Variscan ore formation and metamorphism at the Felbertal scheelite deposit (Austria): constraining tungsten mineralisation from Re–Os dating of molybdenite

The Felbertal scheelite deposit in the Eastern Alps has been regarded as the type locality for stratabound scheelite deposits. It is hosted by a Cambro-Ordovician metavolcanic arc sequence with minor Variscan granitoids (∼ 340 Ma) in the central Tauern Window. Re–Os model ages for molybdenite from the Felbertal tungsten deposit range between ∼ 358 and ∼ 336 Ma and record several pulses of magmatic-hydrothermal-metamorphic molybdenite formation. Molybdenite ages from the K2 orebody, a scheelite-rich quartz mylonite in the Western ore field, indicate that both mineralisation and mylonite are Variscan in age and suggest that the shear zone was active for ∼ 20 million years. Early stage tungsten mineralisation (Scheelite 1) in quartzitic ores in the Eastern ore field, which is free of molybdenite, yielded very low to near blank levels of Re and Os and thus could not be dated. However, molybdenite from scheelite–quartz stringers, previously interpreted as a feeder stockwork to quartzitic scheelite ore of presumed Cambrian age, yielded Variscan Re–Os ages of ∼ 342 and ∼ 337 Ma. Dating of molybdenite contained in scheelite ores thus far provides no indication of a Cambrian component to the tungsten mineralisation. Our data are consistent with a model of either granite intrusion-related ore formation and coeval metamorphic overprint during the Early Carboniferous or, alternatively, molybdenite formation may be exclusively attributed to Variscan metamorphism (see Stein 2006).     

Early Proterozoic syn-and postcollision granites in the northern part of the Baikal fold area

Early Proterozoic granitoids are of a limited occurrence in the Baikal fold area being confined here exclusively to an arcuate belt delineating the outer contour of Baikalides, where rocks of the Early Precambrian basement are exposed. Geochronological and geochemical study of the Kevakta granite massif and Nichatka complex showed that their origin was related with different stages of geological evolution of the Baikal fold area that progressed in diverse geodynamic environments. The Nichatka complex of syncollision granites was emplaced 1908 ± 5 Ma ago, when the Aldan-Olekma microplate collided with the Nechera terrane. Granites of the Kevakta massif (1846 ± 8 Ma) belong to the South Siberian postcollision magmatic belt that developed since ～1.9 Ga during successive accretion of microplates, continental blocks and island arcs to the Siberian craton. In age and other characteristics, these granites sharply differ from granitoids of the Chuya complex they have been formerly attributed to. Accordingly, it is suggested to divide the former association of granitoids into the Chuya complex proper of diorite-granodiorite association ～2.02 Ga old (Neymark et al., 1998) with geochemical characteristics of island-arc granitoids and the Chuya-Kodar complex of postcollision S-type granitoids 1.85 Ga old. The Early Proterozoic evolution of the Baikal fold area and junction zone with Aldan shield lasted about 170 m.y. that is comparable with development periods of analogous structures in other regions of the world.     

Contrasting evolution of low-P rare metal granites from two different terranes in the Hoggar area, Algeria

Two mineralogically different rare metal granites located in two distinct terranes from the Tuareg area are compared: the Tin-Amzi granite in the north of the Laouni Terrane and the Ebelekan granite in the Assodé–Issalane Terrane.The Tin-Amzi granite is enclosed within Eburnean granulitic gneisses, and consists of albite, quartz, protolithionite, K-feldspar and topaz granite (PG). The accessory minerals include columbite tantalite, U- and Hf-rich zircon, Th-uraninite, wolframoixiolite and wolframite. This facies is characterised by a mineralogical evolution from the bottom to the top underlined by a strong resorption of K-feldspar and albite and the crystalliK-feldspar of more abundant topaz and protolithionite II which is further altered in muscovite and Mn-siderite. It is underlain by an albite, K-feldspar, F-rich topaz, quartz and muscovite granite (MG), with W–Nb–Ta oxides, wolframite, Nb-rutile, zircon and scarce uranothorite as accessories.The Ebelekan granite intrudes into a coarse-grained biotite granite enclosed within upper amphibolite-facies metasediments. It comprises a zinnwaldite, albite, topaz porphyritic granite (ZG) with “snow ball” quartz and K-feldspar. The accessories are zircon, monazite, uranothorite, Ta bearing cassiterite, columbite tantalite and wodginite. It is capped by a banded aplite-pegmatite (AP).The geochemistry of Tin-Amzi and Ebelekan granites is nearly comparable. Both are peraluminous (A/CNK=1.10–1.29; ASI=1.17–1.31), sodolithic and fluorine rich with high SiO₂, Al₂O₃, Na₂O+K₂O, Rb, Ga, Li, Ta, Nb, Sn and low FeO, MgO, TiO₂, Ba, Sr, Y, Zr and REE contents. These rare metal Ta bearing granites belong to the P-poor subclass, relating to their P₂O₅ content ( 0.03–0.15 wt.%). Nevertheless, they are distinguished by their concentration of W, Sn and Ta. The Tin-Amzi granite is W–Ta bearing with high W/Sn ratio whereas the Ebelekan granite is Ta–Sn bearing with insignificant W content.At Tin-Amzi the W–Nb–Ta minerals define a sequence formed by W-columbite tantalite followed by wolframoixiolite and finally wolframite showing the effect of hydrothermal overprinting with an extreme W enrichment of the fluids. At Ebelekan, the Sn–Nb–Ta oxides follow a Mn sequence: manganocolumbite→manganotantalite→wodginite+titanowodginite→cassiterite that represents a trend of primary crystallisation resulting from progressive substitution Fe→Mn and Nb→Ta during the magmatic fractionation.     

鲁东官山榴辉岩与围岩接触关系的新发现及其对年代学的启示

鲁东官山榴辉岩呈透镜状包于变质含霓石碱性花岗岩中,榴辉岩的片麻理与主岩片麻理总体呈交切关系,局部可见变质含霓石碱性花岗岩呈细小岩枝状脉贯入榴辉岩中。变质含霓石碱性花岗岩锆石U-Pb法下交点年龄为231±25 Ma,上交点年龄为818±66 Ma。发现了闪长玢岩脉斜切式侵入榴辉岩及变质含霓石碱性花岗岩的接触关系,且闪长玢岩脉中有榴辉岩捕虏体,这种现象指示:闪长玢岩侵位时榴辉岩已折返至地壳较浅部位。研究表明,榴辉岩与变质含霓石碱性花岗岩共同经历了新元古代的超高压变质作用,但变质作用发生时含霓石碱性花岗岩可能处于熔融状态,榴辉岩是其中的固相包体。     

Datation UPb : âge de mise en place du magmatisme bimodal des Jebilet centrales (chaı̂ne Varisque,Maroc). Implications géodynamiques

The bimodal magmatism of central Jebilet is dated to 330.5^+0.68_?0.83 Ma by UPb dating on zircons. This age, similar to that of the syntectonic Jebilet cordierite-bearing granitoids, corresponds to the age of the local major tectonometamorphic event. The syntectonic plutonism of the Jebilet massif, composed of tholeiitic, alkaline, and peraluminous calc-alkaline series, is variegated. Magmas emplacement was favoured by the local extension induced by the motion along the western boundary of the Carboniferous basins of the Moroccan Meseta. The Jebilet massif exemplifies the activation of various magmas sources during an episode of continental convergence and crustal wrenching.     

Strain partitioning and preservation of Ar/Ar ages during Variscan exhumation of a subducted crust (Malpica–Tui complex, NW Spain)

The Malpica–Tui complex (NW Iberian Massif) consists of a Lower Continental Unit of variably deformed and recrystallized granitoids, metasediments and sparse metabasites, overridden by an upper unit with rocks of oceanic affinities. Metamorphic minerals dated by the ⁴⁰Ar/³⁹Ar method record a coherent temporal history of progressive deformation during Variscan metamorphism and exhumation. The earliest stages of deformation (D1) under high-pressure conditions are recorded in phengitic white micas from eclogite-facies rocks at 365–370 Ma. Following this eclogite-facies peak-metamorphism, the continental slab became attached to the overriding plate at deep-crustal levels at ca. 340–350 Ma (D2). Exhumation was accompanied by pervasive deformation (D3) within the continental slab at ca. 330 Ma and major deformation (D4) in the underlying para-autochthon at 315–325 Ma. Final tectonothermal evolution included late folding, localized shearing and granitic intrusions at 280–310 Ma.

Dating of high-pressure rocks by the ⁴⁰Ar/³⁹Ar method yields ages that are synchronous with published Rb–Sr and Sm–Nd ages obtained for both the Malpica–Tui complex and its correlative, the Champtoceaux complex in the French Armorican Massif. The results indicate that phengitic white mica retains its radiogenic argon despite been subjected to relatively high temperatures (500–600 °C) for a period of 20–30 My corresponding to the time-span from the static, eclogite-facies M1 peak-metamorphism through D1-M2 eclogite-facies deformation to amphibolite-facies D2-M3. Our study provides additional evidence that under certain geological conditions (i.e., strain partitioning, fluid deficiency) argon isotope mobility is limited at high temperatures, and that ⁴⁰Ar/³⁹Ar geochronology can be a reliable method for dating high pressure metamorphism.     

Geomechanical model for the post-Variscan evolution of the Permocarboniferous–Mesozoic basins in Northeast Germany

The Permocarboniferous basins in Northeast Germany formed on the heterogeneous and eroded parts of the Variscan orogene and its deformed northern foreland. Transtensional tectonic movements and thermal re-equilibration lead to medium-scale crustal fragmentation, fast subsidence rates and regional emplacement of large amounts of mostly acidic volcanics. The later basin formation and differentiation was triggered by reversals of the large-scale stress field and reactivation of prominent zones of weakness like the Elbe Fault System and the Rhenohercynian/Saxothuringian boundary that separate different Variscan basement domains in the area. The geomechanical behaviour of the latter plays an important role for the geodynamic evolution of the medium to large-scale structural units, which we can observe today in three dimensions on structural maps, geophysical recordings and digital models. This study concentrates on an area that comprises the southern Northeast German Basin, the Saale Basin, the Flechtingen High, the Harz Mountains High and the Subhercynian Basin. The presented data include re-evaluations of special geological and structural maps, the most recent interpretation of the DEKORP BASIN 9601 seismic profile and observations of exposed rock sections in Northeast Germany. On the basis of different structural inventories and different basement properties, we distinguish two structural units to the south and one structural unit to the north of the Elbe Fault System. For each unit, we propose a geomechanical model of basin formation and basin inversion, and show that the Rhenohercynian Fold and Thrust Belt domain is deformed in a thin-skinned manner, while the Mid-German Crystalline Rise Domain, which is the western part of the Saxothuringian Zone, rather shows a thick-skinned deformation pattern. The geomechanical model for the unit north to the Elbe Fault System takes account to the fact that the base of the Zechstein beneath the present Northeast German basin shows hardly any evidence for brittle deformation, which indicates a relative stable basement. Our geomechanical model suggests that the Permocarboniferous deposits may have contributed to the structural stiffness by covering small to medium scale structures of the upper parts of the brittle basement. It is further suggested that the pre-Zechstein successions underneath the present Northeast German basin were possibly strengthening during the Cretaceous basin inversion, which resulted in stress transfer to the long-lived master faults, as indicated for example by the shape of the salt domes in the vicinity of the latter faults. Contrary to this, post-Zechstein successions deformed in a different and rather complex way that was strongly biased by intensive salt tectonic movements.     

Metamorphic and deformational imprint of Cambrian–Lower Ordovician rifting in the Ossa-Morena Zone (Iberian Massif, Spain)

The high-temperature metamorphism recorded in the Valuengo and Monesterio areas constitutes a rare occurrence in the Ossa-Morena Zone of Southwest Iberia, where low-grade metamorphism dominates. The metamorphism of the Valuengo area has been previously considered either Cadomian or Variscan in age, whereas that of Monesterio has been interpreted as a Cadomian imprint. However, these areas share important metamorphic and structural features that point towards a common tectonometamorphic evolution. The metamorphism of the Valuengo and Monesterio areas affects Late Proterozoic and Early Cambrian rocks, and is syn-kinematic with a top-to-the-north mylonitic foliation, which was subsequently deformed by early Variscan folds and thrusts. The U–Pb zircon age (480±7 Ma) we have obtained for an undeformed granite of the Valuengo area is consistent with our geological observations constraining the age of the metamorphism. We propose that this high-temperature metamorphic imprint along a NW–SE ductile extensional shear zone is related to the crustal extension that occurred in the Ossa-Morena Zone during the Cambro-Ordovician rifting. In the same way, the tectonothermal effect of the preorogenic rifting stage may have been wrongly attributed to orogenic processes in other regions as well as in this one.     

Metamorphic evolution of garnet-spinel peridotites from the Variscan Schwarzwald (Germany)

Garnet-spinel peridotites form small, isolated, variably retrogressed bodies within the low-pressure high-temperature gneisses and migmatites of the Variscan basement of the Schwarzwald, southwest Germany. Detailed mineralogical and textural studies as well as geothermobarometric calculations on samples from three occurrences are presented. Two of the garnet-spinel peridotites have equilibrated at 680–770°C, 1.4–1.8 GPa within the garnet-spinel peridotite stability field, one of the samples having experienced an earlier stage within the spinel peridotite stability field (790°C, <1.8 GPa). The third sample, with only garnet and spinel preserved, probably equilibrated within the garnet peridotite stability field at higher pressures. These findings are in line with the distinction of two groups of ultramafic garnet-bearing high-pressure rocks with different equilibration conditions within the Schwarzwald (670–740°C, 1.4–1.8 GPa and 740–850°C, 3.2–4.3 GPa) which has previously been established (Kalt et al. 1995). The equilibration conditions of 670–770°C and 1.4–1.8 GPa for garnet-spinel peridotites from the Central Schwarzwald Gneiss Complex (CSGC) are similar to those for eclogites of the Schwarzwald and also correspond quite well to those for garnet-spinel peridotites from the Moldanubian zone of the Vosges mountains and of ecologites from the Moldanubian s.str. of the Bohemian Massif.