Non-equilibrium Condensation ina Primordial Solar Nebula: Formation of Refractory Metal Nuggets

We present a theoretical investigation of non-equilibrium condensation of refractory metalsinthe primordial solar nebula, in relation to the origin of “Fremdlinges” included inCAIs. Todescribe the nucleation process of grains from vapor, weadopted asemi-phenomenological modelmodified fromthe classical nucleation theoryby the introductionof the second virial coefficient of vapor. This modelachieves excellent agreement with nucleation rate experiment. However,the second virial coefficients are unknown for a vapor of refractory metals. To overcome this, weexpress the nucleation rate by theuse of the chemical potential of dimersinsteadof the second virial coefficient.On the basis of this new nucleation theory,we have performed numerical simulations ofnon-equilibrium condensation of refractory metals andfind thattheircondensation temperatures, T_c, decrease considerably in comparison withequilibrium condensation. Even if the characteristiccooling time scale is aslarge as 1×10⁵ years, the decrease in T_c isfrom 200 to 400 Kfor rare elements such as W, Re,and Os. This remarkablenon-equilibrium behaviormainly stemsfromthelow totalpressure in the primordial solar nebula. From our new modelwealso obtainthe typical size ofgrainsformed in condensation. We findthatthe cooling time should be ?1×10⁵ years for sub-micron-sized or largerrefractory metal nuggetsto form.     

青藏高原500hpa暖性高压生成的热成风适应机制

本文利用热成风适应原理,采取分解分析法对青藏高原500hpa暖性高压的生成机制作了一些定性和定量的讨论。结果表明:在扰动的水平尺度大于热成风适应的特征尺度的条件下,当源地有明显的负值非热成风涡度出现时,流场将向温度场适应,而温度场由于高原的加热作用存在暖中心或暖脊,则适应的结果在高原大气500hpa形成暖性高压,并伴随高层辐合,低层辐散及下沉运动。     

中国稠油油田开发趋向

我国稠油资源非常丰富,在东部和西部几个大油区均有分布,而且储量很大。近年来由于热采等先进技术的应用,使稠油开采得以发展,呈现出良好的前景。     

Convective-conductive transitions and sensitivity of a convecting ice shell to perturbations in heat flux and tidal-heating rate: Implications for Europa

We investigate the response of conductive and convective ice shells on Europa to variations of heat flux and interior tidal-heating rate. We present numerical simulations of convection in Europa's ice shell with Newtonian, temperature-dependent viscosity and tidal heating. Modest variations in the heat flux supplied to the base of a convective ice shell, ΔF, can cause large variations of the ice-shell thickness Δδ. In contrast, for a conductive ice shell, large ΔF involves relatively small Δδ. We demonstrate that, for a fluid with temperature-dependent viscosity, the heat flux undergoes a finite-amplitude jump at the critical Rayleigh number Racr. This jump implies that, for a range of heat fluxes relevant to Europa, two equilibrium states—corresponding to a thin, conductive shell and a thick, convective shell—exist for a given heat flux. We show that, as a result, modest variations in heat flux near the critical Rayleigh number can force the ice shell to switch between the thin, conductive and thick, convective configurations over a ∼10⁷-year interval, with thickness changes of up to ∼10-30 km. Depending on the orbital and thermal history, such switches might occur repeatedly. However, existing evolution models based on parameterized-convection schemes have to date not allowed these transitions to occur. Rapid thickening of the ice shell would cause radial expansion of Europa, which could produce extensional tectonic features such as fractures or bands. Furthermore, based on interpretations for how features such as chaos and ridges are formed, several authors have suggested that Europa's ice shell has recently undergone changes in thickness. Our model provides a mechanism for such changes to occur.     

Trapping and adsorption of CO2 in amorphous ice: A FTIR study

The interaction of carbon dioxide and amorphous water ice at 95 K is studied using transmission infrared spectroscopy. Samples are prepared in two ways: co-deposition of the gases admitted simultaneously or sequential deposition, in which amorphous water ice (ASW) is grown first and CO₂ vapor is added subsequently. In either case, a fraction of the CO₂ molecules is found to interact with water in a way that gives rise to shifts and splittings in the infrared bands with respect to those of a pure CO₂ solid. In co-deposition experiments, a larger amount of carbon dioxide is trapped within the amorphous water than in sequential deposition samples, where a substantial proportion of molecules appears to be trapped in macropores of the ASW. The specific surface area of sequential samples is evaluated and compared to previous literature results. When the sequential samples are heated to 140 K, beyond the onset temperature at which water ice undergoes a phase transition, the CO₂ molecules at the pores relocate inside the bulk in a structure similar to that found in co-deposited samples, as deduced by changes in the shape of the CO₂ infrared bands.     

Surface temperature differences between minerals in crystalline rocks: Implications for granular disaggregation of granites through thermal fatigue

Thermal expansion differences between minerals within rocks under insolation have previously been assumed to drive breakdown by means of granular disaggregation. However, there have been no definitive demonstrations of the efficacy of this weathering mechanism. Different surface temperatures between minerals should magnify thermal expansion differences, and thus subject adjacent minerals to repeated stresses that might cause breakdown through fatigue failure. This work confirms the existence of surface temperature differences between minerals in granitic rocks under simulated short-term temperature fluctuations so as to discriminate their potential for initiating granular disaggregation. The influence of colour, as a surrogate for albedo, and crystal size, as a function of thermal mass are specifically identified because of their ease of quantification. Four rock types with a range of these properties were examined, and subjected to repeated short-term temperature cycles by radiative heating and cooling under laboratory conditions. Results show that while albedo is the main control for overall and individual maximum temperatures, crystal size is the main factor controlling higher temperature differences between minerals. Thus, stones with large differences of mineral sizes can undergo magnified stresses due to thermal expansion differences.     

Thermal evolution of an extensional detachment as constrained by organic metamorphic data and thermal modeling: Graz Paleozoic Nappe Complex (Eastern Alps)

Following Early Cretaceous nappe stacking, the Eastern Alps were affected by late-orogenic extension during the Late Cretaceous. In the eastern segment of this range, a Late Cretaceous detachment separates a very low- to low-grade metamorphic cover (Graz Paleozoic Nappe Complex, GPNC) above a low- to high-grade metamorphic basement. Synchronously, the Kainach Gosau Basin (KGB) collapsed and subsided on top of the section.Metamorphism of organic material within this section has been investigated using vitrinite reflectance data and Raman spectra of extracted carbonaceous material. In the southern part of the GPNC, vitrinite reflectance indicates a decrease in organic maturity towards the stratigraphic youngest unit. The remaining part of the GPNC is characterized by an aureole of elevated vitrinite reflectance values and Raman R2 ratios that parallels the margins of the GPNC. Vitrinite reflectance in the KGB shows a steep coalification gradient and increases significantly towards the western basin margin. The observed stratigraphic trend in the southern GPNC is a result of deep Paleozoic to Early Cretaceous burial. This maturity pattern was overprinted along the margins by advective heat and convective fluids during Late Cretaceous to Paleogene exhumation of basement rocks.During shearing, the fault zone was heated up to ca. 500 °C. This overprint is explained by a two-dimensional thermal model with a ramp-flat fault geometry and a slip rate of 1 to 1.5 cm/year during 5 Ma fault movement. The collapse basin above the detachment subsided in a thermal regime which was characterized by relaxing isotherms.     

http://www.sciencedirect.com/science/article/pii/S1674987111000788

This paper presents numerical investigation on the ore-forming fluid migration driven by tectonic deformation and thermally-induced buoyancy force in the Chanziping ore district in South China. A series of numerical scenarios are considered to examine the effect of meteoric water precipitation, the dip angle of the faults, unconformity surface, and thermal input on the ore genesis. Our computations reveal that the downward basinal fluid flow driven by extensional stress mixes with the upward basal fluid driven by the thermal input from depth at the junction of two faults at a temperature of about 200 C, triggering the precipitation of the Chanziping uranium deposit.     

利用AMTIS数据反演植被和土壤温度

遥感陆面温度 (LST)是目前遥感界面临的重要课题 ,组分温度反演则为LST反演的主攻目标。如果混合像元组分间的温度及发射率存在明显差别 ,就可以从多角度热辐射亮度变化中分离出组分温度的信息。在热辐射矩阵模型的基础上 ,讨论了确定可反演参数和反演组分温度的方法 ,并以AMTIS多角度热红外图像为数据源 ,在进行几何和大气纠正后 ,尝试利用矩阵反演方法分解混合像元中的植被和土壤温度。误差分析表明土壤温度反演结果较好 ,但植被温度的反演精度不高     

Advances in understanding of the mechanism for generation of earthquake thermal precursors detected by satellites

Stresses building up during an earthquake preparation phase also manifest themselves in the form of a so called increased land surface temperature (LST) leading to a thermal precursor prior to the earthquake event. This phenomenon has now been validated by our observations of short-term thermal anomalies detected by infrared satellite sensors for several recent past earthquakes around the world. The rise in infrared radiance temperature was seen to vary between 5 and 12 °C for different earthquakes. We discuss in this paper different explanations for the generation of such anomalies that have been offered. Emission of gases due to the opening and closure of micropores upon induced stresses and also the participation of ground water have been propounded as a possible cause for generation of thermal anomalies. Seismo-ionosphere coupling, by which gases like radon move to the earth–atmosphere interface and cause air ionization thus bringing about a change in air temperature, relative humidity, etc., has been put forth by some workers. A mechanism of low frequency electromagnetic emission was tested and experimented by scientists with rock masses in stressed conditions as those that exist at tectonic locations. The workers proposed the positive hole pair theory, which received support from several scientific groups. Positive holes (sites of electron deficiency) are activated in stressed rocks from pre-existing yet dormant positive hole pairs (PHPs) and their recombination at rock–air interface leads to a LST rise. A combination of remote sensing detection of rock mechanics behavior with a perception of chemistry and geophysics has been applied to propose the remote sensing rock mechanics theory. Remote sensing detections of such anomalies confirm so far proposed lab theories for such a hotly debated field as earthquake precursor study by providing unbiased observations with consistency in time and space distribution.