Groundwater recharge estimation using chloride,stable isotopes and tritium profiles in the sands of northwestern Senegal

A study of environmental chloride, deuterium, oxygen-18, and tritium in deep sand profiles (35 m) has been carried out in order to estimate their relative value for measuring average groundwater recharge. The investigation was located at a 0.1-km² site in Quaternary sands near the northwestern coast of Senegal in a zone of rainfed agriculture. By using a steady-state model for duplicate unsaturated zone chloride profiles, the long-term average recharge at the site was estimated to be 30 mm yr^–1 or around 10% of the average precipitation (290 mm). The chloride concentration of adjacent shallow groundwater was relatively uniform and comparable to the unsaturated zone average, while the spatial variability in the depth distribution of Cl^– in the unsaturated zone was considerable. Stable isotope (deuterium and oxygen-18) data show that there is some isotopic enrichment due to direct evaporation through the soil surface. The degree of heavy isotope enrichment is proportional to the extent of evaporative loss and there is good correspondance with the chloride enrichment. Nevertheless, stable isotopes cannot be used quantitatively to estimate the recharge. The excellent preservation of the peak in thermonuclear tritium in precipitation in the unsaturated zone at depths between 12 and 20 m enables an estimated annual recharge of 24 mm yr^–1 in this area to be calculated, using the piston flow model. Agreement therefore between Cl and³H as tools for recharge measurement is reasonable over the site.     

Using hydrogen,oxygen, and tritium isotopes to identify the hydrological factors contributing to landslides in a mountainous area,central Taiwan

Over a 1-year period, 343 samples, including precipitation, creek, pond, and groundwater, were collected from June 2003 to May 2004. Analyses were performed for stable oxygen and hydrogen isotope compositions. Selected samples were also analyzed for tritium. The goal was to identify possible hydrologic factors contributing to a severe landslide in the Li-Shan area, central Taiwan. The isotope characteristics indicate that groundwater from Fu-Shou-Shan farm located up-slope from the landslide area is a major source for slope groundwater, in addition to precipitation. The groundwater is mainly recharged by pond water at Fu-Shou-Shan farm. According to the calculation of a two-end member equation with δ ¹⁸O, the contribution of farm groundwater to slope groundwater is significantly higher than that of precipitation, up to a factor of five. The estimated drainage efficiency of the existing system is only 23%. Draining off the slope groundwater in the up-slope region to decrease farm groundwater flow into the slope area is a feasible strategy to effectively reduce the risk of landslide.     

Using tritium to document the mean transit time and sources of water contributing to a chain-of-ponds river system: Implications for resource protection

Documenting the interaction between groundwater and rivers is fundamental to understanding hydrological systems. While many studies have examined the location and magnitude of groundwater inflows to rivers, much less is known about the transit times of water in catchments and from where in the aquifer the groundwater originates. Resolving those questions is vital for protecting riverine ecosystems, assessing the impact of contamination, and understanding the potential consequences of groundwater pumping. This study uses tritium (³H) to evaluate the mean transit times of water contributing to Deep Creek (southeast Australia), which is a chain-of-ponds river system. ³H activities of river water vary between 1.47 and 2.91 TU with lower ³H activities recorded during cease-to-flow periods when the river comprises isolated groundwater-fed pools. Regional groundwater 1–2.5 km away from Deep Creek at depths of 7.5–46.5 m has ³H activities of between <0.02 and 0.84 TU. The variation in ³H activities suggest that the water that inflows into Deep Creek is dominated by near-river shallow groundwater with the deeper groundwater only providing significant inflows during drier periods. If the water in the catchment can be represented by a single store with a continuum of ages, mean transit times of the river water range between <1 and 31 years whereas those of the groundwater are at least 75 years and mainly >100 years. Alternatively the variation in ³H activities can be explained by mixing of a young near-river water component with up to 50% older groundwater. The results of this study reinforce the need to protect shallow near-river groundwater from contamination in order to safeguard riverine ecosystems and also illustrate the potential pitfalls in using regional bores to characterise the geochemistry of near-river groundwater.     

全球海洋环流模式中氚分布的模拟

氚（3H）作为一种重要的被动示踪物,经常被用于研究海洋中的物理过程及评估海洋环流模式的模拟性能。使用一个全球海洋环流模式（LICOM）来研究氚在海洋中的分布、存储和输送。模拟的全球氚通量表明,1975年之前氚主要由海气交换输入海洋,特别是在1963年,氚的气体交换输入约为降水输入的2.5倍,1975年之后两种方式的氚输入通量都大幅减少。比对GEOSECS（Geochemical Ocean Sections Study,1972～1978年）和WOCE （World Ocean Circulation Experiment,1989～1995年）大洋观测计划期间的观测资料发现,我们的模式很好地模拟出了氚的海表分布、水柱总量、经向分布以及次表层的高值信号,主要缺点在于模拟的氚向深层的穿透不足,特别是在全球的两个副热带地区,表现尤为明显,氚输入函数的不确定性和模式物理场描述的不足可能是造成误差的主要原因。模式给出的海洋中氚储存总量的结果与基于观测得到的结果比较吻合,如北太平洋海区：1973～1974年模拟结果约为20.4 kg,相同期间观测估计值为21.1±4.7 kg,1989～1995年模拟结果为20.7 kg,相同期间观测估计值为23.4±2.0 kg。氚在等密度面上高低纬的侧向通风明显,模式成功模拟出氚从中高纬的海表进入,沿等密度面向低纬的次表层输送,又经大洋环流和扩散分别向南半球和高纬输送的过程。     

Krypton-85 dating of shallow aquifer in Hebei Plain

The inert gas radioactive isotope 85Kr (with a half-life of 10.74 years), due to its stable physical and chemical properties, is an ideal tracer for shallow groundwater dating. In such a dating application, first the dissolved gas is extracted from groundwater in the field, then krypton is separated from the gas sample, and finally the isotopic abundance 85Kr/Kr will be determined by an ATTA instrument. According to the atmospheric input curve of 85Kr, the 85Kr age of groundwater is determined. We conducted 85Kr analysis in three wells in Zhengding County on the plains in front of the Taihang Mountains, and made a comparison with tritium (3H) method.     

Temporal variation of chemical and isotopic signals in major discharges of an alpine karst aquifer in Turkey: implications with respect to response of karst aquifers to recharge

Proper management of karst aquifers requires a better understanding of flow and transport mechanisms in these systems. Flow in karst aquifers is inherently very complex due to the non-linear and non-stationary relationship between recharge and discharge. Information on this relationship has been acquired for a large (1,000 km²), mountainous (>3,500 m asl) karst aquifer with a deep unsaturated zone (>2,000 m) in the Aladaglar mountain range of south-central Turkey. All major discharges from the aquifer, which drain almost all the recharge, have been observed periodically for specific electrical conductivity, tritium and oxygen-18 variations during a period of 12 months. Observations reveal that the system’s response to recharge depends strongly on the competition between the infiltration and drainage velocities. These velocities, which are controlled by variables such as the time of precipitation, time of infiltration, intensity, and continuity of recharge, determine the degree of dominance of different types of flow mechanisms in the aquifer. Bypass, well-mixed and piston flow mechanisms are used to explain the response of the aquifer to the spatio-temporal variations in recharge. It appears that the aquifer switches among these flow mechanisms depending on the prevailing recharge mode and the competition between infiltration and drainage velocities.     

STUDY ON RECHARGE OF GROUNDWATERS AND INTERRELATIONS BETWEEN VARIOUS WATERS BY MEANS OF ENVIRONMENTAL ISOTOPES

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Environmental tracer transport (H and SF6) in the saturated and unsaturated zones and its use in nitrate pollution management

An important quantity in groundwater protection is the residence time of water in an aquifer. It relates to both the travel time of a pollutant to arrive at a well and the time span required for self-purification of a polluted aquifer after removal of pollutant inputs. Time scales for aquifers can be gained from artificial tracer experiments or from environmental tracer data, the latter offering the only realistic alternative if time scales of years or decades have to be taken into account.

Different tracers show different time scales due to their different transport mechanisms especially in the unsaturated zone. While solute tracers are moved advectively with the seepage water, gas tracers pass the unsaturated zone diffusively through the air phase. Depending on the properties of the unsaturated zone (hydraulic properties, thickness) this difference in behavior can be used to separate the subsurface transport process into the unsaturated and the saturated parts.

In a field study in Germany, SF₆ and ³H were used as environmental tracers. Both have a relatively well-known input function. Interpretation of data from observation wells by a box model approach led to spatially and temporally varying residence times. This was an indication that the influence of the unsaturated zone could not be neglected. While the gas tracer SF₆ shows only residence times in the saturated zone, the tracer ³H reflects the whole travel time of water including both the unsaturated and saturated zones. Using a one-dimensional plug-flow model for the unsaturated zone combined with a detailed two-dimensional flow and transport model for the saturated zone leads to a holistic and consistent interpretation of the measured tracer concentrations. The observed pattern of old water under thick loess cover and younger water under areas where the fractured basalt aquifer crops out is reproduced after adjusting only two parameters: the effective porosity of the saturated aquifer and the product of field capacity and thickness of the unsaturated zone. While the effective porosity of the saturated zone is adjusted by means of the SF₆ data, the field capacity of the loess layer is adjusted by means of the ³H observations. The thickness of the unsaturated zone is deduced from geological and pedological maps. All flow data are obtained from a calibrated flow model, which is based on geological data, observed heads and pumping tests only.

The transport model for the saturated zone was calibrated by fitting the porosity by means of gaseous tracer concentrations (SF₆). The combined saturated–unsaturated zone model was then calibrated by fitting the field capacity of the unsaturated zone by means of ³H concentrations. With this model it was possible to verify the observed NO₃ concentrations at the drinking water wells and to develop predictions for their future development under various scenarios of fertilizer input reduction in specific areas.     

Tritium in ground water of the georgia piedmont: Implications for recharge and flow paths

Environmental tritium was measured in 33 natural water samples representative of precipitation, stream runoff, and groundwater (derived principally from production wells) within the Georgia Piedmont Province. Major ion analyses were used to assist in the interpretation of the tritium results. Tritium concentrations were significantly greater within shallow groundwater derived from the regolith (28–34 TU) and stream runoff (25–30 TU) than within recent rainfall (4–17 TU). Based upon the decay-corrected tritium input function, this probably indicates that at least some of the shallow water is stored within the regolith for a period of approximately 25 years. A ‘post-bomb’ component of recharge was present in all groundwater derived from production wells in the study area. Groundwater sampled from the bedrock aquifers was commonly less tritiated than either stream runoff or shallow water stored in the regolith. the lower tritium concentrations May, have resulted from the mixing of ‘pre-bomb’ water stored within the fractures or the transitional zone directly above the bedrock and modern water stored in the shallow regolith. the preponderance of modern water provides evidence that groundwater flow paths are areally restricted within this setting, probably confined to local surface water drainage basins. the residence time of groundwater in the Piedmont is limited by the lack of deep, gravity-driven regional flow and the localized vertical flow induced by pumping. the results of this study indicate that relatively small tritium concentration variations (10-20 TU) May, have regional hydrological significance in the southeastern Piedmont Province and similar settings.     

Detection of <Superscript>3</Superscript>H and <Superscript>85</Superscript>Kr in groundwater from arsenic-bearing crystalline bedrock of the Goose River basin,Maine

Presence of young groundwater (post-1950) in the Goose River basin is demonstrated with ³H and ⁸⁵Kr analyses. A total of 96 wells and four springs were sampled quarterly from 1999 to 2001 to determine the extent of any recent recharge and to what depth hydraulic continuity existed in the groundwatershed (33.3 km²). Recharge groundwater is less than 50 years in about 31% (³H) to 37% (⁸⁵Kr) of sampled wells and 75% of sampled springs. Young groundwater ages are recorded in wells up to 320 m in depth within fractured- and arsenic-bearing crystalline bedrock. Total arsenic 10 g L^–1 occurs significantly in drinking water with young groundwater flowing through the pumping well intervals. As_total occurs in 89% (⁸⁵Kr) to 93% (³H) of all wells with post-1950 groundwater ages. Young groundwater recharge and elevated geogenic arsenic were discovered only in the anatectic granitoids and migmatized country rock of the southwestern part of the Goose River basin.