晚中生代沂沭断裂带左旋韧性剪切与岩浆迁移规律

沂沭断裂带内部的岩浆侵入与断裂活动关系密切,开展沂沭断裂带内部岩浆年代学研究,对于沂沭断裂带构造背景研究具有积极的参考意义。选取沂沭断裂带内部的莒县浮来山正长岩体、边部的莒南官坊石英正长岩体及侵入该岩体的闪长玢岩脉,开展岩石学及年代学研究。首次发现晚中生代沂沭断裂带左旋韧性剪切,获得浮来山岩体的LA-ICP-MS锆石U-Pb年龄为(125.1±1.7) Ma,官坊岩体年龄为(125.6±2.0) Ma, 发生韧性变形的闪长玢岩脉年龄为(122.8±2.1) Ma。获得的125 Ma岩浆活动年龄与沂沭断裂带东侧的五莲变质核杂岩快速剥露(122~128 Ma)、诸城断陷盆地快速沉降的时间相吻合,该时期沂沭断裂带处于岩石圈减薄与破坏强烈的时期;闪长玢岩脉的122.8 Ma结晶年龄,与五莲变质核杂岩后构造岩体(石场、坊子岩体等)结晶年龄一致,该时期沂沭断裂带处于弱伸展状态,同时也说明胶东半岛岩石圈减薄具有时间上的一致性。晚中生代时期,沂沭断裂带两侧岩浆活动具有逆时针迁移的规律,这一规律可能与伊佐奈岐板块向欧亚板块俯冲的方向、角度、速度的变换有关。     

青藏高原东北缘祁连山三叠系砂岩碎屑锆石U-Pb定年及其物源分析

三叠系沉积物广泛覆盖青藏高原东北缘,其中松潘—甘孜地区三叠系的沉积物得到了较系统的研究,但是青藏高原北缘的祁连山三叠系盆地的研究却较为缺乏。为了丰富相关研究和揭示区域构造演化的特点,通过古水流方向统计、砂岩中碎屑矿物统计和碎屑锆石U-Pb测年等方法对祁连山三叠纪盆地物源进行系统研究。结果表明,祁连山三叠系盆地的古流向主要有南东向、正南向、南西向,物源来自岩浆弧和大规模褶皱造山作用的混合区。祁连山三叠系砂岩中的碎屑锆石的年龄谱主要峰值集中在250~290 Ma、360~460 Ma、1 600~2 000 Ma和2 200~2 600 Ma这4个年龄段。通过对比分析华北板块、华南板块中和秦祁昆中央造山带中岩浆锆石年龄谱特征可知:1 600~2 000 Ma和2 200~2 600 Ma年龄段的锆石来自华北板块,360~460 Ma年龄段的锆石来自北祁连造山带,250~290 Ma年龄段的锆石来自东昆仑的火山岛弧。此外,600~1 000 Ma年龄段锆石很少,这些锆石来自扬子板块,表明在三叠纪扬子克拉通和华北克拉通发生碰撞形成了秦岭造山带,阻断了来自扬子克拉通的物源。     

新特提斯洋晚白垩世演化特点:来自泽当共国日二长花岗岩年代学、地球化学及Sr-Nd同位素证据

为加深对西藏泽当地区新特提斯洋演化的认识,对西藏泽当蛇绿混杂岩带内的共国日二长花岗岩进行了岩石学、岩石地球化学、同位素及年代学等研究,研究显示:共国日二长花岗岩岩体规模小、岩性稳定,LA-ICP-MS锆石U-Pb年龄为(90.40±0.68)Ma,属晚白垩世;岩石地球化学具高硅、富铝、富钾、低钛和准铝质钙碱性花岗岩特征;轻稀土富集、重稀土亏损,具明显的负Eu异常,微量元素表现为相对富集Rb、K、Ba、Th、U等大离子亲石元素,显著亏损Nb、P、Ti等高场强元素;(⁸⁷Sr/⁸⁶Sr)_i=0.705 708~0.706 284,(¹⁴³Nd/¹⁴⁴Nd)_i=0.512 689~0.512 716,ε_Nd(t)=2.00~2.51。以上特征表明,位于泽当蛇绿混杂岩带内的共国日二长花岗岩属于I型花岗岩,由正常岛弧岩浆形成,应为晚白垩世新特提斯洋向北俯冲形成的岛弧环境下俯冲带上部地壳部分熔融的产物,其不属于泽当蛇绿岩的组成部分,表明在90 Ma前泽当洋内弧已经消失。     

U-Pb Zircon and Re-Os Molybdenite Geochronology of theW-Mo Mineralized Region of South Qinling,China, andtheir Tectonic Implications

A W-Mo mineralized region is located along the northern margin of the South Qinling tectonic belt of China. WMo mineralization occurs mainly in Cambrian–Ordovician clastic and carbonate rocks, and the ore bodies are structurally controlled by NW–SE-and NNE–SSW-striking faults. Evidence for magmatism in the area is widespread and is dominated by intermediate–felsic intrusives or apophyses, such as the Dongjiangkou, Yanzhiba, Lanbandeng, and Sihaiping granitic bodies. Quartz-vein-type mineralization and fault-controlled skarn-type mineralization dominate the ore systems, with additional enrichment in residual deposits. At present, there are few or insufficient studies on(1) the age of mineralization,(2) the relationship between intermediate–felsic granite and W-Mo mineralization,(3) the source of ore-forming materials,and(4) the metallogenic and tectonic setting of the mineralized area. In this paper, we present geochronology results for numerous intrusive granitic bodies in the South Qinling tectonic belt. U-Pb zircon geochronology of the Lanbandeng monzogranite and Wangjiaping biotite monzogranite yields ages of 222.7 ± 2.3 and 201.9 ± 1.8 Ma, respectively. In contrast to the Late Triassic age of the Lanbandeng monzogranite, the age of the newly discovered Wangjiaping biotite monzogranite places it at the Triassic–Jurassic boundary. Re-Os molybdenite geochronology on the Qipangou W-Mo deposit yielded a model age of 199.7 ± 3.9 Ma, indicating the deposit formed in the early Yanshanian period of the Early Jurassic. Granitoid intrusions in the mineralized area are characterized by composite granite bodies that crystallized at ca.240–190 Ma. While there were multiple stages of intrusion, most occurred at 210–220 Ma, with waning magmatic activity at 200–190 Ma. The Re-Os age of molybdenite in the region is ca. 200–190 Ma, which may represent a newly discovered period of W-Mo metallogenesis that occurred during the final stages of magmatism. The heat associated with this magmatism drove ore formation and might have provided additional ore-forming components for metallogenesis(represented by the Wangjiaping biotite monzogranite). Ore materials in the mineralized area were derived from mixed crustal and mantle sources. Enrichment of the region occurred during intracontinental orogenesis in the late Indosinian–Yanshanian, subsequent to the main Indosinian collision. At this time, the tectonic environment was dominated by extension and strike-slip motion.     

Geochemistry and Tectonic History of Seamount Remnants in the Xingshuwa Subduction Accretionary Complex of the Xar Moron Area,Eastern Margin of the Central Asian Orogenic Belt

This study focuses on the geology, geochemistry, zircon U-Pb geochronology and tectonic settings of the three types of seamount basalts from the Xingshuwa subduction accretionary complex in the Xar Moron area, eastern margin of the Central Asian Orogenic Belt(CAOB). The seamount remnants are composed of carbonate 'cap' sediments, large volumes of pillow and massive basalts, carbonate breccia slope facies and radiolarian cherts. Group 1 basalts are characterized by high contents of P2 O5 and TiO2 with alkaline affinity and LREE enrichment, indicating that they are derived from intraplate magma. Group 2 basalts display N-MORB LREE depletion patterns, indicating that they were formed at a mid-ocean ridge. Group 3 basalts have shown distinct Nb depletion and high Th/Yb ratios, indicating that they were generated in an island arc tectonic setting. The zircon U-Pb age of Group 1 basalt sample XWT18-131 is 576.4 ± 9.4 Ma, suggesting that the oceanic island seamount was the product of intraplate magmatism related to a mantle plume or 'hot spot' in the late Neoproterozoic. The zircon U-Pb age of Group 2 basalt sample XWT18-132 is 483 ± 22 Ma, indicating that the Paleo-Asian Ocean(PAO) was continuously expanding in the Early Ordovician. The zircon U-Pb age of Group 3 basalt sample XWT18-101 is 240.5 ± 8.2 Ma, suggesting that this area underwent the evolutionary path of ocean-continent transition, developing towards continentalization during the Middle Triassic. Thus, we believe that there was both mantle plume-related intraplate magmatism and intraoceanic subduction during the evolution of the PAO, the CAOB possibly being an evolutionary model of an intraoceanic subduction and mantle plume magmatism complex.     

The U-Pb Geochronology and Lu-Hf Isotope Compositions of Detrital Zircons from the Nanhua Group of the Longsheng Region, South China and their Implications for Pan-African Events

It is unclear whether the South China blocks have an affinity with continental Gondwana due to a lack of direct Pan-African magmatic and metamorphic features. In this study, we conducted U-Pb geochronological and Lu-Hf isotopic analyses for detrital zircons from a sandstone of the Chang’an Formation of the Nanhua Group in the Longsheng region of northern Guangxi, with the aim of constraining the timing of sedimentation and information as to its source, as well as seeking evidence for Pan-African events in the South China blocks. The results show that the ages of detrital zircons peaked at 654.7 ± 6.2 Ma, 773.2 ± 4.1 Ma and 821.9 ± 6.5 Ma, with some at 920–870 Ma; the youngest age indicates the existence of the Pan-African thermal event. The εHf(t) and TDM2 values demonstrate that the study area has experienced three stages of crustal growth at 3.0–2.4 Ga, 2.1–1.5 Ga and 1.3–0.9 Ga. With intensively distributed Neoproterozoic mafic-ultramafic and granitic plutons emplaced at 830–810 Ma along the southwestern section of the Jiangnan Orogenic Belt and positive εHf(t) values from a large group of zircon grains, it is proposed that the sediments of the Chang’an Formation (of Nanhua Group) were largely sourced from the southeastern margin of the Yangtze block. Comparison with the zircon age spectra of the Cathaysian block shows that about 79% of the Pan-African aged detrital zircon grains that have TDM2 = 1352–1031 Ma and εHf(t) = 3.68–8.79, were sourced from the recycled Grenvillian crust of the Cathaysian block, suggesting that the Cathaysian block had a close connection with Gondwana.     

扬子陆块西缘江浪穹窿超基性岩的成因:锆石U-Pb定年、岩石地球化学及Sr-Nd同位素

江浪穹窿位于扬子陆块西缘,本文作者在穹窿南部新发现一套侵入于二叠系及志留系的超基性岩,岩石主要由蛇纹石(约60%)、橄榄石(约30%)和少量磁铁矿(约5%)、角闪石(约5%)组成。为探讨超基性岩的成因,本文进行了LA-ICP-MS锆石U-Pb定年、岩石地球化学及Sr-Nd同位素研究。定年结果表明,超基性岩中发育大量2427~430 Ma的捕获锆石,最年轻一组岩浆锆石²⁰⁶Pb/²³⁸U加权平均年龄为222.3±4.4 Ma(MSWD=1.9,n=6)。主微量元素分析显示岩石：(1)具有低的SiO₂含量(46.76%~39.07%)、高的Mg#值(82.3~74.0)与Cr、Co、Ni丰度;(2)稀土元素含量(ΣREE平均31.8 μg/g)与(La/Yb)_N值(5.26~1.38)偏低,稀土配分型式较为平坦,具有较弱的Ce负异常(Ce/Ce^*=0.80~0.67);(3)富集大离子亲石元素Rb、Ba和U,亏损高场强元素Zr和Hf;(4)(Th/Yb)_PM值(29.8~1.56)、(Th/Ta)_PM值(0.22~0.03)、(La/Nb)_PM值(1.91~0.39)及La/Sm值(5.88~1.11)较低。Sr-Nd同位素分析显示,超基性岩具有较低的(⁸⁷Sr/⁸⁶Sr)_i值(0.706872~0.702598)和高的ε_Nd(t)值(8.02~5.64),成分接近于亏损地幔和岛弧玄武岩,计算表明地壳物质的混染程度低于5%。结合前人研究成果,本文认为超基性岩结晶年龄为222.3 Ma,可能形成于古特提斯洋闭合阶段的岛弧背景;原始岩浆来自高度部分熔融的地幔源区,上升侵位过程中可能经历了铬铁矿与橄榄石的分离结晶作用。此外,捕获锆石的年龄谱反映江浪穹窿很可能存在太古宙—古元古代变质基底,并且具有Rodinia超大陆会聚—裂解以及泛非事件的地质年龄记录。     

Effect of the Dry Ashing Method on Cadmium Isotope Measurements in Soil and Plant Samples

A dry ashing method is commonly used to remove organic material from samples prior to geochemical analysis. In the course of this study, the Cd isotope ratios of a series of soil and plant reference materials and samples were studied to evaluate the effect of the dry ashing method on measurement results of Cd isotope ratios. The samples were pre‐treated using the dry ashing method and high‐pressure bomb for comparison. The results show that the digestion using high‐pressure bombs did not lead to Cd loss, but using the dry ashing method would cause different proportions of Cd loss. The whole range of Cd isotope difference between two methods was from ?0.07‰ to 3.01‰. There was also an obvious difference in measured Cd isotope ratios from the same leaf sample pre‐treated independently by the dry ashing method, indicating that the amount of Cd loss and the effect on Cd isotope measurement during dry ashing is related to the properties of the samples. Therefore, dry ashing may not be appropriate for the removal of organic material in Cd isotope ratio measurement, especially for samples with high organic contents. The δ^114/110Cd values of reference materials NIST SRM 1573a and GSD‐30 are reported for the first time in this study.     

四川盆地开江地区WT1井震旦系陡山沱组物源分析及构造背景判断*

为厘清四川盆地开江地区WT1井震旦系陡山沱组地层发育的构造背景,重塑其原型沉积盆地,为重建古地理及油气进一步勘探部署工作提供科学依据,利用岩石学、岩石地球化学及碎屑锆石U-Pb年代学手段对该井陡山沱组物源进行了分析。岩石地化结果表明WT1井陡山沱组沉积物源岩为中基性火山岩类且经历了中等程度化学风化作用;碎屑锆石U-Pb年龄主要记录了915~850Ma、794~714.5Ma以及622~700Ma 3个阶段的构造岩浆活动,与扬子克拉通北缘及邻区Rodinia超大陆的裂解演化过程有关,该构造活动背景下的中基性火山岩是WT1井陡山沱组沉积的主要物质来源。结果表明四川盆地开江地区的陡山沱组发育于拉张伸展构造背景,属克拉通内裂陷盆地沉积,有利于烃源岩层的发育;同时为Rodinia超大陆的裂解演化过程提供了重要的年代学演化证据。该成果对深入认识四川盆地的地质结构、沉积-构造演化以及油气勘探的战略部署等具有极为重要的科学意义。     

冀东峪耳崖金矿区闪长岩脉地球化学特征及其地质意义

冀东地区位于华北板块北缘燕山造山带东部,矿产资源丰富,是中国金矿的主要产地之一,尤其是热液型金矿。峪耳崖金矿床是冀东众多热液型金矿床的典型代表,金矿主体赋存于侏罗纪峪耳崖花岗岩体内,少部分赋存于侵入花岗岩体的侏罗纪闪长岩脉中。闪长岩脉元素地球化学分析显示：w（SiO₂）为51.99%~61.88%、Mg^#值为0.37~0.64,w（Na₂O+K₂O）为5.07%~8.89%,A/NK为1.37~2.26,A/CNK为0.73~0.96,属准铝质高钾钙碱性系列;富集轻稀土元素和大离子亲石元素Rb、Ba、K、Sr,亏损重稀土元素和高场强元素Nb、Ta、Ti。锆石原位Hf同位素测试表明,ε_Hf（t）为负值,介于-16.5~-6.5之间。综合研究认为：峪耳崖金矿区侏罗纪闪长岩浆源于俯冲流体交代的富集岩石圈地幔,岩浆上侵过程中受到华北板块古老下地壳物质的有限混染;成矿期闪长岩浆为金成矿提供了部分物质来源;峪耳崖金矿区闪长岩脉形成于古太平洋板块向欧亚大陆俯冲的动力学背景。