Nature and role of CO2 in some hot and cold HCO3/Na/CO2-rich Portuguese mineral waters: a review and reinterpretation

 At the northern part of the Portuguese mainland, the upflow zone of several hot and cold HCO₃/Na/CO₂-rich mineral waters is mainly associated with important NNE–SSW faults. Several geochemical studies have been carried out on thermal and non-thermal hydromineral manifestations that occur along or near these long tectonic alignments. The slight chemical differences that exist between these meteoric hot and cold HCO₃/Na/CO₂-rich mineral waters seem to be mainly caused by CO₂. δ¹³C_(TIDC) values observed in these groundwaters range between –6.00 and –1.00‰ versus V-PDB (V denotes Vienna, the site of the International Atomic Energy Agency; PDB originates from the CaCO₃ of the rostrum of a Cretaceous belemnite, Belemnitella americana, collected in the Peedee formation of South Carolina, USA) indicating a deep-seated (mantle) origin for most of the CO₂. Nevertheless, in the case of the heavier δ¹³C_(TIDC) values, the contribution of metamorphic CO₂ or the dissolution of carbonate rock levels at depth cannot be excluded. Concerning the hot waters, the lack of a positive ¹⁸O-shift should be attributed to water-rock interaction in a low temperature environment, rather than to the isotopic influence of CO₂ on the δ¹⁸O-value of the waters. Received: 9 August 1999 · Accepted: 8 March 2000     

Digital quantification of the miospore coloration to assess the thermal maturity: Novel RGB-based measuring technique

The post depositional thermal maturity and its related chemical changes induce the sporomorphs color alteration, which is a common useful tool in the optical microscopy of the organic matters (OM) and their pre-geochemical studies. The present contribution uses the modern available opportunity of digital technology to achieve a quantifying system technique, which includes color measurements and their possible graphic presentation. The normal digital images of sporomorphs from several ages and geological settings are used to obtain color measurements in the form of digital Red, Green and Blue triple color system (RGB). These measurements were accomplished using some software programs such as Photoshop™^© or ImageJ with employing average microscope setup. The triple RGB color readings are plotted on a ternary diagram, which is divided into three fields. These fields express the maturity levels. The presented new RGB-based quantifying technique is economic and provides a simple examination for maturity, which is linked to the hydrocarbon generation. This can partially replace or walk side by side with the vitrinite reflectance microscopy.     

Abodes for life in carbonaceous asteroids?

Thermal evolution models for carbonaceous asteroids that use new data for permeability, pore volume, and water circulation as input parameters provide a window into what are arguably the earliest habitable environments in the Solar System. Plausible models of the Murchison meteorite (CM) parent body show that to first-order, conditions suitable for the stability of liquid water, and thus pre- or post-biotic chemistry, could have persisted within these asteroids for tens of Myr. In particular, our modeling results indicate that a 200-km carbonaceous asteroid with a 40% initial ice content takes almost 60 Myr to cool completely, with habitable temperatures being maintained for ∼24 Myr in the center. Yet, there are a number of indications that even with the requisite liquid water, thermal energy sources to drive chemical gradients, and abundant organic “building blocks” deemed necessary criteria for life, carbonaceous asteroids were intrinsically unfavorable sites for biopoesis. These controls include different degrees of exothermal mineral hydration reactions that boost internal warming but effectively remove liquid water from the system, rapid (1-10 mm yr⁻¹) inward migration of internal habitable volumes in most models, and limitations imposed by low permeabilities and small pore sizes in primitive undifferentiated carbonaceous asteroids. Our results do not preclude the existence of habitable conditions on larger, possibly differentiated objects such as Ceres and the Themis family asteroids due to presumed longer, more intense heating and possible long-lived water reservoirs.     

Orbital and thermal evolutions of four potential targets for a sample return space mission to a primitive near-Earth asteroid

In this paper, we present our study of the orbital and thermal evolutions, due to solar radiative heating, of four near-Earth asteroids (NEAs) considered as potential target candidates for sample return space missions to primitive asteroids. We used a dynamical model of the NEA population to estimate the most likely source region and orbital history of these objects. Then, for each asteroid, we integrated numerically over their entire lifetime a set of 14 initially indistinguishable orbit (clones), obtained by small variations of the nominal initial conditions. Using a thermal model, we then computed surface and sub-surface temperatures of these bodies during their dynamical history. Our aim is to determine whether these bodies are likely to have experienced high temperature level, and whether great temperature changes can be expected due to the orbital changes as well as their maximum and minimum values. Such information is important in the framework of sample return space missions whose goal is to bring back pristine materials. The knowledge of the temperature range of materials at different depth over the orbital evolution of potential targets can help defining sampling strategies that ensure the likelihood that unaltered material will be brought back. Our results suggest that for all the considered potential targets, the surface has experienced for some time temperatures greater than 400 K and at most 500 K with 50% probability. This probability drops rapidly with increasing temperature. Sub-surface materials at a depth of only 3 cm are much more protected from high temperature and generally do not reach temperatures exceeding 450 K (with 50% probability). They should thus be unaltered at this depth at least from a Sun-driven heating point of view. On the other hand, surface material for some of the considered objects can have a range of temperature which can make them less reliable as pristine materials. However, it is assumed here that the same material is constantly exposed to solar heat, while regolith turnover may occur. The latter can be caused by different processes such as seismic shaking and/or impact cratering. This would reduce the total time that materials are exposed to a certain temperature. Thus, it is very likely that a sample collected from any of the four considered targets, or any primitive NEA with similar dynamical properties, will have components that will be thermally unaltered as long as some of it comes from only 3 to 5 cm depth. Such a depth is not considered difficult to reach with some of the current designs of sampling devices.     

云南巧家仓房沟铅锌矿矿床成矿模式

铅锌矿赋存于灯影组硅质条带白云岩中,局部产于筇竹寺组,脉状、透镜状,与峨眉山玄武岩喷发关系密切,属岩浆晚期热液成因。     

Holocene paleoenvironmental changes inferred from diatom assemblages in sediments of Kusawa Lake, Yukon Territory, Canada

The southwest Yukon Territory, Canada, is an important region for recovering sensitive records of Holocene paleoclimatic change. More information is needed, however, to constrain the timing of the major Holocene climatic transitions, and to understand associated impacts on different ecosystems. For example, paleolimnological studies have focused on small lakes and ponds, but the history of large lakes has received little study. We analyzed diatom assemblages, species richness, valve concentrations, and biogenic silica, in the sediments of Kusawa Lake (60°16.5'N; 136°10.9'W; 671 m a.s.l.) to reconstruct the responses of this large (surface area = 142 km²), deep (Z_max = 135 m) freshwater ecosystem to Holocene climatic transitions. Diatoms colonized the lake soon after ice retreat, around 11,000 cal yr BP; assemblages throughout the record were dominated by planktonic types. Diatom concentrations and biogenic silica were high during the Holocene Thermal Maximum between 10,700 and 7300 cal yr BP, then began to decrease in response to cooling associated with orbitally driven reductions in insolation. Diatom assemblages shifted towards taxa with lower surface water temperature optima after 8300 cal yr BP, perhaps in response to abrupt and progressive cooling. Our study confirms that diatom assemblages in large lakes are sensitive to regional-scale paleoclimatic changes.     

Recent Changes Occurred in the Terminus of the Debris-covered Bilafond Glacier in the Karakoram Himalayas Using Remotely Sensed Images and Digital Elevation Models (1978-2011)

Recent changes occurred in terminus of the debris-covered Bilafond Glacier in the Karakoram Range in the Himalayas, Northern Pakistan was investigated in this research. Landsat MSS, TM and ETM＋ images were used for this study. Digital elevation models derived from ASTER GDEM and SRTM were also utilized. Visible, infrared and thermal infrared channels were utilized in order to get accurate glacier change maps. Three methods were tried to map this debris-covered glacier in this research. The glacier has been mapped successfully and the changes in the glacier terminus from 1978 to 2011 have been calculated. Manual, semi-automatic and thermal methods were found to give similar results. It was found that the glacier has undergone serious ablation during this period despite of the fact that many of the larger glaciers in the Hindu Kush and Karakoram mountain regions in the Upper Indus Basin were reported to be expanding. The terminus has been moved back about 600 meters during this period and there was an abrupt change in the glacier terminus during 1990-2002. We propose that debris thickness is not the only factor that influences the glacier ablation but the altitude of the debris-covered glacier as well. Many glaciers in the Karakoram region reported to be expanding were having higher altitudes compared to the study area.     

汶泗河冲洪积扇松散层现场热响应试验数据分析及应用——以兖州市南郊试验场为例

现场热响应试验是获取岩土体热物性参数的主要方法之一,可为试验场区地源热泵工程地埋管换热器类型及长度的选择,浅层地热能评价和开发利用提供基础数据。该文系统介绍了现场热响应试验的目地任务、试验装置、原理、内容和步骤,数据处理方法,并以位于汶泗河冲洪积扇中上流地区的兖州市南郊试验场松散层现场热响应试验为例,介绍了试验场区水文地质条件,试验过程、试验数据分析及应用。     

Thermal and compositional stratification of the inner core

The improvements of the knowledge of the seismic structure of the inner core and the complexities thereby revealed ask for a dynamical origin. Sub-solidus convection was one of the early suggestions to explain the seismic anisotropy, but it requires an unstable density gradient either from thermal or compositional origin, or from both. Temperature and composition profiles in the inner core are computed using a unidimensional model of core evolution including diffusion in the inner core and fractional crystallisation at the inner core boundary (ICB). The thermal conductivity of the core has been recently revised upwardly and, moreover, found to increase with depth. Values of the heat flow across the core mantle boundary (CMB) sufficient to maintain convection in the whole outer core are not sufficient to make the temperature in the inner core super-isentropic and therefore prone to thermal instability. An unreasonably high CMB heat flow is necessary to this end. The compositional stratification results from a competition of the increase of the concentration of light elements in the outer core with inner core growth, which makes the inner core concentration also increase, and of the decrease of the liquidus, which makes the partition coefficient decrease as well as the concentration of light elements in the solid. While the latter (destabilizing) effect dominates at small inner core sizes, the former takes over for a large inner core. The turnover point is encountered for an inner core about half its current size in the case of S, but much larger for the case of O. The combined thermal and compositional buoyancy is stabilizing and solid-state convection in the inner core appears unlikely, unless an early double-diffusive instability can set in.     

Analysis on the law of occurrence of shallow geothermal energy in Zhoukou City of Henan Province,China

In this paper, through data collection and field investigation, the development and utilization status of shallow geothermal energy in Zhoukou urban area was discussed. Based on the analysis of hydrogeological conditions, rock and soil structure characteristics and field test research, the spatial distribution characteristics of rock and soil in the study area were summarized. The study shows that Zhoukou City is located in the alluvial plain of Huanghuai, and the loose deposits of river alluvial genesis range 0-200 m. These loose deposits and groundwater stored in their pores are the main carriers of shallow geothermal energy. In the central part of the Yinghe River in the middle of the study area, the aquifer thickness is within 200 m, the particle size is coarser, the water-bearing degree and recharge capacity is better. On this basis, the paper uses AHP to evaluate the suitability of shallow geothermal energy development and utilization to guide the rational development and utilization of shallow geothermal energy resources.