Distribution and fluxes of metals in the St. Lawrence River from the outflow of Lake Ontario to Québec City

Six anchor stations in the St. Lawrence River from the outflow of Lake Ontario to Quebec City, were occupied for ca. 24 hours in June 1987 during low flow conditions. Samples of water and suspended particulate matter were separated by continuous-flow centrifugation, and were collected every two hours.During this sampling period, fluxes of dissolved forms of zinc, copper and nickel increased in Lac St. François and downstream relative to the sum of the fluxes for the two upstream stations at the outflow of Lake Ontario. Increases in the flux of dissolved zinc and copper were pronounced below Montreal and above Lac St. Pierre. For particulate forms of metals, all five metals show that there are significant inputs in the section of the St. Lawrence River between Lac St. François and the station just above the entrance to Lac St. Pierre.The average concentrations of dissolved cadmium, lead, zinc, copper and nickel ranged from 7–23 ng/l; 9–35 ng/l; 0.434–0.939 g/l; 0.15–0.89 g/l and 0.58–1.12 g/l respectively.Regression analysis of the dissolved and particulate metal concentrations suggests that the concentration of dissolved cadmium, lead, zinc and nickel can be predicted from the regression equation and the determination of particulate metal concentration. This prediction appears to be independent of the suspended particulate matter concentration which varies from ca. 1 to 10 mg/l from the outflow of Lake Ontario to Québec City.     

藏南白垩系黑-红层沉积岩有机质组成分布特征

对藏南江孜县床得剖面白垩系黑层和红层沉积岩进行的有机地球化学研究表明,黑层有机碳含量高于红层5～10倍,红层和黑层饱和烃主峰碳数分别为nC25和nC23;黑层和红层沉积有机质的母质来源都以水生植物和菌藻类等低等生物为主,陆源有机质的输入非常有限;但饱和烃的分布和主峰碳数的差异可能反映了有机母源物质在种群方面的差异,而这种差异可能主要是水体温度存在差异造成的,即红层发育时期水体温度可能高于黑层沉积时期.而在高温度条件下,水生生物和陆生植物的生长发育受到限制,造成原始有机质产率和有机质沉积保存量低可能是红层沉积岩形成的主要原因.     

Impact of lightning on organic matter-rich soils: influence of soil grain size and organic matter content on underground fires

A detailed study was carried out on a piece of land that had been struck by lightning during the violent rainstorm that raged over the Island of S?o Miguel (Azores Archipelago) in late October 2006. Temperature and gas measurements (CO₂, CO, H₂S and CH₄) were performed in four study trenches, dug in an area of ∼3 m², where an underground fire had been initiated by the impact with a lightning stroke, followed by the emission of a column of gases and smoke. The soil under study was originally a well-pedogenized about 80 cm thick bed, made of volcanic clayey to silty tephra fallouts and contained 5.5–9.7% of organic matter. The underground fire was monitored for one week and revealed a peak release of 404 ppm CO and 3.4% CO₂ originating from a horizon located about 45 cm under the soil surface. Measurements of temperature, performed one week after the impact, indicated a maximum value of 326°C inside the soil, while 516.5°C were measured on the surface of a lava block interred about 20 cm under the surface. Subsequently, a stratigraphic and sedimentologic study proved the role of the grain-size of the soil and of the organic matter content of the different horizons of the impact area, in determining the ratio between anoxic/oxidised combustion conditions and in the progress of the process itself. It was also noticed that combustion was not total all over in the soil bed and that the process had slightly migrated toward SW during the observation period. The combustion process went on for about ten days, in spite of several other violent rainstorms, until it was artificially extinguished through the excavations made to obtain study trenches. This particular circumstance evidenced the potential natural hazard represented by this kind of atmospheric event, especially in a land where the volcanic nature of the soil may easily mislead inexperienced observers and, consequently, delay proper action.     

粗颗粒悬移质测验误差分析

本文根据流速与含沙量分布,研究了悬移质积点法对粗颗粒含沙量测验误差.首先指出无论从输沙率还是从悬浮高度看,粗颗粒悬移质集中于河底,致使水文测验中的一些测验方法(如一点法、二点法、三点法等)带有较大的误差.进而分析了各种测法对粗颗粒的相对误差,并且随着颗粒变粗,误差愈来愈大,以致不能接受.这种情况在水库下游河道冲刷过程中,会在一定程度上出现,必须重视研究和调整测验方法.最后通过与长江委水文局在沙市及监利两水文站试验结果对比,证明本文理论上的分析是可信的.     

渤海中南部悬浮物海洋调查资料分析

对于悬浮物 (SPM)的研究目前已引起诸多学者关注。作者利用 1998和 1999年的中德合作海洋调查所获得的资料进行分析。主要进行三个方面的工作 :研究悬浮物与透明度的关系 ;研究悬浮物与浊度的关系 ;估计海底剪切速度。并为研究悬浮物输运提供资料和作前期研究     

秦山核电站邻近水域环境化学要素特征

本文根据1989年4、7、10月和1990年1月(春、夏、秋、冬)秦山核电站邻近水域零点生态调查和水质监测结果的资料整理而成。经研究证明,该海域是河-海混合水域,盐度从小于3至12之间变化,受杭州湾的涌潮、风浪的影响,水体混合比较强烈,悬浮颗粒物质的含量比长江口高。由于该测区所处的海岸、海底地形,生态系统、径流输入以及水体交换状况不同,故其海洋学特征也不相同。     

珠江三角洲晚第四纪沉积物的有机地球化学特征

本文根据有机地球化学资料,首次研究和探讨了珠江三角洲晚第四纪沉积物中有机质丰度和可溶有机质的组成特征。现代沉积物有机质丰度,有机碳为0.58％,氯仿沥青“A”为210ppm,烃含量为33.8ppm;钻孔中有机碳为0.77％,氯仿沥青“A”为253ppm,烃含量为16.4ppm。从有机质组成、红外吸收光谱特征、δ~(13)C、干酪根H/C原子比,均表现为陆生植物为主,水生生物为铺,为腐殖型或腐泥—腐殖型的母质类型。     

Analysis of estuarine colour components during non-monsoon period through Ocean Colour Monitor

Simultaneous acquisition of water samples, radiance and irradiance measurements were carried out from 40 stations in the Mandovi–Zuari estuaries during February to May 2002. From the samples collected, inherent and apparent optical properties (IOP and AOP) such as absorption coefficient (a), upwelling diffuse attenuation coefficient (k_u) and subsurface reflectance (R) were derived. Using these optical properties, radiative transfer at each water column is examined. On the basis of the radiative transfer outcome, band-ratio algorithms are derived for three optically active substances (OAS), viz, chlorophyll-a, suspended sediment and coloured dissolved organic matter (CDOM). The respective algorithms are 670/555, 490/670 and 412/670 nm for chlorophyll-a, suspended sediment and CDOM. These algorithms are applied to Ocean Colour Monitor (OCM), onboard Indian Remote Sensing Satellite (IRS)-Polar Satellite Launch Vehicle (P4), scenes (digital data), to synoptically analyze these OAS. The synoptic analysis of OAS revealed different hydrodynamic characteristics of the estuaries during non-monsoon seasons.     

Fluxes and sources of suspended organic matter in an estuarine turbidity maximum region during low discharge conditions

Water column concentrations of total suspended solids (TSS), particulate organic carbon (POC) and particulate nitrogen (PN) were measured at three different depths in four different locations bracketing the estuarine turbidity maximum (ETM) along the main channel of a temperate riverine estuary (Winyah Bay, South Carolina, USA). Measurements were carried out over full tidal cycle (over 24 h). Salinity, temperature, current magnitude and direction were also monitored at the same time throughout the water column. Tidally averaged net fluxes of salt, TSS, POC and PN were calculated by combining the current measurements with the concentration data. Under the extreme low river discharge conditions that characterized the study period, net landward fluxes of salt were measured in the lower part of the study area, suggesting that the landward transport through the main channel of the estuary was probably balanced by export out through the sides. In contrast, the net fluxes of salt in the upper reaches of the study area were near zero, indicating a closed salt balance in this part of the estuary. In contrast to salt, the net fluxes of TSS, POC and PN in the deeper parts of the water column were consistently landward at all four sites in Winyah Bay indicating the non-conservative behavior of particulate components and their active transport up the estuary in the region around the ETM.The carbon contents (%POC), carbon:nitrogen ratios (org[C:N]a) and stable carbon isotopic compositions (δ¹³C_POC) of the suspended particles varied significantly with depth, location and tidal stage. Tidally averaged compositions showed a significant increase up the estuary in the %POC and org[C:N]a values of suspended particles consistent with the preferential landward transport of carbon-rich particles with higher vascular plant debris content. The combination of tidal resuspension and flood-dominated flow appeared to be responsible for the hydrodynamic sorting of particles along the estuary that resulted in denser, organic-poor particles being transported landward less efficiently. The elemental and isotopic compositions indicated that vascular C₃ plants and estuarine algae were the major sources of the particulate organic matter of all the samples, without any significant contributions from salt marsh C₄ vegetation (Spartina alterniflora) and/or marine phytoplankton.     

Organic matter origin and distribution in suspended particulate materials and surficial sediments from the western Adriatic Sea (Italy)

In this study, organic carbon (OC), total nitrogen (TN), stable carbon isotopic (δ¹³C_OC) and CuO reaction product compositions were used to identify the sources of organic matter (OM) and to quantify the relative importance of allochthonous and autochthonous contributions to the western Adriatic Sea, Italy. Suspended particulate material (195 samples) and surficial sediments (0–1 cm, 70 samples) from shallow cross-shelf transects were collected in February and May 2003, respectively. Vertical water column profiles were acquired along the same transects. Data include depth, potential temperature, salinity, density and chlorophyll fluorimetry.Along the western Adriatic shelf in the near-shore region, the phytoplankton growth was influenced by dynamics of the buoyant plumes from the Po and Appennine rivers. A small amount of very fine terrigenous material remained suspended within the coastal current and was exported southward along the shelf to the slope. High variability in the bulk composition was detected in the Po prodelta surficial sediments, whereas the western Adriatic shelf, although a larger area, exhibited a narrower range of values.A significant decoupling was observed between suspended particles in the water column and surficial deposits. The organic material collected in the water column was compositionally heterogeneous, with contributions from marine phytoplankton, riverine–estuarine phytoplankton and soil-derived OM. Frequent physical reworking of surficial sediments likely leads to the efficient oxidation of marine OC, resulting in the observed accumulation and preservation of refractory soil-derived OC delivered by the Po and Appennine rivers.