辽东桓仁西部古元古代侵入岩年代学及岩石地球化学

华北克拉通东部辽东地区出露古元古代侵入岩,为准确认识辽东地区古元古代构造演化过程,选取北沟岩体、正岔岩体和树柳林子岩体的岩相学、岩石地球化学及年代学特征,探讨了岩体的形成时代、岩石成因及其构造环境。锆石SHRIMP U-Pb年代学研究表明,柳林子岩体年龄为(2 490±8) Ma,北沟岩体年龄为(2 457±11) Ma。北沟岩体高硅富钾,富集Rb、U、Th、K等大离子亲石元素,亏损Nb、Ti、P等高场强元素,为过铝质高钾钙碱性I型花岗岩,Nb/Ta平均值5. 75,Rb/Nb平均值4. 21,源于太古宙古老地壳的部分熔融;正岔岩体高硅富钾,富集Rb、Ba、U、Th、K等大离子亲石元素,亏损Nb、Ti、P等高场强元素,为弱过铝质高钾钙碱性A型花岗岩,Nb/Ta平均值16. 06,Rb/Nb平均值4. 81,源区可能由幔源岩浆底侵带来的热量加热地壳,导致其重熔并与之混合后形成的。柳林子岩体为变质角闪辉长岩,呈亚碱性,富集Rb、Ba、K等大离子亲石元素,亏损Nb、Ti、P等高场强元素,显示其岩浆可能形成于受陆壳微弱混染的软流圈地幔或岩石圈地幔。认为研究区古元古代侵入岩形成于东、西陆块碰撞拼合后的后造山挤压向板内伸展转换的构造环境,为构造体质转换的产物。     

辽东王家堡子地区古元古代花岗岩地球化学特征、锆石U-Pb年龄、Hf同位素及其地质意义

辽东王家堡子地区出露大量古元古代花岗质岩石,前人将其统称为花岗质混杂岩。通过详细的野外地质调查和室内综合研究,将该套花岗质混杂岩解体为条痕状黑云母二长花岗岩和片麻状黑云母二长花岗岩两类。岩石地球化学分析结果显示二者具有一致的地球化学特征。均显示高SiO_2、富K_2O、贫Al_2O_3的特征,K_2O/Na_2O=0.64～2.14,TiO_2含量为0.16%～0.3%,MnO、MgO、CaO和P_2O_5的含量较低,铝指数A/CNK集中分布在1.06～1.1之间,A/NK在1.50～1.62之间,均属于过铝质高钾钙碱性系列;微量元素显示强烈亏损Nb、Ti、Ta等高场强元素,富集Rb、U、K等大离子亲石元素,具有明显的负Eu异常,具有A型花岗岩的特征。条痕状黑云母二长花岗岩大部分锆石为具有清晰振荡环带的岩浆锆石,LA-ICP-MS锆石U-Pb年龄为2188±13Ma,代表该岩石的岩浆结晶年龄。片麻状黑云母二长花岗岩大部分锆石具有明显的变质增生边,部分核部锆石具有清晰的振荡环带,LA-ICP-MS锆石U-Pb测年获得核部年龄为2214±16Ma,代表该岩石的岩浆结晶年龄;增生边年龄为1905±13Ma,应代表该岩石的变质年龄。条痕状黑云母二长花岗岩和片麻状黑云母二长花岗岩的Hf同位素模式年龄分别为2387～2584Ma和2474～2641Ma,平均地壳模式年龄分别为2495～2808Ma和2633～2868Ma,大于岩石形成年龄,暗示研究区古元古代花岗岩源区主要为太古宙基底,混有少量古元古代新生地壳。结合前人报道的埃达克质花岗闪长岩的形成环境,认为胶-辽-吉古元古代造山/活动带早期经历了2.2～2.15Ga的拉伸裂解过程和2.0Ga左右俯冲挤压的构造演化过程。     

Paleoproterozoic volcanic rocks in the southern margin of the North China Craton,central China:Implications for the Columbia supercontinent

The volcanic rocks of the Xiong'er Group are situated in the southern margin of the North China Craton(NCC).Research on the Xiong er Group is important to understand the tectonic evolution of the NCC and the Columbia supercontinent during the Paleoproterozoic.In this study,to constrain the age of the Xiong'er volcanic rocks and identify its tectonic environment,we report zircon LA-ICP-MS data with Hf isotope,whole-rock major and trace element compositions and Sr-Nd-Pb-Hf isotopes of the volcanic rocks of the Xiong'er Group.The Xiong'er volcanic rocks mainly consist of basaltic andesite,andesite.dacite and rhyolite,with minor basalt.Our new sets of data combined with those from previous studies indicate that Xiong'er volcanism should have lasted from 1827 Ma to 1746 Ma as the major phase of the volcanism.These volcanics have extremely low MgO.Cr and Ni contents,are enriched in LREEs and LILEs but depleted in HFSEs(Nb,Ta,and Ti),similar to arc-related volcanic rocks.They are characterized by negative zircon ε_(Hf)_(t) values of-17.4 to 8.8,whole-rock initial ~(87)Sr/~(86)Sr values of 0.7023 to 0.7177 andε_(Nd)(t) values of-10.9 to 6.4.and Pb isotopes(~(206)Pb/~(204)Pb =14.366-16.431,~(207)Pb/~(204)Pb =15.106-15.371,~(208)Pb/~(204)Pb= 32.455-37.422).The available elemental and Sr-Nd-Pb-Hf isotope data suggest that the Xiong'er volcanic rocks were sourced from a mantle contaminated by continental crust.The volcanic rocks of the Xiong'er Group might have been generated by high-degree partial melting of a lithospheric mantle that was originally modified by oceanic subduction in the Archean.Thus,we suggest that the subduction-modified lithospheric mantle occurred in an extensional setting during the breakup of the Columbia supercontinent in the Late Paleoproterozoic,rather than in an arc setting.     

西藏察隅地区古元古代德玛拉岩群的特征

西藏察隅地区出露一套由片岩、片麻岩、变粒岩夹斜长角闪岩及大理岩等组成的中深变质岩系。通过岩石学、岩石地球化学、同位素地质学及原岩建造的研究,并采用构造—岩层—事件方法的分析与对比,新建立了墨色同岩组和蛇躲岩组两个岩石地层单位,统称为德玛拉岩群。依据ＳｍＮｄ法年龄２１４５～２２６４Ｍａ将其时代确定为古元古代。该岩群与印度马德拉斯和斯里兰卡形成于２３００～２１００Ｍａ的孔达岩系十分相似,可能是冈瓦纳古陆核北缘的一套浅海相沉积     

Rhyacian and Neoproterozoic magmatic associations of the Gurupi Belt,Brazil: Implications for the tectonic evolution,and regional correlations

The Gurupi Belt, in north-northeastern Brazil, is a mobile belt developed in the south-southwestern margin of the São Luís cratonic fragment and crops out as a tectonic and erosional window within the Phanerozoic cover. Field, petrographic, geochemical, geochronological, and Nd isotopic information (new and published) constrain the timing and types of magmatic associations present in the belt and the tectonic settings in which they formed. The Rhyacian was the main period of magmatic activity, which can be grouped into two main stages. (1) ~2185–2130 ​Ma: pre-collisional, juvenile, calc-alkaline magnesian and calcic ferroan granitoid suites, and minor calc-alkaline and tholeiitic mafic plutonism (now amphibolites), formed in intra-oceanic to transitional/continental arcs; and intra- or back-arc volcano-sedimentary basin. (2) ~2125–2070 ​Ma: syn- (two-mica granites) to late-collisional (potassic to shoshonitic granites and quartz-syenite) plutonic suites produced after crustal thickening and melting, with localized migmatization, that intruded during the compressive D₁ deformational phase and concomitantly with greenschist to amphibolite metamorphism. There is a zonation of the Rhyacian episodes, with intra-oceanic stages occurring to the northeast, and the continental arc and collisional phases occurring to the southwest, indicating the presence of an active continental margin to the southwest, and subduction from NE to SW (present-day configuration). This magmatic framework is a continuation to the south of what is described for the São Luís cratonic fragment to the north, and the orogenic scenario is identical to what is observed for the same period in the West African Craton (Eburnean/Birrimian orogen), which additionally supports previous geological correlations. In the Neoproterozoic, a few magmatic occurrences are recognized. An extensional event allowed the intrusion of an anorogenic, nepheline syenite at ca. 730 Ma, which was followed by the intrusion of a crustal, calc-alkaline microtonalite, of uncertain tectonic setting, at 624 ​Ma. Both intrusions underwent greenschist to amphibolite facies metamorphism between 580 Ma and 529 ​Ma. This metamorphic event is probably related to crustal thickening, which produced crustal melting and intrusion of two-mica granites between 595 Ma and 549 ​Ma. The absence of oceanic and arc-related assemblages, along with geophysical information about the basement of the Phanerozoic cover indicates an intracontinental setting for the Neoproterozoic–Early Cambrian evolution of the Gurupi Belt, with rifting and posterior closure of the basin, without oceanization. Rifting and closure correlate in time with the onset of Rodinia breakup and West Gondwana assembly, respectively, but we interpret the events in the Gurupi Belt as having no direct role in these two global supercontinent-related events, but, instead, as being related to orogenic events occurring in the periphery of the West African and Amazonian cratons at that time.     

扬子陆块~2.0 Ga的区域变质事件对南北黄陵古元古代差异演化的启示

扬子陆核黄陵地区发育较为完整的太古宙—古元古代片麻岩、表壳岩组合(即崆岭杂岩),前人调查研究认为南北黄陵Ar-Pt1具有一致的物质组成和地质演化过程。笔者分别对南北黄陵太古宙花岗质片麻岩进行锆石年代学研究发现,北黄陵2件样品(HL013-1、HL013-2)均存在大量锆石发育岩浆核-变质边结构,都获得～2.8 Ga原岩结晶年龄和～2.0 Ga变质年龄;而南黄陵1件样品(HL005-3)以具振荡环带结构的岩浆锆石为主,仅获得～2.9 Ga原岩结晶年龄。结合前人研究成果发现,～2.0 Ga的变质年龄在北黄陵太古宙—古元古代的花岗片麻岩、表壳岩中广泛发育,而在南黄陵相似建造中均未获得,一定程度上说明北黄陵地区广泛遭受～2.0 Ga的区域变质作用而南黄陵不发育,南北黄陵在古元古代可能处在不同地块或者同一地块不同部位。2.1～1.6 Ga的构造岩浆事件的分布特点说明扬子陆块可能存在多条古元古代造山带,扬子陆块古元古代以多块体拼贴为特点,广泛记录2.1～1.6 Ga的构造岩浆事件说明扬子陆块是全球哥伦比亚超大陆的重要组成部分。     

Petrography and geochemistry of manganiferous rocks in the Mankwadzi area in the southern Kibi‐Winneba metavolcanic belt,Ghana: Implications for genesis of Mn formations in the Birimian of West Africa

Manganiferous rocks in the Mankwadzi area in the southernmost portion of the Kibi‐Winneba metavolcanic belt, one of several Mn occurrences in the Paleoproterozoic Birimian of Ghana, are hosted in hornblende schist and amphibolite. These rocks are, in places, intruded by hornblende dyke. In outcrop, the manganiferous rocks appear to be conformable with the host schist and amphibolite, are macroscopically dark, fine‐grained and structurally massive to distinctly banded. Observed alternating light and dark occasionally macro‐folded bands suggest post‐depositional deformation of both light and dark bands. Microscopic observations revealed that the light bands are dominantly Si‐rich and the dark bands mainly of opaque minerals. Whole rock analyses of the manganiferous rocks show high contents of MnO (16.75–27.4 wt%) suggesting that the opaque minerals are likely rich in Mn. The analyzed rock samples show moderate to strong enrichments in light rare earth elements compared to heavy rare earth elements. Whereas the manganiferous rocks show perceptibly negative Eu anomaly, host hornblende schist and hornblende dyke do not. Eu anomaly in amphibolite samples is, however, uncertain as the three samples analyzed gave positive, negative and no Eu anomalies. Based on the field characteristics, microscopic and geochemical features, we suggest that the Mn occurrence in the Mankwadzi area originated via sedimentary deposition and was later modified by metamorphism, hydrothermal and/or supergene processes similar to manganiferous occurrences at Nsuta and Tambao in the Birimian of West Africa.     

北阿尔金地区古元古代岩体LA-ICP-MS锆石U-Pb年龄及其地质意义

北阿尔金是塔里木克拉通变质基底的主要出露区之一。对该区具有侵入接触关系的正长花岗岩和花岗片麻岩进行了LA-ICP-MS锆石U-Pb定年研究。正长花岗岩中的锆石多呈椭圆状,具有振荡环带结构,部分颗粒中可见老锆石残核,Th/U值较高,亏损轻稀土元素,富集重稀土元素,具有负Eu异常和正Ce异常的特点,表明该组锆石为岩浆成因。定年结果获得1903±13Ma和2506±55Ma两组年龄加权平均值,前者代表岩体的结晶年龄,后者为捕获锆石年龄,结合区域年代学资料,认为正长花岗岩岩浆侵入过程中可能捕获了太古宇米兰群的古老基底锆石。花岗片麻岩中16个测点的锆石~(207)Pb/~(206)Pb年龄集中于1802±28Ma,代表了岩体侵位时代,其余5个测点的锆石~(207)Pb/~(206)Pb年龄为1911~1951Ma,说明岩浆侵位过程中捕获了部分正长花岗岩的物质。区域地质与同位素年代学研究表明,北阿尔金地区广泛存在2.0~1.8Ga的构造-热事件。获得的花岗质岩石的1.9~1.8Ga的年龄结果,直接证实了北阿尔金存在约1.9Ga的岩浆作用,可能为古元古代Columbia超大陆汇聚事件在该地区的响应,为探讨塔里木板块前寒武纪构造-热事件演化历史提供了新资料。古元古代末期约1.8Ga的花岗片麻岩,代表了后造山伸展阶段的岩浆活动。     

华北地块西南缘古元古代花岗斑岩及其构造意义

在六盘山南段陇县固关镇东部出露多个原认为属于中-新生代的花岗斑岩岩体,其中的白家沟花岗斑岩显示古元古 代壳源岩浆活动的记录,属于钙碱性花岗岩系。该花岗斑岩高SiO2 （71.14%~73.33%）,高碱（Na2O+ K2O=7.61%~8.70%）, 富钾（K2O/Na2O=1.21~2.52,平均为2.03）,具有准铝-弱过铝质特点（铝饱和指数A/CNK=0.93~1.09,平均1.00）。稀土元 素配分曲线呈轻稀土强烈富集的典型“海鸥型”样式,具有明显的Eu负异常（δEu=0.44~0.47）。岩石富集大离子亲石元素 K,Rb,Ba,Th,亏损高场强元素Ti,Nb,Ta,具有壳源A型花岗岩的地球化学特征。对该花岗斑岩进行的锆石U-Pb LA-ICP-MS同位素年代测定获得了1 846±32 Ma的上交点年龄,说明花岗斑岩形成于古元古代而不是前人认为的中-新生 代,上奥陶统背锅山组砾屑灰岩实际上是沉积于古元古代花岗斑岩之上。结合区域地质资料研究结果表明华北地块西南缘 在古元古代时期处于强烈的伸展环境,这可能为古元古代贺兰坳拉槽向南延伸至六盘山南段提供了直接的岩石学证据。     

辽宁营口虎皮峪地区古元古代岩浆事件及地质意义

辽宁营口虎皮峪地区存在3期古元古代侵入岩浆活动:早期虎皮峪辽吉花岗岩成岩时代为2119±16Ma,富硅、富碱、低铝、低钙及负Eu异常显示其具有类似A型花岗岩的地球化学特征,非常低Sr高Yb的特点指示其形成压力很低,与减薄的地壳有关;第二期后松树沟奥长花岗岩成岩时代为1892±16Ma,富硅、富钠、高铝,Na2O/K2O1.35及无Eu异常或正Eu异常显示其具有埃达克质岩石的特征,中—高Sr低Yb的特点指示其形成压力较高、深度较大,与碰撞后加厚地壳底侵玄武岩的部分熔融有关;晚期南台子石英二长岩成岩时代为1850±11Ma,富碱(Na2O+K2O=11.32%~11.93%),里特曼指数δ=4.78~7.20,属碱性岩,低Sr低Yb的特点指示其形成压力中等,深度大概40~50km,是造山作用完成后板内伸展背景下的产物。上述3期岩浆事件对整个辽吉古元古代活动带的构造演化具有重要指示意义:早期辽吉花岗岩可能形成于辽吉古元古代活动带早期弧后伸展阶段;后松树沟奥长花岗岩则代表古元古代晚期碰撞后地壳加厚阶段的产物;南台子石英二长岩属后造山花岗岩,标志着辽东地区克拉通化的完成,开始进入后造山伸展演化阶段。