江南造山带东段旌德岩体锆石LA-ICPMS年龄和Nd-Sr-Hf同位素地球化学

提要：旌德花岗质杂岩体位于安徽南部,由花岗闪长岩和二长花岗岩组成。本研究得到岩体中锆石U-Pb年龄为(141.0±1.0) Ma,认为该年龄代表岩体的侵位年龄。岩体全岩主量元素特征显示出中偏酸性 (SiO2＝66.01%~70.87%),富Al (Al2O3＝14.91%~16.24%),富碱 (alk = 6.64%~8.01%),K2O/Na2O变化范围在0.78~1.04,镁、铁含量较低,MgO：0.68%~1.06%,TFe2O3 (2.0%~3.34%),以及低磷 (P2O5 =0.10%~0.14%)的特点;微量元素主要富集Sr (189×10-6~452×10-6),贫Nb、Ta、P、Ti、Y、Yb,高Sr/Y比值 (23~66)和 (La/Yb)N (13~58),Eu有轻微的负异常到弱的正异常 (δEu＝0.81~1.18)。旌德岩体的地球化学特征与中国东部中生代埃达克质岩相似。ISr＝0.7096~0.7101, εNd(t)＝-6.28~-7.32,εHf(t)值变化于-6.5~-1.1,两阶段模式年龄 tDM2=1.4~1.5 Ga。较年轻的Nd同位素模式年龄、较高的εNd(t)值和εHf(t)值,以及岩体中发育有岩浆混合成因的暗色包体,指示源区可能有地幔物质的贡献。幔源岩浆底侵使下地壳发生部分熔融,并发生了岩浆混合作用,形成了旌德岩体。     

碧玺充填探讨

采用宝石显微镜、红外光谱仪和荧光能谱仪对广州市荔湾广场的105件碧玺样品进行了测试分析。结果表明,绝大多数碧玺样品都存在充填处理的现象,其内部充填物为黄色与白色絮状物,并具有蓝色闪光、流动构造等特征;其中,充填现象不明显的碧玺样品在红外吸收光谱仪和荧光能谱仪下也可检测到有机物及Pb。     

Carbon and oxygen isotopic constraints on paleoclimate and paleoelevation of the southwestern Qaidam basin,northern Tibetan Plateau

We investigate the growth of the northern Tibetan Plateau and associated climate change by applying oxygen and carbon isotopic compositions in Cenozoic strata in the southwestern Qaidam basin. The X-ray diffraction and isotopic studies reveal that the carbonate minerals are mainly authigenic and they do not preserve any evidence for detrital carbonate and diagenesis. The isotope data show large fluctuations in the δ¹⁸O and δ¹³C values in the middle–late Eocene, indicating relatively warm and seasonal dry climate. The positive correlation of the δ¹⁸O and δ¹³C values in the Oligocene and the positive shift of the δ¹³C values from the Eocene to Oligocene suggest that the climate changed to arid in the Oligocene. However, the δ¹⁸O values show negative shift, which is closely related to the global cooling event. During the Miocene, the δ¹³C values vary between –2‰ and –4‰, whereas the δ¹⁸O values show continuous negative shift. The mean δ¹⁸O values decrease from –8.5‰ in the early Miocene to –10.0‰ in the late Miocene. The stable isotope-based paleoaltimetry results suggest that the elevation of the southwestern Qaidam basin was approximately 1500 m in the middle–late Eocene and Oligocene. Subsequently, during Miocene the crustal uplift process started and the elevation reached approximately 2000 m in the early Miocene and 2500 m in the late Miocene, which suggests large-scale growth of the northern Tibet Plateau during the Miocene.     

吉林南部三棵榆树组火山岩的成因:锆石U-Pb年龄和Hf同位素证据

锆石LA-ICP-MS U-Pb测年结果显示,吉林南部地区三棵榆树组粗面岩形成于118 Ma的早白垩世晚期。岩石地球化学研究表明,三棵榆树组粗面岩的SiO2含量为65.11%～65.61%,富碱(K2O=6.29%～7.28%,Na2O=3.71%～4.21%),属于钾玄岩系列,弱过铝质(A/CNK=1.05～1.12),含镁指数Mg#=9～16;稀土元素总量较高(∑REE=317.72×10-6～371.30×10-6),轻重稀土分馏明显(LaN/YbN=19.50～22.80),Eu负异常较弱(δEu=0.75～0.81);微量元素富集Rb、Th、Zr、K,明显亏损Nb、Ta和Sr等,显示典型的大陆地壳特征。锆石的176Hf/177Hf比值介于0.282 206～0.282 309之间,εHf(t)值介于-13.32～-16.97之间,Hf模式年龄(TDM2)介于2.0～2.6 Ga之间,平均为2.2 Ga。上述特征表明,吉林南部地区早白垩世粗面岩主要来源于古元古代地壳物质的部分熔融,形成于伸展构造环境。     

High spatial-resolution monitoring to investigate nitrate export and its drivers in a mesoscale river catchment along an anthropogenic land-cover gradient

Nitrate monitoring is commonly conducted with low-spatial resolution, only at the outlet or at a small number of selected locations. As a result, the information about spatial variations in nitrate export and its drivers is scarce. In this study, we present results of high-spatial resolution monitoring conducted between 2012 and 2017 in 65 sub-catchments in an Alpine mesoscale river catchment characterized by a land-use gradient. We combined stable isotope techniques with Bayesian mixing models and geostatistical methods to investigate nitrate export and its main drivers, namely, microbial N turnover processes, land use and hydrological conditions. In the investigated sub-catchments, mean values of NO₃⁻ concentrations and its isotope signatures (δ¹⁵N_NO3 and δ¹⁸O_NO3) varied from 2.6 to 26.7 mg L⁻¹, from −1.3‰ to 13.1‰, and from −0.4‰ to 10.1‰, respectively. In this study, land use was an important driver for nitrate export. Very strong and strong positive correlations were found between percentages of agricultural land cover and δ¹⁵N_NO3, and NO₃⁻ concentration, respectively. Mean proportional contributions of NO₃⁻ sources varied spatially and seasonally, and followed land-use patterns. The mean contribution of manure and sewage was much higher in the catchments characterized by a high percentage of agricultural and urban land cover comparing to forested sub-catchments. Specific NO₃⁻ loads were strongly correlated with specific discharge and moderately correlated with NO₃⁻ concentrations. The nitrate isotope and concentration analysis results suggest that nitrate from external sources is stored and accumulated in soil storage pools. Nitrification of reduced nitrogen species in those pools plays the most important role for the N-dynamics in the Erlauf river catchment. Consequently, nitrification of reduced N sources was the main nitrate source except for a number of sub-catchments dominated by agricultural land use. In the Erlauf catchment, denitrification plays only a minor role in controlling NO₃⁻ export on a regional scale.     

陕西小秦岭地区太华群的锆石U-Pb年龄和 Hf同位素组成

本文对陕西华山岩体南侧一个太华群黑云斜长片麻岩进行了地球化学、锆石U-Pb年龄和Hf同位素分析.地球化学分析显示其原岩为中酸性钙碱性花岗质岩石,稀土含量较低( ∑REE =83.13×10-6),但富集Pb和LILE元素(如Rb、Ba).锆石的176Hf/177Hf比值变化于0.281258～0.281404,具明显负的εHf(t)值(-6.86～- 11.23).锆石的Hf同位素模式年龄(2.96 ～3.24Ga)表明原岩是由中太古代地壳演化而来.对比显示小秦岭太华群黑云斜长片麻岩与鲁山地区的太华群具有相似的中太古代地壳源区,但它们的形成时代可能不同.锆石内部结构、Th/U比值以及定年结果显示小秦岭地区的太华群在～1.91Ga经历了一期重要的变质热事件,该事件与Columbia超大陆拼合时的全球性碰撞造山事件相关联.小秦岭太华群为华北克拉通块体南缘的地质单元,但各地区太华群在原岩组成、形成时代和变质时代上具有不同的特征,太华群应是一个杂岩体,至少可以解体为新太古代和古元古代两部分.     

Tracing infiltration and recharge using stable isotope in Taihang Mt., North China

The groundwater in headwater region is an important recharge source for the adjacent mountain-front plain. In order to reveal the relationship among precipitation, soil water and groundwater, from June to September in 2004, stable isotopes (deuterium and oxygen-18) in precipitation and soil waters at the depths of 10, 20, 30, 50, 70, 90, and 110 cm were analyzed at two sites covered by black locust (Robinia Pseudoacia L.) (Site A) and grass predominated by Themeda triandra (T. japonica (Willd.) Tanaka) and Bothriochloa ischaemum (B. ischaemum (L.) Keng) (Site B) in an experimental catchment at Taihang Mt., North China, respectively. The δ¹⁸O of precipitation in daily rain events shows large variations (−13.3 to −4.3‰) with a mean of 8.1‰. The δ¹⁸O and δ D of soil waters along profiles in two sites suggest that the influence of canopy cover was just up to 10 cm in top soil water. The soil water moved over the zero flux plane at 70 cm in-depth is expected to escape the evaporative effect at the end of September in both sites. The results show that the stable isotope, instead of tritium as tradition, can be used to trace the soil water behaviors based on the movement of isotopic peak along the vertical profiles in this semi-arid and semi-humid mountainous region. The infiltration depths of soil water in Taihang Mt. are 12 and 10 mm/day from June to September in 2004 in Site A and Site B, respectively. Tracing by stable isotope, recharge fluxes of soil water to local groundwater are of 3.8 and 3.2 mm/day in Site A and Site B, respectively. The results provide desirable information for assessment of local groundwater resources. An erratum to this article can be found at     

Carbon-isotope records of the Early Jurassic (Toarcian) oceanic anoxic event from the Valdorbia (Umbria–Marche Apennines) and Monte Mangart (Julian Alps) sections: palaeoceanographic and stratigraphic implications

The Toarcian oceanic anoxic event ( ca 183 Ma) coincides with a global perturbation marked by enhanced organic carbon burial and a general decrease in calcium carbonate production, probably triggered by changes in the composition of marine plankton and elevated carbon dioxide levels in the atmosphere. This study is based on high-resolution sampling of two stratigraphic successions, located in Valdorbia (Umbria–Marche Apennines) and Monte Mangart (Julian Alps), Italy, which represent expressions of the Toarcian oceanic anoxic event in deep-water pelagic sediments. These successions are characterized by the occurrence of black shales showing relatively low total organic carbon concentrations (compared with coeval strata in Northern Europe), generally < 2%, and low hydrogen indices. On this basis, they are similar to other Toarcian black shales described from the Tethyan region. The positive and negative carbon-isotope records from the two localities permit a high-resolution correlation such that ammonite biostratigraphy information from Valdorbia can be transferred to those parts of the Monte Mangart section that lack these fossils. Spectral analyses of δ¹³C_org values and of CaCO₃ percentages from the sedimentary records of both the Valdorbia and Monte Mangart sections reveal a strong cyclic pattern, best interpreted as an eccentricity signal which hence implies a duration of ca 500 kyr for the negative carbon-isotope excursion. Based on the carbon-isotope curves obtained, the high-resolution correlation between the Italian successions and a section in Yorkshire (Northern Europe) confirms the supposition that the apparent mismatch between the dating of the Toarcian oceanic anoxic event in the Boreal and Tethyan realms is an artefact of biostratigraphy.     

Submarine groundwater discharge and benthic biogeochemical zonation in the Huanghe River Estuary

Submarine groundwater discharge(SGD) has received increasing attention by studies on coastal areas; however,its effects on biogeochemical zonation have not been investigated to date. The Huanghe River Estuary(HRE) is a world class river estuary with high turbidity, and heavy human regulation. This study investigated how SGD is related to the benthic biogeochemistry of the HRE. Based on the distribution of several parameters(e.g., salinity,temperature, dissolved oxygen(DO) levels, p H, radium iso...     

羌塘盆地热觉茶卡-藏夏河地区泉水水化学特征及其地质意义

泉水的水化学特征可以反映氧化-还原环境和水动力条件,近年来被广泛地用于石油、天然气以及天然气水合物的找矿工作中。本文对羌塘盆地热觉茶卡—藏夏河地区37处泉水和13件地表水进行了水化学特征、水溶性烃类气体特征和水中氢氧同位素特征分析,结果表明,羌塘盆地热觉茶卡—藏夏河地区的水型主要为Na₂SO₄型和MgCl₂型,其次为NaHCO₃型和CaCl₂型。矿化度普遍较高,说明该区具有较好的保存条件。铵根离子的平均含量为0.895μg/g,在藏夏河地区高达7.381μg/g,表明在藏夏河东部地区有机质相对较为丰富,这与区域上发育的富有机质页岩结果一致。氢氧同位素结果显示,该区水体的氢氧同位素落在了大气降水线附近,表明水体的来源主要受大气降水的补给。另外,采集的9个泉水样品中均检测出一定含量的水溶甲烷,在白云湖地区的甲烷含量相对较高,显示出较好的油气潜力。综合研究表明,藏夏河东和白云湖地区具有良好的油气烃源岩条件,保存条件较好,显示出良好的油气和天然气水合物资源前景。