吉林南部通化地区古元古代辽吉花岗岩的侵位年代与形成构造背景

辽吉南部古元古代花岗岩极为发育,其中最著名的是具有条痕状构造的正长花岗岩,俗称辽吉花岗岩。因该花岗岩具有条带状、条痕状和似层状构造特征,而被前人认为是由太古宙或元古宙沉积地层经变质变形作用形成,或是交代成因的混合岩。本文通过对分布于吉林南部通化地区辽吉花岗岩的典型代表一钱桌沟岩体的详实野外地质填图及地球化学研究,确定该岩体属岩浆成因的“A”型花岗岩,其岩浆侵位年龄为2160Ma左右。结合目前获得的该区古元古代地层的碎屑锆石年龄,本文认为辽吉花岗岩是辽吉地区古元古代地层沉积的基底岩石,是地层沉积之前地壳拉张作用的结果,属于一种非造山型花岗岩。     

辽宁古元古代地体中富电气石岩石的成因：蒸发岩硼源的证据

辽宁东部古元古界底部地层(南辽河群)中赋存着大型的硼酸盐矿床，含矿层位中广泛分布含电气石的变粒岩和电英岩。空间上这些含电气石的岩石与硼酸盐有着密切的联系，电气石可以作为区域硼矿找矿的标志。已有研究结果表明，该地区的硼酸盐矿床是变质蒸发岩成因。本研究对该区不同产状的电气石和硼酸盐的地质特征，全岩和矿物成分、硼同位素组成进行了分析。本区的电气石包括层状和脉状两大类，而电气石的富集与硼酸盐关系密切，电英岩往往分布在硼酸盐矿体的上盘。而矿体的下盘一般不产出富电气石的岩石。当长英质脉体穿过硼酸盐矿体时，脉体中往往会富集电气石。含电气石岩石的全岩地球化学分析表明，它们的REE及其他微量元素特征以及相关性关系与周围不含电气石的同类岩石十分相似，反映出一种成因上的联系。本区电气石主要属于镁电气石一铁电气石系列，靠近硼矿体的电气石比远离硼矿体的电气石更加富镁，有着更高的Mg／Fe比值。电气石和硼酸盐的硼同位素成分分析显示出二者在同位素组成上的相似性，前者比后者的δ^11B稍低，这可能是由于热液活动过程中同位素分馏的结果。电气石的硼同位素组成在空间上显示出变化规律：远离硼酸盐矿体的电气石的δ^11B值(-5．2‰- 3．6‰)比矿体附近的电气石低(平均 10．5‰)。以上空间和成分上的关系表明硼酸盐可能是形成电气石主要的硼来源，电气石是在热液过程中通过淋滤下伏含硼蒸发岩中的硼形成含硼热液，在与上覆沉积物交代过程中形成含电气石岩石。电气石的条带是热液顺层选择交代的结果。本区电气石与硼酸盐的关系表明，层状电气石可以通过含硼热液交代的方式形成。变质地体中的层状电气石岩石的出现可能与变质蒸发岩有关。这一认识对区域硼矿勘查工作和变质地体的沉积环境分析有借鉴意义。     

Nd isotopic composition of Paleoproterozoic volcanic and granitoid rocks of Vila Riozinho: implications for the crustal evolution of the Tapajós gold province, Amazon craton

Nd data from the Paleoproterozoic magmatic rocks of Vila Riozinho and Jamanxim (Tapajós gold province) indicate that original magmas were not produced exclusively by the remelting of Archean sialic crust and point to dominant Paleoproterozoic sources. ε_Nd(T) values preclude derivation from mantle sources for the ca. 2.0 Ga Vila Riozinho volcanics and older São Jorge granite. They may represent a subduction-related magmatic arc with magmas modified by interaction with crust or a post- to late-orogenic remelting of an older Paleoproterozoic juvenile arc with minimal contribution from the Archean crust. The origin of the 1.88 Ga Parauari, Maloquinha, Iriri, and Moraes Almeida igneous associations and the Jamanxim rhyolites has been attributed to large-scale taphrogenesis that marked the breakup of a large Paleoproterozoic continent. Derivation of the original magmas from the remelting of crustal sources older than ca. 1.9 Ga is consistent with geochemical and Nd isotopic data. Archean remnants probably occur between the Paleoproterozoic terrains of the Ventuari-Tapajós province. Archean terrains of the Amazon craton extend from the Xingu to the Itaituba region but have not been identified in the southern Guyana shield. Thus, data reveal that the boundaries between the central Amazon and Ventuari-Tapajós provinces need better definition and more detailed field and geochronological work.     

华北克拉通桑干地区高压麻粒岩的锆石SHRIMP U-Pb年龄及其地质含义

为了揭示华北克拉通桑干地区古元古代高压麻粒岩变质峰期时限,对选自该区的两个高压麻粒岩样品(DST02,XYS01)进行了锆石SHRIMP U-Pb测年。锆石样品的阴极发光图像显示为球形和无内部结构,Th/U比值变化为0.01~0.93。这些特征表明两样品的锆石应属于变质成因锆石。两样品的SHRIMP测年结果分别给出(1 792±12)Ma和(1 891±46)Ma。根据前人的年代学方面的研究成果,特别是未变质强过铝花岗岩中获得的1 900~1 850 Ma的锆石U-Pb年龄(郭敬辉等,2002)结果来看,本区高压麻粒岩峰期变质时代不会晚于此。因此本文获得的1 850~1 800 Ma的锆石SHRIMP U-Pb年龄应代表退变年龄。而(1 891±46)Ma的年龄限定了峰期高压变质年龄上限。     

Fluid inclusion and stable isotope (O, H, C, and S) constraints on the genesis of the Serrinha gold deposit, Gurupi Belt, northern Brazil

The Serrinha gold deposit of the Gurupi Belt, northern Brazil, belongs to the class of orogenic gold deposits. The deposit is hosted in highly strained graphitic schist belonging to a Paleoproterozoic (∼2,160 Ma) metavolcano-sedimentary sequence. The ore-zones are up to 11 m thick, parallel to the regional NW–SE schistosity, and characterized by quartz-carbonate-sulfide veinlets and minor disseminations. Textural and structural data indicate that mineralization was syn- to late-tectonic and postmetamorphic. Fluid inclusion studies identified early CO₂ (CH₄-N₂) and CO₂ (CH₄-N₂)-H₂O-NaCl inclusions that show highly variable phase ratios, CO₂ homogenization, and total homogenization temperatures both to liquid and vapor, interpreted as the product of fluid immiscibility under fluctuating pressure conditions, more or less associated with postentrapment modifications. The ore-bearing fluid typically has 18–33mol% of CO₂, up to 4mol% of N₂, and less than 2mol% of CH₄ and displays moderate to high densities with salinity around 4.5wt% NaCl equiv. Mineralization occurred around 310 to 335°C and 1.3 to 3.0 kbar, based on fluid inclusion homogenization temperatures and oxygen isotope thermometry with estimated oxygen fugacity indicating relatively reduced conditions. Stable isotope data on quartz, carbonate, and fluid inclusions suggest that veins formed from fluids with δ¹⁸O_H2O and δD_H2O (310–335°C) values of +6.2 to +8.4‰ and −19 to −80‰, respectively, which might be metamorphic and/or magmatic and/or mantle-derived. The carbon isotope composition (δ¹³C) varies from −14.2 to −15.7‰ in carbonates; it is −17.6‰ in fluid inclusion CO₂ and −23.6‰ in graphite from the host rock. The δ³⁴S values of pyrite are −2.6 to −7.9‰. The strongly to moderately negative carbon isotope composition of the carbonates and inclusion fluid CO₂ reflects variable contribution of organic carbon to an originally heavier fluid (magmatic, metamorphic, or mantle-derived) at the site of deposition and sulfur isotopes indicate some oxidation of the originally reduced fluid. The deposition of gold is interpreted to have occurred mainly in response to phase separation and fluid-rock interactions such as CO₂ removal and desulfidation reactions that provoked variations in the fluid pH and redox conditions.     

华北克拉通古元古代区域构造格架及其板块构造演化探讨

华北克拉通古元古代区域构造至少可以划分出三大构造单元：（１）陆内裂谷带（２．３０～２．６０Ｇａ）;（２）陆缘造山带（２．３０～２．６０Ｇａ）;（３）再造的太古代克拉通区（麻粒岩相带）（大于２．５０Ｇａ）．太古代末—古元古代重要的区域性构造－热事件序列依次为：（１）克拉通中部不同地壳层次伸展及裂谷盆地的发育;（２）克拉通北缘构造活动、增生及陆壳基底再造;（３）与大陆裂谷盆地闭合过程相联系的板内造山－前陆盆地发育．板块构造模式可以很好地解释上述构造作用类型．     

U-Pb (zircon) ages for the gneissic terrane west of the Nile,southern Egypt

The first U-Pb zircon ages are reported for the gneissic bedrock inliers previously interpreted as part of the Nile Craton. The inliers crop out in the Egyptian Western Desert, east of the Uweinat area and west of the Eastern Desert. Multi- and single-grain zircon analyses of granitoid gneiss and migmatite from Gebel Um Shagir, Aswan, and another locality approximately 160 km south-west of Aswan, yield simple discordia with near modern day Pb loss trajectories, and the following Neoproterozoic crystallization ages: 626+4/–3, 634 ± 4 and 741 ± 3 Ma. In contrast, multi- and single-grain U-Pb analyses (zircon and sphene) from an anorthositic gabbro at Gebel Kamil (22°46N 26°21E) and an anorthosite at Gebel El Asr (22°46N 31°10E) yield Archean and Paleoproterozoic emplacement ages. The former yield a crystallization age of > 2.67 Ga and a metamorphic age of 2.0 Ga; the latter a metamorphic age of 0.69 Ga and an inheritance age of 1.9–2.1 Ga. Because high grade gneiss and migmatite of Neoproterozoic, Paleoproterozoic and Archean age crop out west of the Nile, pre-Neoproterozoic crust should no longer be identified by its metamorphic grade. By contrast, mapping the anorthosite and related rocks might provide first-order estimates for the extension of pre-Neoproterozoic crust in north-east Africa. It is suggested that Archean and Paleoproterozoic crust of the Uweinat and Congo Craton are contiguous because these U-Pb (zircon) data show no evidence for a Neoproterozoic thermal overprint in the Gebel Kamil area and there is no pronounced Neoproterozoic magmatic activity south of the Uweinat inlier and north of the Congo Craton.     

Chemostratigraphy of Paleoproterozoic carbonate successions of the Wyoming Craton: tectonic forcing of biogeochemical change?

The Archean Wyoming Craton is flanked on the south and east by belts of Paleoproterozoic supracrustal successions whose correlation is complicated by lack of geochronologic constraints and continuous outcrop. However, carbonate units in these successions may be correlated by integrating carbon isotope stratigraphy with lithostratigraphy. The 10 km thick Paleoproterozoic Snowy Pass Supergroup in the Medicine Bow Mountains was deposited on the present-day southern flank of the Wyoming Craton; it contains three discrete levels of glacial diamictite correlative with those in the Huronian Supergroup, on the southern margin of the Superior Craton. The Nash Fork Formation of the upper Snowy Pass Supergroup is significantly younger than the uppermost diamictite and was deposited after the end of the Paleoproterozoic glacial epoch. Carbonates at the base of the Nash Fork Formation record remarkable ¹³C-enrichment, up to +28‰ (V-PDB), whereas those from overlying members of the lower Nash Fork Formation have δ¹³C values between +6 and +8‰. Carbonates from the upper Nash Fork Formation above the carbonaceous shale have carbon isotope values ranging between 0 and +2.5‰. The transition from high carbon isotope values to those near 0‰ in the Nash Fork Formation is similar to that at the end of the ca. 2.2–2.1 Ga carbon isotope excursion in Fennoscandia. This chemostratigraphic trend and deposition of BIFs, Mn-rich lithologies, carbonaceous shales and phosphorites at the end of the global ca. 2.2–2.1 Ga carbon isotope excursion are likely related to ocean overturn associated with the final breakup of the Kenorland supercontinent. Correlative carbonates from the Slaughterhouse Formation in the Sierra Madre, WY, and from the Whalen Group in the Rawhide Creek area in the Hartville Uplift, WY, have highly positive carbon isotope values. In contrast, carbonates from other exposures of the Whalen Group in the Hartville Uplift and all carbonate units in the Black Hills, SD, have carbon isotope values close to 0‰. Combined with existing geochronologic and stratigraphic constraints, these data suggest that the Slaughterhouse Formation and the succession exposed in the Rawhide Creek area of the Hartville Uplift are correlative with the lower and middle Nash Fork Formation and were deposited during the ca. 2.2–2.1 Ga carbon isotope excursion. The Estes and Roberts Draw formations in the Black Hills and carbonates from other exposures in the Hartville Uplift postdate the ca. 2.2–2.1 Ga positive carbon isotope excursion and are most likely correlative with the upper Nash Fork Formation. The passive margin, on which the carbonates with highly positive carbon isotope values were deposited, extended around the southern flank of the Wyoming Craton through the Sierra Madre, Medicine Bow Mountains and Hartville Uplift. The presence of carbonates with carbon isotope values close to 0‰ in the upper Nash Fork Formation and the Whalen Group indicates that the passive margin persisted on the southern flank of the Wyoming Craton after the carbon isotope excursion. Rifting in the Black Hills, likely related to the final breakup of the Kenorland, succeeded the carbon isotope excursion, since the Estes and Roberts Draw formations, deposited during rifting and ocean opening on the eastern flank of the Wyoming Craton, postdate the carbon isotope excursion.     

华北克拉通古元古代地质记录及其构造意义

华北克拉通上存在广泛的古元古代地质记录,尤其是构造岩石组合和同位素年龄资料,显示克拉通上可能存在多条古元古代的汇聚拼合带：如鄂尔多斯地块与华北东部-阴山地块之间的拼合造山带、华北东部地块与狼林地块之间的胶辽造山带以及华北克拉通北缘的安第斯型汇聚边界等。华北克拉通中部地区的古元古代锆百年龄数据统计,显示出2．3～24Ga、20～22Ga和18～1．95Ga三组年龄值,暗示华北克拉通古元古代可能存在两个演化阶段：其中古元古代末期（18～1．95Ga）的造山事件已得到了广泛认可,并认为-9全球Columbia超大陆汇聚事件相关;而2.3～2.4Ga、2.00～2.2Ga所代表的构造热事件的性质和意义尚不明确。我国古元古代末期有关陆块汇聚的构造热事件以及其后的裂解事件群和地层学记录,与新的国际前寒武纪地质年代表建议的古-中元古代界线一致,这将促进我国特别是古-中元古代的前寒武纪研究。     

Petrogenesis of the Paleoproterozoic Guandishan Granitoids in Shanxi Province： Constraints from Geochemistry and Nd Isotopes

The Guandishan granitoids consist mainly of various granitoid intrusions with different scales, including the Huijiazhuang intrusion, Shizhuang intrusion and Hengjian intrusion, which were formed between 1906 Ma and 1848 Ma. On the basis of geological and petrological characteristics, these granitoids can be classified into two groups： the earlier gneissic granodiorites and monzogranites, and the later massive leuco-monzogranites. Their geochemical and Nd isotopic features indicate that they could be derived from complicated partial melting of supracrustal rocks with an affinity of continental arc materials, such as sandy shale and pelite, and with garnet, pyroxene, hornblende and plagioclase as residual phases. Biotite, feldspar and other minerals were most likely fractionated during the magma evolution. Their source may have an affinity with continental arcs, and the granitoids could be derived from the main syn-collisional to late-orogenic tectonic environment, which may be related to the final amalgamation between the Eastern and Western continental blocks in the North China Craton.