粉石英在蓄电池胶壳中的应用

本文着重介绍了粉石英的工艺矿物特性以及其在蓄电池胶壳中的应用效果,证明了粉石英用作蓄电池胶壳的填料,能够改善混炼工艺、提高产品质量、增加填充量、降低生产成本,是一种理想的橡胶填料。     

Rock magnetic record of Cenozoic lake sediments from the Linxia basin and aridification of the Asian inland

High resolution research of rock magnetic records and quartz sands from the Maogou Section in the Linxia basin reveals that after a relatively stable environment between 13.07 Ma and 8.6 Ma, the basin was gradually influxed by eolian dusts at about 8.6 Ma, with two rapid increases at about 6.4 Ma and 5.3 Ma, respectively. The study suggests that drying of northwest China began at 8.6 Ma and strengthened rapidly at about 6.4 Ma and 5.3 Ma. __________ Translated from Marine geology & Quaternary geology, 2007, 27(4): 103–110 [译自: 海洋地质与第四纪地质]     

燧石和脉石英中氩,氯的相关性对^40Ar—^39Ar定年意义

由于过剩Ａｒ的存在,长期以来燧石和脉石英的＾４０Ａｒ－＾３９Ａｒ定年被视为不可能。通过对这类矿物中Ａｒ,Ｃｌ丰度及其相关性研究,可以校正过剩Ａｒ,从而实现了这类矿物的年龄测定,这为沉积岩定年及成矿时代的研究提供了重要手段,应用这一技术测得长城系底砾岩中石英年龄为１７４４±９７Ｍａ,滹沱群郭家寨亚群热事件年龄为１７６６±４９Ｍａ,进而推断长城系与郭家寨亚群的层位呈上下系。     

西准噶尔库什库都克石英闪长岩地球化学、年代学及地质意义

库什库都克石英闪长岩位于新疆西准噶尔的达尔布特晚古生代中酸性岩浆岩带中。通过LA-ICP-MS锆石U-Pb定 年,结合锆石阴极发光图像和U、Th元素特征,获得石英闪长岩的年龄为305.3±2.8 Ma（n=19,MSWD=0.17）,时代属晚石 炭世晚期（C2）。石英闪长岩呈半自形不等粒结构,块状构造,矿物成分主要为斜长石、石英、角闪石和黑云母等,局部发 育含柱状辉石的石英辉长闪长岩。岩石的SiO2含量为59.38%~63.37%,全碱变化于6.55%~7.51%;里特曼指数( σ )变化于 2.62~2.88,铝饱和指数(A/CNK值)介于0.83~0.90,为准铝质;岩石轻稀土富集且轻重稀土元素分馏明显,（La/Yb）N 为2.99~ 3.66,负Eu异常（δEu为0.64~0.79）;岩石相对富集Ba、Nd、Zr、K和LREE等元素,而相对亏损Rb、Nb、Th、Sr、P、Ti 和HREE等元素,属高钾钙碱性准铝质I型花岗岩类岩石。石英闪长岩地球化学特征表明其为上地壳变质玄武岩熔融的产 物,在岩浆演化过程中发生了以斜长石、辉石、金红石和磷灰石为主的分离结晶作用,而角闪石基本未发生分离结晶。区 域构造环境演化分析认为西准噶尔不仅在晚石炭世早期存在与俯冲作用相关的岛弧花岗岩,在晚石炭世晚期-早二叠世早 期也存在持续俯冲作用,在此环境下形成了与俯冲作用相关的岛弧型库什库都克石英闪长岩。     

Chemical characteristics of chromian spinel in plutonic rocks: Implications for deep magma processes and discrimination of tectonic setting

We summarize chemical characteristics of chromian spinels from ultramafic to mafic plutonic rocks (lherzolites, harzburgites, dunites, wehrlites, troctolites, olivine gabbros) with regard to three tectonic settings (mid‐ocean ridge, arc, oceanic hotspot). The chemical range of spinels is distinguishable between the three settings in terms of Cr# (= Cr/(Cr + Al) atomic ratio) and Ti content. The relationships are almost parallel with those of chromian spinels in volcanic rocks, but the Ti content is slightly lower in plutonics than in volcanics at a given tectonic environment. The Cr# of spinels in plutonic rocks is highly diverse; its ranges overlap between the three settings, but extend to higher values (up to 0.8) in arc and oceanic hotspot environments. The Ti content of spinels in plutonics increases, for a given lithology, from the arc to oceanic hotspot settings by mid‐ocean ridge on average. This chemical diversity is consistent with that of erupted magmas from the three settings. If we systematically know the chemistry of chromian spinels from a series of plutonic rocks, we can estimate their tectonic environments of formation. The spinel chemistry is especially useful in dunitic rocks, in which chromian spinel is the only discriminating mineral. Applying this, discordant dunites cutting mantle peridotites were possibly precipitated from arc‐related magmas in the Oman ophiolite, and from an intraplate tholeiite in the Lizard ophiolite, Cornwall.     

Effet de la teneur en eau d'un sol sur la réduction bactérienne d'oxydes de fer

Iron-reducing activity of autochthonous bacteria from two temporary hydromorphic soils is evaluated by the study of iron reductive dissolution, as a function of water content. The release of ferrous iron in solution is coupled to the mineralization of soil organic carbon. Water soil saturation is not necessary for iron reductive dissolution, since the highest dissolution is obtained for a wet, but not water-saturated soil (100% of water holding capacity WHC), and dissolution is also very high in a soil at 75% WHC. To cite this article: S.J. Stemmler et al., C. R. Geoscience 336 (2004).     

Long-Term Observations of Isotope Ratio Accuracy and Reproducibility Using Quadrupole ICP-MS

High precision isotope ratio and trace element determination can be achieved with modern quadrupole ICP-MS provided that short and long-term instrument performance is accurately monitored. Here we present results for the isotope ratios ⁶Li/⁷Li, ¹⁴⁷Sm/¹⁴⁹Sm, ¹⁶⁰Dy/¹⁶¹Dy, ²⁰⁷Pb/²⁰⁶Pb, ²⁰⁸Pb/²⁰⁶Pb, ²⁰⁶Pb/²⁰⁴Pb and ²³⁵U/²³⁸U with which we determined long-term isotope ratio stability of relevance to both trace element and isotope determination. With respect to trace element determination, we first present long-term observations regarding oxide formation rates of Ba and Nd on light REE and heavy REE, as well as Zr on Ag. These showed good correlations and could be used to correct effectively the interference. The efficacy of this correction was demonstrated with analyses of the rock reference material BHVO-2 at both low and high oxide formation rates. Next, we studied the long-term reproducibility of a Dy isotope ratio that was measured to correct for the isobaric interference on Gd. It was found that, regardless of tuning condition, the ratio reproduced very well (0.58% RSD, 1s) and that the estimate of the Gd concentration did not suffer from the large correction (> 10%) caused by the Dy isobar. Long-term reproducibilities of Li, Sm and U isotope ratios, required for accurate mass bias correction when isotopically enriched internal standards of these elements are employed, were measured in the rock reference materials AGV-2 and JA-3 over a time period of up to 3 years. As expected, the Li isotope ratio showed the largest variability (RSD = 7%), but the other two ratios had relative external reproducibilities of only 1.01% (1s, U) and 0.67% (Sm). The mass bias-induced scatter in measurements for Sm and U was so small that the internal standard correction was effective, even for samples with high concentrations of these elements. With regard to Pb-isotope ratio determination, we also present long-term reproducibility for NIST SRM 982, run as an unknown and two accuracy tests for Pb separated from granitoids and from meteorites. It is demonstrated that the obtained ratios, including those involving ²⁰⁴Pb, are accurate relative to MC-ICP-MS determinations and of comparable precision to conventional TIMS analysis. The excellent agreement between all data sets shows the potential of modern quadrupole ICP-MS instrumentation for Pb-isotope determination, particularly for samples with very low Pb content.     

大别山双河片麻状花岗岩岩体石英组构特征及应变分析

对大别山双河片麻状花岗岩岩体中的石英C轴组构、黑云母(001)解理极点和石英颗粒三维应变分别进行系统测量。结果显示,双河岩体在侵位和后期演化过程中以挤压变形为特点,岩体经过NW-SE向和NE-SW向两次挤压,NW-SE向挤压强度较大,奠定了岩体基本的构造形态。结合区域应力场特征分析得出,双河岩体在早三叠世至早侏罗世应力方位为NW-SE向挤压,中侏罗世及后期为NE-SW向挤压,应力场发生顺时针变化。      

Implications of trace element composition of syntaxial quartz cements for the geochemical conditions during quartz precipitation in sandstones

A petrographic investigation revealed polyphase quartz cementation in the Finefrau Sandstone (Upper Carboniferous, Western Germany) and the Solling Sandstone (Lower Triassic, Central Germany). Three different cements could be distinguished in each sandstone based on their cathodoluminescence and trace element composition. The first quartz generation is suggested to have been formed during eogenesis due to dissolution and replacement of feldspar. The mesogenetic paragenesis comprises two generations of quartz and illite, which are accompanied by albite in the Solling Sandstone. Sharp luminescence zoning in quartz overgrowths points to distinct episodes of cementation in both sandstones. Significant amounts of Al, Li and H and traces of Ge and B have been detected in the quartz overgrowths. The Al‐content of the quartz cements in the Finefrau Sandstones exceeds that in the quartz cements in the Solling Sandstone by a factor of five. It is suggested that this compositional variation reflects the conditions in the pore‐water, such as temperature and pH. The Al‐concentration is generally correlated to the Li‐content with the exception of the latest quartz generation in the Finefrau Sandstones which is also most enriched in trace elements. The ratio of Li/Al varies between 0·11 and 0·25 in the two sandstones. The Li/H‐ratio, which ranges from 0·12 to 0·3, is controlled by the activity ratio of Li and H in the pore fluid. Clay minerals are the most important source for Li and high salinities favour the mobilization of Li during diagenesis. Thus, a relatively low salinity and low pH are responsible for the low Li/H‐ratio in the Finefrau Sandstone, while high salinity and neutral to alkaline pH results in a high Li/H‐ratio for the Solling Sandstone. The Ge‐contents are generally near the average of detrital quartz and indicate that pressure dissolution is a major source for quartz cementation. Different chemical compositions of distinct quartz generations indicate changes in the physico‐chemical conditions and point to mobilization of silica from different sources (for example, pressure solution and clay mineral transformations).     

Quartz resources in the Serra de Santa Helena formation,Brazil: A geochemical and technological study

This study presents an evaluation of Brazilian quartz deposits of Corinto and Olhos D'água, in Minas Gerais State, as potential high purity raw material for the production of silica glass. Both deposits are part of the Serra de Santa Helena formation, which holds other quartz deposits. Several quartz samples from these mines were analyzed to evaluate their chemical purity, by determination of the content of trace elements by ICP-MS after acid digestion. The technological characteristics of the ores after flame-fusion into silica glass were evaluated according to their bubble generation and UV transparency. The results indicate that silica glass with chemistry suitable for crucible applications can be obtained from materials of both mines, and even optical grade silica glass can be manufactured using transparent ore from one of the mines. In addition, this work explores the trace elements composition of each mine, as well as their fluid inclusions, and characterizes the mines as being of hydrothermal origin. Small differences in the physical and chemical characteristics of quartz that could affect the technological behavior of the ores are related to the geological history of the mines and provide interesting insights regarding the exploration of other quartz resources within the same geological formation.