二次电流场多次叠加概率成像

基于地下电流场的积分公式,离散化的二次电流场被分解为电性不连续界面上的一系列点电荷电场的代数和.单位正点电荷电场被引入作为空间扫描函数（SDS）,积累电荷出现的概率（COP）函数定义为二次电流场与SDS的互相关.为对概率成像结果进行定量分析解释,提出了规范的积累电荷出现的概率（NCOP）函数.通过应用有限元算法对2D地电模型进行二次电流场合成,实现了二次电流场的多次叠加概率成像.结果表明对均匀半空间中赋存地质异常体的电性结构,概率成像方法对地下异常体的空间位置有较好的指示作用.     

Electro‐Catalytic Degradation of Phenol Organics with SnO2‐Sb2O3/Ti Electrodes

The effect of extraordinary degradation of phenol organics on the SnO₂‐Sb₂O₃/Ti electrode is investigated through experimental research and theoretical analysis. The phenol organics contained 4‐chloro‐phenol, 4‐bromo‐phenol, and 2‐iodo‐phenol. At a current density of 4 mA cm^–2 and an electrolysis time of 12 h, the degradation efficiency of the phenols was over 98% with a relatively short degradation time, whereas the degradation time of the PbO₂/Ti electrode surpassed 40 h while delivering 100% disposal efficiency. Therefore, the effectiveness of electrochemical (EC) oxidation by the SnO₂‐Sb₂O₃/Ti was superior to that of the PbO₂/Ti electrode. At the same time, the SnO₂‐Sb₂O₃/Ti had higher oxygen generation potential and lower electron consumption than the other electrodes. This was mainly due to the effect of the middle Sb₂O₃ layer, which due to its high porosity and good catalytic effect, contributed to a better catalysis than the SnO₂ part.     

Depth–energy and depth–force relationships in open channel flows. II: Analytical findings for power-law cross-sections

In a recent work [Valiani A, Caleffi V. Depth–energy and depth–force relationships in open channel flows: analytical findings. Adv Water Resour 2008;31(3):447–54], the authors analytically inverted the depth–specific energy and depth–total force relationships for flows in open channels with wide rectangular cross-sections.     

岩石中柱状装药爆炸能量分布

岩石中装药爆炸产生的爆破能量可分为爆炸冲击波能量和爆生气体膨胀能量。对爆炸能量分布的理论分析有助于改善爆破效果,提高爆破质量。在柱状耦合装药情况下,分析了冲击波作用下岩石变形和破坏的特点、爆生气体对爆腔的扩腔作用,考虑了在岩体的损伤情况下爆生气体对裂纹的驱裂作用。计算结果表明：埋深在临界深度以下时,岩石中柱状装药爆破冲击波做功消耗的能量约占爆炸总能量的40 %,剩余爆生气体能量中用于扩腔和扩展主要裂隙的能量约占总能量的23 %,剩余大约37 %的能量中有小部分能量用于新增裂纹数目,而大部分损失掉了。     

Case studies of spectral atmospheric transmittance in the ultraviolet and visible regions in Athens, Greece: I. Total transmittance

This work accounts for an investigation about the diurnal variation of total spectral transmittance of solar irradiance under dominant wind conditions as case studies. Such a work is carried out in Athens for the first time. The spectral transmittance values estimated were derived using ground-based spectral measurements of beam irradiance in the range 310–575 nm (UV and VIS). The data were recorded by a system consisting of an automatic solar tracker and a spectrometer. All data were recorded under clear-sky conditions in the city center of Athens and the spectral total atmospheric transmittance was estimated towards zenith to avoid optical mass effects. The comparison reveals that the total atmospheric transmittance is higher under the influence of strong Etesian compared to sea-breeze conditions. The influence of low-pressure systems also plays a depollution role in the basin. Various features of diurnal variation are discussed with respect to emission sources, topographic peculiarities and wind pattern.     

Stokes polarimetry at the Kodaikanal tower tunnel telescope

A Stokes Polarimeter has been developed using a masked CCD arrangement for the measurement of the vector magnetic field of sunspots. Charge shifting within the CCD is used to record near simultaneous orthogonal polarisation. The testing of the Stokes Polarimeter and the behavior of the integrated system combined with the Kodaikanal tower tunnel telescope will be discussed.     

济阳坳陷孤南洼陷低熟油成藏特征

孤南洼陷具有丰富的低熟油资源，低熟油中的生物标志物以高伽玛蜡烷含量，植烷优势，低成熟度为特征。下第三系沙一段是低熟油的源岩，其岩性为富含藻类有机质的油页岩，油泥岩，低熟油在平面上环生烃洼陷分布，剖面上层位集中在沙二－沙一段，断层控制了低熟油的运移距离和聚集层位，低熟油的成藏模式有3种，即自源侧向运移聚集成藏，自源断层垂向运聚成茂混合运取成藏模式。孤南洼陷低熟油盆地内部以侧向运移，侧向充注入岩性－断块圈闭为主，形成单源油藏。在断藏带原油是以垂向运移及垂向充注断块圈闭为主，形成混源油藏。     

利用LA-ICP-MS在16 μm和10 μm激光束斑条件下测定独居石U-Th-Pb年龄

我国锂钾主要矿产资源大多分布在西部偏远地区,其勘查找矿或综合利用迫切需要现场快速分析技术的支持。本文介绍了自行开发的便携式Li-K分析仪的主要性能及其在锂辉石中锂的分析应用。Li-K分析仪是一种基于大气压的液体阴极辉光放电光谱仪,以待测液体为放电阴极,实现样品中Li、K等元素的原子化和激发。该仪器以光纤传导CCD光谱仪作为检测器,其波长范围为345～1015 nm,分辨率3 nm;以Li 670.78 nm和K 769.90 nm分析谱线,在最佳仪器工作条件下测定Li、K的精密度（RSD,n=14）均低于2%,检出限为0.03 μg/mL,检测范围0.1～10 μg/mL。研究表明,不同酸度和酸的类型对谱线强度影响较大,且存在显著的样品基体效应,标准曲线法分析锂辉石中Li的结果偏差高达267%;而标准加入法可克服基体效应的影响,获得与ICP-OES一致性较好的分析结果,为现场开展固体样品中Li的测定奠定了基础。     

可变电荷土壤和恒电荷土壤与氢离子相互作用机理

研究了可变电荷土壤和恒电荷土壤与H相互作用的机理，并比较了它们之间的差别，研究结果表明，氢离子输入土壤后可以转化为表面正电荷，可溶性铝和可交换性酸，但是由于土壤的组成和性质不同，不同土壤中H＋三种去向的贡献不同。H＋转化为表面正电荷是由于土壤表面Fe-OH,Al-OH的质子化造成的，因此H＋转化为表面正电荷的能力与土壤中氧化铁的含量密切相关，从而可变电荷土壤中H＋转化为表面正电荷的贡献比恒电荷土壤中的大。H＋转化为可溶性铝的能力与土教育部 的矿物组成密切相关，随着H＋输入量的增加，土壤中可溶性铝的含量也增加。可变电荷土壤中可溶性铝增加的顺序为红壤＞赤红壤＞铁质砖红壤，在H＋的加入量小于15mmol/kg时，黄棕壤的可溶性铝介于红壤和赤红壤之间，当H＋的加入量大于约15mmol/kg时，黄棕壤的可溶性铝略小于赤红壤，棕壤的可溶性铝明显小于红壤和赤红壤，但比铁质砖红壤高，恒电荷土壤的可变性酸量明显大于可变电荷土壤，但从总的看来，H＋加入量的变化对可交换性酸量的影响不大。     

天然膨润土中蒙脱石丰度的定量方法研究

基于膨润土中蒙脱石的基本结构单元在X射线衍射空间的相干散射的分布和总量是一不变量,同一膨润土矿中单位质量蒙脱石的阳离子交换容量和层电荷密度专一性的特点,本研究提出了阳离子交换容量／层电荷密度、阳离子交换容量和X射线衍射多相Rietveld分析三种蒙脱石丰度的定量方法,并测定了我国不同产地、矿物组成和物化性质各异的10种天然膨润土中蒙脱石丰度,分析了可能的干扰因素。结果表明,三种方法测得的蒙脱石丰度值在3％范围内吻合良好,且具有一致的自相关性。