Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.     

Upper mantle structure of the South American continent and neighboring oceans from surface wave tomography

We present a new three-dimensional SV-wave velocity model for the upper mantle beneath South America and the surrounding oceans, built from the waveform inversion of 5850 Rayleigh wave seismograms. The dense path coverage and the use of higher modes to supplement the fundamental mode of surface waves allow us to constrain seismic heterogeneities with horizontal wavelengths of a few hundred kilometres in the uppermost 400 km of the mantle.The large scale features of our tomographic model confirm previous results from global and regional tomographic studies (e.g. the depth extent of the high velocity cratonic roots down to about 200–250 km).Several new features are highlighted in our model. Down to 100 km depth, the high velocity lid beneath the Amazonian craton is separated in two parts associated with the Guyana and Guapore shields, suggesting that the rifting episode responsible for the formation of the Amazon basin has involved a significant part of the lithosphere. Along the Andean subduction belt, the structure of the high velocity anomaly associated with the sudbduction of the Nazca plate beneath the South American plate reflects the along-strike variation in dip of the subducting plate. Slow velocities are observed down to about 100 km and 150 km at the intersection of the Carnegie and Chile ridges with the continent and are likely to represent the thermal anomalies associated with the subducted ridges. These lowered velocities might correspond to zones of weakness in the subducted plate and may have led to the formation of “slab windows” developed through unzipping of the subducted ridges; these windows might accommodate a transfer of asthenospheric mantle from the Pacific to the Atlantic ocean. From 150 to 250 km depth, the subducting Nazca plate is associated with high seismic velocities between 5°S and 37°S. We find high seismic velocities beneath the Paraná basin down to about 200 km depth, underlain by a low velocity anomaly in the depth range 200–400 km located beneath the Ponta Grossa arc at the southern tip of the basin. This high velocity anomaly is located southward of a narrow S-wave low velocity structure observed between 200 and 500–600 km depth in body wave studies, but irresolvable with our long period datasets. Both anomalies point to a model in which several, possibly diachronous, plumes have risen to the surface to generate the Paraná large igneous province (LIP).     

Modeling of in-situ crystallization processes in the Permian mafic layered intrusion of Mont Collon (Dent Blanche nappe, western Alps)

The Mont Collon mafic complex is one of the best preserved examples of the Early Permian magmatism in the Central Alps, related to the intra-continental collapse of the Variscan belt. It mostly consists (> 95 vol.%) of ol + hy-normative plagioclase-wehrlites, olivine- and cpx-gabbros with cumulitic structures, crosscut by acid dikes. Pegmatitic gabbros, troctolites and anorthosites outcrop locally. A well-preserved cumulative sequence is exposed in the Dents de Bertol area (center of intrusion). P–T calculations indicate that this layered magma chamber emplaced at mid-crustal levels at about 0.5 GPa and 1100 °C. The Mont Collon cumulitic rocks record little magmatic differentiation, as illustrated by the restricted range of clinopyroxene mg-number (Mg#_cpx = 83–89). Whole-rock incompatible trace-element contents (e.g. Nb, Zr, Ba) vary largely and without correlation with major-element composition. These features are characteristic of an in-situ crystallization process with variable amounts of interstitial liquid L trapped between the cumulus mineral phases. LA-ICPMS measurements show that trace-element distribution in the latter is homogeneous, pointing to subsolidus re-equilibration between crystals and interstitial melts. A quantitative modeling based on Langmuir's in-situ crystallization equation successfully duplicated the REE concentrations in cumulitic minerals of all rock facies of the intrusion. The calculated amounts of interstitial liquid L vary between 0 and 35% for degrees of differentiation F of 0 to 20%, relative to the least evolved facies of the intrusion. L values are well correlated with the modal proportions of interstitial amphibole and whole-rock incompatible trace-element concentrations (e.g. Zr, Nb) of the tested samples. However, the in-situ crystallization model reaches its limitations with rock containing high modal content of REE-bearing minerals (i.e. zircon), such as pegmatitic gabbros. Dikes of anorthositic composition, locally crosscutting the layered lithologies, evidence that the Mont Collon rocks evolved in open system with mixing of intercumulus liquids of different origins and possibly contrasting compositions. The proposed model is not able to resolve these complex open systems, but migrating liquids could be partly responsible for the observed dispersion of points in some correlation diagrams. Absence of significant differentiation with recurrent lithologies in the cumulitic pile of Dents de Bertol points to an efficiently convective magma chamber, with possible periodic replenishment.     

Characteristics of Late Permian Deep-Water Sedimentary Environments： A Case Study of Shaiwa Section, Ziyun County, Guizhou Province, Southwestern China

INTRODUCTIONThe Shaiwa Section is located in the town ofSidazhai, Ziyun County, Guizhou Province, south western China ( Fig. 1 ). This area belongs to theNanpanjiang basin of the Yangtze platform. A greatdeal of work purely on the subdivision of the stratahas been carried out in this region (Guizhou Bureauof Geology and Mineral Resources, 1987). However,studies on recoveries of the paleoenvironments of thisarea are rarely reported. Due to rifting and su…     

Age, distribution, tectonics, and eustatic controls of the Paranense and Caribbean marine transgressions in southern Bolivia and Argentina

Marine transgression onto the South American continent took place at least twice in the Miocene along distinct paleogeographic corridors. The first event occurred between 15 and 13 Ma and the second between 10 and 5? Ma. Each event has particular dominant variables (tectonism, eustacy, sediment accumulation rate) that permitted the preservation of the record and development of the sea on the continent. The 15–13 Ma transgression was tectonically and eustatically controlled, flooding older sedimentary accommodation zones on the South American plate during a global high sea level, whereas the 105? Ma event was predominantly tectonically controlled, generated by tectonic loading created in the Cordillera Oriental fold-and-thrust belt. A new 7.72±0.31 Ma ⁴⁰Ar/³⁹Ar date from the Río Parapetí in Bolivia suggests that the 15–13 Ma transgression registered in Argentina produced no continental connection to the Caribbean transgression, registered in Bolivia, because of temporal constraints.     

Revision of the conchostracan genus Estherites from the Upper Cretaceous Nenjiang Formation of the Songliao Basin and its biogeographic significance in China

The diagnosis of Estherites corrugatus from the basal part of the Coniacian Second Member of the Nenjiang Formation in Nenjiang County, north-east China is revised following the application of a new preparation technique to some of the carapaces and an examination of specimens under a scanning electron microscope, both of which revealed morphological features on the carapace that had not been recognized previously. Restudy of the type species of the two subgenera Estherites (Euestherites) and Estherites (Parestherites) also revealed details of carapace features not seen hitherto. These indicate that they should be separated from Estherites. As a result, Euestherites is upgraded to genus level and Parestherites is placed in synonymy. The importance of Estherites and Euestherites is considered in the context of Late Cretaceous assemblages of these crustaceans and the three conchostracan provinces (South-West, South-East and North China) that are recognized to have been present in China during the Turonian–Santonian period.     

Permo-Carboniferous Radiolarians from the Wupata＇erkan Group, Western South Tianshan, Xinjiang, China

The Wupata‘erkan Group, also called Wupata‘erkan Formation, distributed in the South Tianshan, Xinjiang,China, mainly consists of gray and dark gray fine-grained clastic rocks, interlayered with volcanic rocks, carbonates and cherts. Some ultra-basic rocks (blocks) punctuate the formation. The formation was variously assigned to Silurian-Middle Devonian, Silurian-Lower Devonian, and pre-Devonian, mainly based on Atrypa bodini Mansuy, Hypothyridina parallelepipedia (Brour.) and Prismatophyllum hexagonum Yoh collected from the limestone interlayers, respectively.However, radiolarian fossils obtained from 24 chert specimens of the Wupata‘erkan Group, mainly include Albaillella sp.cf. A. undulata Deflandre, Albaillella sp. cf. A. paradoxa Deflandre, Albaillella cf. A. deflandrei Gourmelon, Albaillella sp. cf. A. indensis Won, Albaillella sp. cf. A. excelsa Ishiga, Kito and Imoto, Albaillella sp. and Latentifistulidae gen. et. sp.indet., are earliest Carboniferous and Late Permian. The earliest Carboniferous assemblage is characterized by Albaillella sp. cf. A. undulata Deflandre, Albaillella sp. cf. A. paradoxa Deflandre, Albaillella cf. A. deflandrei Gourmelon and Albaillella sp. cf. A. indensis Won, and the Late Permian assemblage by Albaillella sp. cf. A. excelsa Ishiga, Kito and Imoto. This new stratigraphic evidence indicates that the Wupata‘erkan Group is possibly composed of rocks with different ages from Silurian to Permian, and therefore, it is probably an ophiolite mrlange. The discovery of Late Permian Albaillella sp. cf. A. excelsa provides more reliable evidence supporting the existence of a Permian relic ancient oceanic basin in the western part of Xinjiang South Tianshan.     

The role of baseflow in dissolved solids delivery to streams in the Upper Colorado River Basin

Salinity has a major effect on water users in the Colorado River Basin, estimated to cause almost $300 million per year in economic damages. The Colorado River Basin Salinity Control Program implements and manages projects to reduce salinity loads, investing millions of dollars per year in irrigation upgrades, canal projects, and other mitigation strategies. To inform and improve mitigation efforts, there is a need to better understand sources of salinity to streams and how salinity has changed over time. This study explores salinity in the baseflow fraction of streamflow, assessing whether groundwater is a significant contributor of dissolved solids to streams in the Upper Colorado River Basin (UCRB). Chemical hydrograph separation was used to estimate baseflow discharge and baseflow dissolved solids loads at stream gages (n = 69) across the UCRB. On average, it is estimated that 89% of dissolved solids loads originate from the baseflow fraction of streamflow, indicating that subsurface transport processes play a dominant role in delivering dissolved solids to streams in the UCRB. A statistical trend analysis using weighted regressions on time, discharge, and season was used to evaluate changes in baseflow dissolved solids loads in streams (n = 27) from 1986 to 2011. Decreasing trends in baseflow dissolved solids loads were observed at 63% of streams. At the three most downstream sites, Green River at Green River, UT, Colorado River at Cisco, UT, and the San Juan River near Bluff, UT, baseflow dissolved solids loads decreased by a combined 823,000 metric tons (mT), which is approximately 69% of projected basin‐scale decreases in total dissolved solids loads as a result of salinity control efforts. Decreasing trends in baseflow dissolved solids loads suggest that salinity mitigation projects, landscape changes, and/or climate are reducing dissolved solids transported to streams through the subsurface. Notably, the pace and extent of decreases in baseflow dissolved solids loads declined during the most recent decade; average decreasing loads during the 2000s (28,200 mT) were only 54% of average decreasing loads in the 1990s (51,700 mT).     

Hydrologic responses to land cover change: the case of Jedeb mesoscale catchment,Abay/Upper Blue Nile basin,Ethiopia

The objective of this study was to quantify the impacts of land use/land cover (LULC) change on the hydrology of the Jedeb, an agricultural dominated mesoscale catchment, in the Abay/Upper Blue Nile basin, Ethiopia. Two methods have been used. First, the trends of certain daily flow variability parameters were evaluated to detect statistical significance of the change of the hydrologic response. Second, a conceptual monthly hydrological model was used to detect changes in the model parameters over different periods to infer LULC change. The results from the statistical analysis of the daily flows between 1973 and 2010 reveal a significant change in the response of the catchment. Peak flow is enhanced, i.e. response appears to be flashier. There is a significant increase in the rise and fall rates of the flow hydrograph, as well as the number of low‐flow pulses below a threshold level. The discharge pulses show a declining duration with time. The model result depicts a change in model parameters over different periods, which could be attributed to an LULC change. The model parameters representing soil moisture conditions indicated a gradual decreasing trend, implying limited storage capacity likely attributed to increasing agricultural farming practices in the catchment. This resulted in more surface runoff and less infiltration into the soil layers. The results of the monthly flow duration curve analysis indicated large changes of the flow regime. The high flow has increased by 45% between the 1990s and 2000s, whereas the reduction in low flows was larger: a 15% decrease between 1970s and 1980s, 39% between 1980s and 1990s and up to 71% between 1990s and 2000s. These results, could guide informed catchment management practices to reduce surface runoff and augment soil moisture level in the Jedeb catchment. Copyright © 2013 John Wiley & Sons, Ltd.     

COAL GEOLOGY

正20141574 Chen Hao(Exploration and Development Research Institute,Daqing Oilfield Company,Daqing 163712,China)High-Resolution Sequences and Coal Accumulating Laws in Nantun Formation of Huhe Lake Sag(Petroleum GeologyOilfield Development in Daqing,ISSN1000-3754,CN23-1286/TQ,32(4),2013,p.15-19,5 illus.,15 refs.)Key words:coal accumulation regularity,coal