西秦岭温泉钼矿床成矿作用时限及其对斑岩型钼矿床系统分类制约

斑岩系统是一个涉及岩浆和热液作用的复杂系统,建立精细的斑岩系统成因模型对于寻找更为丰富的金属矿产尤为重要,成矿作用时限是建立成因模型和指导矿产勘查的关键。温泉钼矿床是西秦岭造山带内与晚三叠世花岗岩有关的斑岩型钼矿床,其在西秦岭造山带的独特发育蕴含印支期斑岩成矿作用、大陆地壳演化及矿产勘查关键科学问题。钼矿体主要赋存于温泉复式岩体Ⅱ单元和Ⅲ单元的黑云母二长花岗斑岩和似斑状二长花岗岩中,钼以细脉和浸染状矿化形式产出。赋矿岩石单元锆石U-Pb年龄为224.6±2.5Ma到216.2±1.7Ma,Ⅱ和Ⅲ单元分别侵位于~223Ma和~217Ma,持续约8Myr。辉钼矿Re-Os年龄为212.7±2.6Ma到215.1±2.6Ma,暗示晚三叠世钼成矿作用与花岗质岩浆作用密切时空关系,且成矿年龄稍晚,反映钼矿化主要发生在岩浆作用晚期阶段。成岩、成矿作用发生于华北板块与华南板块全面对接后秦岭造山带构造体制由碰撞到后碰撞的转折阶段,响应南秦岭变质变形、勉-略洋盆闭合及大别-苏鲁超高压岩石板片折返统一地质事件。黑云母K-Ar年龄为207~226Ma,可能反映~223Ma和~208Ma的岩体冷却事件和~216Ma的岩浆-热液成矿作用。锆石U-Pb、辉钼矿Re-Os和黑云母K-Ar多元同位素定年系统准确刻画岩体侵位、热液成矿与冷却事件上有所重叠,岩浆-热液分异演化充分,且具有较高的冷却速率,精确厘定温泉斑岩系统岩浆活动的"多期性"(复式岩体)、成矿事件的"瞬时性"(~214Ma)和成矿作用的"持续性"(~8Myr)。同时,系统对比全球典型斑岩钼(铜)矿床成矿动力学背景,细化分类方案,即产于挤压背景的大洋俯冲和大陆碰撞环境矿床及产于伸展背景的后碰撞、陆缘弧后和板内裂谷环境矿床。明确在大洋俯冲→大陆碰撞→后碰撞→板内裂谷旋回的四个阶段均可以产生规模的斑岩型钼(铜)矿床,且挤压向伸展过渡的构造体制转换尤其是大型矿床形成的有利环境。     

北阿尔金地区米兰红柳沟蛇绿岩的岩石学特征和SHRIMP定年

米兰红柳沟蛇绿岩是北阿尔金蛇绿岩带中发育和保留最好的蛇绿岩,主要由地幔橄榄岩、镁铁-超镁铁质堆晶杂岩、岩墙群和基性熔岩等组成.它们以规模不等的构造岩块产出,大者长十余km,宽近1km,组成一条近100km长的蛇绿混杂岩带.地幔橄榄岩以方辉橄榄岩为主,有少量纯橄岩,主要由橄榄石(Fo=91.2～92.7),斜方辉石(En=93-98)和少量单斜辉石(En=46)组成;副矿物尖晶石Cr#为43～69(平均55),Mg#为43～64(平均58),表现出深海橄榄岩(Abyssal peridotite)和俯冲带环境(SSZ)橄榄岩成分特点.深成堆晶岩主要由异剥橄榄岩-橄榄二辉石岩-(橄榄)辉石岩-辉长岩-斜长岩,该组合的堆晶岩通常被认为是SSZ构造背景的产物.席状岩墙群的岩石成分与熔岩一致,其TiO2(1%～1.5%)和低含量的K2O<0.3%和P2O5表明具有MORB型的岩石特征,并得到了不相容元素和LREE平坦型和亏损型的球粒陨石标准化模型等证据的支持.该地区另存在一套高Tj的洋岛型拉斑玄武岩.两类熔岩的存在,以及地幔橄榄岩和堆晶岩的不同特征,表明米兰红柳沟蛇绿岩组合可能来自不同构造背景.带中与洋壳俯冲有关的蓝片岩和榴辉岩组成的高压变质带的存在,以及与俯冲碰撞有关的不同类型花岗岩类的产出,表明米兰红柳沟蛇绿混杂岩带代表了一个复杂的板块缝合带.蛇绿岩中辉长岩的锆石SHRIMP年代为479±8Ma,这是获得的第一个北阿尔金蛇绿岩的锆石SHRIMP U-Pb同位素年龄,认为代表蛇绿岩的形成时代.因此,北阿尔金缝合带无论在年龄和特征等方面,均可以与阿尔金断裂带东部的北祁连缝合带对比,证实两个带曾经是一个带,被阿尔金断裂左旋错断了约400km.     

U-Pb Zircon Dating of the Granitic Conglomerates of the Hutuo Group： Affinities to the Wutai Granitoids and Significance to the Tectonic Evolution of the Trans-North China Orogen

1 Introduction The North China Craton (NCC) is considered to be the oldest and largest cratonic block in China. Recent studies to gain understanding of basement architecture of the NCC has led to its division into the Western and Eastern Blocks, separated by a N-S trending Paleoproterozoic Trans-North China Orogen (TNCO) (Fig. 1; Zhao et al., 1998, 1999a, 2000a, 2001a; Wilde et al., 2002). Although there is now abroad consensus that the final assembly of the NCC was completed by th…     

Two belts of HTLP sub-regional metamorphism in the New England Orogen,eastern Australia: occurrence and characteristics exemplified by the Wongwibinda Metamorphic Complex

Abstract

Two north–south-trending belts of high-temperature–low-pressure (HTLP) sub-regional metamorphism have been identified in the New England Orogen of eastern Australia. Metamorphic complexes in the ～1300?km long Early-Permian Inland belt have ages ca 300–290?Ma, and those of the ～400?km long Mid-Permian Coastal belt ca 275–270?Ma. These periods correspond to the beginning and end of an extended (early–mid Permian) phase of subduction rollback and crustal thinning in eastern Australia. This paper describes and incorporates recent work on the Wongwibinda Metamorphic Complex in the southern New England Orogen as a basis for comparison with thirteen other HTLP sub-regional occurrences within the orogen. These are described in as much detail as is currently available. Some outcrops of HTLP rocks in difficult terrain have been subject to limited study and only conditional comparisons can be made. However, a significant number of characteristics shared between the complexes including: their location at the higher-temperature end of broad areas of very low-grade to greenschist facies metamorphic rocks, indicative of tilted crustal blocks; their association with major shear zones; the presence of migmatite at the high-temperature end of a steep metamorphic field gradient; the presence of two-mica granite formed by the melting of the local sedimentary pile; and temporal association with S-type granites; imply a common extension-related mechanism of formation for these HTLP belts. The connection with major faults and shear zones suggests the belts trace major crustal-scale extensional structures that migrated eastwards from ca 300 to 270?Ma.

1. KEY POINTS

2. Two previously undocumented belts of HTLP subregional metamorphism are identified within the NEO.

3. Available dating indicates that metamorphism occurred along the belts at the beginning and end of a major early–mid Permian extensional phase in eastern Gondwana/Australia.

4. The characteristics of the HTLP complexes including their association with shear zones indicates they may delineate major loci of extension.

     

北祁连黑矿型和塞浦路斯型硫化物矿床容矿火山岩的物质来源与形成环境

文章以白银厂石英角斑岩和石居里富钠玄武岩为代表,对产于北祁连造山带的"黑矿型"和"塞浦路斯型"铜多金属块状硫化物矿床的容矿火山岩做了系统的常量元素、微量元素、稀土元素及锶、钕、铅同位素分析。结果表明,这2种火山岩均表现出俯冲带岩浆作用的特征。所不同的是,白银厂"黑矿型"块状硫化物矿床容矿火山岩形成于活动大陆边缘的陆缘弧环境;石居里"塞浦路斯型"硫化物铜矿床形成于大洋板块内部的洋生弧环境。与各自的形成环境相对应,白银厂的石英角斑岩来源于原生地幔在俯冲板片流体参与下的部分熔融,岩浆在上升侵位过程中有部分大陆地壳物质混入。石居里的富钠玄武岩同样也是产生于原生地幔在板片流体作用下的部分熔融,但没有遭受陆壳物质混染。     

Relics of the Mozambique Ocean in the central East African Orogen: evidence from the Vohibory Block of southern Madagascar

The Vohibory Block of south‐western Madagascar is part of the East African Orogen, the formation of which is related to the assembly of the Gondwana supercontinent. It is dominated by metabasic rocks, which have chemical compositions similar to those of recent basalts from a mid‐ocean ridge, back‐arc setting and island‐arc setting. The age of formation of protolith basalts has been dated at 850–700 Ma by U–Pb SHRIMP analysis of magmatic cores in zircon, pointing to an origin related to the Neoproterozoic Mozambique Ocean. The metabasic rocks are interpreted as representing components of an island arc with an associated back‐arc basin. In the early stage of the Pan‐African orogeny, these rocks experienced high‐pressure amphibolite to granulite facies metamorphism (9–12 kbar, 750–880 °C), dated at 612 ± 5 Ma from metamorphic rims in zircon. The metamorphism was most likely related to accretion of the arc terrane to the margin of the Azania microcontinent (Proto‐Madagascar) and closure of the back‐arc basin. The main metamorphism is significantly older than high‐temperature metamorphism in other tectonic units of southern Madagascar, indicating a distinct tectono‐metamorphic history.     

Poly-orogenic multi-stage metamorphic evolution inferred via P–T pseudosections: An example from Aspromonte Massif basement rocks (Southern Calabria, Italy)

The metamorphic evolution of a key sector of the western Mediterranean internal Alpine orogenic belt (southern Calabrian Peloritani Orogen) is identified and described by means of P–T pseudosections calculated for selected metapelite specimens, showing evidence of multi-stage metamorphism.Attention focused on the two lowermost basement nappes of the Aspromonte Massif (southern Calabria), which were differently affected by poly-orogenic multi-stage evolution. After a complete Variscan orogenic cycle, the upper unit (Aspromonte Peloritani Unit) was involved in a late-Alpine shearing event. In contrast, the several underlying metapelite slices, here grouped together as Lower Metapelite Group, show exclusive evidence of a complete Alpine orogenic cycle.In order to obtain reliable P–T constraints, an integrated approach was employed, based on: a) garnet isopleth thermobarometry; and b) theoretical predictions of the P–T stability fields of representative equilibrium assemblages. This approach, which takes into account the role of the local equilibrium volumes in controlling textural developments, yielded reliable information about P–T conditions from early to peak metamorphic stages, as well as estimates of the retrograde trajectory in the pseudosection P–T space.According to inferred detailed P–T paths, the evolution of the Aspromonte Peloritani Unit is characterised by a multi-stage Variscan cycle, subdivided into an early crustal thickening stage with P–T conditions ranging from 0.56 ± 0.05 GPa at 570 ± 10 °C to 0.63–0.93 GPa at 650–710 °C (peak conditions) and evolving to a later crustal thinning episode in lower P–T conditions (0.25 GPa at 540 °C), as documented by the retrograde trajectory.Conversely, the prograde evolution of the rocks of the Lower Metapelite Group shows evidence of a HP-LT early Alpine multi-stage cycle, with P–T evolving from 0.75–0.90 GPa at 510–530 °C towards peak conditions, with pressure increasing northwards from 1.12 ± 0.02 GPa to 1.24 ± 0.02 GPa, and temperatures of 540–570 °C.A late-Alpine mylonitic overprint affected the rocks of both the Aspromonte Peloritani Unit and the Lower Metapelite Group. This overprint was characterised by an initial retrograde decompression trajectory (0.75 ± 0.05 GPa at 570–600 °C), followed by a joint cooling history, ranging from 0.38 ± 0.14 at temperature from 450 to 520 °C.These inferred results were then used: a) to interpret the Lower Metapelite Group as a single crystalline basement unit exclusively affected by a complete Alpine orogenic cycle, according to the very similar features of P–T paths, comparable petrography and analogous structural characteristics; b) as a tool for more reliable correlations between the Aspromonte Massif, the other Calabrian terranes and the north African Orogenic Complexes. They may therefore consider a contribution to the geodynamic modelling of the western Mediterranean.     

喜马拉雅造山带晚中新世麻迦淡色花岗岩的构建机制

在北喜马拉雅萨迦片麻岩穹窿西南侧发育有麻迦淡色花岗岩体,出露于南北向申扎—定结裂谷正断层的下盘,属一处较大规模的晚中新世淡色花岗岩体。该岩体具有较均一的元素和同位素(Sr和Nd)组成,但与多数喜马拉雅淡色花岗岩相比,具有异常高的(~(87)Sr/~(86)Sr)_i比值(0.85033~0.85034)和异常低的_(εNd)(t)值(-19.26~-18.30)组成,指示其部分熔融源区有更成熟古老地壳物质的参与。麻迦淡色花岗岩SHRIMP锆石U-Pb定年结果显示:1该岩体主要记录了至少两阶段岩浆结晶作用,分别发生在11.6±0.2 Ma和9.6±0.2 Ma;2个别13.8~16.0 Ma的岩浆作用年龄;3多数锆石继承核年龄分布于泛非期,少数年龄为中元古代(1558~1584 Ma)。在麻迦淡色花岗岩体南侧约40km处的日玛那穹窿,同位于申扎—定结南北向正断层的下盘,出露有大量原岩年龄为古元古代的日玛那糜棱岩,元素地球化学特征上类似于变泥质岩,显示高SiO_2(70.6%~74.6%),Al_2O_3(12.3%~14.0%),K_2O(4.22%~4.93%),A/CNK(1.50~1.58)和K_2O/Na_2O(1.42~2.18),代表了部分熔融源区可能存在的古老地壳物质岩石单元。因此,以麻迦淡色花岗岩为代表的北喜马拉雅晚中新世地壳深熔作用可能与青藏高原后碰撞阶段东西向伸展作用相关,泛非期变泥质岩及少量日玛那糜棱岩所代表的更古老岩石单元在16.0 Ma开始发生部分熔融,并在11.6 Ma至9.6 Ma之间达到深熔作用峰期,熔体活动可能持续了~2myr,以岩脉汇聚的形式延南北向正断层上升,构成侵位至北喜马拉雅特提斯沉积岩系之中的晚中新世麻迦淡色花岗岩体。     

Geochemistry of the Batang Group in the Zhaokalong Area,Yushu, Qinghai: Implications for the Late Triassic Tectonism in the Northern Sanjiang Region,China

The Batang Group in the Zhaokalong area not only hosts an important Fe-Cu polymetallic deposit but also reveal important insights for the Late Triassic tectonism in the northern Sanjiang region. In order to delineate the tectonic setting and evolutionary process of the paleo arc-basin system, geochemical studies on the Batang Group strata have been carried out. The results suggest that andesite in the Zhaokalong area mainly belongs to the tholeiite series and is characterized by obvious fractionation of LREE and HREE, enrichment in LILE and depletion in HFSE, and a distinctly elevated δ~(34)SCDT average of 10.5‰. The sandstone is classified as lithic sandstone, which is also characterized by obvious fractionation of LREE and HREE, as well as weak negative Ce and Eu anomalies. The limestone displays positive Eu anomalies, with δ~(13)CPDB ranging from-1.3‰ to 4.4‰ and δ~(18) OSMOW ranging from 14.6‰ to 22.5‰. These results indicate that the andesite has a dual signature of both arc andesite and rift volcanic rocks, whereas the sandstone may be formed in an active continental margin, and the limestone could be deposited in a weak oxidizing shallow sea. The sandstone in the Zhaokalong area represents sedimentation in a platform slope facies, corresponding to the main stage of the Jinshajing oceanic basin subduction during the middle period of Late Triassic. The continental arc volcanic activity resulted from subsequent strengthened subduction, forming the andesite in the North Qiangtang backarc basin. Afterwards, the limestone was formed after the cessation of magmatic activity. The information gleaned from the Batang Group strata helped constrain the evolution of the paleo-Jomda island arc and Jinshajiang oceanic subduction in the Late Triassic.     

A curious case of agreement between conventional thermobarometry and phase equilibria modelling in granulites: New constraints on P–T estimates in the Antarctica segment of the Musgrave–Albany–Fraser–Wilkes Orogen

The Windmill Islands region in Wilkes Land, east Antarctica, preserves granulite facies metamorphic mineral assemblages that yield seemingly comparable P–T estimates from conventional thermobarometry and mineral equilibria modelling. This is uncommon in granulite facies terranes, where conventional thermobarometry and phase equilibria modelling generally produce conflicting P–T estimates because peak mineral compositions tend to be modified by retrograde diffusion processes. In situ U–Pb monazite geochronology and calculated metamorphic phase diagrams show that the Windmill Islands experienced two phases of high thermal gradient metamorphism during the Mesoproterozoic. The first phase of metamorphism is recorded by monazite ages in two widely separated samples and occurred at c. 1,305 Ma. This event was regional in extent, involved crustally derived magmatism and reached conditions of ~3.2–5 kbar and 690–770°C corresponding to very high thermal gradients of >150°C/kbar. The elevated thermal regime is interpreted to reflect a period of extension or increased extension in a back‐arc setting that existed prior to c. 1,330 Ma. The first metamorphic event was overprinted by granulite facies metamorphism at c. 1,180 Ma that was coeval with the intrusion of charnockite. This event involved peak temperatures of ~840–850°C and pressures of ~4–5 kbar. A phase of granitic magmatism at c. 1,250–1,210 Ma, prior to the intrusion of the charnockite, is interpreted to reflect a phase of compression within an overall back‐arc setting. Existing conventional thermobarometry suggests conditions of ~4 kbar and 750°C for M₁ and 4–7 kbar and 750–900°C for M₂. The apparent similarities between the phase equilibria modelling and existing conventional thermobarometry may suggest either that the terrane cooled relatively quickly, or that the P–T ranges obtained from conventional thermobarometry are sufficiently imprecise that they cover the range of P–T conditions obtained in this study. However, without phase equilibria modelling, the veracity of existing conventional P–T estimates cannot be evaluated. The calculated phase diagrams from this study allow the direct comparison of P–T conditions in the Windmill Islands with phase equilibria models from other regions in the Musgrave–Albany–Fraser–Wilkes Orogen. This shows that the metamorphic evolution of the Wilkes Land region is very similar to that of the eastern Albany–Fraser Orogen and Musgrave Province in Australia, and further demonstrates the remarkable consistency in the timing of metamorphism and the thermal gradients along the ~5,000 km strike length of this system.