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51.
用电感耦合等离子体质谱法(ICP-MS)测定地质样品中的稀土及难熔元素,混合酸敞开酸溶法和碱熔融法是两种主要的溶样方法。但地质样品组分复杂,元素之间存在相互共生的现象,对于特殊元素、特殊样品用传统酸溶法会造成部分元素消解不完全,使测定结果不准确;而碱熔法的操作过程繁琐,且溶液盐度高,易产生基体干扰和堵塞仪器进样系统。本文改进了传统四酸和五酸体系,采用氢氟酸-硝酸-硫酸敞开酸溶体系,用国家一级标准物质制作标准曲线测定15种稀土元素,方法准确度(ΔlgC)为0.001~0.027。同时改进了偏硼酸锂碱熔法,样品用偏硼酸锂碱熔提取,加入氢氧化钠调节溶液至碱性条件,所测元素与偏硼酸锂共沉淀后过滤分离熔剂,再用硝酸复溶测定15种稀土元素及铌钽锆铪。两种溶样方法的测定值与认定值的相对误差为1.09%~9.30%。将混合酸敞开酸溶法测定稀土元素、偏硼酸锂碱熔法测定铌钽锆铪的结果与其他实验室密闭酸溶法相比,两组数据的相对偏差为0.13%~15.32%。本实验表明,混合酸敞开酸溶法适用于测定地质样品中的稀土元素,偏硼酸锂碱熔法不仅适用于测定地质样品中的稀土元素及铌钽锆铪,也适用于测定如古老高压变质岩石及铝含量高的样品中的铌钽锆铪。 相似文献
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西太平洋暖池区气象学特征分析 总被引:1,自引:0,他引:1
本文根据TOGA-COARE强化观测资料及卫星资料分析讨论了西太平洋暖池区11-2月间海面气象要素的平均特征。分析发现海面气压平均日变化似乎同中纬度区明显不同。文中还分析讨论了在西太暖池区西风爆发、赤道浅涡、信风逆温及ITCE和南太平洋辐合带SPCZ的变化特征。 相似文献
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河南省土壤湿度年变化规律 总被引:1,自引:0,他引:1
利用河南省土壤墒情预报模型中建立的河南省台站土壤墒情数据库资料,对不同类型土壤湿度进行分析,从而确定不同类型土壤湿度差异、地下水对土壤湿度的影响及河南省土壤湿度的年变化规律。 相似文献
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《International Journal of Digital Earth》2013,6(3):203-218
Abstract While data like HJ-1 CCD images have advantageous spatial characteristics for describing crop properties, the temporal resolution of the data is rather low, which can be easily made worse by cloud contamination. In contrast, although Moderate Resolution Imaging Spectroradiometer (MODIS) can only achieve a spatial resolution of 250 m in its normalised difference vegetation index (NDVI) product, it has a high temporal resolution, covering the Earth up to multiple times per day. To combine the high spatial resolution and high temporal resolution of different data sources, a new method (Spatial and Temporal Adaptive Vegetation index Fusion Model [STAVFM]) for blending NDVI of different spatial and temporal resolutions to produce high spatial–temporal resolution NDVI datasets was developed based on Spatial and Temporal Adaptive Reflectance Fusion Model (STARFM). STAVFM defines a time window according to the temporal variation of crops, takes crop phenophase into consideration and improves the temporal weighting algorithm. The result showed that the new method can combine the temporal information of MODIS NDVI and spatial difference information of HJ-1 CCD NDVI to generate an NDVI dataset with both high spatial and high temporal resolution. An application of the generated NDVI dataset in crop biomass estimation was provided. An average absolute error of 17.2% was achieved. The estimated winter wheat biomass correlated well with observed biomass (R 2 of 0.876). We conclude that the new dataset will improve the application of crop biomass estimation by describing the crop biomass accumulation in detail. There is potential to apply the approach in many other studies, including crop production estimation, crop growth monitoring and agricultural ecosystem carbon cycle research, which will contribute to the implementation of Digital Earth by describing land surface processes in detail. 相似文献
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An extensive series of incoherent scatter studies of the ionospheric D-region was carried out at the Arecibo radar facility during 1978 and 1979. They included several full-day sequences of electron density measurements over a range of altitudes, and also included a sequence during the serendipitous occurrence of a large solar flare. For the solar flare event simultaneous data on solar X-ray fluxes in several wavelength bands were available from the GOES-2 and ISEE-3 satellites.
In the course of development of a large ionospheric computer model at Los Alamos we have used the solar flare data as a reality check. The solar X-ray flux data were used as inputs for computing ionization rates. The model computer includes 999 chemical reactions, and also includes diffusion and transport processes. In the course of the flare studies we used the data comparisons to adjust the values of three chemical rate coefficients that were poorly known. With those adjustments the model computations fitted the data quite well.
Subsequent to the flare analysis we have been using the same model with some minor updates to compute the expected diurnal variations of the ambient D-region under conditions chosen to match those existing at the times of the incoherent scatter measurements. Comparisons of the computations and the data will be shown, and the relative importance of the several separate ionization processes will be discussed. We also compare model results with experimental data on concentrations of NO. 相似文献
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图像配准技术是近年来发展迅速的图像处理技术之一,是图像融合、目标提取与定位、变化监测、高分辨率影像重建等处理工作不可缺少的步骤。首先给出了多源遥感影像配准的概念和基本过程,然后着重从匹配基元、转换函数、相似性测度、匹配策略4个方面对国内外现有的影像配准技术和方法进行了分析和评述,最后指出了影像配准技术所面临的主要难题和发展方向。 相似文献