热液矿床石英铅同位素组成及其地质意义

作者以若尔盖铀矿床为例，研究了含矿热液形成的石英脉石英的铅同位素组成，并将其作为联系母源铅同位素组成的桥梁，判别铀的来源。结果表明，矿床中石英铅同位素组成与含矿黄铁矿和中酸性构造－岩浆成因的花岗岩铅同位素组成具线性演化关系。由此提出含矿热液中的铀来自中酸性构造－岩浆岩而不是地层岩石的新见解，同时提出利用热液石英铅同位素组成判别非放射性矿床成矿元素来源的可能性。     

凤太矿集区金铅锌矿地球化学特征及找矿方向

通过对金、铅锌矿成矿规律和地球化学特征的研究,讨论陕西凤太矿集区今后的找矿方向,并初步圈定了4处找矿靶区。     

铜陵地区老鸦岭层状钼矿床铅同位素组成研究

安徽铜陵老鸦岭矿床中二叠系大隆组(P2d)顶部的含矿(钼矿化)黑色页岩以及附近(立新煤矿)同一层位不含矿黑色页岩的实测铅同位素组成分别为：^206Pb/^204Pb20.20～22.37,^207Pb/^204Pb15.67～15.82,^208Pb/^204Pb38.47～38.60和^206Pb/204Pb18.83～20.80,^207Pb/^204Pb15.65～15.76,^208Pb/^204Pb38．84～39．22。对137Ma的放射成因Pb进行校正后的铅同位素组成表明，含矿黑色页岩和不含矿黑色页岩均与燕山晚期火成岩无关，老鸦岭含矿黑色页岩可能具沉积成因。对沉积(约250Ma)以来的放射成因Pb进行校正后的铅同位素组成表明：不含矿黑色页岩的Pb源自上地壳，而含矿黑色页岩的Pb(因而推测其他成矿金属)可能源于上地壳物质(与不含矿黑色页岩的Pb源相似)与下地壳物质的混合。     

Petrology and Geochemistry of Early Cretaceous Bimodal Continental Flood Volcanism of the NW Etendeka, Namibia. Part 1: Introduction, Mafic Lavas and Re-evaluation of Mantle Source Components

The bimodal NW Etendeka province is located at the continentalend of the Tristan plume trace in coastal Namibia. It comprisesa high-Ti (Khumib type) and three low-Ti basalt (Tafelberg,Kuidas and Esmeralda types) suites, with, at stratigraphicallyhigher level, interstratified high-Ti latites (three units)and quartz latites (five units), and one low-Ti quartz latite.Khumib basalts are enriched in high field strength elementsand light rare earth elements relative to low-Ti types and exhibittrace element affinities with Tristan da Cunha lavas. The unradiogenic²⁰⁶Pb/²⁰⁴Pb ratios of Khumib basalts are distinctive, most plottingto the left of the 132 Ma Geochron, together with elevated ²⁰⁷Pb/²⁰⁴Pbratios, and Sr–Nd isotopic compositions plotting in thelower ¹⁴³Nd/¹⁴⁴Nd part of mantle array (EM1-like). The low-Tibasalts have less coherent trace element patterns and variable,radiogenic initial Sr (     

U-Pb Zircon Calendar for Namaquan (Grenville) Crustal Events in the Granulite-facies Terrane of the O'okiep Copper District of South Africa

The O'okiep Copper District is underlain by voluminous 1035–1210Ma granite gneiss and granite with remnants of metamorphosedsupracrustal rocks. This assemblage was intruded by the 1030Ma copper-bearing Koperberg Suite that includes jotunite, anorthosite,biotite diorite and hypersthene-bearing rocks ranging from leuconoriteto hypersthenite. New sensitive high-resolution ion microprobeage data demonstrate the presence of 1700–2000 Ma zirconas xenocrysts in all of the intrusive rocks, and as detritalzircon in the metasediments of the Khurisberg Subgroup. Thesedata are consistent with published Sm–Nd model ages ofc. 1700 Ma (T_CHUR) and c. 2000 Ma (T_DM) of many of the intrusivesthat support a major crust-forming event in Eburnian (Hudsonian)times. In addition, U–Th–Pb analyses of zirconsfrom all major rock units define two tectono-magmatic episodesof the Namaquan Orogeny: (1) the O'okiepian Episode (1180–1210Ma), represented by regional granite plutonism, notably theNababeep and Modderfontein Granite Gneisses and the Concordiaand Kweekfontein Granites that accompanied and outlasted (e.g.Kweekfontein Granite) regional tectonism [F₂(D₂)] and granulite-faciesmetamorphism (M₂); (2) the Klondikean Episode (1020–1040Ma), which includes the intrusion of the porphyritic RietbergGranite and of the Koperberg Suite that are devoid of regionalplanar or linear fabrics. Klondikean tectonism (D₃) is reflectedby major east–west-trending open folds [F₃(D_3a)], andby localized east–west-trending near-vertical ductilefolds [‘steep structures’; F₄(D_3b)] whose formationwas broadly coeval with the intrusion of the Koperberg Suite.A regional, largely thermal, amphibolite- to granulite-faciesmetamorphism (M₃) accompanied D₃. This study demonstrates, interalia, that the complete spectrum of rock-types of the KoperbergSuite, together with the Rietberg Granite, was intruded in ashort time-interval (<10 Myr) at c. 1030 Ma, and that therewere lengthy periods of about 150 Myr of tectonic quiescencewithin the Namaquan Orogeny: (1) between the O'okiepian andKlondikean Episodes; (2) from the end of the latter to the formalend of Namaquan Orogenesis 800–850 Ma ago. KEY WORDS: U–Pb, zircon; O'okiep, Namaqualand; granite plutonism; granulite facies; Koperberg Suite; Namaquan (Grenville) Orogeny     

A Sequence of Pan-African and Hercynian Events Recorded in Zircons from an Orthogneiss from the Hercynian Belt of Western Central Iberia--an Ion Microprobe U-Pb Study

Sensitive high-resolution ion microprobe U–Pb dating showsthat a biotite orthogneiss from the Hercynian belt of westerncentral Iberia contains 1000–300 Ma zircon. Older, 1000–570Ma ages within this range represent inherited, detrital materialamong which four age components may be recognized:     

U–Pb geochronology of the southern Brasília belt (SE-Brazil): sedimentary provenance, Neoproterozoic orogeny and assembly of West Gondwana

The Brasília belt borders the western margin of the São Francisco Craton and records the history of ocean opening and closing related to the formation of West Gondwana. This study reports new U–Pb data from the southern sector of the belt in order to provide temporal limits for the deposition and ages of provenance of sediments accumulated in passive margin successions around the south and southwestern margins of the São Francisco Craton, and date the orogenic events leading to the amalgamation of West Gondwana.Ages of detrital zircons (by ID–TIMS and LA-MC-ICPMS) were obtained from metasedimentary units of the passive margin of the São Francisco Craton from the main tectonic domains of the belt: the internal allochthons (Araxá Group in the Áraxá and Passos Nappes), the external allochthons (Canastra Group, Serra da Boa Esperança Metasedimentary Sequence and Andrelândia Group) and the autochthonous or Cratonic Domain (Andrelândia Group). The patterns of provenance ages for these units are uniform and are characterised as follows: Archean–Paleoproterozoic ages (3.4–3.3, 3.1–2.7, and 2.5–2.4 Ga); Paleoproterozoic ages attributed to the Transamazonian event (2.3–1.9 Ga, with a peak at ca. 2.15 Ga) and to the ca. 1.75 Ga Espinhaço rifting of the São Francisco Craton; ages between 1.6 and 1.2 Ga, with a peak at 1.3 Ga, revealing an unexpected variety of Mesoproterozoic sources, still undetected in the São Francisco Craton; and ages between 0.9 and 1.0 Ga related to the rifting event that led to the individualisation of the São Francisco paleo-continent and formation of its passive margins. An amphibolite intercalation in the Araxá Group yields a rutile age of ca. 0.9 Ga and documents the occurrence of mafic magmatism coeval with sedimentation in the marginal basin.Detrital zircons from the autochthonous and parautochthonous Andrelândia Group, deposited on the southern margin of the São Francisco Craton, yielded a provenance pattern similar to that of the allochthonous units. This result implies that 1.6–1.2 Ga source rocks must be present in the São Francisco Craton. They could be located either in the cratonic area, which is mostly covered by the Neoproterozoic epicontinental deposits of the Bambuí Group, or in the outer paleo-continental margin, buried under the allochthonous units of the Brasília belt.Crustal melting and generation of syntectonic crustal granites and migmatisation at ca. 630 Ma mark the orogenic event that started with westward subduction of the São Francisco plate and ended with continental collision against the Paraná block (and Goiás terrane). Continuing collision led to the exhumation and cooling of the Araxá and Passos metamorphic nappes, as indicated by monazite ages of ca. 605 Ma and mark the final stages of tectonometamorphic activity in the southern Brasília belt.Whilst continent–continent collision was proceeding on the western margin of the São Francisco Craton along the southern Brasília belt, eastward subduction in the East was generating the 634–599 Ma Rio Negro magmatic arc which collided with the eastern São Francisco margin at 595–560 Ma, much later than in the Brasília belt. Thus, the tectonic effects of the Ribeira belt reached the southernmost sector of the Brasília belt creating a zone of superposition. The thermal front of this event affected the proximal Andrelândia Group at ca. 588 Ma, as indicated by monazite age.The participation of the Amazonian craton in the assembly of western Gondwana occurred at 545–500 Ma in the Paraguay belt and ca. 500 Ma in the Araguaia belt. This, together with the results presented in this work lead to the conclusion that the collision between the Paraná block and Goiás terrane with the São Francisco Craton along the Brasília belt preceded the accretion of the Amazonian craton by 50–100 million years.     

U–Pb ages of Neoarchean granitoids from the Black Hills, South Dakota, USA: implications for crustal evolution in the Archean Wyoming province

Zircons in basement rocks from the eastern Wyoming province (Black Hills, South Dakota, USA) have been analyzed by ion microprobe (SHRIMP) in order to determine precise ages of Archean tectonomagmatic events. In the northern Black Hills (NBH) near Nemo, Phanerozoic and Proterozoic (meta)sedimentary rocks are nonconformably underlain by Archean biotite–feldspar gneiss (BFG) and Little Elk gneissic granite (LEG), both of which intrude older schists. The Archean granitoid gneisses exhibit a pervasive NW–SE-trending fabric, whereas an earlier NE–SW-trending fabric occurs sporadically only in the BFG, which is intruded by the somewhat younger LEG. Zircon crystals obtained from the LEG and BFG exhibit double terminations, oscillatory zoning, and Th/U ratios of 0.6±0.3—thereby confirming a magmatic origin for both lithologies. In situ analysis of the most U–Pb concordant domains yields equivalent ²⁰⁷Pb/²⁰⁶Pb ages (upper intercept, U–Pb concordia) of 2559±6 and 2563±6 Ma (both ±2σ) for the LEG and BFG, respectively, which constrains a late Neoarchean age for sequential pulses of magmatism in the NBH. Unzoned (in BSE) patches of 2560 Ma zircon commonly truncate coeval zonation in the same crystals with no change in Th/U ratio, suggesting that deuteric, fluid-assisted recrystallization accompanied post-magmatic cooling. A xenocrystic core of magmatic zircon observed in one LEG zircon yields a concordant age of 2894±6 Ma (±2σ). This xenocryst represents the oldest crustal material reported thus far in the Black Hills. Whether this older zircon originated as unmelted residue of 2900 Ma crust that potentially underlies the Black Hills or as detritus derived from 2900 Ma crustal sources in the Wyoming province cannot be discerned. In the southern Black Hills (SBH), the peraluminous granite at Bear Mountain (BMG) of previously unknown age intrudes biotite–plagioclase schist. Zircon crystals from the BMG are highly metamict and altered, but locally preserve small domains suitable for in situ analysis. A U–Pb concordia upper intercept age of 2596±11 Ma (±2σ) obtained for zircon confirms both the late Neoarchean magmatic age of the BMG and a minimum age for the schist it intrudes. Taken together, these data indicate that the Neoarchean basement granitoids were emplaced at 2590–2600 Ma (SBH) and 2560 Ma (NBH), most likely in response to subduction associated with plate convergence (final assembly of supercontinent Kenorland?). In contrast, thin rims present on some LEG–BFG zircons exhibit strong U–Pb discordance, high common Pb, and low Th/U ratios—suggesting growth or modification under hydrothermal conditions, as previously suggested for similar zircons from SE Wyoming. The LEG–BFG zircon rims yield a nominal upper intercept date of 1940–2180 Ma, which may represent a composite of multiple rifting events known to have affected the Nemo area between 2480 and 1960 Ma. Together, these observations confirm the existence of a Paleoproterozoic rift margin along the easternmost Wyoming craton. Moreover, the 2480–1960 Ma time frame inferred for rifting in the Black Hills (Nemo area) corresponds closely to a 2450–2100 Ma time frame previously inferred for the fragmentation of supercontinent Kenorland.     

Indicator mineralogy of kimberlite boulders from eskers in the Kirkland Lake and Lake Timiskaming areas, Ontario, Canada

Sixteen kimberlite boulders were collected from three sites on the Munro and Misema River Eskers in the Kirkland Lake kimberlite field and one site on the Sharp Lake esker in the Lake Timiskaming kimberlite field. The boulders were processed for heavy-mineral concentrates from which grains of Mg-ilmenite, chromite, garnet, clinopyroxene and olivine were picked, counted and analyzed by electron microprobe. Based on relative abundances and composition of these mineral phases, the boulders could be assigned to six mineralogically different groups, five for the Kirkland Lake area and one for the Lake Timiskaming area. Their indicator mineral composition and abundances are compared to existing data for known kimberlites in both the Kirkland Lake and Lake Timiskaming areas. Six boulders from the Munro Esker form a compositionally homogeneous group (I) in which the Mg-ilmenite population is very similar to that of the A1 kimberlite, located 7–12 km N (up-ice), directly adjacent to the Munro esker in the Kirkland Lake kimberlite field. U–Pb perovskite ages of three of the group I boulders overlap with that of the A1 kimberlite. Three other boulders recovered from the same localities in the Munro Esker also show some broad similarities in Mg-ilmenite composition and age to the A1 kimberlite. However, they are sufficiently different in mineral abundances and composition from each other and from the A1 kimberlite to assign them to different groups (II–IV). Their sources could be different phases of the same kimberlite or—more likely—three different, hitherto unknown kimberlites up-ice of the sample localities along the Munro Esker in the Kirkland Lake kimberlite field. A single boulder from the Misema River esker, Kirkland Lake, has mineral compositions that do not match any of the known kimberlites from the Kirkland Lake field. This suggests another unknown kimberlite exists in the area up-ice of the Larder Lake pit along the Misema River esker. Six boulders from the Sharp Lake esker, within the Lake Timiskaming field, form a homogeneous group with distinct mineral compositions unmatched by any of the known kimberlites in the Lake Timiskaming field. U–Pb perovskite age determinations on two of these boulders support this notion. These boulders are likely derived from an unknown kimberlite source up-ice from the Seed kimberlite, 4 km NW of the Sharp Lake pit, since indicator minerals with identical compositions to those of the Sharp Lake boulders have been found in till samples collected down-ice from Seed. Based on abundance and composition of indicator minerals, most importantly Mg-ilmenite, and supported by U–Pb age dating of perovskite, we conclude that the sources of 10 of the 16 boulders must be several hitherto unknown kimberlite bodies in the Kirkland Lake and Lake Timiskaming kimberlite fields.     

Refining the pre-industrial atmospheric Pb isotope evolution curve in Europe using an 8000 year old peat core from NW Spain

Pb pollution has existed for several millennia and remains relevant today. By using peat cores as environmental archives it is possible to reconstruct this long history on a regional scale. This is a significant contribution to the findings from ice core records, the only other archive recording purely atmospheric additions. Without information that allows linking and comparison between sites regionally, within Europe and elsewhere, our ability to make coherent global models of the natural Pb cycle, and anthropogenic forcing of this cycle, is limited. In this respect, the characteristics of the Pb pre-pollution aerosol (PPA) are important to define globally. We characterize for the first time a PPA in Southern Europe with [Pb] = 0.78 ± 0.86 μg g^− 1, net Pb accumulation rates of 0.032 ± 0.030 mg m^− 2 y^− 1 and a ²⁰⁶Pb / ²⁰⁷Pb signature of 1.25470 ± 0.02575. This PPA Pb isotope signature is more radiogenic than that found thus far in Western and Northern Europe. Spain is a historically important mining site. Using three-isotope plots and a pool of potential Pb isotope signatures, a detailed source appointment of both natural and anthropogenic Pb sources was made. We found evidence of Saharan aridification and its termination ∼4400 BP and/or agricultural signals and strong local control (from rock and soil) of the Pb PPA. Human impact is first recorded at 3210 BP but does not exceed 50% of deposited Pb until 3005 BP. Mines in SE Spain dominate early Pb pollution history at this site. During the rise of Roman rule, contributions come from mines in N, NW and SW Spain with no strong indication of other European mining activities. In Medieval and Industrial times local contributions to the peat bog are reduced.