贺兰坳拉槽向南延伸至六盘山南段提供了直接的岩石学证据。     

胶东地区燕山期岩浆活动及其构造环境——来自单颗锆石SHRIMP年代学的记录

山东胶东地区中生代构造-岩浆事件和金矿成矿作用密切相关,其主要构造-岩浆事件包括:1220~200 Ma,扬子板块相对华北板块的南北向碰撞形成苏鲁高压-超高压变质带及同造山花岗岩与造山后高碱正长岩,属于典型的幔源型花岗岩系列;2 165~150 Ma,晚侏罗世时期形成与金矿有关的玲珑(昆嵛山)造山早期片麻状二长花岗岩组合,为过铝质花岗岩类,属胶东基底岩系的部分重熔产物。3 135~110 Ma,由壳幔混合岩浆结晶分异形成郭家岭花岗岩和伟德山花岗闪长岩。燕山期是胶东地区岩浆活动的鼎盛时期,表现为四次强烈的构造-岩浆事件,代表了燕山造山事件四个构造幕,并以挤压与伸展相互转化为特征。研究表明胶东地区中生代花岗岩具有继承性和再生性特点,采自郭家岭花岗闪长岩中的SHRIMP锆石U-Pb同位素年代学测定结果表明:锆石由核部到边部年龄值分别为2573~2194Ma、164.8~147.8和126.6~126.2Ma,显示了胶东结晶基底、玲珑花岗岩和郭家岭花岗岩形成的年代学信息,揭示了它们之间复杂的继承性和再生性,即新太古代胶东岩群、TTG岩系和古元古代荆山群、粉子山群等胶东基底岩系交代重熔形成S型玲珑花岗岩,由壳幔混合岩浆形成的郭家岭花岗岩在形成与侵位过程中重熔交代了部分玲珑花岗岩物质并侵位于玲珑花岗岩中。分析认为2573.4~2194.4 Ma是胶东结晶基底的年龄信息,164.8~147.8Ma代表了玲珑花岗岩形成的年龄信息,126.2~126.6Ma则代表了郭家岭花岗岩形成的年龄信息。这种年龄信息组合也反映了胶东地区从新太古代陆块形成、古元古代克拉通化到三叠纪华北陆块与扬子陆块碰撞至玲珑S型花岗岩形成、郭家岭壳幔混合型花岗岩形成演化的年代学记录,浓缩了胶东地区中生代岩浆起源和演化的过程,进而为诠释胶东地区深部岩浆作用过程提供了新的资料,并对后续的相关科学研究尤其是金矿的多期成矿作用提供了佐证。     

Lead isotope evolution of the Central European upper mantle:Constraints from the Bohemian Massif

The Pb isotope composition of the upper mantle beneath Central Europe is heterogeneous due to the subduction of regionally contrasting material during the Variscan and Alpine orogenies.Late Variscan to Cenozoic mantlederived melts allow mapping this heterogeneity on a regional scale for the last ca.340 Myr.Late Cretaceous and Cenozoic anorogenic magmatic rocks of the Bohemian Massif(lamprophyres,volcanic rocks of basanite/tephrite and trachyte/phonolite series) concentrate mostly in the Eger Rift.Cretaceous ultramafic lamprophyres yielded the most radiogenic Pb isotope signatures reflecting a maximum contribution from metasomatised lithospheric mantle,whereas Tertiary alkaline lamprophyres originated from mantle with less radiogenic ~(206)Pb/~(204)b ratios suggesting a more substantial modification of lithospheric source by interaction with asthenosphericderived melts.Cenozoic volcanic rocks of the basanite/tephrite and trachyte/phonolite series define a linear mixing trend between these components,indicating dilution of the initial lithospheric mantle signature by upwelling asthenosphere during rifting.The Pb isotope composition of Late Cretaceous and Cenozoic magmatic rocks of the Bohemian Massif follows the same Pb growth curve as Variscan orogenic lamprophyres and lamproites that formed during the collision between Laurussia,Gondwana,and associated terranes.This implies that the crustal Pb signature in the post-Variscan mantle is repeatedly sampled by younger anorogenic melts.Most Cenozoic mantle-derived rocks of Central Europe show similar Pb isotope ranges as the Bohemian Massif.     

Tonian rift-related, A-type continental plutonism in the Araçuaí Orogen, eastern Brazil: New evidence for the breakup stage of the São Francisco–Congo Paleocontinent

Zircon U–Pb SHRIMP, petrographical and geochemical data lead to the first characterization of the Tonian plutonism (Salto da Divisa Granite Suite), ascribed to the continental rift stage of the precursor basin of the Araçuaí Orogen (Eastern Brazil). The suite includes batholitic plutons and comprises mainly fluorite-bearing, dominantly mesoperthitic hornblende–biotite leucogranites. The presence of mafic (tholeiitic) gabbroic enclaves and syn-plutonic dykes confers to the suite a bimodal character. The plutons were locally deformed and foliated under amphibolite facies conditions, in response to the Neoproterozoic collage of the Araçuaí Orogen against the São Francisco Cratonic margin. However, undeformed magmatic facies are well preserved at inner portions of the plutons. The granitoids are metaluminous, with high SiO₂ and HFSE: Nb, Zr, Y, Ta and REE (except Eu); low CaO, Al₂O₃, Sc, Ba, Sr; high FeOt/MgO ratios, characterizing a chemical signature akin to the subalkaline, A-2 type granites. U–Pb SHRIMP data obtained on zircons from the main pluton yielded a magmatic crystallization age of 875 ± 9 Ma. Some inherited xenocrysts revealed ages of ca. 2080 Ma, corresponding to ages of the host rocks, a Paleoproterozoic basement. Nd isotopic evolution studies confirm the Paleoproterozoic influence on magma genesis with a T_DM model age of ca. 1.6 Ga and ε_Nd of − 5.58 at 880 Ma. The African counterpart, the West Congo Belt, encompasses thick rift-related alkaline volcanic-sedimentary basin (Zadinian and Mayumbian groups, and associated anorogenic granites), dated in the interval of ca. 1000–900 Ma. The age differences between the Salto da Divisa Suite intrusion and the anorogenic magmatic episode at the West Congo Belt suggests a westward migration (i.e. to the Brazilian side) of the thermal axis of the rift, ca. 30 Ma after the ending of the extensional process in Africa.     

Generation of Late Cretaceous silicic rocks in SE China: Age, major element and numerical simulation constraints

Rhyolite-dominating bimodal volcanic suites (rhyolite/basalt), mafic dikes and A-type granites distribute from N Zhejiang to S Fujian over 800 km in the Southeast Coast Magmatic Belt (SCMB) – the Late Yanshanian (LY) orogenic belt in SE China. Data of ⁴⁰Ar/³⁹Ar and K–Ar whole-rock ages and LA-ICPMS U–Pb zircon ages indicate that rhyolitic volcanism (101–72 Ma) is contemporaneous with the A-type granitic intrusions (100–90 Ma) and mafic dike injections (94–77 Ma). This time span is used to define the upper volcanic series in Zhejiang–Fujian areas. One striking feature of rhyolites in the SCMB is that many are strongly peraluminous (SP) and others, mostly restrict in Fujian, are peralkaline to mildly peraluminous (P-MP) and chemically resemble A-type granites. The SP character is unique among well-known large rhyolite provinces worldwide. Based on experimental works for a common thermal regime and inherited zircon age information, we suggest that SP and P-MP rhyolites represent low pressure melting of the felsic (quartzofeldspathic) granite (±metapelite) and the accompanied granodioritic, tonalitic and trondhjemitic member of the core complex assemblage, respectively, to account for the decreasing aluminosity. They could have also been contaminated by young igneous rocks, and ancient crust to a lesser degree, during ascent to the surface. Plate subduction and lithosphere extension processes, respectively, are numerically simulated for the magma generation of these rhyolites using the mafic underplating model. Results suggest that the most effective controlling factor to generate SP and associated P-MP (A-type) magmas during 95–80 Ma is thinning of the lithosphere thickness with a high exhumation rate. Under this circumstance, the core complex assemblage can be uplifted to lower level of the crust and match the constraint of experimental works.     

Petrogenesis of Al–silicate-bearing trondhjemitic migmatites from NE Sardinia, Italy

The migmatites from Punta Sirenella (NE Sardinia) are layered rocks containing 3–5 vol.% of centimeter-sized stromatic leucosomes which are mainly trondhjemitic and only rarely granitic in composition. They underwent three deformation phases, from D₁ to D₃. The D₁ deformation shows a top to the NW shear component followed by a top to the NE/SE component along the XZ plane of the S₂ schistosity. Migmatization started early, during the compressional and crustal thickening stage of Variscan orogeny and was still in progress during the following extensional stage of unroofing and exhumation.

The trondhjemitic leucosomes, mainly consisting of quartz, plagioclase, biotite ± garnet ± kyanite ± fibrolite, retrograde muscovite and rare K-feldspar, are locally bordered by millimeter-sized biotite-rich melanosomes. The rare granitic leucosomes differ from trondhjemitic ones only in the increase in modal content of K-feldspar, up to 25%. Partial melting started in the kyanite field at about 700–720 °C and 0.8–0.9 GPa, and was followed by re-equilibration at 650–670 °C and 0.4–0.6 GPa, producing fibrolite–biotite intergrowth and coarse-grained muscovite.

The leucosomes have higher SiO₂, CaO, Na₂O, Sr and lower Al₂O₃, Fe₂O₃, MgO, TiO₂, K₂O, P₂O₅, Rb, Ba, Cr, V, Zr, Nb, Zn and REE content with respect to proximal hosts and pelitic metagreywackes. Sporadic anomalous high content of calcium and ferromagnesian elements in some leucosomes is due to entrainment of significant amounts of restitic plagioclase, biotite and accessory phases. The rare granitic leucosomes reveal peritectic K-feldspar produced by muscovite-dehydration melting. Most leucosomes show low REE content, moderately fractionated REE patterns and marked positive Eu anomaly. Proximal hosts and pelitic metagraywackes are characterized by higher REE content, more fractionated REE patterns and slightly negative Eu anomaly.

The trondhjemitic leucosomes were generated by H₂O-fluxed melting at 700 °C of a greywacke to pelitic–greywacke metasedimentary source-rock. The disequilibrium melting process is the most reliable melting model for Punta Sirenella leucosomes.