Organic Material and Trace Elements of Bituminous Rocks in the Ozankiiy Field, Ankara, Turkey

Bituminous rocks in the Ozankoey （Ankara） field are different from those of the Paleocene- Eocene Mengen and Giineytepe （Bolu） regions in metal enrichment levels. Organic carbon （Corg） content of organic material-rich rocks in the Ozankoey （Ankara） field is 3.66-40.72% wt averaging 14.34%. The dominant organic materials are algae/amorphous accompanied by minor amount of herbaceous material （The dominant kerogen type is Type-I with a limited amount of Type-Ⅱ kerogen.）. The bituminous rocks in the Ozankoey field are enriched in heavy metals such as Ni, Mn, As and Cr. In comparison with the average enrichment values of dements, Ni, Mn, As and Cr in bituminous shales of the Ozankoey field are as about 4.38, 14.93, 10.90 and 5.58 times as average values. The average concentrations of these heavy metals are also as high as 215× 10^-6, 828 × 10^-6, 58.54 × 10^-6, and 148 × 10^-6 respectively. In addition, sorption properties of day and organic materials are also important for metal enrichments in the bituminous shales.     

Organic Material and Trace Elements of Bituminous Rocks in the Ozank(?)y Field,Ankara,Turkey

Bituminous rocks in the Ozank(?)y(Ankara) field are different from those of the Paleocene- Eocene Mengen and Güineytepe(Bolu) regions in metal enrichment levels.Organic carbon(C_(org)) content of organic material-rich rocks in the Ozank(?)y(Ankara) field is 3.66-40.72% wt averaging 14.34%.The dominant organic materials are algae/amorphous accompanied by minor amount of herbaceous material(The dominant kerogen type is Type-Ⅰwith a limited amount of Type-Ⅱkerogen.). The bituminous rocks in the Ozank(?)y field are enriched in heavy metals such as Ni,Mn,As and Cr.In comparison with the average enrichment values of elements,Ni,Mn,As and Cr in bituminous shales of the Ozank(?)y field are as about 4.38,14.93,10.90 and 5.58 times as average values.The average concentrations of these heavy metals are also as high as 215×10~(-6),828×10~(-6),58.54×10~(-6),and 148×10~(-6) respectively.In addition,sorption properties of clay and organic materials are also important for metal enrichments in the bituminous shales.     

Eocene tonalite–granodiorite from the Havza (Samsun) area,northern Turkey: adakite-like melts of lithospheric mantle and crust generated in a post-collisional setting

ABSTRACT

Eocene intermediate to felsic plutons of different sizes and compositions are widespread in the Eastern Pontides Orogenic Belt in northern Turkey. Of these, the Ta?l?k Tepe pluton in the Havza (Samsun) area is fine-to-medium-grained, with granular, porphyritic, and micrographic textures, and include mafic microgranular enclaves (MMEs). LA-ICP-MS U-Pb zircon dating yielded emplacement ages of 42.9 (± 1.4) and 40.5 (± 1.3) Ma for the host granodioritic pluton and the dioritic MMEs, respectively. Petrochemically, the host pluton has I-type, high-K calc-alkaline, and metaluminous-to-slightly peraluminous features (A/CNK = 0.95–1.06). The host pluton also shows geochemical features of adakite-like rocks with high SiO₂ (67–68 wt%) and Al₂O₃ (15.5–16.0 wt%) content and Ba/La (17–23), Sr/Y (40.7–61.6), and La_N/Yb_N (14.4–23.7) ratios and low Y (8.2–9.9 ppm) and Yb_N (3.1–4.4) contents. Whole-rock major and trace element variations suggest that fractional crystallisation played a significant role in the pluton evolution. The N-MORB normalised trace element patterns of the pluton are similar to those of MMEs with enrichment in large-ion lithophile elements, Th and Ce, and negative Nb and Ti anomalies. Chondrite-normalised rare earth element plots show moderate-to-highly enriched concave patterns (La_N/Lu_N = 14.2–21.6) with insignificant negative Eu anomalies (Eu_N/Eu* = 0.86–1.14), all of which imply hornblende fractionation during magmatic evolution. The pluton samples have ⁸⁷Sr/⁸⁶Sr ratios of 0.704767 to 0.704927, ¹⁴³Nd/¹⁴⁴Nd ratios of 0.512767–0.512774, εNd values of (+2.52) – (+2.65), and δ¹⁸O values of 7.9–9.7‰. The isotopic compositions of the host pluton and MMEs are similar to I-type granitoids derived from mantle sources. The MMEs show incomplete magma mixing/mingling, representing small bodies of mafic parental magma. Combined with regional studies, these new data suggest that the parental magma of the studied adakite-like pluton was generated from the lithospheric mantle and then modified by fractional crystallisation and assimilation in a post-collisional setting.     

A taxonomic study on the families Lepadellidae and Trichocercidae （Rotifera： Monogononta） of Turkey

Thirteen rotifer species belonging to the families Lepadellidae and Trichocercidae were studied taxonomically from nine water bodies in Turkey. Lepadella biloba is a new entry to the Turkish rotifer fauna. All species were drawn under a light microscope using a camera lucida.     

Late Cretaceous blueschist facies metamorphism in southern Thrace (Turkey) and its geodynamic implications

A blueschist facies tectonic sliver, 9 km long and 1 km wide, crops out within the Miocene clastic rocks bounded by the strands of the North Anatolian Fault zone in southern Thrace, NW Turkey. Two types of blueschist facies rock assemblages occur in the sliver: (i) A serpentinite body with numerous dykes of incipient blueschist facies metadiabase (ii) a well‐foliated and thoroughly recrystallized rock assemblage consisting of blueschist, marble and metachert. Both are partially enveloped by an Upper Eocene wildflysch, which includes olistoliths of serpentinite–metadiabase, Upper Cretaceous and Palaeogene pelagic limestone, Upper Eocene reefal limestone, radiolarian chert, quartzite and minor greenschist. Field relations in combination with the bore core data suggest that the tectonic sliver forms a positive flower structure within the Miocene clastic rocks in a transpressional strike–slip setting, and represents an uplifted part of the pre‐Eocene basement. The blueschists are represented by lawsonite–glaucophane‐bearing assemblages equilibrated at 270–310 °C and ～0.8 GPa. The metadiabase dykes in the serpentinite, on the other hand, are represented by pumpellyite–glaucophane–lawsonite‐assemblages that most probably equilibrated below 290 °C and at 0.75 GPa. One metadiabase olistolith in the Upper Eocene flysch sequence contains the mineral assemblage epidote + pumpellyite + glaucophane, recording P–T conditions of 290–350 °C and 0.65–0.78 GPa, indicative of slightly lower depths and different thermal setting. Timing of the blueschist facies metamorphism is constrained to c. 86 Ma (Coniacian/Santonian) by Rb–Sr phengite–whole rock and incremental ⁴⁰Ar–³⁹Ar phengite dating on blueschists. The activity of the strike–slip fault post‐dates the blueschist facies metamorphism and exhumation, and is only responsible for the present outcrop pattern and post‐Miocene exhumation (～2 km). The high‐P/T metamorphic rocks of southern Thrace and the Biga Peninsula are located to the southeast of the Circum Rhodope Belt and indicate Late Cretaceous subduction and accretion under the northern continent, i.e. the Rhodope Massif, enveloped by the Circum Rhodope Belt. The Late Cretaceous is therefore a time of continued accretionary growth of this continental domain.     

Quality control and homogeneity of Turkish precipitation data

Outlier trimming and homogeneity checking/correction were performed on the monthly precipitation time series of various lengths from 267 stations in Turkey. Outlier values are usually found during dry summer months, and are concentrated mostly over the southern parts of the country, where the dry period is most pronounced, implying natural extremes rather than wrong measurements. Homogeneity analysis was done using the Standard Normal Homogeneity Test, on an individual monthly basis, which led to many non‐testable series due to lack of reference stations, especially during summer months. Yet, remaining testable months were usually helpful for the assessment of homogenity, revealing a well distributed set of stations that proved to be homogeneous. There were still a number of stations which either could not be tested efficiently, or were classified as inhomogeneous. Lack of metadata is argued to be largely responsible for inefficient homogeneity testing. Copyright © 2008 John Wiley & Sons, Ltd.     

土耳其贝帕扎里采集卤钻井三期工程井组布置的优化设计

土耳其贝帕扎里采集卤钻井三期工程的井组布置设计是在一、二期矿区内利用部分现有井场、现有采集卤管线的基础上,采用了更加优化的三井井组、五井井组、双通道平行井组及复杂井组。此设计减少了投资、缩短了基建周期、便于生产管理,使资源得到更合理的开发利用,增大了矿区现有产能,更大满足了加工厂对卤水的需要。全矿区共布置15个溶采单元,共包括25个井组采矿通道,垂直井29口,水平井23口。     

Mineralogical and Petrological Characteristics of the Neoproterozoic Orthoamphibolite and Orthogneisses in the Mutki Area, the Bitlis Massif, Southeast Turkey

<正>The rocks form as amphibolite±garnet±epidote and orthogneisses in the Pan-African basement of the Bitlis Massif.The petrochemical data of the studied metamorphic rocks suggest different igneous protoliths ranging from calcalkaline basalt to andesite in composition. Petrochemically,the rocks can be classified as group 1(low Zr and La) and group 2(high Zr and La), all showing various enrichments in large ion lithophiles and light rare earth elements,and a depletion in high-field strength elements,suggestive of a destructive plate margin setting.The protoliths of the all samples might have formed mostly by the partial melting of an enriched source,possibly coupled with the fractional crystallization of plagioclase,apatite,and titaniferous magnetite±olivine±clinopyroxene±amphibole in relation with subduction-related magmatism neighboring the Andeantype active margins of Gondwana.The group 2 samples could,however,be generated by a relatively lower degree of the partial melting of an inhomogeneous source with a preponderance of a high-level, fractional crystallization process in comparison to group 1.The protoliths of the samples were metamorphosed up to amphibolite facies conditions,which destroys original igneous texture and mineral assemblages.Geothermobarometric calculations show that the metamorphic rocks are finally equilibrated between 540 and 610℃and～5 kbars,following a clockwise P-T-t path.     

Origin of the hydrocarbon gases carbon dioxide and hydrogen sulfide in Dodan Field (SE-Turkey)

Gas occurrences consisting of carbon dioxide (CO₂), hydrogen sulfide (H₂S), and hydrocarbon (HC) gases and oil within the Dodan Field in southeastern Turkey are located in Cretaceous carbonate reservoir rocks in the Garzan and Mardin Formations. The aim of this study was to determine gas composition and to define the origin of gases in Dodan Field. For this purpose, gas samples were analyzed for their molecular and isotopic composition. The isotopic composition of CO₂, with values of −1.5‰ and −2.8‰, suggested abiogenic origin from limestone. δ³⁴S values of H₂S ranged from +11.9 to +13.4‰. H₂S is most likely formed from thermochemical sulfate reduction (TSR) and bacterial sulfate reduction (BSR) within the Bakuk Formation. The Bakuk Formation is composed of a dolomite dominated carbonate succession also containing anhydrite. TSR may occur within an evaporitic environment at temperatures of approximately 120–145 °C. Basin modeling revealed that these temperatures were reached within the Bakuk Formation at 10 Ma. Furthermore, sulfate reducing bacteria were found in oil–water phase samples from Dodan Field. As a result, the H₂S in Dodan Field can be considered to have formed by BSR and TSR.As indicated by their isotopic composition, HC gases are of thermogenic origin and were generated within the Upper Permian Kas and Gomaniibrik Formations. As indicated by the heavier isotopic composition of methane and ethane, HC gases were later altered by TSR. Based on our results, the Dodan gas field may have formed as a result of the interaction of the following processes during the last 7–8 Ma: 1) thermogenic gas generation in Permian source rocks, 2) the formation of thrust faults, 3) the lateral-up dip migration of HC-gases due to thrust faults from the Kas Formation into the Bakuk Formation, 4) the formation of H₂S and CO₂ by TSR within the Bakuk Formation, 5) the vertical migration of gases into reservoirs through the thrust fault, and 6) lateral-up dip migration within reservoir rocks toward the Dodan structure.