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81.
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83.
Initial coagulation rates of colloidal hematite (-Fe2O3) particles (diameter less than 0.1 µm) were measured experimentally in well-defined laboratory systems at constant temperature. The relative stability ratio,W, was obtained at various ionic strengths in NaCl medium and at pH values in the range from 3 to 12. ExperimentalW values ranged from 1 to 104 in various systems. The results delineate the roles ofspecific andgeneralized coagulation mechanisms for iron oxides. Among the specifically-interacting species (G
ads
0
>G
coul
0
) studied were phosphate, monomeric organic acids of various structures, and polymeric organic acids. The critical coagulation-restabilization concentrations of specifically-interacting anions (from 10–7 to 10–4 molar) can be compared with the general effects of non-specific electrolyte coagulants (10–3 to 10–1 molar). The laboratory results are interpreted with the help of a Surface Complex Formation/Diffuse Layer Model (SCF/DLM) which describes variations of interfacial charge and potential resulting from variations of coagulating species in solution. Comparison of these laboratory experiments with observations on iron behavior in estuarine and lake waters aids in understanding iron removal mechanisms and coagulation time scales in natural systems. 相似文献
84.
Koichiro Fujinaga Tatsuo Nozaki Takazumi Nishiuchi Kiyoko Kuwahara Asuhiro Kato 《Resource Geology》2006,56(4):399-414
Abstract. Major and trace element contents are reported for Permian manganese ore and associated greenstone from the Ananai manganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The manganese deposit occurs between greenstone and red chert, or among red chert beds. Chemical compositions of manganese ore are characterized by enrichments in Mn, Ca, P, Co, Ni, Zn, Sr and Ba, and negative Ce and positive Eu anomalies relative to post-Archean average Australian Shale (PAAS). Geochemical features of the manganese ore are similar to those of modern submarine hydrother-mal manganese deposits from volcanic arc or hotspot setting. In addition, geochemical characteristics of the greenstone closely associated with the Ananai manganese deposit are analogous to those of with-in plate alkaline basalt (WPA). Consequently, the Ananai manganese deposit was most likely formed by hydrothermal activity related to hotspot volcanism in the Panthalassa Ocean during the Middle Permian. This is the first report documenting the terrestrially-exposed manganese deposit that was a submarine precipitate at hotspot. 相似文献
85.
Abstract. Lermontovskoe tungsten skarn deposit in central Sikhote-Alin is concluded to have formed at 132 Ma in the Early Cretaceous, based on K-Ar age data for muscovite concentrates from high-grade scheelite ore and greisenized granite. Late Paleozoic limestone in Jurassic - early Early Cretaceous accretionary complexes was replaced during hydrothermal activity related to the Lermontovskoe granodiorite stock of reduced type. The ores, characterized by Mo-poor scheelite and Fe3+- poor mineral assemblages, indicate that this deposit is a reduced-type tungsten skarn (Sato, 1980, 1982), in accordance with the reduced nature of the granodiorite stock.
The Lermontovskoe deposit, the oldest mineralization so far known in the Sikhote-Alin orogen, formed in the initial stage of Early Cretaceous felsic magmatism. The magmatism began shortly after the accretionary tectonics ceased, suggesting an abrupt change of subduction system. Style of the Early Cretaceous magmatism and mineralization is significantly different between central Sikhote-Alin and Northeast Japan; reduced-type and oxidized-type, respectively. The different styles may reflect different tectonic environments; compressional and extensional, respectively. These two areas, which were closer together before the opening of the Japan Sea in the Miocene, may have been juxtaposed under a transpressional tectonic regime after the magmatism. 相似文献
The Lermontovskoe deposit, the oldest mineralization so far known in the Sikhote-Alin orogen, formed in the initial stage of Early Cretaceous felsic magmatism. The magmatism began shortly after the accretionary tectonics ceased, suggesting an abrupt change of subduction system. Style of the Early Cretaceous magmatism and mineralization is significantly different between central Sikhote-Alin and Northeast Japan; reduced-type and oxidized-type, respectively. The different styles may reflect different tectonic environments; compressional and extensional, respectively. These two areas, which were closer together before the opening of the Japan Sea in the Miocene, may have been juxtaposed under a transpressional tectonic regime after the magmatism. 相似文献
86.
A reassessment of models for hydrocarbon generation in the Khibiny nepheline syenite complex, Kola Peninsula, Russia 总被引:2,自引:0,他引:2
Although hydrocarbon-bearing fluids have been known from the alkaline igneous rocks of the Khibiny intrusion for many years, their origin remains enigmatic. A recently proposed model of post-magmatic hydrocarbon (HC) generation through Fischer-Tropsch (FT) type reactions suggests the hydration of Fe-bearing phases and release of H2 which reacts with magmatically derived CO2 to form CH4 and higher HCs. However, new petrographic, microthermometric, laser Raman, bulk gas and isotope data are presented and discussed in the context of previously published work in order to reassess models of HC generation. The gas phase is dominated by CH4 with only minor proportions of higher hydrocarbons. No remnants of the proposed primary CO2-rich fluid are found in the complex. The majority of the fluid inclusions are of secondary nature and trapped in healed microfractures. This indicates a high fluid flux after magma crystallisation. Entrapment conditions for fluid inclusions are 450–550 °C at 2.8–4.5 kbar. These temperatures are too high for hydrocarbon gas generation through the FT reaction. Chemical analyses of rims of Fe-rich phases suggest that they are not the result of alteration but instead represent changes in magma composition during crystallisation. Furthermore, there is no clear relationship between the presence of Fe-rich minerals and the abundance of fluid inclusion planes (FIPs) as reported elsewhere. δ13C values for methane range from − 22.4‰ to − 5.4‰, confirming a largely abiogenic origin for the gas. The presence of primary CH4-dominated fluid inclusions and melt inclusions, which contain a methane-rich gas phase, indicates a magmatic origin of the HCs. An increase in methane content, together with a decrease in δ13C isotope values towards the intrusion margin suggests that magmatically derived abiogenic hydrocarbons may have mixed with biogenic hydrocarbons derived from the surrounding country rocks. 相似文献
87.
Application of the QUILF thermobarometer to the peralkaline trachytes and pantellerites of the Eburru volcanic complex, East African Rift, Kenya 总被引:1,自引:0,他引:1
Minghua Ren Peter A. Omenda Elizabeth Y. Anthony John C. White Ray Macdonald D.K. Bailey 《Lithos》2006,91(1-4):109-124
The Quaternary Eburru volcanic complex in the south-central Kenya Rift consists of pantelleritic trachytes and pantellerites. The phenocryst assemblage in the trachytes is sanidine + fayalite + ferrohedenbergite + aenigmatite ± quartz ± ilmenite ± magnetite ± pyrrhotite ± pyrite. In the pantellerites, the assemblage is sanidine + quartz + ferrohedenbergite + fayalite + aenigmatite + ferrorichterite + pyrrhotite ± apatite, although fayalite, ferrohedenbergite and ilmenite are absent from more evolved rocks (e.g. with SiO2 > 71%). QUILF temperature calculations for the trachytes range from 709 to 793 °C and for the pantellerites 668–708 °C, the latter temperatures being among the lowest recorded for peralkaline silicic magmas. The QUILF thermobarometer demonstrates that the Eburru magmas crystallized at relatively low oxidation states (ΔFMQ + 0.5 to − 1.6) for both trachytes and pantellerites. The trachytes and pantellerites evolved along separate liquid lines of descent, the trachytes possibly deriving from a more mafic parent by fractional crystallization and the pantellerites from extreme fractionation of comenditic magmas. 相似文献
88.
Pirouz Mojtahed-Zadeh 《GeoJournal》2006,66(4):273-283
Erratum to: GeoJournal 62: 51–58 DOI 10.1007/s10708-005-8562-2 The erroneous version of this article was originally published in GeoJournal 62: 51–58. This amended version corrects the formatting errors which are evident in the original version.Abstract It is universally accepted that the need for defining precise lines of separation and points of contacts between states is the byproduct of the emergence of nation-states and ‘world economy’ in the nineteenth century Europe. Nevertheless, it is hard to overlook the fact that these modern notions are rooted in periods prior to the emergence in Europe of nation-states. There are indications that ancient civilizations were familiar with the notion of ‘state’ in connection with the concepts of territory and boundary. Ancient texts reveal that this basic principle existed in ancient Persian literature in respect of matters of state, territory, and boundary. Similarly, the likelihood exists that these Persian notions could have influenced Roman civilization. It is widely believed that a combination of ancient Greco-Roman and Persian civilizations is a major contributor to what culturally constitutes ‘West’. Later in the Sassanid period the inter-linked notions of state, territory, and boundary developed substantially, coming quite close to their contemporary forms. On the other hand, considering that ‘justice’ was the corner stone of ancient Persian Political philosophy, the idea that ancient␣Iranian spatial arrangement might have contributed to the evolution of the concept of democracy in the West may not be too difficult to contemplate.The online version of the original article can be found at 相似文献
89.
This article discusses the involvement of older women and men in voluntary work in rural communities in the Netherlands. Gender,
ageing and civil society form the core concepts in the article. Politicians and policy makers in the Netherlands are worried
about the perceived decline of civil society and about the consequences of this decline for specific categories of older women
in terms of well-being and social exclusion. The paper presents the results of two surveys of involvement of older women and
men in civic organisations, voluntary work and local actions. The surveys indicate high levels of involvement of both women
and men. No gender differences are found in activity level. However, the data demonstrate the gendered nature of civil society.
Women are more engaged in informal voluntary work and informal local actions, while men are more active in formal organisations
and functions. This gender segmentation is not absolute, however. Many older women and men transgress the traditional feminine–masculine
boundaries. The surveys highlight the involvement of women and men in rural communities, but indicate lower activity levels
in urban areas. 相似文献
90.
Dissolved trace elements in river water: spatial distribution and the influencing factor, a study for the Pearl River Delta Economic Zone, China 总被引:1,自引:0,他引:1
T. P. Ouyang Z. Y. Zhu Y. Q. Kuang N. S. Huang J. J. Tan G. Z. Guo L. S. Gu B. Sun 《Environmental Geology》2006,49(5):733-742
Twenty-nine water samples were collected from different river channels of the Pearl River Delta Economic Zone, China. An inductively
coupled plasma-mass spectromonitor (ICP-MS) was used to measure concentrations of the trace elements in these samples. The
results suggest that the average concentrations of rare earth elements in river water show an increasing trend from the West
River, the North River, the rivers of the Pearl River Delta, and the Shenzhen River to the East River. Relatively high concentrations
of heavy metals appear in the East River, the rivers of the Pearl River Delta and the Shenzhen River, while the West River
and the North River have relatively low heavy metal concentrations. Trace element concentrations in samples collected near
urban or industrial areas are much higher than those of samples collected from distant areas, away from urban and industrial
areas. After natural conditions, human activities have significant influence on the trace element concentrations in river
water. This trace element concentration’s spatial distribution in the river water from the Pearl River Delta Economic Zone
is actually an integrated effect of natural conditions and human activity. 相似文献