高、低煤阶煤层气藏地质特征及控气作用差异性研究

高、低煤阶煤层气地质特征及控气作用差异性是研究煤层气富集成藏的重要组成部分,是煤层气勘探开发理论研究过程中重要的基础性研究领域之一。本文以中国沁水、阜新盆地和美国粉河盆地等典型的含气盆地为例,探讨了高、低煤阶煤层气的储层物性差异,分析了构造控气和水文地质控气作用的差异性。研究表明,高煤阶气藏含气量高,CH4百分含量高,δ13C1值大于-38.75‰,储层渗透率变化小,储层改造难,构造热事件对煤层气的生成、富集贡献大,持续的水动力使气藏遭到破坏,且破坏幅度大,现今地下水格局对气藏的形成具有一定的影响;低煤阶气藏含气量低,CH4百分含量低,δ13C1值大于-49.11‰,储层渗透率变化大,储层易改造,煤热演化史及煤阶影响着煤层气的生成、富集,在煤层气生成过程中活跃的水动力是甲烷生成的主要的水文地质条件之一,但持续的水动力使气藏遭到破坏,且破坏幅度小,而合适的地层水矿化度则是低煤阶煤层气生成的重要条件,地下水格局对气藏的调整和改造起到决定性的影响。     

Delineation of groundwater protection zones by the backward particle tracking method: theoretical background and GIS-based stochastic analysis

The backward particle tracking method, an effective and powerful tool that can be used to delineate groundwater protection zones, is presented. The theoretical background and insights on the applicability of this method are provided. Moreover, the present work enriches the backward particle tracking method with an uncertainty analysis concerning the porosity values, applying a Monte Carlo (MC) approach, coupled with the use of geographical information systems (GIS). As an application example, a wellfield in the Komotini area, Greece, is investigated. The present study may serve as a potential guideline for wellfield delineation, particularly in areas like Greece where lack of data related to the hydrogeological system is often a problem.     

The largest karst cave discovered in a tunnel during motorway construction in Slovenia’s Classical Karst (Kras)

Karst researchers of the Karst Research Institute ZRC SAZU are regularly consulted during the planning of Slovenia’s motorways and invited to observe and monitor construction in the karst areas. More than 350 caves have been discovered in the course of building 60 km of new motorways over the past decade. Access to the most important caves is preserved by concrete tubes closed with metal covers at the roadside. The largest cave system in a tunnel, named LC-S647, is almost entirely preserved. The protection of this cave will serve as a good example for the preservation of natural heritage in the future. Construction work for the motorway uncovered a high degree of karstification. In particular, the discovery of this cave in the Kastelec tunnel LC-S647 showed the existence of a major cave system in the geological and speleological past. A number of unconnected passages have also been found. Caves discovered during highway construction have brought new knowledge about the cavernosity and the geological history of this part of the karst.     

Landslide susceptibility mapping for a landslide-prone area (Findikli,NE of Turkey) by likelihood-frequency ratio and weighted linear combination models

Landslides are very common natural problems in the Black Sea Region of Turkey due to the steep topography, improper use of land cover and adverse climatic conditions for landslides. In the western part of region, many studies have been carried out especially in the last decade for landslide susceptibility mapping using different evaluation methods such as deterministic approach, landslide distribution, qualitative, statistical and distribution-free analyses. The purpose of this study is to produce landslide susceptibility maps of a landslide-prone area (Findikli district, Rize) located at the eastern part of the Black Sea Region of Turkey by likelihood frequency ratio (LRM) model and weighted linear combination (WLC) model and to compare the results obtained. For this purpose, landslide inventory map of the area were prepared for the years of 1983 and 1995 by detailed field surveys and aerial-photography studies. Slope angle, slope aspect, lithology, distance from drainage lines, distance from roads and the land-cover of the study area are considered as the landslide-conditioning parameters. The differences between the susceptibility maps derived by the LRM and the WLC models are relatively minor when broad-based classifications are taken into account. However, the WLC map showed more details but the other map produced by LRM model produced weak results. The reason for this result is considered to be the fact that the majority of pixels in the LRM map have high values than the WLC-derived susceptibility map. In order to validate the two susceptibility maps, both of them were compared with the landslide inventory map. Although the landslides do not exist in the very high susceptibility class of the both maps, 79% of the landslides fall into the high and very high susceptibility zones of the WLC map while this is 49% for the LRM map. This shows that the WLC model exhibited higher performance than the LRM model.     

Greening as strategic development in industrial change - Why companies participate in eco-networks

Networking between companies and other regional key actors has grown into a widespread instrument for economic development since the 1990s. Participatory networks have formed the concept for many activities of Local Agenda 21. Simultaneously, economic geography has focused on network theories to explain innovation in and the economic success of regions.This article focuses on the reasons why individual actors participate in environmentally oriented information networks. The questions approached are: Does the concept of learning within networks influence a firm’s development? How do the participants interact with each other? What effects do the networks have on their environment (arenas)?The changing arenas of a firm are analysed with regard to environmental concerns. These changes need to be anticipated for reliable strategies. To gain information and knowledge about current behaviour and activities, the functions of networks as learning platforms are discussed. Drawing upon arguments from different network theories, the motivations of participating in a network are threefold: actor and firm oriented, network internal (inter-firm), and network external. From these, a generic target cube of network motivations and actions is set up.The concept is reviewed by examining 12 ‘regional environmental information-oriented corporation networks’ (RUN) in the Greater Munich Area. The empirical material reveals that this type of network does not provide a guarantee for significant improvements in a firm’s environmental behaviour. However, participants learn about best practices while pursuing explicit or implicit aims as to influence their arenas.     

Numerical estimation of REV and permeability tensor for fractured rock masses by composite element method

The Monte Carlo method is used to generate parent stochastic discrete fracture network, from which a series of fractured rock samples of different sizes and orientations are extracted. The fracture network combined with a regular grid forms composite element mesh of the fractured rock sample, in which each composite element is composed of sub‐elements incised by fracture segments. The composite element method (CEM) for the seepage is implemented to obtain the nodal hydraulic potential as well as the seepage flow rates through the fractured rock samples. The application of CEM enables a large quantity of stochastic tests for the fractured rock samples because the pre‐process is facilitated greatly. By changing the sizes and orientations of the samples, the analysis of the seepage characteristics is realized to evaluate the variation of the permeability components, the existence of the permeability tensor and the representative element volume. The feasibility and effectiveness are illustrated in a numerical example. Copyright © 2008 John Wiley & Sons, Ltd.     

Implementation of reconstructed geomorphologic units in landslide susceptibility mapping: the Melen Gorge (NW Turkey)

In the international literature, although considerable amount of publications on the landslide susceptibility mapping exist, geomorphology as a conditioning factor is still used in limited number of studies. Considering this factor, the purpose of this article paper is to implement the geomorphologic parameters derived by reconstructed topography in landslide susceptibility mapping. According to the method employed in this study, terrain is generalized by the contours passed through the convex slopes of the valleys that were formed by fluvial erosion. Therefore, slope conditions before landsliding can be obtained. The reconstructed morphometric and geomorphologic units are taken into account as a conditioning parameter when assessing landslide susceptibility. Two different data, one of which is obtained from the reconstructed DEM, have been employed to produce two landslide susceptibility maps. The binary logistic regression is used to develop landslide susceptibility maps for the Melen Gorge in the Northwestern part of Turkey. Due to the high correct classification percentages and spatial effectiveness of the maps, the landslide susceptibility map comprised the reconstructed morphometric parameters exhibits a better performance than the other. Five different datasets are selected randomly to apply proper sampling strategy for training. As a consequence of the analyses, the most proper outcomes are obtained from the dataset of the reconstructed topographical parameters and geomorphologic units, and lithological variables that are implemented together. Correct classification percentage and root mean square error (RMSE) values of the validation dataset are calculated as 86.28% and 0.35, respectively. Prediction capacity of the different datasets reveal that the landslide susceptibility map obtained from the reconstructed parameters has a higher prediction capacity than the other. Moreover, the landslide susceptibility map obtained from the reconstructed parameters produces logical results.     

青藏高原西部赛利普中新世火山岩源区:地球化学及Sr-Nd同位素制约

青藏高原拉萨地块西部赛利普地区新生代火山岩依据主量元素可划分为超钾质、钾质和钙碱性系列,主要的岩石类型为粗面安山岩、粗面岩,一个超钾质岩石的40Ar-39Ar年龄为17.58Ma,指示出火山活动为中新世.超钾质、钾质和钙碱性火山岩都显示出富集LREE及LILE(Th、U)、亏损HFSE(Nb、Ta、Ti)的特征.超钾质火山岩具有较高的K2O(6.31%～8.55%)、MgO(6.75%～8.96%)、Cr(270.7×10-6～460.4×10-6)、Ni(142.3×10-6～233.9×10-6)含量,较高的(87Sr/86Sr)i(0.71883～0.72732)和较低的εNd(-14.78～-15.37),指示可能起源于一个前期亏损并经后期俯冲作用改造的富钾的方辉橄榄岩富集地幔源区.钾质火山岩具有比超钾质火山岩低的K2O、MgO、Cr、Ni含量以及高的Ba、Sr含量,初始87Sr/86Sr为0.71553～0.71628,初始143Nd/144Nd为0.51197～0.51198,在空间上与超钾质火山岩共生,可能是前者母岩浆的演化产物.钙碱性火山岩具有较高的Sr(881.7×10-6～1309.2×10-6)、Sr/Y比值(50～108)和较低的Y(12.05×10-6～18.02×10-6),明显亏损重稀土Yb(0.93×10-6～1.30×10-6),类似于典型的埃达克质岩成分特征但相对高钾,并具有相对低的(87Sr/86Sr);(0.70928～0.71374)以及高的εNd(-7.90～-10.91),指示起源于富钾增厚下地壳物质的部分熔融.区域上拉萨地块超钾质岩、钾质岩与N-S向地堑系在空间上共存、时间上相吻合,由此本文认为拉萨地块中新世钾质.超钾质岩和南北向地堑系的形成可能与中新世早期北向俯冲的印度大陆岩石圈断离有关.     

陕西白河县月儿潭绿松石与次生磷钙铝矾研究

对陕西省白河县月儿潭风化严重的绿松石样品进行了岩石薄片观察、化学成分测试、X射线粉晶衍射和红外吸收光谱分析等研究.结果表明,绿松石风化分解由天蓝色退色成黄绿色,最后变成白色,结构也由致密细腻变得松散多孔,主要原因是发生了硫酸根对磷酸根的交代作用,最终的交代产物主要是磷钙铝矾.     

Re-Os同位素对峨眉山大火成岩省成因制约的探讨

峨眉山大火成岩省（ELIP）主要由玄武岩、玄武质火山碎屑岩及少量的苦橄岩（包括越南的科马提岩）、长英质岩石以及层状岩体和岩墙组成,其物质来源直接关系到其成因是否与地幔柱活动有关。Re-Os同位素体系是地核、地幔和地壳物质的最佳示踪剂。前人对ELIP内的Re-Os同位素研究表明,低Ti玄武岩的Os含量为0．006×10^-9-0．40010^-9,^187Os／^188Os初始值为0．1371～1．403,并提出其与地幔柱活动有关;而高Ti玄武岩的Os含量为0．00410^-9～0．56010^-9,^187Os／^188Os初始值为0．1271～5．19,认为起源于大陆岩石圈地幔或地幔柱上升过程中受到大量岩石圈地幔“混染”（xu JF et al．,2007）;科马提岩的0s含量为1．2410^-9～7．0010^-9,^187Os／^188Os初始值为0．1251～0．1261,苦橄岩的Os含量为0．3210^-9～2．32910^-9,^187Os／^188Os初始值为0．1233～0．1266,指示苦橄岩和科马提岩均来自亏损地幔源区（Hanski et al．,2004;陈雷等,2007）。本文利用Os含量最低、^187Os／^188Os最高的高Ti玄武岩作为地壳端员,用铁质陨石、原始上地幔（PUM）和亏损地幔（DMM）作为地核和各种地幔端员,分别做二元混合计算,结果显示绝大多数玄武岩和所有苦橄岩及科马提岩均落在地壳和DMM混合曲线附近,并且邻区特提斯洋地幔岩与DMM具有相近的Os含量和^187Os／^188Os组成,据此推测峨眉山火成岩的形成与特提斯洋的活动有关,主要受控于地壳和亏损地幔的相互作用。