金活动态提取剂提取-电感耦合等离子体质谱法测定深穿透地球化学样品中的金

金的地球化学勘查基于金的准确测定,地球化学样品中金含量通常处于ng/g水平,需先进行分离富集,再采用电感耦合等离子体质谱法(ICP-MS)或石墨炉原子吸收光谱法(GFAAS)进行测定。当前,隐伏矿床勘查是地球化学探测技术的发展前沿,金活动态提取技术是寻找隐伏金矿的有效手段之一。相比于全量分析,金的活动态含量更低,需要解决选择性提取、高效预富集与准确测定等一系列难题。本文采用柠檬酸铵与土壤中黏土矿物及次生矿物作用促使吸附和可交换组分的金进入提取液,以硫脲和硫代硫酸钠络合金使活动态金向提取液中扩散,达到选择性提取的目的,建立了提取液中金的预富集及ICP-MS测定方法。实验确定的分析条件为:采用5g/L柠檬酸铵-2g/L硫脲-5g/L硫代硫酸钠为提取剂,提取时间24h,在酸性硫脲介质下用活性炭富集金,金吸附率可达89.6%～109.2%,灰化解吸温度为650～700℃。本方法检出限为0.05ng/g,相对标准偏差(RSD)为9.4%～10.2%,加标回收率为91.2%～93.4%。与已报道的硫酸铁-硫脲-硫代硫酸钠溶液提取再GFAAS测定的方法相比,本方法具有检出限低、测试线性范围宽、测试速度快的优势;应用于森林覆盖区黑龙江东安金矿区地球化学探测试验,金活动态异常与隐伏金矿位置一致。     

太湖生态脆弱性特征与消除对策的初步探讨

本文研究了Ｈｇ＾２＋,Ｃｄ＾２＋对痧生经济植物莼菜冬芽茎叶叶绿素含量,叶绿素ａ／ｂ值,可溶性蛋白含量,Ｏ＾－２含量以及活笥氧清除系统活性（ＳＯＤ,ＣＡＴ,ＰＯＤ）的影响,实验结果表明：叶绿素含量,叶绿素ａ／ｂ值、可溶性蛋白含量随着Ｈｇ＾２＋,Ｃｄ＾２＋处理浓度的加大呈下降趋势;     

Vortical mechanism for collimation and acceleration of jets

A vortical mechanism for the collimation and acceleration of astrophysical jets is proposed on the basis of exact solutions of the hydrodynamic equations in a homogeneous gravitational field taking viscosity into account. Velocity profiles in the form of a jet structure with a uniformly rotating trunk whose pressure decreases in time, and longitudinal and converging radial flows of matter, are examined. Because of the radial flow, the angular velocity of the trunk and the velocity of the longitudinal flow of matter can accelerate exponentially or in the manner of an “explosive” instability. Flows of this type have low energy dissipation and can serve as unique channels for the acceleration and collimation of jet eruptions from young stars, as well as from active galactic nuclei and quasars. __________ Translated from Astrofizika, Vol. 51, No. 3, pp. 431–444 (August 2008).     

基于黏度时变性的桩端压力浆液上返高度模型及工程应用

桩端后压浆浆液上返高度对后压浆桩承载力的计算影响较大。基于幂律型流体的黏度时变性特征,推导了考虑黏度时变性的桩端压力浆液上返的理论计算公式,并给出了参数的确定方法及成层土中浆液上返高度的迭代算法;结合台州湾大桥的接线工程,利用电磁波CT对桩基后压浆的加固效果进行了探测分析。结果表明,采用浆液沿压浆管道阻力损失的拟合值并考虑黏度时变性得到的浆液上返高度的计算结果与实测结果基本吻合且偏于安全,而忽略黏度时变性得到的计算结果偏大,会对后压浆桩的承载力设计造成不利影响。此外,电磁波CT能观测到桩体、水泥浆加固体及土体的分布情况,且能推测出水泥浆液在桩端的扩散范围和沿桩身的上返高度,可用于评价后压浆桩的压浆效果。研究成果可为后压浆桩的设计和效果检测提供参考和指导。     

Rheological behavior of dredged slurries at high water contents

Each year in the world, there is significant amount of dredged slurries generated during geotechnical jobs. In the slurry storage process, the rheological behavior is a key factor affecting the motion of dredged slurries. To gain better understanding on this behavior, experiments on dredged slurries with different liquid limits are conducted using rotary viscometer. It has been found that, as water content increases, slurry property can change from Bingham plastic fluids to Newtonian fluids. In log–log coordinates, their corresponding yield stress and plastic viscosity are in linear relationship with their water contents and the intersection of these two lines can be treated as the turning point which is 4.7 times the liquid limit. The yield stress and plastic viscosity of different dredged slurries can be normalized efficiently using normalized water content. So, in this paper, a new quantitative prediction method for yield stress and plastic viscosity is proposed, which is effective for use in alkined modes of motion, is proposed.     

Prediction of one-dimensional compression behavior of Nansha clay using fractional derivatives

Nansha clay is an interactive marine and terrestrial deposited soft clay that is widely spread in Guangzhou, Pearl River Delta, China. To avoid excessive settlement after construction, there is a need for better quantifying the time-dependent deformation of the soft clay. This paper presents a preliminary study to predict the one-dimensional compression of Nansha clay using fractional derivatives. A fractional Merchant model was introduced to describe the time-dependent settlement, and analytical solutions were obtained in terms of the Mittag-Leffler function. The oedometer test results were presented to validate this model. Compared with classical rheological models, the fractional derivative-based model enabled close estimation of the one-dimensional compression with fewer parameters. The meaning of the order of fractional derivative and its relationship with the clay physical properties were explored. It shows that a smaller value of this order corresponded to a higher coefficient of consolidation and a lower coefficient of secondary consolidation. The amplitude of both the primary and secondary consolidation of clay may be estimated quantitatively by the order of fractional derivative. Taken together, these results may open up new avenues for theoretical and empirical modeling of rheological phenomena in clay using fractional derivatives.     

利用GRACE卫星数据提取苏门答腊地震同震和震后重力变化

基于GRACE重力卫星数据,采用P3M6去相关滤波技术、350 km半径的高斯平滑技术与差分方法,提取2004年苏门答腊Mw9.3地震的同震和震后重力场时空演化过程。该地震断层下盘同震重力变化达到4.6 μGal,上盘同震重力变化最大值为-8.3 μGal,该结果与球体位错理论计算结果在量级和分布形态上具有较好的一致性。震后7 a断层下盘重力变化累计达到5.6 μGal,超过同震变化信号|而断层上盘震后重力变化只有0.6 μGal,仅为同震变化信号的11%。该现象表明,断层下盘所在海洋地层的粘滞性较低,地层相对柔软,其地层在震后由于较大的粘滞性松弛效应而持续变形,并伴随较大的重力变化|而断层上盘所在的地层接近陆地地壳特性,地层相对脆硬,震后受地层的粘滞性响应而导致的重力变化相对较小。     

流变边界层及其对华北克拉通热/地震岩石圈底界差异的意义

二维热传导/对流数值模型显示,纯传导的固体岩石圈与纯对流的流体软流圈之间存在一过渡层,即流变边界层,其间传导与对流共同作用来传递热量.流变边界层厚度主要由软流圈黏性系数（η）控制,而受固体岩石圈厚度及热状态影响很小.随着η从1×10²¹Pa·s降低至1×10¹⁹ Pa·s,流变边界层也随之减薄,流变边界层的厚度与lg（η）成正比. 流变边界层的存在是造成热岩石圈与地震岩石圈厚度差异的重要因素. 全球典型克拉通岩石圈的对比结果表明,地震岩石圈厚度普遍大于热岩石圈厚度,二者的差异多数在70~90 km,很好地验证了流变边界层的存在. 研究发现二者的差异在华北克拉通自西向东逐渐减小：由西部鄂尔多斯的约80 km减少至渤海湾盆地的约20 km. 反映出华北克拉通岩石圈下部流变边界层厚度自西向东减薄,意味着软流圈黏性系数自西向东逐渐降低.这可能与中生代太平洋俯冲脱水形成的低黏大地幔楔有关,从一侧面印证了太平洋俯冲对华北克拉通破坏的影响.     

不同应力状态下软黏土蠕变特性试验研究

土的蠕变性质受到许多因素的影响,在不同的应力条件下土会呈现出不同的性状。天津滨海吹填软土同样具有一般软土的蠕变特性,以其为研究对象,利用土体三轴流变试验机进行了三轴不固结不排水蠕变试验和单轴压缩蠕变试验,并选取了10个时间节点取样进行微型十字板剪切试验,研究抗剪强度变化规律。试验结果表明,单轴压缩蠕变和三轴蠕变历时曲线都具有非线性的特征,随应力水平的提高,单轴压缩蠕变的应力-应变等时曲线向应力轴靠拢,三轴蠕变的应力-应变等时曲线向应变轴靠拢;线性蠕变变形的情况下黏滞系数主要与时间有关,非线性的情况下与时间和应力水平都相关;在三轴蠕变状态下压缩模量随时间增长而减小,长期强度随时间先降低再趋于稳定;单轴压缩时压缩模量随时间增长而提高,长期强度随时间先增长后稳定。最后经过推导得出了不同应力状态下的长期强度随时间、偏应力的函数关系式。