Experimental diffusion of hydrogen into synthetic fluid inclusions in quartz

Abstract Quartz-hosted, synthetic CO₂-H₂O fluid inclusions behave as open systems with respect to diffusional transfer of hydrogen during laboratory-simulated metamorphic re-equilibration at 650, 750 and 825°C and 1.5 kbar total pressure with f_O2 defined by the C-CH₄ buffer. Microthermometry and Raman spectroscopy show that the initial CO₂-H₂O inclusions become CO₂-CH₄-H₂-H_2O
inclusions after diffusive influx of hydrogen from the reducing confining medium. Measurable changes are observed in inclusion compositions after only 15 days of re-equilibration, implying significant hydrogen mobility at still lower temperatures over geological time spans. Results of synthetic inclusion re-equilibrium experiments have profound implications for the interpretation of natural fluid-inclusion data; failure to account for potential hydrogen migration in inclusions from high-temperature geological environments may lead to erroneous estimates of P-T, and/or the compositions of metamorphic fluids.     

Natural gas generation model and its response in accumulated fluids in the Yinggehai basin

The generation of natural gases is much more complicated in comparison with liquid petro-leum in that natural gases could be generated from both humic and sapropelic organic matter at different stages and that natural gases could be organic and inorganic …     

国际地球自转服务(IERS)评介

回顾了建立国际地球自转服务(IERS)的历史过程,简述了IERS机构各部门的设置及其作用。着重介绍了IERS重建的理由和过程以及新IERS机构的组成。最后给出IERS成果对现有科学研究的作用和意义。     

The acute and chronic effects of wastes associated with offshore oil and gas production on temperate and tropical marine ecological processes

A review of the acute and chronic effects of produced formation water (PFW), drilling fluids (muds) including oil-based cutting muds, water-based cutting muds, ester-based cutting muds and chemical additives, and crude oils associated with offshore oil and gas production was undertaken in relation to both temperate and tropical marine ecological processes. The main environmental effects are summarized, often in tabular form. Generally, the temporal and spatial scales of these studies, along with the large levels of inherent variation in natural environments, have precluded our ability to predict the potential long-term environmental impacts of the offshore oil and gas production industry. A series of critical questions regarding the environmental effects of the offshore oil and gas production industry that still remain unanswered are provided for future consideration.     

吉林省油页岩勘探中聚合物钻井液防塌机理的试验研究与应用

在试验研究的基础上对比了无机聚合物硅酸盐和有机聚合物聚乙烯醇(PVA)、部分水解聚丙烯酰胺(PHPA)和非水解聚丙烯酰胺(PAM)的防塌能力;由试验得出吸附成膜的速度和保护膜的致密程度是决定钻井液体系防塌能力的关键因素;钻井液体系的防塌能力是无机聚合物和有机聚合物协同作用的结果;部分水解聚丙烯酰胺钻井液体系的防塌能力较非水解聚丙烯酰胺钻井液体系的防塌能力强。研制的无固相聚合物钻井液在吉林农安、伊通、舒兰和梅河口4个矿区近3 000 m的钻探施工中,孔壁稳定,孔内事故少,岩芯采取率达98%以上。     

Lithium isotope fractionation in the southern Cascadia subduction zone

We present lithium (Li) abundances and isotope compositions for a suite of anhydrous olivine tholeiites (HAOTs) and hydrous basalt-andesitic (BA) lavas from the Mt. Shasta and Medicine Lake regions, California. The values of δ⁷Li vary from + 0.9‰ to + 6.4‰ and correlate inversely with distance from the trench. These data are consistent with continuous isotope fractionation of Li during dehydration of the subducted oceanic lithosphere, an interpretation corroborated by uniformly high pre-eruptive H₂O contents in basaltic andesites accompanied by high Li, Rb, Sr, Ba and Pb abundances. The subduction-derived component that was added to these hydrous magmas is shown to be very similar beneath both Mt. Shasta and Medicine Lake volcanoes despite characteristically distinct Li isotope compositions in the magmas themselves. More evolved andesites and dacites from Mt. Shasta have δ⁷Li from + 2.8 to + 6.9‰ which is identical with the range obtained for HAOTs and BA lavas from Mt. Shasta. Therefore, Li isotopes do not provide evidence for any other crustal component admixed to Mt. Shasta andesites or dacites during magmatic differentiation and magma mixing in the crust.     

The long-time decay of rotating homogeneous flows over variable topography

The long-time decay of rotating, homogeneous flows over variable topography is analyzed by means of laboratory experiments and numerical simulations. The influence of the topography on the flow evolution is associated with stretching and squeezing effects on fluid columns as they experience changes in depth, and with viscous effects produced by the boundary condition at the solid bottom of the tank. In particular, experiments with a sine-shaped topography in one of the horizontal directions are analyzed by using two different basic flows. First, the evolution of dipolar vortices drifting across the topography while slowly decaying, is examined. The second set of experiments considers the evolution and decay of an initially circular vortex transforming into a tripolar structure. The experiments are well represented by numerical simulations based on a quasi-two-dimensional formulation with variable topography.     

地幔流体的交代作用——来自碱性正长岩及其深源岩石包体的证据

滇西玉龙县小桥头硅化霓辉正长斑岩中,含有较多镁铁-超镁铁质深源包体岩石。经岩相学和电子探针及扫描电镜分析发现,伴随交代蚀变,寄主岩和各类镁铁-超镁铁质包体岩石中,普遍发育沿粒间和矿物晶体裂隙或解理纹贯入或穿插的黑色不透明物质,主要由微晶硅酸盐矿物和磁铁矿组成。本文研究认为,硅酸盐矿物与磁铁矿在背散射电子图像中表现为熔离特征,这种在透光显微镜下呈黑色不透明的微晶固体,是引发交代蚀变、具熔浆流体特点和超临界流体性质的地幔流体交代作用的一种微观表现。     

Three-dimensional mapping of salt stores in the Murray-Darling Basin,Australia: 2. Calculating landscape salt loads from airborne electromagnetic and laboratory data

Salt is widespread in the Australian landscape – in soil, regolith and groundwater – leading to concerns that land management practices may be putting much agricultural land and important water resources at risk of salinisation. Defining the location and nature of salt stores is an important first step in understanding the processes leading to salinity of soils, streams and groundwater resources, and predicting areas that may be at risk. Airborne geophysics can define subsurface salt stores and mobilisation pathways. Airborne electromagnetics (AEM) can map the three-dimensional conductivity structure of the landscape but does not, intrinsically, quantify the amount of salt. Salinity, moisture content, porosity and mineralogy all contribute to the electromagnetic signal, and each can vary significantly throughout the landscape.In the Lower Balonne catchment, Queensland, the relationship between AEM and the amount of salt in the landscape was quantified using laboratory analyses of pore fluids from core samples. A general statistical relationship was established between AEM conductivity and salt load (defined as the product of pore fluid salinity, porosity and moisture content)—with a significant positive correlation although data were generally widely dispersed. Comparison of calculated salt load with borehole electromagnetic logs gives insight into the factors contributing to dispersion in the AEM data.The relationship transforms bulk conductivity to salt load in 5 m layers, allowing the generation of a three-dimensional map of the salt load. This is a powerful tool for identifying areas that may require monitoring and management interventions to reduce salinity risk. An example is given of salt loads beneath an established irrigation area in the Lower Balonne catchment, Queensland.     

滇-黔-桂微细浸染型金矿床时空分布与成矿流体来源研究

滇-黔-桂微细浸染型金成矿带处于滇-黔-桂裂谷中。金矿床分布与深大断裂存在依附性。金矿带基本展布于深大断裂限定的三角区内,金矿床则分布于深大断裂旁侧或其交叉部位。由幔源岩浆岩(超基性岩及玄武岩)和幔源矿物沿深大断裂分布可推断,深大断裂延伸较深,可达上地幔,属超壳深大断裂。金矿床分布不受地层层位的限制,金矿化具有多层位成矿性。铅、硫、碳、氢、氧同位素地球化学综合对比研究表明,成矿热液中的矿质、矿化剂和水具深源与浅源的混合特征。热液成矿期矿石中石英及萤石的电子自旋共振(ESR)定年结果为68.40±32.41Ma,表明本区金矿床的成矿可能发生在燕山晚期-喜山早期。