Zoned quartz and feldspar phenocrysts of the Upper Carboniferous eastern Erzgebirge volcano-plutonic complex were studied by cathodoluminescence and minor and trace element profiling. The results verify the suitability of quartz and feldspar phenocrysts as recorders of differentiation trends, magma mixing and recharge events, and suggest that much heterogeneity in plutonic systems may be overlooked on a whole-rock scale. Multiple resorption surfaces and zones, element concentration steps in zoned quartz (Ti) and feldspar phenocrysts (anorthite content, Ba, Sr), and plagioclase-mantled K-feldspars etc. indicate mixing of silicic magma with a more mafic magma for several magmatic phases of the eastern Erzgebirge volcano-plutonic complex. Generally, feldspar appears to be sensitive to the physicochemical changes of the melt, whereas quartz phenocrysts are more stable and can survive a longer period of evolution and final effusion of silicic magmas. The regional distribution of mixing-compatible textures suggests that magma mingling and mixing was a major process in the evolution of these late-Variscan granites and associated volcanic rocks.
Quartz phenocrysts from 14 magmatic phases of the eastern Erzgebirge volcano-plutonic complex provide information on the relative timing of different mixing processes, storage and recharge, allowing a model for the distribution of magma reservoirs in space and time. At least two levels of magma storage are envisioned: deep reservoirs between 24 and 17 km (the crystallisation level of quartz phenocrysts) and subvolcanic reservoirs between 13 and 6 km. Deflation of the shallow reservoirs during the extrusion of the Teplice rhyolites triggered the formation of the Altenberg-Teplice caldera above the eastern Erzgebirge volcano-plutonic complex. The deep magma reservoir of the Teplice rhyolite also has a genetic relationship to the younger mineralised A-type granites, as indicated by quartz phenocryst populations. The pre-caldera biotite granites and the rhyodacitic Schönfeld volcanic rocks represent temporally and spatially separate magma sources. However, the deep magma reservoir of both is assumed to have been at a depth of 24–17 km. The drastic chemical contrast between the pre-caldera Schönfeld (Westfalian B–C) and the syn-caldera Teplice (Westfalian C–D) volcanic rocks is related to the change from late-orogenic geotectonic environment to post-orogenic faulting, and is considered an important chronostratigraphic marker. 相似文献
Changes in the urban environment of Dhaka City have been evaluated from the geochemical compositions of bottom sediments from two lakes, Gulshan-1 and –2. Abundances of Pb, Zn, Fe2O3 and total sulfur in a Gulshan-1 core gradually increase toward the sediment–water interface. Three stages of condition change can be recognized in Gulshan-1, based on trace metal concentration patterns. The basal Stage I corresponds to background Dhaka sedimentation, whereas gradual increase in Stage II represents the beginning of pollution. Marked increases in Pb and Zn in Stage III reflect rapid urban development and increased emissions to the atmosphere. The condition of the Dhaka environment is compared to that of Japan based on Zn–Fe2O3 and Pb–Fe2O3 relations. Zn–Fe2O3 ratios in Stage I Dhaka sediments are similar to normal Japanese sediments, whereas Stage II data lie on the same trend as Japan urban sediments. Dhaka Stage III samples have greater Zn:Fe2O3 ratios than Japanese urban sediments, suggesting Zn pollution from poorly-controlled industrial sources. In contrast, the Dhaka Pb–Fe2O3 trend lies between normal and urban Japanese sediments. Although vehicle emissions in Dhaka are now significant, the data suggest that Pb pollution from this source remains in its early stages. 相似文献
This paper describes the influence of siliceous and iron-rich calcic low-temperature hydrothermal fluids (LTHF) on the mineralogy and geochemistry of the Late Permian No. 11 Coal (anthracitic, Rr=2.85%) in the Dafang Coalfield in northwestern Guizhou Province, China. The No. 11 Coal has high contents of vein ankerite (10.2 vol.%) and vein quartz (11.4 vol.%), with formation temperatures of 85 and 180 °C, respectively, indicating that vein ankerite and vein quartz were derived from low-temperature calcic and siliceous hydrothermal fluids in two epigenetic episodes. The vein quartz appears to have formed earlier than vein ankerite did, and at least three distinct stages of ankerite formation with different Ca/Sr and Fe/Mn ratios were observed.The two types of mineral veins are sources of different suites of major and trace metals. Scanning electron microscope and sequential extraction studies show that, in addition to Fe, Mg, and Ca, vein ankerite is the dominant source of Mn, Cu, Ni, Pb, and Zn in the coal, and the contents of these five elements are as high as 0.09% and 74.0, 33.6, 185, and 289 μg/g, respectively. In contrast, vein quartz is the main carrier mineral for platinum-group elements (PGEs) Pd, Pt, and Ir in the coal, and the contents of Pd, Pt, and Ir are 1.57, 0.15, and 0.007 μg/g, respectively. Sequential extraction showed a high PGE content in the silicate fraction, up to 10.4 μg/g Pd, 1.23 μg/g Pt, and 0.05 μg/g Ir, respectively. It is concluded that the formation of ankerite and quartz and the anomalous enrichment of trace elements in the No. 11 Coal in the Dafang Coalfield, Guizhou, result from the influx of calcic and siliceous low-temperature hydrothermal fluids. 相似文献
Coastal uses and other human activities have inevitably impinged on the Gulf environment; therefore, these regions require continuous monitoring. The investigated area covered the maximum fragments of Dubai coastal region in the Arabian Gulf. The determination of major oxides and trace metal concentrations in Dubai sediments revealed three heavily and moderately contaminated regions. One is in the far northeastern part at Al-Hamriya Sts 1–3 and contaminated by Fe, Cu, Pb, and Zn; the second is in the mid-northeastern part at Dry Docks and contaminated by Cu, Ni, Pb, and Zn; and finally, the third is in the near southwestern part at Dubal and contaminated by Fe, Mg, Cr, Ni, and Zn. Al-Hamriya St 3 represented the highest values of Cu, Pb, and Zn, whereas Dubal exhibited the maximum values of Fe, Mg, Ba, Cr, Mn, Ni, and V. The anthropogenic discharge and natural deposits are the main sources of contamination. In general, all trace and major elements showed the minimal levels at Jebel Ali Sanctuary (Sts 11, 12, 13) except for Sr and Ca, which showed their maximum values. The highest concentrations of Ca and Sr are mainly attributed to carbonate gravel sands and sands, which cover most stations. Each of V and Ni showed negative correlation with TPH, which may be indicated that the source of oil contamination in the region is not related to crude oil but mostly attributable to anthropogenic sources. The significant positive correlation, which was found between trace metals and TOC indicates that organic matter plays an important role in the accumulation of trace metals in case of Cu, Zn, and Pb. 相似文献
Geochemical and isotopic analyses of the Cretaceous–Paleogene (K/Pg) boundary deposits were conducted at the Caravaca section (External Subbetic, southeast of Spain) in order to evaluate the recovery of the macrobenthic tracemaker community and the bioturbational disturbance. Samples from the infilling material of several lower Danian dark-colored trace fossils (Chondrites, Planolites, Thalassinoides and Zoophycos) located in the uppermost 8-cm of the light upper Maastrichtian strata, as well as samples from the host sedimentary rock of these trace fossils, were analyzed and compared with data from the lower Danian deposits. The values of element ratios indicative of extraterrestrial contamination (Cr/Al, Co/Al and Ni/Al) are higher in the infilling trace fossil material than in the upper Maastrichtian and lower Danian deposits, which suggests a contribution of the ejecta layer. Regarding the isotope composition, the δ13C values are lower in the infilling material than in the Maastrichtian host sedimentary rocks surrounding the traces, while the δ18O are higher in the infilling material. The geochemical and isotopic compositions of the infilling material evidence the unconsolidated character of the sediment, including the red boundary layer. Softground conditions confirm a relatively rapid recovery by the macrobenthic tracemaker community, starting a few millimeters above the K/Pg boundary layer. The mixture of the infilling material of the trace fossils moreover reveals a significant macrobenthic tracemaker activity affecting K–Pg boundary transition sediments that may have significantly altered original signatures. 相似文献
An analysis of lower Barremian invertebrate trace fossils at the El Hoyo dinosaur tracksite (Teruel, Spain) was conducted in order to interpret the macrobenthic tracemaker community and the palaeoenvironmental conditions during bioturbation. Abundant bioturbation structures are characterized by meniscate, cylindrical, straight to sinuous, unbranched epichnia, showing the absence of lining, mantle and longitudinal striations. These structures are included in the ichnogenus Taenidium. Burrow width, distance between menisci, type of their fill, and general shape, allow for identification of the ichnospecies Taenidium serpentinum and T. barretti. Dominance to near exclusiveness of Taenidium in the invertebrate trace fossil assemblage suggests assignation to the Scoyenia ichnofacies. This agrees with the presence of vertebrate tracks. Accordingly, a transitional zone between terrestrial and nonmarine aquatic environments, i.e., floodplain areas adjacent to rivers and affected by low energy conditions, could correspond to the El Hoyo site. The pervasive ichnofabric of Taenidium reveals an opportunistic behaviour of the tracemaker, bioturbating rapidly after deposition; bioturbation took place in moist to wet substrates—softgrounds—in shallow tiers, during favourable yet episodic conditions. The opportunistic strategy might owe to a rapid accumulation of nutrients buried within the sediment during alluvial discharges. After bioturbation, minor erosions during fluvial discharges or subaerial exposure may have caused differences in the preservation of the Taenidium. 相似文献