Assessing surface water quality of the Yangtze Estuary with genotoxicity data

The present study investigated the genotoxicity of the surface water samples from the Yangtze Estuary with the Ames test in three seasons. Several important chemical parameters, such as COD inorganic nitrogen, active phosphate and heavy metals, were also analyzed at the same time. According the results, surface water samples from the south branch and a few of samples at the seaward end of the Yangtze Estuary show positive genotoxicity in some seasons. Chemical analysis revealed that the Yangtze Estuary was seriously polluted by inorganic nitrogen and by active phosphate. However, chemical parameters could not demonstrate the spatial variation of water quality of the estuary, and they could not assess adverse effects of chemicals in mixtures as well. Therefore, it is recommended that genotoxicity data, mutation rate of the Salmonella typhimurium strain TA98 at the dose of 1 l per plate, be taken as a new parameter assessing surface water quality of the Yangtze Estuary. Our studies also suggested that genetic toxicology assays, such as the Ames test, could be applied as a routine measure to monitoring marine environment in China. The paper proposes a development of the National Seawater Quality Standard of China.     

Thermal expansion of gehlenite, Ca2Al[AlSiO7], and the related aluminates LnCaAl[Al2O7] with Ln=Tb, Sm

The thermal expansion of gehlenite, Ca₂Al[AlSiO₇], (up to T=830 K), TbCaAl[Al₂O₇] (up to T=1,100 K) and SmCaAl[Al₂O₇] (up to T=1,024 K) has been determined. All compounds are of the melilite structure type with space group Thermal expansion data was obtained from in situ X-ray powder diffraction experiments in-house and at HASYLAB at the Deutsches Elektronen Synchrotron (DESY) in Hamburg (Germany). The thermal expansion coefficients for gehlenite were found to be: α₁=7.2(4)×10⁻⁶ K⁻¹+3.6(7)×10⁻⁹ΔT K⁻² and α₃=15.0(1)×10⁻⁶ K⁻¹. For TbCaAl[Al₂O₇] the respective values are: α₁=7.0(2)×10⁻⁶ K⁻¹+2.0(2)×10⁻⁹ΔT K⁻² and α₃=8.5(2)×10⁻⁶ K⁻¹+2.0(3)×10⁻⁹ΔT K⁻², and the thermal expansion coefficients for SmCaAl[Al₂O₇] are: α₁=6.9(2)× 10⁻⁶ K⁻¹+1.7(2)×10⁻⁹ΔT K⁻² and α₃=9.344(5)×10⁻⁶ K⁻¹. The expansion-mechanisms of the three compounds are explained in terms of structural trends obtained from Rietveld refinements of the crystal structures of the compounds against the powder diffraction patterns. No structural phase transitions have been observed. While gehlenite behaves like a ’proper’ layer structure, the aluminates show increased framework structure behaviour. This is most probably explained by stronger coulombic interactions between the tetrahedral conformation and the layer-bridging cations due to the coupled substitution (Ca²⁺+Si⁴⁺)-(Ln ³⁺+Al³⁺) in the melilite-type structure. Electronic Supplementary Material Supplementary material is available for this article at     

Experimental and numerical investigations of stresses in a fully grouted rock bolts

Rock bolts are widely used for rock reinforcement in hard-rock mining and civil engineering since a long time. However the use of fully grouted rock bolts and cable bolts is limited in coal mines. In order to improve performance of the rock bolts as a supplementary roof support system for any type of roof condition in coal measured formations, it is necessary to have a good understanding of the behavior of the bolt–grout and grout–rock interactions as well as the mechanism of load transfer in rock bolts.As the performance of grouted bolts depends on bond strength, extensive laboratory pullout as well as pushout tests were conducted in the present investigations with the variations in the bolt diameters, length and cement–water mixing ratios of grout. The load–displacement curves were developed and were verified with the numerical results obtained from finite element analysis using ALGOR software.Numerical models were validated for pushout tests and a detailed analysis was carried out to know the displacement, stress, strain distribution along the bolt.     

A study on the bio-hydro mechanical effects of the tree roots on the Agaclı coal reclaimed – forested land

The research area that is in the north of Istanbul (Turkey) and it is a land of open pit coal mining residuals reclaimed and turned to forest in 1988–1989. The materials that are open pit mine spoils are formed by sandy loam, sandy clay loam, heavy loam and clay (noncalcareous Pliocene I sediments). Pseudoacacia (Robinia pseudoacacia), Maritima Pine (Pinus pinaster) and Stone Pine (Pinus pinea) are planted on these materials. The aims of this research were to determine the strength of the material provided by tree roots and evaluate the performance of the forestation practices at lands especially where open pit coal mining spoil (residual) materials piled up. The research has been performed at two stages. The first one was hydro-mechanical effect concerned about material moisture depletion as a result of transpiration and the second one was bio-mechanical effects due to strength parameters of the roots and their growth pattern within the material. All results were evaluated in relation to tensile strength and displacement curves due to pre and post failure behaviors of materials and root systems. The results showed the increase of the displacement of the material was the significant indicator of the bio-mechanics tensile strength of the material provided by the tree roots. The fast growing type of tree roots have stabilized the material up to a depth for 80–100 cm by covering the coal residual materials within 12 years.     

水平分层弹性粘弹性介质的静力响应

本文首先利用传播矩阵法构造出了水平分层弹性介质在表载、体力及内部力源联合作用下的一般模型。然后利用“对应原理”将弹性问题的一般模型推广到粘弹性问题的一般模型——粘弹性分层介质传播矩阵基本方程。最后用粘弹性分层介质传播矩阵方程对一个实际地学问题做了试算,计算结果说明,用传播矩阵法处理粘弹性问题是非常有效的。     

SDINS/GPS in-flight alignment using GPS carrier phase rate

The alignments of the strapdown inertial navigation system (SDINS) utilizing GPS carrier phase rate measurements is introduced. In this paper, a measurement model of GPS carrier phase rate under two antenna configurations is derived in order to be used for the SDINS alignment process. For in-flight alignment, the performance of the proposed SDINS/GPS integration method is analyzed using the covariance analysis and the overall performance is briefly confirmed by the navigation result of a van test. Furthermore, we find that during in-flight alignment the proposed SDINS/GPS integrated system using GPS carrier phase rate measurements can be implemented in real time because the integer ambiguity problem resulting from carrier phase measurements is avoided.     

The hydrogeothermal basin of Sofia graben (Bulgaria)

Abstract In the Mesozoic basement and Neogene filling of Sofia tectonic graben a non-homogenous system of thermal water reservoirs connected to a united hydrogeothermal basin occurred. The basin contains and reproduces five types of low mineralized thermal waters and four types of mineralized thermal waters with exotic composition. The water temperatures are 30–80(90) ^°C. The total potential of the basin is assessed at 500 l/s thermal waters and 48 MWt thermal power. The utilization of thermal waters in the area of the Bulgarian capital has its roots and traditions in antiquity, and a promising future. The new town plan of Sofia provides construction of 35 centers for developing a versatile and prosperous hydrothermal business.     

Trace elements in medium-temperature (40–80 °C) thermal waters from the Mura basin (North-Eastern Slovenia)

Medium-temperature thermal waters in the Mura basin occur in hydrogeological systems different in age, burial depth, temperature, porosity and permeability, and the presence of free carbon dioxide which penetrates through the fractures from pre-Tertiary basement. The waters commonly belong to sodium-bicarbonate hydrogeochemical facies, but may have significantly different amounts of total dissolved solids, including trace elements. Thermal waters occurring in low-permeable, well-compacted and moderately fractured Tertiary sediments older than Upper Pliocene are the richest in trace elements, although their abundance may be very variable from one aquifer to another. The ratios of major alkaline and alkaline earth elements (Na, K, Ca) and trace elements (Li, Rb, Cs, Ba, Sr) commonly show relative enrichment in highly mineralised waters with respect to the waters with lower mineralisation. Rare earth elements (REEs) and Y show only minor fractionation in the highly mineralised waters, whereas in the waters with lower mineralisation strong fractionation of heavy rare earth elements (HREEs) over light rare earth elements (LREEs) occurs, along with a pronounced positive europium anomaly. Positive Th/U ratios are commonly observed, although both actinide elements occur in the range of some hundredths of ppb to some ppb. Trace elements were particularly useful in the study of well cycling in two hydraulically interconnected geothermal wells in the town of Murska Sobota, which produce a mixture of low- and high-mineralised waters.     

Therapeutic waters in the Polish geological and mining law

The Polish legislation gives groundwaters declared as curative ones a high rank of basic minerals or, in well-defined cases, of common minerals. Both kinds of minerals are subject of mining law regulations. This explains the use of the word deposit which, in the case of groundwaters, often does not reflect reality.     

Vulnerability assessment in karstic areas: validation by field experiments

Several methods have been developed for vulnerability mapping in karstic areas. These methods need additional validation by field experiments. Several tests have been carried out in the Swiss Jura with natural and artificial tracers. The protective role of some intrinsic properties of the system, such as glacial deposits covering karst, epikarst storage and system dilution effect, have been clearly demonstrated. Use of three tracers in parallel showed the reactivity of the epikarst: all tracers arrived at the same time, but their relative concentration stayed clearly different. A classification of contamination scenarios into four classes is proposed. It is shown that the relevance of some intrinsic properties depends on the considered scenario class. The hydrodynamic state of the aquifer influences greatly flow velocities and can strongly modify contaminant concentrations at the output of the system. The spatial repartition (point vs diffuse) and the quantity of contaminant entering the system will also influence the output response. Hence, results from tracing experiments cannot be used straightforward for obtaining a representative value of flow velocity, dispersion or recovery rate.