广西南丹地区有色金属尾砂型人工矿床地质特征及其资源化

广西南丹地区尾矿分布于大厂、车河、芒场等矿区。尾砂来自以锡石为主的多金属矿床，尾砂中除Sn，Pb，Zn，Ag，Sb的质量分数达到工业指标外，Au亦达到综合利用指标。通过试验证明，对尾矿中的细微粒锡石可采用风力分级选矿、磁选和化学选矿等方法回收；尾砂中的非金属资源可作为填充材料、水泥原料利用，使尾砂型人工矿床充分的资源化。     

辽宁省鞍本地区铁尾矿资源现状及其开发利用

辽宁省的鞍山、本溪两市为我国重要的钢铁基地，各矿山长期生产遗留的铁尾矿问题越来越引起人们的重视，如污染环境、诱发地质灾害等，如何解决已成为地质、环保、水工界的关注。     

Effect of suction on the mechanical behaviour of iron ore rock

The effect of suction on the behaviour of iron ore has been studied from both physical and mechanical points of view. The porosity and the suction phenomena have been analysed using different experimental techniques. Uniaxial compressive tests on partially saturated samples have shown that the suction is responsible for strength and cohesion improvement. Considering the theory of partially saturated porous soils of Coussy and Dangla (Mécanique des sols non saturés (2002 edn). Hermès Science: 2002; 390), we have proposed a constitutive law for partially saturated iron ore. The real increase in the apparent cohesion due to the capillary attraction forces is overestimated if the yield function is written in terms of effective stresses. The effect of the capillary cohesion has been modelled with a function in the expression of the apparent cohesion of the yield function. The effect of suction on the mechanical behaviour has been represented in the effective stresses space and in the total stresses space like the Alonso model (Géotechnique 1990; 40 :405–430). Copyright © 2005 John Wiley & Sons, Ltd.     

杭州城区“最具出游力”人群休闲旅游障碍性因素的实证分析

休闲旅游作为一种旅游方式和休闲活动内容越来越受到重视，通过对杭州市“最具出游力”人群调查，运用旅游地理学分析方法发现，影响他们进行休闲旅游的因素最重要的是时间因素、交通因素和学习因素，传统观点中的经济因素地位明显下降；同时分析了不同职业、性别和年龄人员中各因素作用的差异。这种实证性的调查分析方法和结论对于休闲旅游理论和杭州市休闲产业的发展都有一定意义。     

Characterizing rainfall–groundwater dynamics in a hard‐rock aquifer system using time series,geographic information system and geostatistical modelling

The aim of this study was to investigate rainfall–groundwater dynamics over space and annual time scales in a hard‐rock aquifer system of India by employing time series, geographic information system and geostatistical modelling techniques. Trends in 43‐year (1965–2007) annual rainfall time series of ten rainfall stations and 16‐year (1991–2006) pre‐monsoon and post‐monsoon groundwater levels of 140 sites were identified by using Mann–Kendall, Spearman rank order correlation and Kendall rank correlation tests. Trends were quantified by Kendall slope method. Furthermore, the study involves novelty of examining homogeneity of pre‐monsoon and post‐monsoon groundwater levels, for the first time, by applying seven tests. Regression analysis between rainfall and post‐monsoon groundwater levels was performed. The pre‐monsoon and post‐monsoon groundwater levels for four periods – 1991–1994, 1995–1998, 1999–2002 and 2003–2006 – were subjected to geographic information system‐based geostatistical modelling. The rainfall showed considerable spatiotemporal variations, with a declining trend at the Mavli rainfall station (p‐value < 0.05). The Levene's tests revealed spatial homogeneity of rainfall at α = 0.05. Regression analyses indicated significant relationships (r² > 0.5) between groundwater level and rainfall for eight rainfall stations. Non‐homogeneity and declining trends in the groundwater level, attributed to anthropogenic and hydrologic factors, were found at 5–61 more sites in pre‐monsoon compared with post‐monsoon season. The groundwater declining rates in phyllite–schist, gneiss, schist and granite formations were found to be 0.18, 0.26, 0.21 and 0.14 m year^?1 and 0.13, 0.19, 0.16 and 0.02 m year^?1 during the pre‐monsoon and post‐monsoon seasons, respectively. The geostatistical analyses for four time periods revealed linkages between the rainfall and groundwater levels. Copyright © 2013 John Wiley & Sons, Ltd.     

Significance of adakites in petrogenesis of early Silurian magmatism at the Yudai copper deposit in the Kalatag district,NW China

Yudai is a newly discovered copper deposit associated with a porphyritic quartz diorite, in the Kalatag district of the eastern Tianshan, China. SHRIMP U-Pb dating of zircons from the diorite yielded an age of 432 ± 3 Ma. The diorite is peraluminous (ASI = 0.98–1.10), calc-alkaline to tholeiitic with high Al₂O₃ of 16.6–17.7 wt% and Mg^# of 57.4–67.4. Trace element characteristics of the diorite show it is enriched in Ba, K and Sr, and depleted in Nb, Ta, Ti, with a positive Eu anomaly and high Sr/Y and La/Yb ratios. This diorite has positive ε_Nd(t) values ranging from 6.2 to 8.4 with low initial ⁸⁷Sr/⁸⁶Sr ratios of 0.704336 to 0.704450. These geochemical and isotopic characteristics indicate that the adakite-like diorite, associated with the copper mineralization, was emplaced in an island arc setting and resulted from partial melting of subducted oceanic plate in a mantle wedge.     

泡沫塑料吸附分离富集-电感耦合等离子体质谱法测定稀土矿石中的镓

采用电感耦合等离子体质谱法(ICP-MS)测定稀土矿石中的镓,高含量的稀土元素会造成严重的质谱干扰。本文采用聚氨酯泡沫塑料在6 mol/L盐酸介质中吸附样品溶液中的镓后,以0.5 mol/L氯化铵水浴加热解脱30 min,镓的吸附-解脱效率超过99%,稀土元素等干扰物质基本不进入解脱液中,即在富集镓的同时实现了镓与基体元素的高效分离,降低了质谱干扰。本方法检出限低(0.022μg/g),经土壤及水系沉积物标准物质验证,镓的测定值与标准值吻合(绝对偏差为0.38%~4.70%),实际稀土矿石样品的加标回收率为94.1%~100.6%,精密度(RSD)低于4%(n=12),可应用于分析一般地质样品以及稀土矿石中的镓。     

内蒙古火龙沟铅锌矿床成矿岩体年代学、地球化学及其地质意义

内蒙古火龙沟铅锌矿床是近期勘查发现、预期可达中型规模以上的铅锌矿床之一,笔者对该矿区的侵入岩——正长花岗岩进行了LA-MC-ICP-MS锆石U_Pb定年和主量、微量元素分析,锆石U_Pb定年结果为(224.0±2.5)Ma,表明,该岩体侵位于晚三叠世。岩石地球化学研究结果显示火龙沟正长花岗岩体具有明显富Si O2和ALK、贫Mg O和TFe的特点,A/NK-A/CNK图解显示正长花岗岩属于准铝质花岗岩。微量元素蛛网图显示富集大离子亲石元素Rb、Th、U、K,亏损高场强元素Nb、Ta、Ti。稀土元素配分模式表现出富集LREE,亏损HREE的右倾型,LREE/HREE=8.04~10.40,具有明显Eu的负异常。花岗岩锆饱和温度计算结果表明该花岗岩岩浆形成温度为820℃,属于高温花岗岩,以上地球化学特征和高温的特点表明该花岗岩为A型花岗岩。结合区域构造演化历史,笔者认为该花岗岩体形成于古亚洲洋闭合后的造山后垮塌岩石圈伸展构造环境。     

中国叠生型铁矿床成矿特征探讨

叠生成矿作用主要是指早期成矿作用被晚期成矿作用叠加、复合和改造。晚期成矿作用的性质常与早期成矿作用不同,也就是说,在早先己有矿床(或矿体、矿源层)的基础上,叠加复合了晚期成矿作用,即成矿时间上有先后、空间产出上有重叠、并对早先形成的矿床进行复杂的复合、叠加和改造,使成矿作用具有多样性、复杂性,并可形成大矿、富矿。铁矿床中叠生成矿作用广泛发育。按矿床或矿体产出和形成的地质特征,中国叠生型铁矿床可分为风化淋滤型、热液叠加改造型和热液叠加复合型3个亚类。风化淋滤型铁矿床在中国分布有限,规模不大,工业利用价值不大,因而中国的叠生型铁矿床主要是指热液叠加改造型和热液叠加复合型两个亚类。热液叠加改造型主要是指早期的铁矿床(或矿体、矿源层)经后期热液叠加改造,使早期的较贫铁矿床(或矿体、矿源层)成为较富铁矿床(或矿体),这是中国BIF型铁矿床中最重要的富铁矿类型,以鞍本地区弓长岭二矿区为典型代表。弓长岭二矿区铁矿,早期在新太古代形成条带状磁铁石英岩(2528 Ma,贫矿石),后期在古元古代,含矿热液交代改造贫铁矿形成富铁矿(1840 Ma)。热液叠加复合型主要是指后期脉型铁(或稀土元素等)矿床叠加在早期(沉积或其他成因)铁等矿床上而形成的矿床,如白云鄂博铁-铌-稀土元素矿床和黔西菱铁矿矿床。白云鄂博铁-铌-稀土元素矿床的形成与火成碳酸岩有关,在中元古代(1.3 Ga)左右,区内火成碳酸岩的侵位,在早期主要形成以岩浆熔离作用为主的铁-铌-稀土元素矿,晚期叠加了加里东期稀土-铌矿化热液脉。古陆边缘构造带或陆内活化带是形成叠生型铁矿床的有利构造空间,较大的地球化学块体,为形成多期、多成因的矿床提供物质来源,叠生型铁矿床的形成明显受构造的控制。叠生成矿是复杂地质过程的一种具体表现。热液叠加改造型和热液叠加复合型的叠生型铁矿床的形成是因中国独特的大地构造环境决定的。叠生成矿作用的研究,尚处在初步阶段。加强对叠生成矿作用的研究,了解其形成的地质背景、成矿机制、作用过程、控矿因素等,对发展矿床学研究,认识区域成矿特征和指导地质找矿具有重要的理论和实际意义。     

河南老湾金矿床上上河矿段矿床地质和成矿流体地球化学

河南桐柏老湾金矿床是桐柏-大别山(北坡)金银成矿带内大型造山带型金矿床之一。文章对该矿床的上上河矿段进行了矿床地质和成矿流体地球化学研究,旨在查明该矿段的流体成矿过程。根据矿脉穿插关系、矿石结构构造、矿物共生组合以及黄铁矿的粒度和晶形,将老湾金矿上上河矿段成矿过程划分为:石英粗粒自形黄铁矿(Ⅰ)、石英细粒半自形-他形黄铁矿(Ⅱ)、石英多金属硫化物(Ⅲ)及石英碳酸盐(Ⅳ)4个阶段。镜下观察显示,矿床中的包裹体类型有含CO_2包裹体(LH_2O+LCO_2+VCO_2)、纯CO_2包裹体(LCO_2+VCO_2)、液相包裹体(LH_2O+VH_2O)及少量含子晶包裹体(LH_2O+VH_2O+S)。第Ⅰ阶段、第Ⅱ阶段和第Ⅲ阶段均可见含CO_2包裹体、纯CO_2包裹体和液相包裹体,有时可见含CO_2包裹体与液相包裹体共存。流体包裹体显微测温结果表明,成矿流体可近似看做中温、低盐度、富CO_2的NaCl-H_2O-CO_2体系,纯CO_2包裹体和液相包裹体所代表的流体可能是由含CO_2包裹体所代表的Na Cl-H_2O-CO_2流体经不混溶形成的,三者在寄主矿物沉淀时,被同时捕获而共存。从第Ⅰ阶段到第Ⅳ阶段,成矿流体温度从303~379℃逐渐降低到138~195℃,盐度w(Na Cleq)从4.07%~9.59%逐渐降低到1.06%~2.74%。在成矿的第Ⅰ阶段成矿流体发生了不混溶作用,而在第Ⅱ阶段和第Ⅲ阶段流体中的CO_2起泡分离再次引发了不混溶作用。从第Ⅰ阶段到第Ⅲ阶段,成矿流体的δ18OH_2O从6.56‰~9.71‰经1.89‰~4.01‰变化到0.08‰,δDH_2O从-78.1‰~-64.2‰经-79.5‰~-76.3‰变化到-72.6‰,表明老湾金矿第Ⅰ阶段成矿流体主要为岩浆热液,第Ⅱ阶段成矿流体中有少量大气降水加入,第Ⅲ阶段成矿流体中大气降水的比例明显加大。