帕米尔东北缘穷阿木太克岩体年代学、地球化学特征及地质意义

分布于帕米尔东北缘羌塘地块上的穷阿木太克岩体,与班公湖怒江洋的闭合有着密切关系。岩体主要由英云闪长岩、花岗闪长岩和二长花岗岩组成。LA-ICP-MS锆石U-Pb测年结果显示,穷阿木太克岩体的形成年龄为(107.0±1.2) Ma(MSWD=0.55),属于早白垩世晚期。地球化学结果显示,主量元素具有富Ca、富K、富碱等特点,岩石Al含量较高,为弱过铝质花岗岩系列,具典型的钙碱性特征。稀土元素具有轻稀土富集、重稀土亏损的右倾型特征,并显示弱的负铕异常。微量元素表现出大离子亲石元素Rb、Th、U、K高度富集和高场强元素Nb、Ta、Ti、Hf强烈亏损。岩石在成因上可能是地壳下部基性岩石经熔融或部分熔融作用形成的。结合本区所处的构造环境,早白垩世晚期穷阿木太克岩体可能形成于羌塘地块与冈底斯地块之间同碰撞(挤压环境)向碰撞后(伸展环境)的转化阶段,为后造山花岗岩类,岩石系列从早到晚由中钾钙碱性系列向钾玄岩系列演化。     

A synthesis of iron deposits in the eastern Tianshan,NW China

The northern Xinjiang region is one of the most significant iron metallogenic provinces in China.Iron deposits are found mainly within three regions:the Altay,western Tianshan,and eastern Tianshan orogenic belts.Previous studies have elaborated on the genesis of Fe deposits in the Altay orogenic belt and western Tianshan.However,the geological characteristics and mineralization history of iron deposits in the eastern Tianshan are still poorly understood.In this paper I describe the geological characteristics of iron deposits in the eastern Tianshan,and discuss their genetic types as well as metallogenic-tectonic settings,Iron deposits are preferentially distributed in central and southern parts of the eastern Tianshan.The known iron deposits in the eastern Tianshan show characteristics of magmatic Fe-Ti-V(e.g.,Weiya and Niumaoquan),sedimentary-metamorphic type(e.g.,Tianhu),and iron skarn(e.g.,Hongyuntan).In addition to the abovementioned iron deposits,many iron deposits in the eastern Tianshan are hosted in submarine volcanic rocks with well-developed skarn mineral assemblages.Their geological characteristics and magnetite compositions suggest that they may belong to distal skarns.SIMS zircon U-Pb analyses suggest that the Fe-Ti oxide ores from Niumaoquan and Weiya deposits were formed at 307.7±1.3 Ma and 242.7±1.9 Ma,respectively.Combined with available isotopic age data,the timing of Fe mineralization in the eastern Tianshan can be divided into four broad intervals:Early Ordovician-Early Silurian(476-438 Ma),Carboniferous(335-303 Ma),Early Permian(295-282 Ma),and Triassic(ca.243 Ma).Each of these episodes corresponds to a period of subduction,post-collision,and intraplate tectonics during the Paleozoic and Mesozoic time.     

新疆白干湖钨锡矿田东北部花岗岩锆石SIMS U-Pb 年龄、地球化学特征及构造意义

白干湖矿田东北部出露钾长花岗岩和二长花岗岩,具有相近的成岩年龄和相似的地球化学特征,表明为同源演化的复式岩体。利用SIMS方法获得二者锆石U-Pb谐和年龄是422±3Ma和421±3.7Ma,为晚志留世。岩石主量元素地球化学特征二者表现为弱过铝质(A/CNK为0.99～1.02)或准铝质(A/CNK为0.92～0.94)、高钾(K2O/Na2O分别为1.08～1.31和1.03～1.22)、高碱((Na2O+K2O)分别为8.59%～9.38%和9.54%～9.69%)、钙碱性或弱碱性(δ分别为2.39～3.17和4.02～4.22)、Fe#(TFeO/MgO分别为9.58～12.26和8.94～9.96)高。稀土元素总体含量(分别为228×10-6～448×10-6和271×10-6～392×10-6)较高,微量元素亏损Ba、Nb、Sr、Ti、P和富集La、Ce、Zr、Sm,总体显示A型花岗岩的特征。R1-R2图解显示岩体构造背景落入晚造山区域。Sr-Yb图解显示岩体落入低Sr高Yb的区域,暗示拉伸的地壳减薄的环境。Pearce图解显示构造环境为板内为主。综合区域背景资料,认为该岩体形成于加里东造山旋回的后碰撞阶段。     

胶东招掖地区滦家河花岗岩锆石U-Pb年代学、岩石地球化学及其地质意义

滦家河花岗岩体是胶东金矿区内的重要岩体,其岩性主要为中粗粒黑云母二长花岗岩。锆石LA—ICP—MS U—Pb年代学研究表明,滦家河花岗岩形成于149±2 Ma,属晚侏罗世。滦家河花岗岩Si O2的含量为64.58%~72.05%,相对较高;A/CNK值为0.98~1.22。微量元素特征显示,滦家河花岗岩富集大离子亲石元素(LILE)Rb、Ba、K,强烈亏损高场强元素(HFSE)Nb、Ta、Ti、P;稀土元素特征显示轻稀土强烈富集,重稀土极度亏损,轻微正铕异常。岩石的Nb/La和Nd/Th比值显示壳源花岗岩的特征,Rb/Sr比值暗示可能有部分幔源物质混入。结合区域地质分析认为,侏罗纪开始,太平洋板块向欧亚大陆的俯冲引发大规模幔源岩浆底侵,导致地壳物质部分熔融形成滦家河花岗岩。     

Contrasting water–rock interaction behaviors of antimony and arsenic in contaminated rivers around an antimony mine,Hunan Province,China

Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals.     

Pb and other ore metals in modern seafloor tectonic environments: Evidence from melt inclusions

Many modern seafloor tectonic environments are host to hydrothermal systems and associated polymetallic sulfide deposits. Metal transport and precipitation are controlled by magmatic processes such as pre-eruptive degassing and the hydrothermal cycle. The original availability of Pb and other ore metals in a given setting is dependent on concentrations in the original magmatic source or additional enrichment processes. We have examined the Pb budget of melt inclusions from nine modern seafloor settings representing back-arcs, mid-ocean ridges and seamounts. Melt inclusions provide information on the characteristics of parental magmas, including insights into metal budgets. Trace element data in melt inclusions hosted in plagioclase, olivine and pyroxene were obtained by laser-ablation inductively-coupled mass-spectrometry.Results from back-arcs emphasize the impact of slab-subduction and dehydration processes on the chemical characteristics of generated magmas. Volatile- and fluid-mobile element-rich melt inclusions at Manus basin and Okinawa trough reflect a robust contribution of elements from the subducting slab as evidenced by relatively low Ce/Pb ratios. At Bransfield strait, on the other hand, melt inclusions are volatile poor, and fluid-mobile element ratios are similar to mid-ocean ridge values indicating little or no contribution from the slab. High Cu concentrations at Manus basin and Okinawa trough can be explained by fluxing of ferric iron from the subducting slab benefiting the production of sulfate over sulfide.Metal budgets for seamounts located on and nearby the axis of mid-ocean ridge segments appear to be independent of any input of mantle plume material. Results from the southern Explorer ridge (strong lower mantle influence, transitional- and enriched-MORBs), Pito and Axial seamounts (moderate lower mantle influence, transitional-MORBs) and a Foundation near-ridge seamount (little to no mantle influence, normal-MORB) show that, despite similar tectonic environments and varying contributions of mantle plume material, Cu, Zn and Pb values do not vary significantly between the enriched and non-enriched magma components of a given setting.     

Provenance of Holocene beach sand in the Western Iberian margin: the use of the Kolmogorov–Smirnov test for the deciphering of sediment recycling in a modern coastal system

Detrital zircons from Holocene beach sand and igneous zircons from the Cretaceous syenite forming Cape Sines (Western Iberian margin) were dated using laser ablation – inductively coupled plasma – mass spectrometry. The U–Pb ages obtained were used for comparison with previous radiometric data from Carboniferous greywacke, Pliocene–Pleistocene sand and Cretaceous syenite forming the sea cliff at Cape Sines and the contiguous coast. New U–Pb dating of igneous morphologically simple and complex zircons from the syenite of the Sines pluton suggests that the history of zircon crystallization was more extensive (ca 87 to 74 Ma), in contrast to the findings of previous geochronology studies (ca 76 to 74 Ma). The U–Pb ages obtained in Holocene sand revealed a wide interval, ranging from the Cretaceous to the Archean, with predominance of Cretaceous (37%), Palaeozoic (35%) and Neoproterozoic (19%) detrital‐zircon ages. The paucity of round to sub‐rounded grains seems to indicate a short transportation history for most of the Cretaceous zircons (ca 95 to 73 Ma) which are more abundant in the beach sand that was sampled south of Cape Sines. Comparative analysis using the Kolmogorov–Smirnov statistical method, analysing sub‐populations separately, suggests that the zircon populations of the Carboniferous and Cretaceous rocks forming the sea cliff were reproduced faithfully in Quaternary sand, indicating sediment recycling. The similarity of the pre‐Cretaceous ages (>ca 280 Ma) of detrital zircons found in Holocene sand, as compared with Carboniferous greywacke and Pliocene–Pleistocene sand, provides support for the hypothesis that detritus was reworked into the beach from older sedimentary rocks exposed along the sea cliff. The largest percentage of Cretaceous zircons (<ca 95 Ma) found in Holocene sand, as compared with Pliocene–Pleistocene sand (secondary recycled source), suggests that the Sines pluton was the one of the primary sources that became progressively more exposed to erosion during Quaternary uplift. This work highlights the application of the Kolmogorov–Smirnov method in comparison of zircon age populations used to identify provenance and sediment recycling in modern and ancient detrital sedimentary sequences.     

Accretion and exhumation at a Variscan active margin, recorded in the Saxothuringian flysch

The Saxothuringian flysch basin, on the north flank of the Central European Variscides, was fed and eventually overthrust by the northwestern, active margin of the Tepla-Barrandian terrane. Clast spectra, mineral composition and isotopic ages of detrital mica and zircon have been analyzed in order to constrain accretion and exhumation of rocks in the orogenic wedge. The earliest clastic sediments preserved are of early Famennian age (ca. 370?Ma). They are exposed immediately to the NW of the suture, and belong to the par-autochthon of the foreland. Besides ultramafic (?ophiolite) material, these rocks contain clasts derived from Early Paleozoic continental slope sediments, originally deposited at the NW margin of the Saxothuringian basin. These findings, together with the paleogeographic position of the Famennian clastics debris on the northwestern passive margin, indicate that the Saxothuringian narrow ocean had been closed by that time. Microprobe analyses of detrital hornblendes suggest derivation from the “Randamphibolit” unit, now present in the middle part of the Saxothuringian allochthon (Münchberg nappes). Detrital zircons of metamorphic rocks formed a little earlier (ca. 380?Ma) indicate rapid recycling at the tectonic front. The middle part of the flysch sequence (ca. early to middle Viséan), both in the par-autochthon and in the allochthon, contains abundant clasts of Paleozoic rocks derived from the northwestern slope and rise, together with debris of Cadomian basement, 500-Ma granitoids and 380?Ma (early Variscan) crystalline rocks. All of these source rocks were still available in the youngest part of the flysch (c. middle to late Viséan), but some clasts record, in addition, accretion of the northwestern shelf. Our findings permit deduction of minimum rates of tectonic shortening well in excess of 10–30?mm per year, and rates of exhumation of ca. 3?mm/a, and possibly more.     

扬子陆块西缘中元古代晚期元谋花岗岩的时代、成因及构造意义

扬子陆块西缘晚中元古代地质演化史一直存在较大争议,本文选择以扬子西缘元谋杂岩中一套二长花岗岩为研究对象,开展岩相学、锆石U-Pb年代学、全岩地球化学等综合研究,为认识和理解扬子西缘晚中元古代地质演化提供支撑。两件元谋二长花岗岩样品的LA-ICP-MS锆石U-Pb年龄分别为1086±10 Ma（MSWD=1.4,n=50）和1099±10 Ma（MSWD=1.8,n=58）。所有样品具有高硅（SiO₂为69.44%~73.98%）、富碱（Na₂O+K₂O为6.11%~7.72%）、贫钙（CaO为0.39%~1.46%）、贫镁（MgO为0.52%~0.76%）、低钛（TiO₂为0.30%~0.59%）的特点,同时表现出强过铝质（A/CNK=1.19~1.35）及中钾钙碱性–钾玄岩系列特征。它们具有高的稀土元素总量（∑REE=211.60×10⁻⁶~349.01×10⁻⁶）,呈现轻稀土元素富集和重稀土元素亏损（（La/Yb）_N=4.32~7.36）;富集Rb、U、Th等大离子亲石元素和Zr、Th、Hf等,亏损Nb、Ta、Ba等元素,并具有明显的负Eu异常（δEu=0.46~0.59）,锆石饱和温度介于827~912℃之间,展示了A型花岗岩的属性。这些二长花岗岩可能是通过中上地壳的中酸性火成岩的部分熔融形成,结合前人的研究成果,它们最可能形成于弧后的伸展环境,综合扬子陆块周缘晚中元古代的岩浆记录,元谋杂岩中1.09 Ga二长花岗岩的形成应与扬子陆块开始参与Rodinia超大陆聚合有关。

     

粤北佛冈岩体中粒斑状花岗岩地球化学、年代学及地质意义

佛冈岩体是南岭地区最大的复式岩基,主体岩性为中粒斑状黑云母二长花岗岩,近期在佛冈岩体北缘新发现了大型离子吸附型稀土矿床。对佛冈花岗岩岩石样品进行了LA-ICP-MS锆石U-Pb定年,得出结晶年龄分别为160.5±2.9Ma、161.9±2.6Ma和164.5±2.4Ma,表明岩体形成于中晚侏罗世。岩体具有高硅、富碱富铝的特征(K2O/Na2O=1.48~2.17,A/CNK=1.05~1.27),属钙碱性过铝质钾玄质花岗岩;富集Rb、Th、U、K、Pb、Nd、Zr和Hf等元素,亏损Ba、Nb、Ta、La、Ce、Sr、P和Ti等元素,具明显的负Eu异常(δEu=0.17~0.41)。初步研究结果表明,佛冈岩体主体由上地壳砂-泥质岩在高温条件下部分熔融而成,是陆壳改造型(即S型)花岗岩,形成于古太平洋板块向欧亚板块俯冲的构造背景。