甘肃桦树沟铁铜矿床地球化学及成因

甘肃桦树为铁铜矿床地质、同位素地球化学、包裹体地球化学、同位素年代学研究表明，该矿床形成于震旦纪裂陷海盆环境，矿床成因属典型的热水沉积成矿。     

Rb–Sr Dating of Gold‐Bearing Pyrite in the Jinchang Porphyry Cu–Au Deposit,Heilongjiang Province,NE China

The Jinchang Cu–Au deposit in Heilongjiang Province, NE China, is located in the easternmost part of the Central Asian Orogenic Belt. Rb–Sr analyses of auriferous pyrite from the deposit yielded an isochron age of 113.7 ±2.5 Ma, consistent with previously reported Re–Os ages. Both sets of ages represent the timing of Cu–Au mineralization because (i) the pyrite was separated from quartz–sulfide veins of the mineralization stage in granite porphyry; (ii) fluid inclusions have relatively high Rb, Sr, and Os content, allowing precise measurement; (iii) there are no other mineral inclusions or secondary fluids in pyrite to disturb the Rb–Sr or Re–Os decay systems; and (iv) the closure temperatures of the two decay systems are ≥500°C (compared with the homogenization temperatures of fluid inclusions of 230–510°C). It is proposed that ore‐forming components were derived from mantle–crust mixing, with ore‐forming fluids being mainly exsolved from magmas with minor amounts of meteoric water. The age of mineralization at Jinchang and in the adjacent regions, combined with the tectonic evolution of the northeast China epicontinental region, indicates that the formation of the Jinchang porphyry Cu–Au deposit was associated with Early Cretaceous subduction of the paleo‐Pacific Plate.     

滇东北富乐铅锌矿床微量元素和S-Pb同位素地球化学研究

富乐铅锌矿床位于我国西南川滇黔铅锌多金属矿集区的东南部,矿体呈层状、透镜状赋存于中二叠统阳新组白云岩中,受层间破碎带控制。该矿床铅锌金属资源量超过50万吨,铅锌平均品位大于15. 6%。碳酸盐岩围岩溶蚀、重结晶和热液角砾岩化是该矿床普遍发育的热液蚀变类型,是酸性热液流体与碳酸盐岩围岩化学反应的结果。热液白云岩在成矿期前、成矿期和成矿期后都可形成,晚期形成的热液白云岩往往会部分替换早期形成的白云石,热液沿裂隙充填过程中,会引起围岩重结晶作用,形成明显的蚀变晕。矿石中主要硫化物包括闪锌矿、方铅矿和黄铁矿,伴有少量的黄铜矿和黝铜矿,白云石和方解石是主要脉石矿物。矿石的主要构造有致密块状、浸染状、脉状和角砾状。本次工作在富乐矿床厘定出三种颜色闪锌矿,即黑色、红色和棕色。LA-ICPMS研究表明,三种颜色闪锌矿中Cd、Cu、Ga和Ge等元素不同程度富集,而Fe、Mn和In等元素有不同程度亏损。在LA-ICPMS时间分辨率剖面图中,上述元素均呈水平直线出现,与Zn和S等主要元素的含量曲线平行,表明它们可能以类质同象形式赋存于闪锌矿中。而Sb、Pb和Ag等元素在LA-ICPMS时间分辨率剖面图中,呈较大波动趋势,暗示这些元素可能以微细粒包体存在,这与显微观测发现闪锌矿中有方铅矿微小矿物颗粒相吻合。本研究初步认为富乐闪锌矿颜色可能是Ni、Cu、Tl、Ga、Hg、Fe和Cr等多种元素共同引起的,其中Ni、Cu和Ga使闪锌矿呈紫色,Cu使闪锌矿呈红色,Ga使闪锌矿呈黄色。三种颜色闪锌矿样品的硫同位素组成变化较小,其δ~(34)S值变化范围为12. 2‰～14. 6‰,具有富集34S特征,与二叠系海相硫酸盐的δ~(34)S值相似,暗示热化学硫酸盐还原作用(TSR)可能是该矿床HS~-或S~(2-)离子形成的主要机制。不同颜色闪锌矿的~(207)Pb/~(204)Pb、~(206)Pb/~(204)Pb和~(208)Pb/~(204)Pb值分别为15. 604～15. 737、18. 570～18. 732和38. 532～38. 667。大部分闪锌矿的Pb同位素组成与基底昆阳群浅变质岩石的Pb同位素组成相似,少量闪锌矿具有与峨眉山玄武岩和赋矿沉积岩相似的Pb同位素组成,表明富乐铅锌矿床的成矿金属主要来源于基底岩石,并可能受到沉积岩和玄武岩的影响。综上所述,本文认为富乐铅锌矿床是一个形成于挤压背景下、受层间构造控制的高品位、富分散元素后生碳酸盐岩容矿型铅锌矿床。     

大兴安岭地区古利库金(银)矿床成因探讨

古利库金(银)矿床的形成与早白垩世中晚期火山喷发活动及其所形成的火山穹隆构造有关,矿体定位于火山活动波及范围内,平均成矿温度220℃,平均成矿压力135×105Pa,成矿深度约500～600m,属冰长石-绢云母型浅成低温热液矿床,与国内外同类型矿床具有可比性.     

安徽铜陵胡村南铜钼矿床流体成矿过程

胡村南铜钼矿床是在安徽铜陵铜(金)矿集区中发现的第一个矽卡岩-斑岩复合型铜钼矿床,在长江中下游成矿带具有特殊性和典型性。文章对该矿床进行了矿床地质和流体包裹体研究,旨在查明该矿床的流体成矿过程。胡村南铜钼矿床流体成矿过程可以划分为高温气成热液期、中高温热液期和低温热液期3个成矿期。高温气成热液期发育钾长石化和矽卡岩化,中高温热液期发育绿泥石化、绿帘石化和绢云母化,而低温热液期主要发育碳酸盐化。其中,中高温热液期为主要矿化期,形成辉钼矿和黄铜矿等多种硫化物网脉。高温气成热液期矿物中发育富液相和含子晶多相包裹体,中高温热液期矿物中也主要发育富液相包裹体和含子晶多相包裹体,但可见少量的富气相包裹体,低温热液期矿物中只发育富液相包裹体。从高温气成热液期经中高温热液期到低温热液期,成矿流体均一温度从435℃以上,经203~458℃,降低到156~276℃;盐度w(NaCleq)从14.0%~64.9%,经4.6%~47.5%,降低到1.0%~15.5%。成矿流体在其演化过程中发生过不混溶作用和沸腾作用。不混溶作用发生在气成热液期,使成矿流体中的成矿元素大量富集。沸腾作用发生在中高温热液期,导致成矿流体中的成矿元素卸载而沉淀出大量金属硫化物。     

西天山阿吾拉勒成矿带群吉A型花岗岩成因、地质意义及成矿潜力评价

群吉钠长斑岩具有富Si O2(65.3%~76.9%)、Na_2O+K_2O(6.02%~9.66%)、FeOT/Mg O(6.01~21.4),中等的A/CNK(0.90~1.04),低Al2O3(9.82%~15.64%)、Ca O(0.47%~1.84%)、MgO(0.13%~0.45%)的主量元素特征,同时富集Th、U、Ta、Zr、Hf等HFSE,轻稀土富集、重稀土相对平坦分布。高的Zr(468×10~(-6)~707×10~(-6))、Y(20.7×10~(-6)~91.4×10~(-6))、Nb(21.3×10~(-6)~57.7×10~(-6))、Ga(11.2×10~(-6)~19.7×10~(-6))以及Ce(36.7×10~(-6)~98.2×10~(-6))和Zr饱和温度(880℃)特征表明岩体具有A型花岗岩的特征。群吉钠长斑岩的ISr值较低(0.70203~0.70549),εNd(t=303Ma)为正值(+4.1~+5.2),同时全岩Pb同位素落于地幔和下地壳之间的区域,表明形成该岩体的源岩可能为下地壳玄武质岩石。地壳的伸展引起了软流圈地幔底侵,在异常地温梯度下被底侵的玄武质下地壳发生部分熔融,形成该地区晚古生代A型花岗岩岩体。群吉地区A型花岗岩的发现,表明在晚石炭纪西天山阿吾拉勒地区为伸展的构造背景,同时岩石圈的拆沉、下地壳的加厚在晚石炭纪就已发生。群吉钠长斑岩中有局部或全部的铜矿化,该岩体是阿吾拉勒成矿带主要的含矿岩体。钠长斑岩基质中含有自形-半自形的黄铁矿及斑岩中锆石较低的Ce4+/Ce3+(19.5~93.0,平均为39.6),反映了岩浆低氧逸度的成岩条件,这种条件使得S从高价态变为了低价态,有利于成矿。岩浆中Zr的含量与岩浆中的水分含量成反比,H2O的加入也可以使岩浆具有高的氧逸度,因此岩浆中高的Zr含量及低的氧逸度,说明岩浆的源区为"干"体系,H2O的加入很少,而较"干"的体系对形成大型斑岩矿床不利。     

Fluid Inclusion Geochemistry of Metallic Ore Deposits in the South- Central Sector of theDa Hinggan Mountains in China

Physicochemical parameters of mineralization such as temperature, pressure, salinity, density, composition and boiling of ore fluids as well as pH, Eh, fo2 and reducing parameter in theprocess of mineralization of major ore deposits in the study district have been obtained by the authors through systematic observation and determination of characteristics and phase changes of fluid inclusions at different temperatures and analysis of gaseous and liquid phase compositions of the inclusions, thus providing a scientific basis for the division of mineralization-alteration stages, types of mineral deposits and minerogenetic series and the deepening of the knowledge about the ore-forming processes and mechanisms of mineral deposits. It is indicated that the deposits of the same type have similar fluid inclusion geochemical features and physicochemical parameters though they belong to different minerogenetic series, while the compositions of inclusions are not conditioned by deposit types but closely related to     

Reviews on Potash Deposit Metallogenic Conditions

Potash salt is one of key scarce strategic resources. Searching for large scale of potash salt deposit is one big problerm which Chinese academic community faces. Many new discoveries of world potash deposit have been made in recent ten years, which provide abundant practical information and complement the potash metallogenic theory. Through the summary of the potash forming characteristics at home and abroad, the paper studies the potash forming time, tectonic condition, paleogeographic condition, paleoclimate, basin location and salt source. Potash is mainly formed in Permian, Cretaceous, late Jurassic, Cambrian and Devonian. The combination of structure and environment helps to form large scale of evaporation. The climate cycle is related with crust activity. As the other ore deposit, the formation of potash ore also needs dry climate. Potash is the product of final stage in brine evolution, and therefore, it needs persistent drought climate. However, the climate condition is very complicated. Drought climate belt also occurs in humid climate stage, which is controlled by geomorphology. Potash ore can also form in local drought condition. Generally, potash forms in rock salt basin. However, the actual situation is very complicated. Some potash basin is coincided with rock salt basin, some is on one side of rock salt basin; and some are even in the outside of rock salt basin. Salt materials can be from three sources: marine source, terrigenous source and deep source.The paper gives an overview of the research status about the potash deposit forming conditions, which has great guiding significance for searching potash deposit in China. The paper also summarizes the three types of metallogenic models for potash deposit, including epicontinental metallogenic model, abnormal marine evaporation model and rift valley model. The three models are mainly different in material sources, in which the potash in epicontinental metallogenic model is from seawater; the potash in abnormal evaporation model is from nonmarine brine and the potash in rift valley model is mainly from deep material of volcanic activity.     

三维可视化技术在锡铁山矿区信息化建设中的应用研究

运用Vulcan三维可视化软件,对锡铁山铅-锌矿区3062m中段以下05-75线之间的主要矿体进行三维可视化研究,全方位、真实地表达近年来的地质勘探成果,并通过储量计算与找矿预测,为下一步地质勘探工作提供科学依据,为矿区信息化建设提供基础资料。     

黔北铝土矿含矿岩系的沉积时代研究

通过对黔北铝土矿含矿岩系下伏灰岩中丰富的筵类化石和含矿岩系中大量的植物化石的鉴定和研究。结合对黔北地区沉积旋回和古气候的分析,认为黔北铝土矿含矿岩系的下伏灰岩为黄龙组地层。而上覆于黄龙组之上的铝土岩系,其沉积时代应为早二叠世马平组沉积期的晚期,层位相当于Pseudoschwagerina化石带。