湘东北—桂北中元古界岩石地球化学特征

湘东北—桂北中元古代冷家溪群和四堡群的变玄武岩类显示过渡型拉斑玄武岩类的地球化学特征,变砂岩类和变泥岩类（绢云板岩类）显示大陆边缘的砂岩类和泥岩类的地球化学特征。根据岩石地球化学和沉积相（低密度流复理石建造）特征,推测湘东北冷家溪群和桂北四堡群主要形成于大陆边缘深水环境。     

铁矿床中黑柱石富集特例剖析

黑柱石是一种少见的含钙铁硅酸盐矿物。通过富含黑柱石的青海省双庆铁矿区与仅含少量黑柱石的福建省马坑铁矿区矿床地质特征的对比,认为矿床中黑柱石的产生与中基性火成岩的参与有关;黑柱石的解体与硼的参与有关。     

浙西北前震旦纪火山岩的Nd、Sr同位素地球化学

在浙西北双溪坞群和上墅组火山岩系获得较可靠的Sm－Nd同位素年龄的基础上，本文进一步做了Nd、Sr同位素地球化学研究。∈Nd（T）和∈Sr（T）示踪判别了该区前震旦纪火山岩浆源区特征及其物质来源。同时，Nd同位素模式年龄为该区存在更古老基底提供了重要的地质年代信息。     

Tracking temporal palynofloral changes close to Cretaceous-Paleogene boundary in Deccan volcanic associated sediments of eastern part of central Deccan volcanic province

Deccan volcanic sequences( DVS) in the central Deccan volcanic province( CDVP) are designated as Sahyadri Group having ~ 500 m thick lava pile associated with multiple sedimentary beds at different stratigraphic levels. In the eastern part of CDVP between the latitude 19 °55 '--20 °25 ' N and the longitudes 78 °15 '--78 °30 ' E,palynological investigation of the intertrappean sedimentary beds at five stratigraphic levels was carried out. The study was basically aimed for tracking the floral and environmental changes across the Deccan transition. The resulting finds indicate that the intertrappean sediments at the lowest stratigraphic level between the earliest lava flows are characterized by presence of marker Maastrichtian palynomorphs- Gabonisporis vigourouxii,Aquilapollenites bengalensis,Azolla cretacea and Farabeipollis associated with triporate and tricolpate pollen grains,phytoliths of Oryzeae of Poaceae family and peridinoid dinoflagellate cysts. The increasing volcanism deteriorated the existing flora as evident by absence of pollen-spores and presence of only structured biodegraded organic matter,fungal spores,acritarchs and algal( Botryococcus) remains in the sediments of higher-up in the sequence. For chronostratigraphic constraints on the lava flows magnetic polarity of the flows bracketing the intertrappean beds was investigated. The results indicated presence of N-R-N-R magnetic polarity in the basal lava pile that are interpreted as representing the magnetochron C30 N to C28 R( Maastrichtian-Paleogene). The floral change begins with the onset of volcanism in the chron C30 N and floral deterioration is observed in C29 N with increasing volcanism and it is only in the chron C28 R( Danian) that some evidence of recovery of flora is recorded. The current study shows that in eastern part of CDVP the post Cretaceous-Paleogene boundary eruptions represent the main phase of eruptions that triggered deterioration of the flora.     

松辽盆地深层断陷沙河子组烃源岩分布预测与生气潜力

松辽盆地下白垩统沙河子组是深层断陷的主要烃源岩发育层系,目前钻井揭示其厚度大（＞700 m）,埋藏深（＞3500 m）,但钻井大都分布于深层断陷的边部,断陷内部烃源岩层揭示少。根据断陷结构样式及地震反射特征,总结出单断箕状断陷和双断地堑式断陷两种沙河子组烃源岩发育模式,并确定深层烃源岩主要有五种存在形式。断陷中部席状平行结构、成层性、连续性好的地震反射特征的烃源岩最为落实,主要为深湖-半深湖相,暗色泥岩厚度大,暗地比高（45％～70％）。深层沙河子组烃源岩总生气量约148.38×1012 m3,天然气资源潜力巨大。     

试论碳酸盐岩上覆红土的形成模式及演化趋势

据长期对岩溶及红土化作用等的研究成果,本文全面系统地分析了碳酸盐岩上覆红土的形成及演化规律,提出了一个新的碳酸盐岩上覆红土的形成模式,进而深入阐明了碳酸盐岩上覆红土的演化规律及其在现代气候条件下的演化趋势等,在解决岩溶及红土学术界存在的碳酸盐岩上覆红土的形成、碳酸盐岩与上覆红土之间的相互关系及其发展演化规律等一系列重大疑难问题上向前迈进了一步,对相关学科的发展将产生积极的推动作用.     

青海省祁连县山阴凹槽海相火山岩型锌铜矿床地球化学特征及其成因意义

祁连县山阴凹槽锌铜矿是中国一个典型的铜多金属成矿区,但总体研究程度较低,目前尚未见到地球化学研究报道。笔者结合矿床地质探讨火山岩主微量元素、稀土元素特征,矿床硫-铅同位素组成与成因。成矿火山岩SiO2（46.96%~53.85%）、TiO2（0.90%~2.02%）质量分数较高,岩石以轻微富集大离子亲石元素（Rb、Ba、K）、相对亏损高场强元素（Nb、Ta、Ti）和Eu轻微正异常、Ce轻微负异常为特征,具有岛弧拉斑玄武岩和N-MORB的双重地球化学特征。火山岩岩浆来源于被俯冲流体交代的亏损地幔,形成环境为弧后盆地扩张环境。锌铜矿化的诸多因素,包括物质来源、容矿围岩和矿液通道等都与火山岩有关,锌矿主要赋存于硅化大理岩中,铜矿主要赋存于大理岩与片理化玄武岩接触带。     

Resistivity of reservoir sandstones and organic rich shales on the Barents Shelf:Implications for interpreting CSEM data

Marine controlled source electromagnetic(CSEM)data have been utilized in the past decade during petroleum exploration of the Barents Shelf,particularly for de-risking the highly porous sandstone reservoirs of the Upper Triassic to Middle Jurassic Realgrunnen Subgroup.In this contribution we compare the resistivity response from CSEM data to resistivity from wireline logs in both water-and hydrocarbon-bearing wells.We show that there is a very good match between these types of data,particularly when reservoirs are shallow.CSEM data,however,only provide information on the subsurface resistivity.Careful,geology-driven interpretation of CSEM data is required to maximize the impact on exploration success.This is particularly important when quantifying the relative re-sistivity contribution of high-saturation hydrocarbon-bearing sandstone and that of the overlying cap rock.In the presented case the cap rock comprises predominantly organic rich Upper Jurassic-Early Cretaceous shales of the Hekkingen Formation(i.e.a regional source rock).The resistivity response of the reservoir and its cap rock become merged in CSEM data due to the transverse resistance equivalence principle.As a result of this,it is imperative to understand both the relative contributions from reservoir and cap rock,and the geological sig-nificance of any lateral resistivity variation in each of the units.In this contribution,we quantify the resistivity of organic rich mudstone,i.e.source rock,and reservoir sandstones,using 131 exploration boreholes from the Barents Shelf.The highest resistivity(＞10,000 Ωm)is evident in the hydrocarbon-bearing Realgrunnen Subgroup which is reported from 48 boreholes,43 of which are used for this study.Pay zone resistivity is primarily controlled by reservoir quality(i.e.porosity and shale fraction)and fluid phase(i.e.gas,oil and water saturation).In the investigated wells,the shale dominated Hekkingen Formation exhibits enhanced resistivity compared to the background(i.e.the underlying and overlying stratigraphy),though rarely exceeds 20Ωm.Marine mudstones typically show good correlation between measured organic richness and resistivity/sonic velocity log signatures.We conclude that the resistivity contribution to the CSEM response from hydrocarbon-bearing sandstones out-weighs that of the organic rich cap rocks.     

北祁连东段红土堡基性火山岩锆石LA-ICP-MS U-Pb年代学及其地质意义

为精确限定红土堡基性火山岩的形成时代,结合阴极发光分析,分别对北祁连东段红土堡枕状玄武岩和辉绿岩墙进行了LA - ICP - MS 单颗粒锆石微区U - Pb 同位素测年。红土堡枕状玄武岩获得（443.4 ±1.7 ）Ma 和（1 782 ±34 ）Ma 两组年龄值;同时,获得红土堡基性火山岩中辉绿岩墙的年龄为（385.7 ±7.9 ）Ma,并含有（1 697 ±6 ） ～（2 692 ±4 ）Ma 的捕晶锆石年龄信息。认为红土堡基性火山岩的形成时代为晚奥陶世,与其北的陈家河中酸性火山岩的形成时代大体一致,推断红土堡基性火山岩的原始岩浆不同程度遭受了陇山岩群的混染。这一新资料,对进一步研究北祁连造山带东段大地构造格局、构造演化以及北秦岭—北祁连衔接关系具有重要意义。     

二叠系火山碎屑岩气藏天然气地球化学特征及气源分析——以四川盆地成都—简阳地区永探1井为例

2018年12月底,在四川盆地二叠系火山岩发育地区部署的风险探井永探1井测试获得22.5万m³/d的高产工业气流,实现了二叠系火山碎屑岩的重大勘探突破,展现了火山碎屑岩气藏的巨大勘探潜力。本文根据该钻井成果资料,应用分析化验数据,采用不同地区气-气对比方法,开展了成都—简阳地区天然气地球化学特征分析、源-储接触关系解剖及气源综合对比。在此基础上,对二叠系火山碎屑岩气藏天然气成因进行了鉴别,对天然气来源进行了判识。结果表明：永探1井火山岩气藏天然气均为典型的干气,干燥系数达0.997,CH₄质量分数高,平均为99.03%,C₂H₆质量分数低,平均为0.35%,C₃H₈几乎没有,不含H₂S;天然气甲烷、乙烷碳同位素值均较轻,甲烷碳同位素平均值为-32.17‰,乙烷碳同位素平均值为-34.27‰,且岩心及镜下可见大量残余沥青,天然气成因鉴别分析表明永探1井火山岩气藏天然气为原油二次裂解气;通过源-储接触关系解剖以及天然气甲烷、乙烷碳同位素对比分析,表明永探1井火山碎屑岩气藏天然气主要来源于德阳—安岳台内裂陷内发育的巨厚下寒武统筇竹寺组优质烃源岩,部分来源于中二叠统。