Field-based experimental determination of the weathering rates of the Cappadocian tuffs

Since the last eruption in the Cappadocia region that resulted in the formation of irregular, hard, thick lava layers on top of the Cappadocian tuffs, atmospheric processes have preferentially sculptured the tuffs. The erosion processes have resulted in some beautiful topographical landscape features, the so-called “fairy chimneys”. However, erosion, which is an important factor in the formation of fairy chimneys in the early stages, has a negative effect on their future. Over time, the number of visitors to this region has also increased and, therefore, in addition to natural erosion, the effects of localized erosion resulting from tourism at the site have increased in the last few decades. The physical, mineralogical and mechanical properties of the Cappadocian tuffs have been widely investigated in previous studies, but, their weathering characteristics, particularly weathering rate, were not determined in these studies. Determination of the weathering rate of these rocks is mandatory, especially for conservation projects, which should be urgently applied in order to protect this heritage. In this study, a comprehensive research program was carried out on the weathering properties of the Cappadocian tuffs and the weathering rate was determined in field and laboratory investigations. To this purpose, a detailed field investigation was performed. Besides field observations, the mineralogical, physical and mechanical properties of tuffs were also determined. In addition to durability evaluation by the slake durability index test, wetting–drying and freezing–thawing tests were also performed for weathering rate assessment of the Cappadocian tuffs. In order to account for overburden load on some specific parts of pillars, these wetting–drying and freezing–thawing tests were performed under loads. The results obtained from field observations of old man-made structures and from laboratory studies show that the weathering rate varies between 0.03 and 0.59 mm/year for the Esbelli tuff, and 0.4 and 2.5 mm/year for softer part of the Kavak member.     

东昆仑闹仓坚沟组流纹质凝灰岩锆石U-Pb年龄及其地质意义

应用激光烧蚀多接收器电感耦合等离子体质谱(LA-MC-ICP MS)方法对东昆仑秀沟盆地闹仓坚沟组火山岩样品进行了锆石U-Pb定年研究。流纹质凝灰岩(DG25-4)中锆石的阴极发光图像具有振荡环带结构,属于典型的岩浆锆石。15个岩浆锆石206Pb/238U表面年龄集中在239~249 Ma之间,206Pb/238U加权平均值为243.5 ± 1.7 Ma,它记录了火山岩的形成年龄,说明该地区闹仓坚沟组形成于中三叠世早期。这一研究还在闹仓坚沟组火山岩中发现了早古生代和元古宇继承锆石,提供了昆南地体可能存在元古宇基底的信息。      

Geochemical correlation of Ordovician flow tuffs in North Wales

Ordovician rhyolitic tuffs in North Wales are correlated on the basis of their whole-rock trace element composition. Multivariate statistics verify that major ignimbrite sheets are chemically unique, with Zr, Y and Nb being the most useful elements to characterize individual deposits. Fractionation processes during transport and emplacement of the pyroclastic flows results in little lateral variation in the whole-rock geochemistry of deposits; different diagenetic histories in subaerial and subaqueous environments did not mask recognition of primary ignimbrite units. A partially welded vitric ash flow tuff is correlated with the Pitts Head Tuff ash flow sheet, and a tuff horizon previously assumed to be reworked Pitts Head Tuff is shown to be chemically most similar to the fourth member of the Capel Curig Volcanic Formation. Validity of these correlations is upheld by biostratigraphic and sedimentological evidence. The new correlations necessitate a revision of the stratigraphy in North Wales and indicate a significant lapse of time (perhaps one million years) between emplacement of the Pitts Head Tuff and eruption of the Lower Rhyolitic Tuff of the overlying Snowdon Volcanic Group.     

Tephra glass chemistry provides storage and discharge details of five magma reservoirs which fed the 75 ka Youngest Toba Tuff eruption,northern Sumatra

The Youngest Toba Tuff contains five distinct glass populations, identified from Ba, Sr and Y compositions, termed PI (lowest Ba) – PV (highest Ba), representing five compositionally distinct pre-eruptive magma batches that fed the eruption. The PI–PV compositions display systematic changes, with higher FeO, CaO, MgO, TiO₂ and lower incompatible element concentrations in the low-SiO₂ PIV/PV, than the high-SiO₂ PI–PIII compositions. Glass shard abundances indicate PIV and PV were the least voluminous magma batches, and PI and PIII the most voluminous. Pressure estimates using rhyolite-MELTS indicate PV magma equilibrated at ~6 km, and PI magma at ~3.8 km. Glass population proportions in distal tephra and proximal (caldera-wall) material describe an eruption which commenced by emptying the deepest PIV and PV reservoirs, this being preferentially deposited in a narrow band across southern India (possibly due to jet-stream and/or plinian eruption transport), and as abundant pumice clasts in the lowermost proximal ignimbrites. Later, shallower magma reservoirs erupted, with PI being the most abundant as the eruption ended, sourcing the majority of distal ash from co-ignimbrite clouds (PI- and PIII-dominant), where associated ignimbrites isolated earlier (PIV- and PV-rich) deposits. This study shows how analysis of tephra glass compositional data can yield pre-eruption magma volume estimates, and enable aspects of magma storage conditions and eruption dynamics to be described.     

Occurrence of volcanic ash in the Quaternary alluvial deposits,lower Narmada basin,western India

This communication reports the occurrence of an ash layer intercalated within the late Quaternary alluvial succession of the Madhumati River, a tributary of the lower Narmada River. Petrographic, morphological and chemical details of glass shards and pumice fragments have formed the basis of this study. The ash has been correlated with the Youngest Toba Tuff. The finding of ash layer interbedded in Quaternary alluvial sequences of western Indian continental margin is significant, as ash being datable material, a near precise time-controlled stratigraphy can be interpreted for the Quaternary sediments of western India. The distant volcanic source of this ash requires a fresh re-assessment of ash volume and palaeoclimatic interpretations.     

Age of the Yarrabee and accessory tuffs: implications for the upper Permian sediment-accumulation rates across the Bowen Basin

The Yarrabee Tuff is a stratigraphically significant marker across the Bowen Basin separating the Fort Cooper–Burngrove–Fair Hill formations from the overlying Rangal and equivalent coal measures. At least three to four persistent tuffs (referred here as accessary tuffs) beneath the Yarrabee Tuff were recognised in the Fort Cooper Coal Measures as suitable for regional stratigraphic correlations. In this study, we determined the ages of the Yarrabee and accessary tuffs across different morphotectonic zones of the basin through high-precision U–Pb dating of zircon with the CA-IDTIMS technique. The age of the Yarrabee Tuff is found to be 252.69 ± 0.16 Ma in the Duckworth 11 well, 253.07 ± 0.22 Ma in the Crocker Gully 2 well and <252.58 ± 0.23 Ma in the Peat 1 well. The age range of the Yarrabee Tuff coincides with the previously published date of the Kaloola Tuff Member in Meeleebee 5 suggesting that the tuffs are stratigraphically equivalent. The age range for the accessory tuff 1 is 253.12 ± 0.12 Ma to 252.85 ± 0.16 Ma, 253.45 ± 0.08 Ma for accessory tuff 2 and 253.77 ± 0.17 Ma to 253.57± 0.18 Ma for accessory tuff 3, placing them in the upper Changhsingian Stage. The age of the accessory tuff 6 (less laterally consistent in the basin) from the Fair Hill Formation is 254.03 ± 0.03 Ma, placing it in the lower Changhsingian Stage. The age-constrained intervals allow the estimation of sedimentation rates using decompacted coal and clastic sediment thickness. In the Taroom Trough, the temporal variation in sedimentation rates is found to be 902 m/Ma in the Fair Hill Formation decreasing to 234.5 m/Ma in the overlying Burngrove Formation, reflecting a decrease in accommodation or sediment supply upwards in the sequence. Across the basin, the sedimentation rates for the Burngrove Formation are consistently higher in the Taroom Trough ranging between 234.5 and 224.5 m/Ma and lower rates of 112 m/Ma in the Roma Shelf. This regional variation reflects areas of high sedimentation rates that are high accommodation sites recognised by split coal seams and increased interburden. Conversely, low sedimentation rates reflect low accommodation sites, such as the Roma Shelf and the Burunga Anticline that are characterised by coalesced coal seams. The results help to understand stratal relationships across variable accommodation sites, basin-fill history of the basin including extent of sediment supply and paleotopographic controls during the evolution of the Bowen Basin. We also discuss criteria for interpreting the results of CA-IDTIMS U–Pb dating and consider the possible geological uncertainties related to either the primary magmatic processes or secondary reworking of tuffs at the site of deposition.     

Palaeoenvironmental response to the ∼74 ka Toba ash-fall in the Jurreru and Middle Son valleys in southern and north-central India

Distal deposits of rhyolitic volcanic ash from the ∼74 ka “supervolcanic” eruption of Toba, in northern Sumatra, are preserved in numerous river valleys across peninsular India. The Toba eruption is hypothesized to have resulted in climate change and the devastation of ecosystems and hominin populations. This study reports the results of the analysis of sediments and stratigraphical sequences from sites in the Jurreru and Middle Son valleys in southern and north-central India. The aim of the study is to determine the extent of palaeoenvironmental change in both valleys as a result of the ash-fall. Inferences based on evidence from the Jurreru valley are more detailed, where pre- and post-Toba palaeoenvironmental changes are divided into seven phases. The results indicate that ash-fall deposits in both valleys underwent several phases of reworking that possibly lasted for several years, indicating that ash was mobile in the landscape for a considerable period of time prior to burial. This could have enhanced and lengthened the detrimental effects of the ash on vegetation and water sources, as well as animal and hominin populations.     

A Fissure-Controlled Acidic Volcanic Centre (Ordovician) at Yr Arddu,North Wales

The Yr Arddu Tuffs (Ordovician) are a sequence of predominantly welded acid ash-flow tuffs in the outlier centred on Yr Arddu (North Wales). The tuffs accumulated above a NNE-trending fracture, the Yr Arddu Fracture, which had previously influenced sedimentation. The heterogeneity of the tuffs and their restricted development suggest that they represent proximal accumulations from small or suppressed (boiling-over) eruption columns. The eruptions and emplacement developed, at least in the initial stages, in a submarine environment. Lithological, geochemical and palaeontological evidence indicates that the tuffs represent the earliest eruptive phase of the Lower Rhyolitic Tuff Formation. They were later intruded by comagmatic rhyolite domes, whose alignment reflects the continued influence of the early fracture.     

Buried oblique‐slip faults in the Irish Caledonides

Despite over a century of geological investigation, the Ordovician evolution of South Mayo, western Ireland, is still imperfectly understood. An example of this is the supposed lateral equivalence of two formations within the succession, the Rosroe and Derrylea Formations of Arenig age, exposed on opposite limbs of a major east–west syncline. These formations exhibit characteristics which suggest that they were not deposited in the same basin. Both formations contain tuff horizons. Geochemical analysis of these tuffs shows that each formation contains chemically distinct volcanic signatures suggesting deposition in separate sub‐basins. Previously the Rosroe Formation on the south limb of the syncline was considered the coarse‐grained proximal equivalent of the finer‐grained Derrylea Formation, both being deposited in a deep‐water fan environment. Previously published palaeocurrent data together with new data show the Rosroe Formation to have been derived from the northeast and therefore it cannot be the proximal equivalent of the Derrylea Formation. Additionally, the two formations show different and distinct associations of heavy mineral assemblages. It is suggested that one explanation for these data is that both formations were deposited in separate sub‐basins controlled by oblique slip sinistral faults, similar in some respects to the Cenozoic basins of the Gulf of California. In the Irish case these faults would have been largely buried by later Ordovician sedimentation. Some models for the Ordovician evolution of this area postulate the presence of an initial oceanic arc situated above a southward directed subduction zone. The presence of thick proximal submarine tuffs derived from an arc environment in the Rosroe Formation suggest that at least by this time the subduction zone was in fact northward directed and outboard of the arc. Copyright © 2002 John Wiley & Sons, Ltd.