鄂尔多斯盆地CO2地质封存适宜性与潜力评价

针对目前利用层次分析法对CO₂地质封存进行适宜性评价过程中,极少结合研究区域实际计算低层次评价指标权重,对适宜性评价结果又缺少进一步的分析,结合鄂尔多斯盆地的地质特征,通过计算指标组成权重和适宜性得分对盆地开展了CO₂地质封存适宜性评价,并以适宜区杏子川油田长4+5盖层为例,开展了盖层封闭性评价实验研究。同时,采用相应的计算方法对鄂尔多斯盆地深部咸水层和油藏的CO₂地质封存潜力进行了计算。结果表明：鄂尔多斯盆地在三叠系开展CO₂地质封存的适宜性最好,石炭-二叠系和奥陶系则次之;杏子川油田三叠系延长组长4+5盖层对区域开展CO₂地质封存具备良好的封闭性;鄂尔多斯盆地深部咸水层和油藏的CO₂有效封存量分别为1.33×10 ¹⁰ t和1.91×10 ⁹ t,且在延长石油吴起、靖边及杏子川油田共有56个CO₂地质封存适宜区,其CO₂有效封存量可达1.77×10 ⁸ t。     

模式内部变率引起的1.5℃和2℃升温阈值出现时间模拟的不确定性研究

模式内部变率是模拟结果不确定性的重要来源,然而它对于1.5℃和2℃升温阈值出现时间不确定性的影响尚不清楚。因此,基于耦合模式比较计划第五阶段(CMIP5)的多模式数据研究了模式内部变率对1.5℃和2℃升温阈值出现时间不确定性的影响以及对未来排放情景的敏感性。结果表明,模式内部变率对升温阈值出现时间模拟的影响与外强迫的影响相当,单个模式内部不同成员达到全球平均1.5℃或2℃增温的年份相差2~12年;其影响具有明显的空间差异,影响极大值出现在欧亚大陆以北洋面、白令海峡周围区域、北美东北部及其与格陵兰岛之间的海域、南半球高纬地区等;低排放情景下模式内部变率的影响大于高排放情景。     

An Operational Precipitable Water Vapor Retrieval Algorithm for Fengyun-2F/VISSR Using a Modified Three-Band Physical Split-Window Method

The Visible and Infrared Spin-Scan Radiometer(VISSR) onboard the Fengyun-2(FY-2) satellite can provide valuable thermal infrared observations to help create a precipitable water vapor(PWV) product with high spatial and temporal resolutions. The current FY-2/VISSR PWV product in operation is produced by using a traditional two-band physical split-window(PSW) method, which produces low quality results under dry atmospheric conditions. Based on the sensitivity characteristics of FY-2 F/VISSR water vapor channel and two split-window channels to atmospheric water vapor, this study developed a new, robust operational PWV retrieval algorithm for FY-2 F to improve the operational precision of the current PWV product. The algorithm uses a modified three-band PSW method, which adds a scale for the water vapor channel in the improved three-band PSW method. Integrated PWV products from the radiosonde data in 2016 are used here to validate the precision of the PWV retrieved by the modified three-band and traditional two-band PSW methods. The mean bias, root mean square error(RMSE), and correlation coefficient of the PWV retrieved by the modified three-band PSW method are 0.28 mm, 4.53 mm, and 0.969, respectively. The accuracy is much better than the PWV retrieved by the two-band method, whose mean bias, RMSE, and correlation coefficient are 12.67 mm, 29.35 mm, and 0.23. Especially, in mid-or high-latitude regions, the RMSE of the PWV is improved from 10 to 2 mm by changing the inversion in the two-band method to the modified three-band PSW method. Furthermore, the modified three-band PSW results show a better consistency with the radiosonde PWV at any zonal belt and season than the two-band PSW results. This new algorithm could significantly improve the quality of the current FY-2 F/VISSR PWV product, especially at sites where the actual PWV are lower than 15 mm.     

NUMERICAL PREDICTION OF AN EXTREME RAINSTORM OVER THE PEARL RIVER DELTA REGION ON 7 MAY 2017 BASED ON WRF-ENKF

An ensemble Kalman filter based on the Weather Research and Forecasting Model (WRF-EnKF) is used to explore the effectiveness of the assimilation of surface observation data in an extreme local rainstorm over the Pearl River Delta region on 7 May 2017. Before the occurrence of rainstorm, the signals of weather forecasts in this case are too weak to be predicted by numerical weather model, but the surface temperature over the urban area are high. The results of this study show that the wind field, temperature, and water vapor are obviously adjusted by assimilating surface data of 10-m wind, 2-m temperature, and 2-m water vapor mixing ratio at 2300 BST 6 May, especially below the height of 2 km. The southerly wind over the Pearl River Delta region is enhanced, and the convergence of wind over the northern Guangzhou city is also enhanced. Additionally, temperature, water vapor mixing ratio and pseudoequivalent potential temperature are obviously increased over the urban region, providing favorable conditions for the occurrence of heavy precipitation. After assimilation, the predictions of 12-h rainfall amount, temperature, and relative humidity are significantly improved, and the rainfall intensity and distribution in this case can be successfully reproduced. Moreover, sensitivity tests suggest that the assimilation of 2-m temperature is the key to predict this extreme rainfall and just assimilating data of surface wind or water vapor is not workable, implying that urban heat island effect may be an important factor in this extreme rainstorm.     

利用FY-2F快速扫描资料分析对流初生阶段的云顶物理量特征

基于FY-2F静止气象卫星提供的2015年5—9月的高分辨率数据,通过温度阈值法识别出深、浅对流后,分析和比较了深、浅对流在对流初生(convective initiation,CI)至发展阶段中云顶高度、云顶快速降温率(cloud top cooling rate,CTC)以及多通道差值等云顶物理量特征的变化异同。结果表明:深、浅对流在CI阶段的云顶物理量特征具有相似变化特征,即云顶高度均在短时间内快速上升,CTC值均先减小后增大;深、浅对流差异表现为深(浅)对流云顶上升高度能(不能)超越水汽层高度;深对流CTC最低值较浅对流CTC最低值更低。基于CI阶段深、浅对流的CTC最低值的差异,通过个例验证,表明利用深、浅对流CTC最低值的差异,可以在识别出CI的基础,判断出CI是否发展成为深对流,从而能提前做出预警。     

上地幔超高压流体的金刚石压砧实验研究

地球深部流体主要是NaCl-H2O溶液,越到地球深部,它赋存的温度、压力越高,性质状态也不断变化,反之,亦然。当NaCl-H2O流体进入和脱离(上升过程)超临界状态时,其性质会发生截然不同的变化,影响着各种地质过程。使用金刚石压砧在高温高压下原位观测流体的实验,用谱学方法,结合同步辐射光源技术,成为定量化研究地球深部高温超高压流体的有效方法。作者使用同步辐射光源的红外谱研究了10GPa下的NaCl-H2O溶液;在地球化学动力学实验室研究了3GPa,650℃下的NaCl-H2O溶液红外谱,此测量方法可以提供温度压力和体积等数据,能研究其状态。NaCl-H2O溶液红外谱表明水分子主要振动谱受压力和温度影响是不同的。压力增加促使水分子主要振动谱向低波数变化。但是温度增加的效应相反。常温高压下水被压缩,结晶向紧密堆积变化。高温高压下的水有气、液、固和超临界流体各相。水分子间的氢键在近临界态开始减弱,氢键网络被破坏。     

P2P环境中的全局空间数据目录研究

P2P计算通过大量自治的节点协作共享资源与计算,为空间数据和空间操作的分布提供了新的分布式计算模式。分布在不同Peer上的空间数据库节点通过P2P协作构成一个超级全局空间数据库,全局空间数据目录是P2P环境下快速定位空间数据资源和空间计算节点的关键技术。Peer数据库节点的数据模式、元数据、资源状态参数等抽象为一系列关键词集合。全局目录基于Peer空间数据库节点的外包矩形进行动态聚类并建立P2P环境下的空间索引,支持Peer空间数据库节点的动态加入和退出,支持复杂空间查询和关键词查询。该文给出了全局空间数据目录的组织模型、P2P空间数据索引及空间资源发现算法。     

东亚季风气候对Heinrich2事件的响应:来自石笋的高分辨率记录

据湖北省神农架天鹅洞一支石笋11个230Th年龄和254个δ18O数据,建立了28.5～22.0kaB.P.同位素分辨率平均约30a的东亚季风气候变化序列。该石笋δ18O曲线与南京葫芦洞石笋记录在重叠时段基本一致,说明本区石笋δ18O反映了区域性东亚季风经向环流特征。在24.3kaB.P.左右,石笋δ18O明显正偏,持续时间近1ka,指示一次显著的弱夏季风事件,与北大西洋倒数第二次冰漂碎屑事件(Heinrich2)同步发生,可视为东亚季风气候对H2事件的响应。高分辨率的δ18O序列揭示了H2事件的内部结构特征:(1)事件发生的突变性,石笋δ18O记录指示事件发生时在100a内δ18O从-8.59‰迅速正偏为-6.75‰,振幅达1.84‰;(2)事件结束的渐变性,δ18O正偏到-6.75‰后便以阶梯状缓慢负偏到-8.86‰至事件结束,持续时间近900a。这一过程与末次盛冰期东亚季风气候H1事件表现的季风强弱转换方式基本一致,说明末次盛冰期东亚季风气候H型事件具有共同的内部结构特征。研究表明,末次盛冰期东亚季风气候H事件的突变可能受北大西洋驱动并经青藏高原冰川变化放大。     

第一原理计算过渡金属掺杂尖晶石型LiMn2O4的电子结构

尽管对过渡金属掺杂锰酸锂后放电平台的升高现象有众多实验研究,但对其机理的研究却鲜见报道.采用第一原理的密度泛函理论,计算了过渡金属M(M=Ti、Cr、Fe、Co、Ni、Cu、Zn)掺杂尖晶石型LiMn2O4的电子结构,并以此分析放电平台的升高机理.电子态密度分析发现由于M-3d能带的诱导作用,出现了新的O-2p能带,而锂脱出时获得的电子,主要是由费米能级附近O-2p能带提供的.当过渡金属M由Ti变化到Zn时,M-3d能带逐渐向低能量的方向移动,新的O-2p能带出现的位置也随之下移,当Li脱出时,需要更多的能量才能从低能量的O-2p能带上获得电子,因而体系能够获得较高的嵌入电压.     

区域性森林大火的真正成因

森林大火真正起因于地球排气中易燃还原性气体在腐殖层的临界积聚(气体体积分数大约为5%~6%)。现场气体(H2,CO)系统测量结果证实了这一点。测量结果显示,该林区腐殖层中H2、CO质量分数分别为(10~170)×10-6(本底值为0·5×10-6)和(2~60)×10-6(本底值为0·5×10-6),二者均远高于大气本底值数十到数百倍,而且未燃区的测值显然高于1998年燃区。